CN102531380A - Gold-free golden-red agent and preparation method thereof - Google Patents
Gold-free golden-red agent and preparation method thereof Download PDFInfo
- Publication number
- CN102531380A CN102531380A CN2011104537017A CN201110453701A CN102531380A CN 102531380 A CN102531380 A CN 102531380A CN 2011104537017 A CN2011104537017 A CN 2011104537017A CN 201110453701 A CN201110453701 A CN 201110453701A CN 102531380 A CN102531380 A CN 102531380A
- Authority
- CN
- China
- Prior art keywords
- gold
- oxide
- red toner
- golden
- golden red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Developing Agents For Electrophotography (AREA)
Abstract
The invention relates to a gold-free golden-red agent and a preparation method thereof. The gold-free golden-red agent is used for replacing the existing pigment using gold, novel technology and new formula are adopted, and the new formula includes producing the gold-free golden-red agent according to right proportion of zirconium fluoride, silicon oxide, silver carbonate, rubidium oxide, neodymium oxide, yttrium oxide and kaolin. Color and physicochemical indexes of produced products are the same as gold-containing products, price of the products is remarkably reduced, the products are nonhazardous and pollution-free, and the gold-free golden-free agent is beneficial for environment protection and physical and mental health of people and has good economic benefit and social benefit.
Description
Technical field
The present invention relates to pottery and glass and use the pigment technology field, relate in particular to a kind of no golden red toner and preparation method thereof.
Background technology
Continuous development along with pottery and glass industry; To have broken away from kind single with glassy product for pottery, and pattern dullness and formed comparatively complete product system is in pottery or glassy product production process; Use different pigment can produce colourful product; Pigment is to be used for the ceramic marble paper printing, flat stamping wire mark pigment, and the starting material that adopted during pigment ratio directly influence its cost.
The general gold that adopts is made violet pigment in pottery and glass material at present, and well-known, gold is one of metal rare, the most most precious in the metal; Because a large amount of uses of gold; Its natural storage capacity is very deficient, and it is also very expensive to use gold to do its cost of raw material, how to reduce cost; Substituting the problem that prior art adopts gold to make violet pigment in pottery and glass material, is the problem that the present invention need solve.
There is defective in prior art, haves much room for improvement.
Summary of the invention
The objective of the invention is, the problem that exists to prior art provides a kind of no golden red toner and preparation method thereof, has solved prior art and has used gold to make the high problem of the existing cost of violet pigment.
Technical scheme of the present invention is following: a kind of no golden red toner is characterized in that: said golden red toner component raw material weight per distribution ratio is:
Wherein: said golden red toner component raw material weight per distribution ratio is: Zirconium tetrafluoride 52%, silicon oxide 25%, silver carbonate 9%, rubidium oxide 2%, Neodymium trioxide 1%, yttrium oxide 1% and kaolin 10%.
A kind of preparation method who does not have the golden red toner is characterized in that: said method comprises the steps:
A, batching, said batching are pressed column weight amount per-cent and are prepared:
B, with mixing behind the said batching crushing screening, get 100 parts of said batchings and place ball mill to add water to process slip for 60 parts, ball milling to 250 order, screenings is less than 0.1%;
C, with the slip behind ball milling oven dry and beat more than powder to 100 order, place gas fired kiln under 1250~1350 ℃ of high temperature weakly reducing atmospheres or place the electric furnace temperature to be controlled under 1250~1350 ℃ of neutral atmospheres to burn till, soaking time is 4.5~5.5 hours.
Beneficial effect of the present invention is: after the present invention adopts technique scheme; There not to be the pigment that the golden red toner substitutes existing employing gold,, make product quality and physical and chemical index identical with the product that contains golden pigment owing to adopted new prescription novel process; Reduced product price significantly; And toxicological harmless is pollution-free, and environment protection and people's physical and mental health has all been brought very big benefit, has good economic benefit and social benefit.
Embodiment
The invention provides a kind of no golden red toner and preparation method thereof; Through adopting new prescription; Utilize the correct proportioning of raw materials such as Zirconium tetrafluoride, silicon oxide and silver to make batching be purple; And do not contain the golden red toner of gold component through the preparation of rational production technique, solve prior art and used gold to make the high problem of the existing cost of violet pigment.
For making the object of the invention, technical scheme and advantage clearer, clear and definite, below lift embodiment to further explain of the present invention.
Table 1
It is following that the present invention does not have golden red toner preparation method:
According to the prescription of table 1, component raw material is prepared burden by weight percentage in the table 1, and said raw material is carried out weighing, mixes behind the crushing screening;
(1) batching in the table 1 is placed ball mill by 100 parts of weight and adds water process slip for 60 parts, ball milling to 250 order, screenings is less than 0.1%;
(2) slip behind the ball milling is dried and beaten more than powder to 100 order; Place gas fired kiln under 1250~1350 ℃ of high temperature weakly reducing atmospheres, to burn till; Optimum temps is controlled at 1300 ℃ or place the electric furnace temperature to be controlled under 1250~1350 ℃ of neutral atmospheres to burn till; Optimum temps is controlled at 1280 ℃, and soaking time is 4.5~5.5 hours, and best soaking time is 5 hours.
What should explain is; Above embodiment is only unrestricted in order to technical scheme of the present invention to be described; Although with reference to preferred embodiment the present invention is specified, those of ordinary skill in the art should be appreciated that and can make amendment or be equal to replacement technical scheme of the present invention; And not breaking away from the spirit and the scope of technical scheme of the present invention, it all should be encompassed in the middle of the claim scope of the present invention.
Claims (3)
1. no golden red toner, it is characterized in that: said golden red toner component raw material weight per distribution ratio is:
Zirconium tetrafluoride 45%~60%
Silicon oxide 15%~30%
Silver carbonate 5%~10%
Rubidium oxide 0.4%~2%
Neodymium trioxide 0.2%~1%
Yttrium oxide 0.3%~3%
Kaolin 10%~20%.
2. according to the described no golden red toner of claim 1, it is characterized in that: said golden red toner component raw material weight per distribution ratio is: Zirconium tetrafluoride 52%, silicon oxide 25%, silver carbonate 9%, rubidium oxide 2%, Neodymium trioxide 1%, yttrium oxide 1% and kaolin 10%.
3. preparation method who does not have the golden red toner, it is characterized in that: said method comprises the steps:
A. prepare burden, said batching is pressed column weight amount per-cent and is prepared:
Zirconium tetrafluoride 45%~60%
Silicon oxide 15%~30%
Silver carbonate 5%~10%
Rubidium oxide 0.4%~2%
Neodymium trioxide 0.3%~1%
Yttrium oxide 0.2%~3%
Kaolin 10%~20%
B. with mixing behind the said batching crushing screening, get 100 parts of said batchings and place ball mill to add water to process slip for 60 parts, ball milling to 250 order, screenings is less than 0.1%;
C. with the slip behind ball milling oven dry and beat more than powder to 100 order, place gas fired kiln under 1250~1350 ℃ of high temperature weakly reducing atmospheres or place the electric furnace temperature to be controlled under 1250~1350 ℃ of neutral atmospheres to burn till, soaking time is 4.5~5.5 hours.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110453701 CN102531380B (en) | 2011-12-30 | 2011-12-30 | Gold-free golden-red agent and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110453701 CN102531380B (en) | 2011-12-30 | 2011-12-30 | Gold-free golden-red agent and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102531380A true CN102531380A (en) | 2012-07-04 |
CN102531380B CN102531380B (en) | 2013-10-09 |
Family
ID=46339583
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 201110453701 Active CN102531380B (en) | 2011-12-30 | 2011-12-30 | Gold-free golden-red agent and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102531380B (en) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5019808A (en) * | 1973-05-11 | 1975-03-03 | ||
CN1112590A (en) * | 1994-03-30 | 1995-11-29 | 凯尔迪克陶瓷颜料股份公司 | Process for the production of purple pigments |
US6074754A (en) * | 1996-11-14 | 2000-06-13 | Degussa Aktiengesellschaft | Spherical pigments, process for producing them and use thereof |
CN101643367A (en) * | 2009-08-21 | 2010-02-10 | 山东省硅酸盐研究设计院 | Environmental-friendly orange red ceramic pigment colorant and preparing method thereof |
CN101696123A (en) * | 2009-10-26 | 2010-04-21 | 景德镇陶瓷学院 | Pollution-free low temperature bronze red pastel pigment and preparation method thereof |
CN102060570A (en) * | 2010-12-28 | 2011-05-18 | 醴陵市彩虹颜料有限公司 | High-temperature underglaze gold ruby pigment and preparation method thereof |
-
2011
- 2011-12-30 CN CN 201110453701 patent/CN102531380B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5019808A (en) * | 1973-05-11 | 1975-03-03 | ||
CN1112590A (en) * | 1994-03-30 | 1995-11-29 | 凯尔迪克陶瓷颜料股份公司 | Process for the production of purple pigments |
US5707436A (en) * | 1994-03-30 | 1998-01-13 | Cerdec Aktiengesellschaft Keramische Farben | Process for the production of purple pigments |
US6074754A (en) * | 1996-11-14 | 2000-06-13 | Degussa Aktiengesellschaft | Spherical pigments, process for producing them and use thereof |
CN101643367A (en) * | 2009-08-21 | 2010-02-10 | 山东省硅酸盐研究设计院 | Environmental-friendly orange red ceramic pigment colorant and preparing method thereof |
CN101696123A (en) * | 2009-10-26 | 2010-04-21 | 景德镇陶瓷学院 | Pollution-free low temperature bronze red pastel pigment and preparation method thereof |
CN102060570A (en) * | 2010-12-28 | 2011-05-18 | 醴陵市彩虹颜料有限公司 | High-temperature underglaze gold ruby pigment and preparation method thereof |
Non-Patent Citations (7)
Title |
---|
丁姬: "《各种因素对釉上金红颜料呈色的影响》", 《中国陶瓷》 * |
余荣台等: "《金红颜料色剂紫金泥的测试与分析》", 《中国陶瓷》 * |
刘西德等: "《一种新型金色颜料的研制》", 《化学世界》 * |
张新华等: "《影响金红颜料呈色的几种因素》", 《山东陶瓷》 * |
曹春娥等: "《无铅、无砷粉彩颜料玻璃白研究》", 《中国陶瓷》 * |
曹春娥等: "《无铅、砷金红粉彩颜料的呈色机理》", 《硅酸盐学报》 * |
邵明梁等: "《红色陶瓷颜料琐议》", 《陶瓷工程》 * |
Also Published As
Publication number | Publication date |
---|---|
CN102531380B (en) | 2013-10-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105330158B (en) | A kind of glaze of dark ceramics and preparation method thereof | |
CN103896634B (en) | High-temperature domestic porcelain metallic bright glaze and product decorated by same | |
CN104016667B (en) | A kind of preparation method of middle temperature magnesium-intensified ceramic and the product making thereof | |
CN106430959B (en) | A kind of tea-dust glaze and preparation method thereof | |
CN101481261A (en) | Titanium, zinc and pyroxene crystal glaze and preparing method thereof | |
CN103482967B (en) | Processing craft of new bone china blank and glaze | |
CN107098588B (en) | A kind of transparent glass-ceramics glaze and its preparation method and application | |
CN105622076B (en) | Shellfish ice crystals porcelain billet body pug and its manufacture craft | |
CN104692833A (en) | High-hardness wollastonite glaze slip and preparation method thereof | |
CN106007381A (en) | Single-layer fambe pigmented glaze and preparation method thereof | |
CN113402265A (en) | White-bottom black-flower enamel and preparation method thereof | |
CN105777060A (en) | Cinnabar-body celadon body material, cinnabar-body celadon ware and preparation methods thereof | |
CN114735999A (en) | Super-white light-transmitting jade ceramic tile and processing method thereof | |
CN106007663B (en) | Without glaze high density illuminate crystalline substance porcelain and preparation method thereof | |
CN106316127B (en) | Medium-temperature golden plum crystal glaze and preparation method thereof | |
CN108046751A (en) | A kind of ceramic material and its ceramic | |
CN107619268B (en) | Porcelain formula and production process | |
CN107129268A (en) | Dehua green onion root ceramic whiteware device and its preparation technology | |
CN109748506A (en) | Metallic crystal glaze, ceramic tile and preparation method thereof | |
CN102503564A (en) | Isostatic pressing glaze for electroceramics and preparation method thereof | |
CN108752017B (en) | Fused zirconia corundum brick and preparation method thereof | |
CN108821590A (en) | The unleaded metal glaze of Gold production and its preparation process | |
CN102531380B (en) | Gold-free golden-red agent and preparation method thereof | |
CN107417104A (en) | A kind of pottery moon white glaze and preparation method thereof | |
CN110482863B (en) | White opaque glaze, white opaque glaze ceramic product and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP01 | Change in the name or title of a patent holder |
Address after: Yixing dingshuzhen West Village 214221 Jiangsu city of Wuxi Province Patentee after: Jiangsu Beifu Technology Co., Ltd Address before: Yixing dingshuzhen West Village 214221 Jiangsu city of Wuxi Province Patentee before: Jiangsu Baifu Technology Co., Ltd. |
|
CP01 | Change in the name or title of a patent holder |