CN102524316B - Chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees and preparation method thereof - Google Patents
Chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees and preparation method thereof Download PDFInfo
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- CN102524316B CN102524316B CN 201110390780 CN201110390780A CN102524316B CN 102524316 B CN102524316 B CN 102524316B CN 201110390780 CN201110390780 CN 201110390780 CN 201110390780 A CN201110390780 A CN 201110390780A CN 102524316 B CN102524316 B CN 102524316B
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Abstract
The invention discloses a chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees and a preparation method thereof. The spraying agent contains active ingredients, an additive and a propellant. The active ingredients comprise chitosan, tea-tree essential oil, polyvinyl alcohol, a plant growth regulator and glacial acetic acid. The spraying agent can form a layer of cold-proof antibacterial protective film on cutting surfaces of rubber trees, and not only enables the cutting surfaces of the rubber trees to avoid freezing injury and live through the wintersafely and protects the cutting surfaces from bark cracking and gummosis, but also is capable of protecting the cutting surfaces of the rubber trees from infection of pest and disease damages of strip canker, bark beetle and the like. The spraying agent is mild in preparation conditions and simple in preparation process, industrialized production of the chitosan-based anti-freezing antibacterial spraying agent is easy, and the chitosan-based anti-freezing antibacterial spraying agent is convenient to carry and simple to operate.
Description
[technical field]
The present invention relates to a kind of agricultural spray, be specifically related to a kind of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees and preparation method thereof.
[background technology]
The glue district is planted by China often has microthermal climate winter, causes tapped part of rubber tree to suffer cold damage and disease occurs, and directly affects the output in next year, especially particularly serious for the poor kind of some cold tolerances or temperature is lower in the winter time local freeze injury.Pass the winter safely in order to ensure tapped part of rubber tree, producing vegetable oil prescription commonly used at present, the indigenous method that industrial vaseline and yellow mud are mixed cow dung seals coat with rubber tree face as coating agent, yet these methods are all owing to existence is in various degree used inconvenient, cost is high, has harmful effect or winter protection effect undesirable etc. former thereby be very limited in actual applications to bark; Chinese patent CN92111143.6 also discloses a kind of protecting agent for tapped part of rubber tree, the gluey medicament that is formed by polyvinyl alcohol, efosite, zinc sulphate, ammonium molybdate, growth regulator and additive mixed preparing, employing is coated with the envelope mode and is applied on the face, its raw material is more, use inconvenient, cost is higher, and curative effect is low, need to repeatedly be coated with envelope; Chinese patent CN01106038.7 also discloses the agent of a kind of tapped part of rubber tree anti-frost protection, and by the emulsion that Wax, emulsifier, plant growth regulator, water are made, its raw material type is also more, and production cost is high; Chinese patent CN200610048880.5 also discloses a kind of rubber tree tapping face coldness-proof coating agent and production method thereof, formed by the rubber seed oil of 35-50% and the vaseline of 50-65%, although this coating agent cost is lower, but still be to adopt to be coated with the envelope mode and to put on face, antifreezing effect is undesirable, uses inconvenience, and efficiency is low, and coating agent acts on single without antibiotic effect.Open the processing of cutting tree for being injured, land reclamation and cultivation is planted Jiao Qu and is taked to clip dried-up, or face adopts medical ventolin and pitch mixture to be coated with envelope, as bark beetle eaten into into, then spray 1% malathion or 1% dichlorvos.Not only antifreezing effect is poor for these traditional Winter protection methods, need repeatedly repeat soil and smear coating agent, and function is single, uses the construction trouble, and efficiency is lower, is difficult to reach large-area promoting the use of.
This shows, all there is defective in various degree in the antifreeze coating agent of tapped part of rubber tree that uses at present.
Therefore, also need at present to provide a kind of anti-freezing antibacterial, preparation technology simple, be easy to large-scale production, tapped part of rubber tree anti-frost protection agent easy to use.
[summary of the invention]
The object of the present invention is to provide a kind of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees; Another order of the present invention is to provide a kind of preparation method of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees.
A kind of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees of the present invention, contain following component by weight:
Active component 10-50 part;
Additive 1-20 part;
Propellant 20-80 part.
A kind of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees of the present invention, as active component, contain following component by weight:
Further, a kind of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees of the present invention, contain following component by weight:
Active component 20-40 part;
Additive 2-10 part;
Propellant 50-80 part.
A kind of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees of the present invention, as active component, contain following component by weight:
A kind of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees of the present invention, preferably:
Active component 25-35 part;
Additive 2-5 part;
Propellant 60-80 part.
Most preferredly be:
32 parts of active components;
3 parts of additives;
65 parts of propellants.
A kind of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees of the present invention, as active component, preferably:
Most preferredly be:
A kind of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees of the present invention, as additive, preferably a kind of in methyl hydroxyethylcellulose, ethylhydroxyethylcellulose, methylhydroxypropylcellulose, the sodium carboxymethylcellulose, most preferably methyl hydroxyethylcellulose; As propellant, preferably a kind of among F-11, difluoromethane, three chloro-tetrafluoroethanes, most preferably F-11; As plant growth regulator, preferably a kind of in heteroauxin, indolebutyric acid, the methyl α-naphthyl acetate, most preferably indolebutyric acid.
Weight portion of the present invention can be the known unit of weights such as g, kg.
The preparation method of a kind of chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees of the present invention may further comprise the steps:
A) grinding of shitosan powder is sieved, at room temperature be dissolved in the glacial acetic acid solution, the chitosan solution that obtains is carried out suction filtration, discard insoluble matter, the filtrate of acquisition is for subsequent use;
B) in the filtrate that a) obtains, add tea tree ethereal oil, polyvinyl alcohol, plant growth regulator, make active component, for subsequent use;
C) at b) add additive in the active component that makes, mixing, the container of packing into adds propellant under 60-110kPa pressure, make chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees.
Key point of the present invention
Key problem in technology point of the present invention is:
1, employing has natural bactericidal performance and the good characteristics such as good biocompatibility, biological degradation, and has a broad antifungal spectrum is widely used in the abundant shitosans in field and source such as medicine, biotechnology, food.The spacial framework that is cross-linked to form between the molecule of shitosan, easy film forming, this film tensile strength is large, good toughness, alkaline-resisting and organic solvent-resistant, its antibiotic film forming spray is sprayed at skin, mucous membrane affected part and injured surface, can be with brand-new physics and biological antibiotic mechanism, can isolate, pathogenic microbe killing (comprising bacterium, fungi and virus etc.), can promote tissue repair and regeneration simultaneously.
2, for the tapped part of rubber tree Phytophthora spp, to be caused by the multiple phytophthora of phytophthora, wherein take phytophthora brown rot of citrus (Phytophthora citrophthora) as Main Pathogenic Bacteria, employing has the effects such as bactericidal antiphlogistic, be widely used in the products such as soap, face cream, milky lotion, deodorant, disinfectant, air freshener, the tea tree extract with good clean-up effect is tea tree ethereal oil one by one.At this, it is worth mentioning that, for more rare in the prevention that tea tree ethereal oil is applied to plant disease and the treatment.
3, except employing has the shitosan and tea tree ethereal oil of bactericidal effect; the present invention has also adopted polyvinyl alcohol and the plant growth regulator with winter protection and trophism; adding simultaneously propellant and additive is auxiliary material; replace tradition to be coated with the envelope form of construction work with the spraying form of construction work; greatly raise labour efficiency; reduce production costs; can form one deck winter protection antibacterial protecting film at tapped part of rubber tree; can protect tapped part of rubber tree to pass the winter safely, can prevent that again tapped part of rubber tree from infecting the damage by disease and insect such as strip canker and bark beetle.
Technique effect of the present invention
Chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees of the present invention, owing to being based on the stronger bactericidal effect of the good filming function of shitosan, bacteriostasis and tea tree ethereal oil, the winter protection of polyvinyl alcohol and growth regulator and trophism, adding simultaneously propellant and additive is auxiliary material, solved present tapped part of rubber tree antifreezing agent antifreezing effect poor, act on the problems such as single, use construction trouble.Compared with prior art, have following distinguishing feature:
1, anti-freezing antibacterial is effective, and preparation technology is simple, is easy to industrialization production, and is easy to carry, operates simple and easy;
2, replace tradition to be coated with the envelope form of construction work with the spraying form of construction work; greatly raise labour efficiency; reduce production costs; and use this spray; can form one deck winter protection antibacterial protecting film at tapped part of rubber tree, can protect tapped part of rubber tree to pass the winter safely, can prevent that again tapped part of rubber tree from infecting the damage by disease and insect such as strip canker and bark beetle; the bark healing regeneration rate that improves face reaches 15-30%, and next year, Rubber Yield can improve 10-20%.
[embodiment]
Should be understood that following embodiment only to be used for explanation the present invention and be not used in and limit the scope of the invention.Except as otherwise noted, the umber that hereinafter adopts is weight portion.
Embodiment 1
This spray component by weight is as follows:
20 parts of active components;
2 parts of additive methyl hydroxyethylcelluloses;
78 parts of propellant F-11s.
Wherein, the shitosan in the active component, tea tree ethereal oil, polyvinyl alcohol, plant growth regulator and mass fraction are that the umber of the glacial acetic acid of 1-3% is:
Take by weighing 2 parts of tea tree ethereal oils, 3 parts of polyvinyl alcohol, 1 part of plant growth regulator heteroauxin, 15 parts of shitosans are ground to join 79 parts of mass fractions after sieving be in the glacial acetic acid of 1-3%, continuous stirring and dissolving under the room temperature, suction filtration and discard insoluble matter until completely dissolved, slowly add 2 parts of tea tree ethereal oils in the chitosan solution, then add 3 parts of polyvinyl alcohol, 1 part of plant growth regulator heteroauxin, make 20 parts of active components; Add 2 parts of additive methyl hydroxyethylcelluloses according to the weight proportion of active component and mix, the container of packing into adds 78 parts propellant F-11 under 60-110kPa pressure, make chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees.
Embodiment 2
This spray component by weight is as follows:
40 parts of active components;
10 parts of additive methyl hydroxyethylcelluloses;
50 parts of propellant difluoromethane.
Wherein, the shitosan in the active component, tea tree ethereal oil, polyvinyl alcohol, plant growth regulator and mass fraction are that the umber of the glacial acetic acid of 1-3% is:
Take by weighing 5 parts of tea tree ethereal oils, 10 parts of polyvinyl alcohol, 3 parts of plant growth regulator indolebutyric acids, 5 parts of shitosans are ground to join 77 parts of mass fractions after sieving be in the glacial acetic acid of 1-3%, continuous stirring and dissolving under the room temperature, suction filtration and discard insoluble matter until completely dissolved, slowly add 5 parts of tea tree ethereal oils in the chitosan solution, then add 10 parts of polyvinyl alcohol, 3 parts of plant growth regulator indolebutyric acids, make 40 parts of active components; Add 10 parts of additive methyl hydroxyethylcelluloses according to the weight proportion of active component and mix, the container of packing into adds 50 parts propellant difluoromethane under 60-110kPa pressure, make chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees.
Embodiment 3
This spray component by weight is as follows:
Active component: 35 parts;
5 parts of additive sodium carboxymethylcelluloses;
60 parts of propellant F-11s;
Wherein, the shitosan in the active component, tea tree ethereal oil, polyvinyl alcohol, plant growth regulator and mass fraction are that the umber of the glacial acetic acid of 1-3% is:
Take by weighing 4 parts of tea tree ethereal oils, 4 parts of polyvinyl alcohol, 2 parts of plant growth regulator indolebutyric acids, 10 parts of shitosans are ground to join 80 parts of mass fractions after sieving be in the glacial acetic acid of 1-3%, continuous stirring and dissolving under the room temperature, suction filtration and discard insoluble matter until completely dissolved, slowly add 4 parts of tea tree ethereal oils in the chitosan solution, then add 4 parts of polyvinyl alcohol, 2 parts of plant growth regulator indolebutyric acids, make 35 parts of active components; Add 5 parts of additive sodium carboxymethylcelluloses according to the weight proportion of active component and mix, the container of packing into adds 60 parts propellant F-11 under 60-110kPa pressure, make chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees.
Embodiment 4
This spray component by weight is as follows:
32 parts of active components;
3 parts of additive methyl hydroxyethylcelluloses;
65 parts of propellant F-11s.
Wherein, the shitosan in the active component, tea tree ethereal oil, polyvinyl alcohol, plant growth regulator and mass fraction are that the umber of the glacial acetic acid of 1-3% is:
Take by weighing 3 parts of tea tree ethereal oils, 5 parts of polyvinyl alcohol, 2 parts of plant growth regulator indolebutyric acids, 12 parts of shitosans are ground to join 78 parts of mass fractions after sieving be in the glacial acetic acid of 1-3%, continuous stirring and dissolving under the room temperature, suction filtration and discard insoluble matter until completely dissolved, slowly add 3 parts of tea tree ethereal oils in the chitosan solution, then add 5 parts of polyvinyl alcohol, 2 parts of plant growth regulator indolebutyric acids, make 32 parts of active components; Add 3 parts of additive methyl hydroxyethylcelluloses according to the weight proportion of active component and mix, the container of packing into adds 65 parts propellant F-11 under 60-110kPa pressure, make chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees.
Claims (5)
1. chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees is characterized in that this spray contains following component by weight:
Active component 10-50 part;
Additive 1-20 part;
Propellant 20-80 part;
Described active component contains following component by institute's weight portion:
Shitosan 1-20 part;
Tea tree ethereal oil 1-5 part;
Polyvinyl alcohol 1-10 part;
Plant growth regulator 1-5 part;
Mass fraction is glacial acetic acid 50-100 part of 1-3%.
2. tapped part of rubber tree anti-freezing antibacterial spray according to claim 1 is characterized in that described additive is a kind of in methyl hydroxyethylcellulose, ethylhydroxyethylcellulose, methylhydroxypropylcellulose or the sodium carboxymethylcellulose.
3. tapped part of rubber tree anti-freezing antibacterial spray according to claim 1 is characterized in that described propellant is a kind of among F-11, difluoromethane or three chloro-tetrafluoroethanes.
4. tapped part of rubber tree anti-freezing antibacterial spray according to claim 2 is characterized in that described plant growth regulator is a kind of in heteroauxin, indolebutyric acid or the methyl α-naphthyl acetate.
5. the preparation method of tapped part of rubber tree anti-freezing antibacterial spray according to claim 1 and 2 is characterized in that may further comprise the steps:
A) grinding of shitosan powder is sieved, at room temperature be dissolved in the glacial acetic acid solution, the chitosan solution that obtains is carried out suction filtration, discard insoluble matter, the filtrate of acquisition is for subsequent use;
B) in the filtrate that a) obtains, add tea tree ethereal oil, polyvinyl alcohol, plant growth regulator, make active component, for subsequent use;
C) at b) add the additive mixing in the active component that makes, the container of packing into adds propellant under 60-110kPa pressure, make chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110390780 CN102524316B (en) | 2011-11-25 | 2011-11-25 | Chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110390780 CN102524316B (en) | 2011-11-25 | 2011-11-25 | Chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102524316A CN102524316A (en) | 2012-07-04 |
| CN102524316B true CN102524316B (en) | 2013-09-18 |
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| CN 201110390780 Expired - Fee Related CN102524316B (en) | 2011-11-25 | 2011-11-25 | Chitosan-based anti-freezing antibacterial spraying agent for cutting surfaces of rubber trees and preparation method thereof |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103749537B (en) * | 2012-12-26 | 2015-04-15 | 辽宁省杨树研究所 | Anti-freezing and disease-prevention film agent for trees, and preparation method and application thereof |
| CN103553772B (en) * | 2013-10-23 | 2015-03-18 | 陈赫 | Compound preparation for nursing tapping panel dryness and strip ulcer of rubber trees, as well as preparation method and application thereof |
| CN104430546B (en) * | 2014-12-09 | 2017-04-19 | 陈干忠 | High-yield disease-resistant and mothproof composite preparation for rubber trees as well as preparation method and application thereof |
| CN104472285B (en) * | 2015-01-13 | 2016-12-07 | 薛金国 | Prevent preparation and the method for plant frozen injury |
| CN106665575A (en) * | 2016-12-15 | 2017-05-17 | 新昌县奥而特农业科技有限公司 | Anti-freezing anti-microbial spray for cut section of rubber tree and preparation method thereof |
| CN106900728B (en) * | 2017-02-22 | 2019-02-22 | 中国热带农业科学院橡胶研究所 | A kind of rubber tree cold-resistance agent and its application |
| CN109984134B (en) * | 2017-12-31 | 2021-06-25 | 海南正业中农高科股份有限公司 | Composition containing chitosan and potassium indolebutyrate and application thereof |
| CN111296505A (en) * | 2020-04-01 | 2020-06-19 | 佳木斯大学 | Slow-release pesticide preparation and preparation method and application thereof |
| CN116636533B (en) * | 2023-07-27 | 2023-10-20 | 海南大学三亚南繁研究院 | Method for improving cold resistance of rubber sapling |
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| JP2001114619A (en) * | 1999-10-14 | 2001-04-24 | St Louis International Inc | Essential oil for aromatherapy and method for using the same |
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| WO2010124131A1 (en) * | 2009-04-23 | 2010-10-28 | State Of Oregon Acting By And Through The State Board Of Higher Education On Behalf Of Oregaon State University | Flexible films and methods of making and using flexible films |
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| CN1080117A (en) * | 1992-09-29 | 1994-01-05 | 华南热带作物科学研究院橡胶栽培研究所 | Protecting agent for tapped part of rubber tree |
| JP2001114619A (en) * | 1999-10-14 | 2001-04-24 | St Louis International Inc | Essential oil for aromatherapy and method for using the same |
| CN1362015A (en) * | 2001-01-05 | 2002-08-07 | 中国石油化工股份有限公司 | Rubber tree cut antifreezing protector |
| CN101932245A (en) * | 2007-12-12 | 2010-12-29 | 纳米创新基金会 | Protective layer for plants and trees, the production thereof and use thereof |
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