CN102524267A - Pymetrozine suspension preparation containing vegetable oil and derivatives thereof and preparation method and application thereof - Google Patents
Pymetrozine suspension preparation containing vegetable oil and derivatives thereof and preparation method and application thereof Download PDFInfo
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- CN102524267A CN102524267A CN2010105930085A CN201010593008A CN102524267A CN 102524267 A CN102524267 A CN 102524267A CN 2010105930085 A CN2010105930085 A CN 2010105930085A CN 201010593008 A CN201010593008 A CN 201010593008A CN 102524267 A CN102524267 A CN 102524267A
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Abstract
The invention discloses a preparation method and application of a pymetrozine suspension preparation containing vegetable oil and derivatives thereof. The preparation comprises the following components by weight percent: 1-50% of pymetrozine, 1-40% of vegetable oil and derivatives thereof, 0.5-10% of wetting agent, 0.5-10% of dispersing agent, 2-15% of emulsifying agent, 0.05-5% of thickening agent, 0.05-5% of defoaming agent, 1-10% of antifreezing agent, 0.1-10% of preservative and the balance of water, wherein the total weight percent is 100%. The preparation method and application have the following beneficial effects: the original components are improved and the vegetable oil and derivatives thereof are added, and the preparation has the advantages of evaporation resistance, strong pesticide spreading and adhesion capabilities, strong permeability and the like, thus improving the bioactivity of the original preparation products and obviously improving the use effect of the preparation in the field; and the preparation can be used for preventing and controlling pests with piercing-sucking mouthparts on various crops.
Description
Technical field
The present invention relates to a kind of pesticidal preparations, relate to a kind of pymetrozine suspension agent that contains vegetable oil and derivative thereof specifically.
Background technology
Agricultural chemicals suspension agent is many to be dispersion medium with water, and the insoluble or former medicine of solid that is slightly soluble in water by the effect of surfactant and other auxiliary agent, evenly disperses the more stable liquid-solid phase system that form the tiny higher suspension of a kind of particle, can flow through grinding.Compare with missible oil, the advantage that avoids the use of a large amount of organic solvents is arranged; Compare with wettable powder, do not have the dust drift of dispersing in processing with when using, all lower to people and animals' toxicity and excitant, can alleviate poisoning to crop, more can in preserving transportation, not burn, safety is higher; The danger that user and entire environment are caused is quite low.Yet suspending agent is meant solid granule and is suspended in the water, dimension in use, soup spray cloth is on the plant leaf blade surface; Behind liquid evaporation; Medicament covers blade surface with the form of solid granule, when external environment changes, is easy to cause the loss of agricultural chemicals solid particle like strong wind, rainwater weather; Therefore the medicament availability is lower in use for this kind formulation, and field efficacy is also not ideal enough.
Pyrrole aphid ketone belongs to pyridines or Triazinone insecticide, is the brand-new non-insects agent of killing livestock, and is developed in 1988 by Switzerland Ciba-Geigy company the earliest, and this product shows excellent control efficiency to the sucking pest of various crop.
Utilize electricity to penetrate figure (EPG) technology research and show no matter be drop, feed or test injection, if aphid or
Plant hopper one touches pyrrole aphid ketone and almost produces the lancet blocking effect immediately, stops to get food at once, and final hungry causing death, and this process is irreversible.Therefore, pyrrole aphid ketone has excellent blocking-up insect and passes malicious function.Pyrrole aphid ketone has action of contace poison to insect, also has systemic activity simultaneously.Can also can be in plant corpus in the phloem transporting in the xylem transporting; Therefore both can be used as foliar spray, also can be used for soil treatment.Because its good transporting characteristic, the branches and leaves that after the cauline leaf spraying, newly grow also can be effectively protected.
Summary of the invention
The objective of the invention is to provides a kind of pymetrozine suspension agent that contains vegetable oil and derivative thereof to the technical problem that background technology proposes; And the preparation method and the application of this suspending agent be provided; It has solved the problem that the missible oil of wetting powder and low content works the mischief to people, livestock and environment, has solved the suspending agent drug effect again technically and has showed dissatisfactory problem.
The present invention has added vegetable oil and derivative thereof as oil phase component in suspending agent, have anti-evaporating, medicament is sprawled advantages such as adhesive ability is strong, permeability is strong, has therefore improved the biologically active of original formulation products, significantly improves preparation field result of use.
The objective of the invention is to realize through following technical scheme:
A kind of pymetrozine suspension preparation that contains vegetable oil and derivative thereof; Contain the former medicine of pyrrole aphid ketone, vegetable oil and derivative thereof, wetting agent, dispersant, emulsifier, thickener, antifoaming agent, antifreezing agent, preservative, wherein the weight ratio of each component is: the former medicine of pyrrole aphid ketone 1～50%, vegetable oil and derivative 1～40% thereof, wetting agent 0.5～10%, dispersant 0.5～10%, emulsifier 2～15%, thickener 0.05～5%, antifoaming agent 0.05～5%, antifreezing agent 1～10%, preservative 0.1～10%, surplus are water.
Wherein vegetable oil and derivative thereof can be selected one or several in corn oil, rapeseed oil, soybean oil, sunflower oil, peanut oil, turpentine oil, the vegetable oil that methylates, biodiesel, the methyl oleate for use.
Wetting agent is selected from one or several in aliphatic alcohol sulfate, alpha-alkene sulfonate, dialkyl group succinate sulfonate sodium, fatty alcohol, APES succinic acid half ester sulfonate, fatty acid amide N methyl taurine sodium salt, APES sulphate, alkyl phenol sulfonic sodium, the extraordinary polyether-modified polysiloxane of alkyl phenol, AEO, the alkylphenol-polyethenoxy base ether; Dispersant is selected from one or more in fatty alcohol ether sulfate, nonyl phenolic ether sulfuric ester, triphen ethyl-phenol APEO, sulfuric ester triethanolamine salt, MODIFIED LIGNOSULPHONATE, naphthalene sulfonic acid-formaldehyde condensation product, sodium lignin sulfonate, the alkyl naphthalene formaldehyde condensate sulfonates; Emulsifier is selected from one or more in sorbitan mono-oleic acid ester, sorbitan fatty acid ester APEO, fatty alcohol and ethylene oxide condensate, polyoxyethylene fatty acid ester, three ethanol list oleins, castor oil and the ethylene oxide condensate.
In wetting agent preferred fat alcohol sulfate, fatty acid amide N methyl taurine sodium salt, fatty alcohol, the APES succinic acid half ester sulfonate one or more; In dispersant preferred fat alcohol ether phosphate, nonyl phenol ether phosphate, the phosphate triethanolamine salt one or more; One or more of emulsifier preferred fat alcohol and ethylene oxide condensate, polyoxyethylene fatty acid ester, castor oil and ethylene oxide condensate.The suspending agent that adopts above-mentioned wetting agent, dispersant and emulsifier to form has the dispersed and mobile of height.
Thickener is selected from one or several in gum Arabic, xanthan gum, methylcellulose, CMC, hydroxyethylcellulose, PAA, polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl acetate, gaseous state silica, the aluminium-magnesium silicate; That antifoaming agent is selected from is silicone based, fatty alcohol, C10～12 representative examples of saturated aliphatic carboxylic and the ester class thereof of C8～10, in ester-ether type compound one or several; Antifreezing agent is selected from one or several in ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, polyethylene glycol, glycerine-ether diglycol, urea, ammonium sulfate, the citric acid; Preservative is selected from one or several in formaldehyde, paraformaldehyde, benzoic acid, the Sodium Benzoate.
The preparation method of the above-mentioned pymetrozine suspension preparation that contains vegetable oil and derivative thereof; Be with pyrrole aphid ketone, wetting agent, dispersant, thickener, antifoaming agent, antifreezing agent, preservative and water; According to the rules after the ratio weighing, using sand mill to carry out sand milling, to be crushed to the particle diameter fineness be 1～5 μ m, vegetable oil and derivative thereof with emulsifier in proportion after the weighing; Join behind the sand milling in the material, and with homogenizer shear, thickening, froth breaking be prepared from.
The application of the above-mentioned pymetrozine suspension preparation that contains vegetable oil and derivative thereof anti-eliminate aphis section, Delphacidae, Aleyrodidae, Cicadellidae insect on crop.Especially the application in control cotton aphid, water rice hopper, vegetables Bemisia tabaci.
Beneficial effect of the present invention:
Key of the present invention is in suspending agent, to have added vegetable oil and derivative thereof to substitute; Have anti-evaporating, medicament is sprawled advantages such as adhesive ability is strong, permeability is strong; Therefore improved the biologically active of original formulation products; Significantly improve preparation field result of use, said preparation is used for various crop control sucking pest.
Embodiment
Below in conjunction with embodiment the present invention is further described:
Embodiment 1:
To methylate soybean oil 10kg, castor oil mixes with ethylene oxide condensate 5kg that to join with the former medicine 25kg of pyrrole aphid ketone, aliphatic alcohol sulfate 2.5kg, alpha-alkene sulfonate 0.5kg, fatty alcohol ether sulfate 2kg, aluminium-magnesium silicate 0.5kg, silicone defoaming agent 0.05kg, ethylene glycol 5kg, Sodium Benzoate 0.5kg, surplus as oil phase be water; Circulate in the system of waterproof pulverization to 1～5 μ m with sand mill, carry out homogenize, thickening, froth breaking with homogenizer again and promptly make 25% milky white pymetrozine suspension agent product.
Embodiment 2:
Joining with pyrrole aphid ketone former medicine 5kg, aliphatic alcohol sulfate 2.5kg, fatty acid amide N methyl taurine salt 2kg, nonyl phenolic ether sulfuric ester 5kg, gum Arabic 3kg, silicone defoaming agent 2kg, propane diols 5kg, formaldehyde 1kg, surplus as oil phase corn oil 30kg, polyoxyethylene fatty acid ester 10kg mixing is water; Circulate in the system of waterproof pulverization to 1～5 μ m with sand mill, carry out homogenize, thickening, froth breaking with homogenizer again and promptly make 5% milky white pymetrozine suspension agent product.
Embodiment 3:
Joining with pyrrole aphid ketone former medicine 50kg, APES succinic acid half ester sulfonate 2kg, alpha-alkene sulfonate 0.5kg, sodium lignin sulfonate 2.5kg, methylcellulose 3kg, silicone defoaming agent 1kg, glycerine 5kg, benzoic acid 0.5kg, surplus as oil phase soybean oil 15kg, three ethanol list olein 10kg mixing is water; Circulate in the system of waterproof pulverization to 1～5 μ m with sand mill, carry out homogenize, thickening, froth breaking with homogenizer again and promptly make 50% milky white pymetrozine suspension agent product.
Embodiment 4:
Corn oil 20kg, fatty alcohol mixed with ethylene oxide condensate 15kg to join with the former medicine 20kg of pyrrole aphid ketone, fatty acid amide N methyl taurine sodium salt 2.5kg, sulfuric ester triethanolamine salt 2kg, polyvinylpyrrolidone 1kg, silicone defoaming agent 3kg, polyethylene glycol 3kg, paraformaldehyde 5kg, surplus as oil phase be water; Circulate in the system of waterproof pulverization to 1～5 μ m with sand mill, carry out homogenize, thickening, froth breaking with homogenizer again and promptly make 20% milky white pymetrozine suspension agent product.
Embodiment 5:
Joining with pyrrole aphid ketone former medicine 15kg, APES succinic acid half ester sulfonate 5kg, naphthalene sulfonic acid-formaldehyde condensation product 5kg, polyvinyl alcohol 0.5kg, C8～10 aliphatic alcohols antifoaming agent 0.1kgs, diethylene glycol (DEG) 5kg, benzoic acid 1kg, surplus as oil phase turpentine oil 15kg, polyoxyethylene fatty acid ester 15kg mixing is water; Circulate in the system of waterproof pulverization to 1～5 μ m with sand mill, carry out homogenize, thickening, froth breaking with homogenizer again and promptly make 15% milky white pymetrozine suspension agent product.
Embodiment 6:
The 25% pyrrole aphid ketone that embodiment 1 is prepared contains the suspending agent of vegetable oil and derivative thereof, prevents the field control effectiveness test that eliminates aphis with 25% pymetrozine suspension agent before transforming and 25% pyrrole aphid ketone wetting powder, and the result is following:
The anti-field efficacy that eliminates aphis
Can find out by the result, (1 mu=667m of active ingredient 6g/ mu
2) time embodiment 1 anti-effect that eliminates aphis apparently higher than 25% pyrrole aphid ketone WP of same content, and be higher than 25% pyrrole aphid ketone SC.Therefore can obviously improve the field control effect of preparation through adding vegetable oil and derivative thereof in original preparation.
Embodiment 7:
The 25% pyrrole aphid ketone that embodiment 1 is prepared contains the suspending agent of vegetable oil and derivative thereof, and with the field control effectiveness test that 25% pymetrozine suspension agent before transforming and 25% pyrrole aphid ketone wetting powder are prevented and treated the paddy rice brown planthopper, the result is following:
The field efficacy of control paddy rice brown planthopper
Can find out by the result, (1 mu=667m of active ingredient 6g/ mu
2) time embodiment 1 control paddy rice brown planthopper effect apparently higher than the 25% pyrrole aphid ketone WP and the 25% pyrrole aphid ketone SC of same content, therefore can obviously improve the field control effect of preparation through in original preparation, adding vegetable oil and derivative thereof.
Claims (10)
1. a pymetrozine suspension preparation that contains vegetable oil and derivative thereof is characterized in that, the composition of this suspension formulation content is by weight counted:
Pyrrole aphid ketone 1～50%
Vegetable oil and derivative 1～40% thereof
Wetting agent 0.5～10%
Dispersant 0.5～10%
Emulsifier 2～15%
Thickener 0.05～5%
Antifoaming agent 0.05～5%
Antifreezing agent 1～10%
Preservative 0.1～10%
Water supplies 100%
2. the pymetrozine suspension preparation that contains vegetable oil and derivative thereof according to claim 1; It is characterized in that described vegetable oil and derivative thereof are selected from one or several in corn oil, rapeseed oil, soybean oil, sunflower oil, peanut oil, turpentine oil, the vegetable oil that methylates, the biodiesel.
3. the pymetrozine suspension preparation that contains vegetable oil and derivative thereof according to claim 1; It is characterized in that described wetting agent is selected from one or several in aliphatic alcohol sulfate, alpha-alkene sulfonate, dialkyl group succinate sulfonate sodium, fatty alcohol, APES succinic acid half ester sulfonate, fatty acid amide N methyl taurine sodium salt, APES sulphate, alkyl phenol sulfonic sodium, the extraordinary polyether-modified polysiloxane of alkyl phenol, AEO, the alkylphenol-polyethenoxy base ether.
4. the pymetrozine suspension preparation that contains vegetable oil and derivative thereof according to claim 1; It is characterized in that described dispersant is selected from one or more in fatty alcohol ether sulfate, nonyl phenolic ether sulfuric ester, triphen ethyl-phenol APEO, sulfuric ester triethanolamine salt, MODIFIED LIGNOSULPHONATE, naphthalene sulfonic acid-formaldehyde condensation product, sodium lignin sulfonate, the alkyl naphthalene formaldehyde condensate sulfonates.
5. the pymetrozine suspension preparation that contains vegetable oil and derivative thereof according to claim 1; It is characterized in that described emulsifier is selected from one or more in sorbitan mono-oleic acid ester, sorbitan fatty acid ester APEO, fatty alcohol and ethylene oxide condensate, polyoxyethylene fatty acid ester, three ethanol list oleins, castor oil and the ethylene oxide condensate.
6. the pymetrozine suspension preparation that contains vegetable oil and derivative thereof according to claim 1; It is characterized in that described thickener is selected from one or several in gum Arabic, xanthan gum, methylcellulose, CMC, hydroxyethylcellulose, PAA, polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl acetate, gaseous state silica, the aluminium-magnesium silicate.
7. the pymetrozine suspension preparation that contains vegetable oil and derivative thereof according to claim 1; It is characterized in that that described antifoaming agent is selected from is silicone based, fatty alcohol, C10～12 representative examples of saturated aliphatic carboxylic and the ester class thereof of C8～10, in ester-ether type compound one or several; Described antifreezing agent is selected from one or several in ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, polyethylene glycol, glycerine-ether diglycol, urea, ammonium sulfate, the citric acid; Described preservative is selected from one or several in formaldehyde, paraformaldehyde, benzoic acid, the Sodium Benzoate.
8. the described compound method that contains the pymetrozine suspension preparation of vegetable oil and derivative thereof of claim 1; It is characterized in that; This method is: with pyrrole aphid ketone, wetting agent, dispersant, thickener, antifoaming agent, antifreezing agent, preservative and water; According to the rules after the ratio weighing, using sand mill to carry out sand milling, to be crushed to the particle diameter fineness be 1～5 μ m, vegetable oil and derivative thereof with emulsifier in proportion after the weighing; Join behind the sand milling in the material, and with homogenizer shear, thickening, froth breaking be prepared from.
9. the described application that contains pymetrozine suspension preparation anti-eliminate aphis section, Delphacidae, Aleyrodidae, Cicadellidae insect on crop of vegetable oil and derivative thereof of claim 1.
10. application according to claim 9 is characterized in that containing the application of pymetrozine suspension preparation in control cotton aphid, water rice hopper, vegetables Bemisia tabaci of vegetable oil and derivative thereof.
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| CN2010105930085A CN102524267A (en) | 2010-12-17 | 2010-12-17 | Pymetrozine suspension preparation containing vegetable oil and derivatives thereof and preparation method and application thereof |
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| CN2010105930085A CN102524267A (en) | 2010-12-17 | 2010-12-17 | Pymetrozine suspension preparation containing vegetable oil and derivatives thereof and preparation method and application thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107306946A (en) * | 2017-05-10 | 2017-11-03 | 中国农业大学 | A kind of egg oil agricultural chemicals and its preparation method and application |
| CN108293987A (en) * | 2017-01-11 | 2018-07-20 | 北京赛特超润界面科技有限公司 | A kind of composition preventing drop rebound and sputtering on super hydrophobic surface and its application in pesticide |
| CN109699661A (en) * | 2019-02-13 | 2019-05-03 | 中化化工科学技术研究总院有限公司 | A kind of aviation low volume insecticidal suspending agent and its preparation and application |
| CN115843793A (en) * | 2022-12-14 | 2023-03-28 | 南通施壮化工有限公司 | Pymetrozine-containing water suspension and preparation method thereof |
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2010
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| US6566305B1 (en) * | 1998-07-03 | 2003-05-20 | Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic | Phytosanitary treatment by foliar absorption using a modified oil |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108293987A (en) * | 2017-01-11 | 2018-07-20 | 北京赛特超润界面科技有限公司 | A kind of composition preventing drop rebound and sputtering on super hydrophobic surface and its application in pesticide |
| CN107306946A (en) * | 2017-05-10 | 2017-11-03 | 中国农业大学 | A kind of egg oil agricultural chemicals and its preparation method and application |
| CN109699661A (en) * | 2019-02-13 | 2019-05-03 | 中化化工科学技术研究总院有限公司 | A kind of aviation low volume insecticidal suspending agent and its preparation and application |
| CN109699661B (en) * | 2019-02-13 | 2022-04-05 | 中化化工科学技术研究总院有限公司 | Aviation low-amount spray insecticidal suspending agent and preparation and use methods thereof |
| CN115843793A (en) * | 2022-12-14 | 2023-03-28 | 南通施壮化工有限公司 | Pymetrozine-containing water suspension and preparation method thereof |
| CN115843793B (en) * | 2022-12-14 | 2024-04-12 | 南通施壮化工有限公司 | Water suspending agent containing pymetrozine and preparation method thereof |
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Application publication date: 20120704 |