CN102511494A - Combined pesticide preparation containing organic phosphorus - Google Patents

Combined pesticide preparation containing organic phosphorus Download PDF

Info

Publication number
CN102511494A
CN102511494A CN2011104349802A CN201110434980A CN102511494A CN 102511494 A CN102511494 A CN 102511494A CN 2011104349802 A CN2011104349802 A CN 2011104349802A CN 201110434980 A CN201110434980 A CN 201110434980A CN 102511494 A CN102511494 A CN 102511494A
Authority
CN
China
Prior art keywords
spiral shell
acid esters
dibasic acid
shell mite
mite dibasic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2011104349802A
Other languages
Chinese (zh)
Inventor
韦荣相
迟海军
王鲁
李婧婧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanning Defengfu Chemical Co Ltd
Original Assignee
Nanning Defengfu Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanning Defengfu Chemical Co Ltd filed Critical Nanning Defengfu Chemical Co Ltd
Priority to CN2011104349802A priority Critical patent/CN102511494A/en
Publication of CN102511494A publication Critical patent/CN102511494A/en
Pending legal-status Critical Current

Links

Abstract

The invention relates to a combined pesticide preparation containing organic phosphorus, characterized in that the effective components comprise di-spirodiclofen and an organic phosphorous insecticide, wherein the organic phosphorous insecticide can be one of chlorpyrifos, profenofos, phoxim, pyridafenthion or acephate. Compared with a single-pesticide, the combined pesticide obviously increases the control effect and reduces the application amounts of di-spirodiclofen and the organic phosphorous insecticide, thus the insect resistance is overcome, the generation of the insect resistance is delayed, and the service life of the medicament is prolonged. The combined pesticide preparation can be made into missible oil, micron emulsions, emulsions in water, water dispersible granules or suspending agents.

Description

A kind ofly contain organic Phosphorus mixed insecticide preparation
Technical field
The present invention relates to a kind of organic Phosphorus mixed insecticide preparation that contains, relate in particular to a kind of organic Phosphorus mixed insecticide preparation that contains.
Background technology
In recent years; Because single and not science medication, caused insect many agricultural chemicals of current use to be produced resistance in various degree, especially breeding amount are big, the tangible insect of generation overlap; Like diamond-back moth, thrips, rice leaf roller, aleyrodid, plant hopper etc., resistance development is fast.For example; The diamond-back moth of southern area of China has produced high-level resistance to conventional pesticide kinds such as organic phosphor, carbamate, pyrethroids; Even the novel insecticide variety of comparisons such as fluorine pyridine urea, capillary, AVM also produced the resistance of higher level; Alternative in the production, still effective insecticidal agent kind seldom, and this will further increase the weight of the development of pest resistance, therefore; Be badly in need of efficient, wide spectrum, with the good new product of Environmental compatibility, as medication by turns in the resistance management.
The combination of active principles of different agricultural chemicals is processed Recompounded pesticide, be exploitation at present and development novel pesticide a kind of effectively with mode efficiently.
Spiral shell mite dibasic acid esters is the novel pesticide of on the basis of spiral shell mite ester, transforming out; Brand new; The mechanism of action is unique, and this product is except that the characteristic with lasting period length, and the high 2-3 of its specific activity spiral shell mite ester doubly; It all has good preventive effect to two spotted spider mite, yellow spider, iron tick, yellow tea mite, Tetranychus cinnabarinus and Tetranychus urticae etc., and the mite insect that can be used for solanaceous crops such as fruit tree such as citrus, grape and eggplant, capsicum, tomato is administered.
Summary of the invention
The objective of the invention is to: a kind of organic Phosphorus mixed insecticide preparation that contains is provided, both can have reduced dosage, reduce cost, can overcome the pest resistance to insecticide that had existed already again.
The technical scheme that the present invention solves the problems of the technologies described above is following:
1. one kind contains organic Phosphorus mixed insecticide preparation, and its active ingredient is spiral shell mite dibasic acid esters and organophosphorus insecticides, spiral shell mite dibasic acid esters by weight 1~40%, organophosphorus insecticides by weight 1~40%, and all the other are auxiliary agents, the each component total amount is 100%; Organophosphorus insecticide wherein can be chlopyrifos, Profenofos, phoxim, pyridaphethione or orthene.
Above-mentioned a kind of organic Phosphorus mixed insecticide preparation that contains, said spiral shell mite dibasic acid esters is 1~20% by weight, organophosphorus insecticides is 1~20% by weight.
Above-mentioned a kind of organic Phosphorus mixed insecticide preparation that contains can be made into missible oil, microemulsion, aqueous emulsion, water dispersible granules or suspending agent.
Above-mentioned a kind of organic Phosphorus mixed insecticide preparation that contains is processed spiral shell mite dibasic acid esters chlorpyrifos micro emulsion, and the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 4%,
Chlopyrifos is 1%,
N-Methyl pyrrolidone 9%,
Calcium dodecyl benzene sulfonate 6%,
Nonyl phenol polyethenoxy ether 5%,
Water is 75%.
Above-mentioned a kind of organic Phosphorus mixed insecticide preparation that contains is processed spiral shell mite dibasic acid esters chlopyrifos water dispersible granules, and the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 5%,
Chlopyrifos is 40%,
Sodium methylene bis-naphthalene sulfonate is 7%,
Lauryl sodium sulfate is 3%,
Ammonium sulfate is 6%,
Precipitated calcium carbonate is 39%.
Above-mentioned a kind of organic Phosphorus mixed insecticide preparation that contains is processed spiral shell mite dibasic acid esters Profenofos missible oil, and the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 10%,
Profenofos is 30%,
N-Methyl pyrrolidone is 10%,
Calcium dodecyl benzene sulfonate is 8%,
Xylol is 42%.
Above-mentioned a kind of organic Phosphorus mixed insecticide preparation that contains is processed spiral shell mite dibasic acid esters orthene missible oil, and the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 40%,
Orthene is 8%,
N-Methyl pyrrolidone is 5%,
Dimethyl formamide is 5%,
Calcium dodecyl benzene sulfonate is 6%,
Xylol is 36%.
Above-mentioned a kind of organic Phosphorus mixed insecticide preparation that contains is processed spiral shell mite dibasic acid esters pyridaphethione aqueous emulsion, and the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 6%,
Pyridaphethione is 24%,
N-Methyl pyrrolidone is 10%,
Octyl group alkane phenol polyethenoxy ether is 5%,
Ethylene glycol is 3%,
Dimethyl silicone polymer 0.3%,
Water is 51.7%.
Above-mentioned a kind of organic Phosphorus mixed insecticide preparation that contains is processed spiral shell mite dibasic acid esters phoxim suspending agent, and the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 5%,
Phoxim is 25%,
Sodium lignin sulfonate is 4%,
Lauryl sodium sulfate 3%,
Ethylene glycol is 2%,
Gum Arabic 1%,
Water is 60%.
The present invention compared with prior art produces following beneficial effect: (1) is compared with single agent, and this composition pesticide has obviously improved control efficiency than single agent; (2) compare with spiral shell mite dibasic acid esters, organophosphorus insecticide, reduced the usage amount of active ingredient spiral shell mite dibasic acid esters, the agent of organic phosphates list; (3) the field dosage be can significantly reduce, environmental pollution and residue of pesticide effectively reduced; (4) mechanism of action of active ingredient is different in the composition, and the generation that helps overcoming pest resistance He delay pest resistance to insecticide prolongs medicament service life.
Embodiment
In order to make the object of the invention, technical scheme and advantage clearer, the present invention further describes with following specific embodiment, but the present invention is limited to these examples absolutely not.If no special instructions, the ratio of below mentioning (comprising percentage) all is a mass ratio.
Embodiment 1
22% spiral shell mite dibasic acid esters chlorpyrifos ec
Spiral shell mite dibasic acid esters 20 grams, chlopyrifos 2 grams, N-Methyl pyrrolidone 8 grams, ethoxylated dodecyl alcohol 4 grams, calcium dodecyl benzene sulfonate 6 grams, xylol complement to 100 grams.
Active component, emulsifier and the soluble additive ratio in prescription is added in the mixing kettle successively, stir, make 22% spiral shell mite dibasic acid esters chlorpyrifos ec.
This embodiment is applied to prevent and treat the paddy rice rice leaf roller, and 22% spiral shell mite dibasic acid esters chlorpyrifos ec is sprayed by effective ingredient consumption 10 gram/mu thin ups, and the control efficiency of 1 day, 7 days and 15 days is respectively 90.3%, 97.5%, 92.8% behind the medicine; 15% spiral shell mite dibasic acid esters missible oil is according to the spraying of effective ingredient consumption 15 gram/mu thin ups, and preventive effect was respectively 68.6%, 82.8% and 78.5% in 1 day, 7 days, 15 days; The spraying of 48% chlorpyrifos ec effective ingredient consumption, 40 gram/mu thin ups, 1 day, 7 days, 15 days preventive effect is respectively 70.3%, 84.1% and 80.7% behind the medicine.Higher behind spiral shell mite dibasic acid esters and the chlorpyrifos mixture than single agent preventive effect; Quick-acting and lasting effect to rice leaf roller all obviously are better than single agent; And still less than the consumption of the single agent of chlopyrifos.
Embodiment 2
24% spiral shell mite dibasic acid esters chlorpyrifos aqueous emulsion
Spiral shell mite dibasic acid esters 4 grams, chlopyrifos 20 grams, N-Methyl pyrrolidone 10 grams, oleic acid polyoxyethylene groups ester 5 grams, ethylene glycol 3 grams, dimethyl silicone polymer 0.3 gram, water complement to 100 grams.
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; With water-soluble component (antifreezing agent, antifoaming agent) and the mixed water that gets of water; Under high-speed stirred, oil phase is mixed with water, make 24% spiral shell mite dibasic acid esters chlorpyrifos aqueous emulsion.
This embodiment is applied to prevent and treat resistant bollworm, and 24% spiral shell mite dibasic acid esters chlorpyrifos aqueous emulsion is sprayed by active ingredient 20 gram/mu thin ups, and the control efficiency of 2 days and 7 days is respectively 94.1%, 90.5% behind the medicine.15% spiral shell mite dibasic acid esters missible oil is sprayed by active ingredient 15 gram/mu thin ups, and the preventive effect of 2 days and 7 days is respectively 82.3%, 78.6% behind the medicine; 48% chlorpyrifos ec is sprayed by active ingredient 40 gram/mu thin ups, 2 days and 7 days preventive effect difference 63.2%, 60.8% behind the medicine.Synergistic effect is obvious behind spiral shell mite dibasic acid esters and the chlorpyrifos mixture, and the preventive effect of antagonism cotton bollworm obviously is better than chlopyrifos, the agent of spiral shell mite dibasic acid esters list, and composite dose consumption is far smaller than single agent consumption.
Embodiment 3
5% spiral shell mite dibasic acid esters chlorpyrifos micro emulsion
Spiral shell mite dibasic acid esters 4 grams, chlopyrifos 1 gram, N-Methyl pyrrolidone 9 grams, calcium dodecyl benzene sulfonate 6 grams, nonyl phenol polyethenoxy ether 5 grams, water complement to 100 grams.
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; Under high-speed stirred, oil phase is mixed with water, make 5% spiral shell mite dibasic acid esters chlorpyrifos micro emulsion.
This embodiment is applied to prevent and treat the fresh kidney beans thrips, and 5% spiral shell mite dibasic acid esters chlorpyrifos micro emulsion is sprayed by effective ingredient consumption 8 gram/mu thin ups, and 3 days and 15 days control efficiency are respectively 96.3% and 78.9% behind the medicine; 15% spiral shell mite dibasic acid esters missible oil is by the spraying of effective ingredient consumption 10 gram/mu thin ups; Behind the medicine 3 days with 15 days preventive effect be respectively 77.3% and 62.1%: 48% chlorpyrifos ec spray by effective ingredient consumption 30 gram/mu thin ups; The preventive effect of 3 days and 15 days is respectively 75.2% and 56.4% behind the medicine; Composite dose lasting period is obviously long than the lasting period of chlopyrifos, the agent of spiral shell mite dibasic acid esters list, consumption still less, and preventive effect is higher.
Embodiment 4
45% spiral shell mite dibasic acid esters chlopyrifos water dispersible granules
Spiral shell mite dibasic acid esters 5 grams, chlopyrifos 40 grams, sodium methylene bis-naphthalene sulfonate 7 grams, lauryl sodium sulfate 3 grams, ammonium sulfate 6 grams, precipitated calcium carbonate complement to 100 grams.
Active component, dispersant, wetting agent, disintegrant and filler is even by the mixed of prescription, become wetting powder through comminution by gas stream, add a certain amount of water extrusion again and make material, after dry screened, obtain 45% spiral shell mite dibasic acid esters chlopyrifos water dispersible granules.
This embodiment is applied to prevent and treat the wild cabbage diamond-back moth, and by the spraying of effective ingredient consumption 15 gram/mu thin ups, 2 days control efficiency is 96.3% behind the medicine with 45% spiral shell mite dibasic acid esters chlopyrifos water dispersible granules; 15% spiral shell mite dibasic acid esters missible oil is by the spraying of effective ingredient consumption 15 gram/mu thin ups, and 2 days control efficiency is 78.5% behind the medicine; 48% chlorpyrifos ec is by the spraying of effective ingredient consumption 30 gram/mu thin ups, and 2 days preventive effect is 71.8% behind the medicine.It is thus clear that composite dose integrated control effect is higher than two single agent, and than the single agent consumption of chlopyrifos still less.
Embodiment 5
30% spiral shell mite dibasic acid esters Profenofos aqueous emulsion
Spiral shell mite dibasic acid esters 10 grams, Profenofos 20 grams, cyclohexanone 8 grams, ethoxylated dodecyl alcohol 5 grams, glycerine 3 grams, dimethyl silicone polymer 0.3 gram, water complement to 100 grams.
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; With water-soluble component and the mixed waters that gets of water such as antifreezing agent, antifoaming agents; Under high-speed stirred, oil phase is mixed with water, make 30% spiral shell mite dibasic acid esters Profenofos aqueous emulsion.
Present embodiment is applied to prevent and treat the Brussels sprouts diamond-back moth, doublely controls prodenia litura.30% spiral shell mite dibasic acid esters Profenofos aqueous emulsion dilute is sprayed by effective ingredient consumption 15 gram/mus, and 3 days preventive effects to diamond-back moth are 93.8% behind the medicine, are 86.0% to the double preventive effect of controlling of prodenia litura; 15% spiral shell mite dibasic acid esters missible oil is pressed identical method use by effective ingredient consumption 15 gram/mus, and 3 days preventive effects to diamond-back moth are 86.1% behind the medicine, is 63.6% to the double preventive effect of controlling of prodenia litura; 20% Profenofos missible oil uses by identical method according to effective ingredient consumption 30 gram/mus, and 3 days preventive effects to diamond-back moth are 68.5% behind the medicine, is 60.2% to the double preventive effect of controlling of prodenia litura.It is thus clear that composite dose integrated control effect all is higher than two kinds of single agent, and composite dose than Profenofos list agent consumption still less.
Embodiment 6
40% spiral shell mite dibasic acid esters Profenofos missible oil
Spiral shell mite dibasic acid esters 10 grams, Profenofos 30 grams, N-Methyl pyrrolidone 10 grams, calcium dodecyl benzene sulfonate 8 grams, xylol complement to 100 grams.
Active component, emulsifier and the soluble additive ratio in prescription is added in the mixing kettle successively, stir, make 40% spiral shell mite dibasic acid esters Profenofos missible oil.
This embodiment is applied to prevent and treat the cotton cotton bollworm, and 40% spiral shell mite dibasic acid esters Profenofos missible oil is sprayed by effective ingredient consumption 15 gram/mu thin ups, and the control efficiency of 2 days and 7 days is respectively 95.4%, 82.2% behind the medicine.15% spiral shell mite dibasic acid esters missible oil is sprayed by effective ingredient consumption 15 gram/mu thin ups, and the preventive effect of 2 days and 7 days is respectively 86.5%, 83.2% behind the medicine; 20% Profenofos missible oil is sprayed by effective ingredient consumption 40 gram/mu thin ups, 2 days and 7 days preventive effect difference 63.5%, 58.4% behind the medicine.The composite back synergistic effect of spiral shell mite dibasic acid esters and Profenofos is obvious.
Embodiment 7
40% spiral shell mite dibasic acid esters phoxim emulsifiable concentrate
Spiral shell mite dibasic acid esters 8 grams, phoxim 32 grams, dimethyl formamide 10 grams, calcium dodecyl benzene sulfonate 5 grams, ethoxylated dodecyl alcohol 5 grams, xylol complement to 100 grams.
Active component, emulsifier and the soluble additive ratio in prescription is added in the mixing kettle successively, stir, make 40% spiral shell mite dibasic acid esters phoxim emulsifiable concentrate.
Present embodiment is used and control radish phyllotreta striolata, and 40% spiral shell mite dibasic acid esters phoxim emulsifiable concentrate is by the spraying of effective ingredient consumption 10 gram/mu thin ups, and 3 days preventive effects are that 94.2%, 7 day preventive effect is 83.1% behind the medicine; 15% spiral shell mite dibasic acid esters missible oil is pressed identical method use by effective ingredient consumption 10 gram/mus, and the preventive effect of 3 days and 7 days is respectively 80.5% and 69.8% behind the medicine; 40% phoxim emulsifiable concentrate is pressed identical method use by active ingredient 30 gram/mus, and the preventive effect of 3 days and 7 days is respectively 67.3% and 51.6% behind the medicine.Synergistic effect is obvious behind spiral shell mite dibasic acid esters and the phoxim compound.
Embodiment 8
48% spiral shell mite dibasic acid esters orthene missible oil
Spiral shell mite dibasic acid esters 40 grams, orthene 8 grams, N-Methyl pyrrolidone 5 grams, dimethyl formamide 5 grams, calcium dodecyl benzene sulfonate 6 grams, xylol complement to 100 grams.
Active component, emulsifier and the soluble additive ratio in prescription is added in the mixing kettle successively, stir and all collude, make 48% spiral shell mite dibasic acid esters orthene missible oil.
Present embodiment is applied to prevent and treat the cotton green plant bug, doublely controls other cotton-plant pest-insects.In spraying at dusk, 7 days preventive effects to green plant bug are 97.3% to 48% spiral shell mite dibasic acid esters orthene missible oil behind the medicine according to effective ingredient consumption 30 gram/mu thin ups, and the double preventive effect of controlling of cotten aphid and Bemisia tabaci is respectively 90.6% and 88.3%; 15% spiral shell mite dibasic acid esters missible oil uses according to effective ingredient consumption 15 gram/mus after the same method, and 7 days preventive effects to green plant bug are 80.8% behind the medicine, and the double preventive effect of controlling of cotten aphid and Bemisia tabaci is respectively 75.2% and 72.0%; 20% orthene missible oil is pressed identical method use by effective ingredient consumption 40 gram/mus, and 7 days preventive effects to green plant bug are 63.5% behind the medicine, and the double preventive effect of controlling of cotten aphid and Bemisia tabaci is respectively 51.7% and 58.4%.It is thus clear that the composite dose of preventive effect to cotton-plant pest-insects all is higher than single agent, reached and used a kind of medicament, the purpose of preventing and treating multiple cotton-plant pest-insects.
Embodiment 9
10% spiral shell mite dibasic acid esters phoxim microemulsion
Spiral shell mite dibasic acid esters 1 gram, phoxim 9 grams, N-Methyl pyrrolidone 10 grams, calcium dodecyl benzene sulfonate 6 grams, water complement to 100 grams.
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; Under high-speed stirred, oil phase is mixed with water, make 10% spiral shell mite dibasic acid esters phoxim microemulsion.
Present embodiment is applied to prevent and treat paddy rice rice field the 1st generation striped rice borer early, and 10% spiral shell mite dibasic acid esters phoxim microemulsion is by the spraying of effective ingredient consumption 20 gram/mu thin ups, and 7 days preventive effects are 90.8% behind the medicine; 15% spiral shell mite dibasic acid esters missible oil uses by identical method by effective ingredient consumption 20 gram/mus, and the back 7 days preventive effect that wraps with straw is 73.4%; 40% phoxim emulsifiable concentrate uses by identical method by effective ingredient consumption 40 gram/mus, and 7 days preventive effect is 80.2% behind the medicine.It is thus clear that composite dose dosage obviously is less than the dosage of single agent, and preventive effect is higher than single agent.
Embodiment 10
30% spiral shell mite dibasic acid esters pyridaphethione aqueous emulsion
Spiral shell mite dibasic acid esters 6 grams, pyridaphethione 24 grams, N-Methyl pyrrolidone 10 grams, octyl group alkane phenol polyethenoxy ether 5 grams, ethylene glycol 3 grams, dimethyl silicone polymer 0.3 gram, water complement to 100 grams.
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; With water-soluble component and the mixed waters that gets of water such as antifreezing agent, antifoaming agents; Under high-speed stirred, oil phase is mixed with water, make 30% spiral shell mite dibasic acid esters pyridaphethione aqueous emulsion.
Present embodiment is applied to prevent and treat the conventional semilate rice two generations striped rice borer of paddy rice, and 30% spiral shell mite dibasic acid esters pyridaphethione aqueous emulsion is by the spraying of effective ingredient consumption 15 gram/mu thin ups, and 7 days preventive effects are 93.2% behind the medicine; 15% spiral shell mite dibasic acid esters missible oil uses by identical method by effective ingredient consumption 15 gram/mus, and 7 days preventive effect is 76.3% behind the medicine; 20% pyridaphethione missible oil uses by identical method by effective ingredient consumption 30 gram/mus, and 7 days preventive effect is 70.6% behind the medicine.
Embodiment 11
30% spiral shell mite dibasic acid esters phoxim suspending agent
Spiral shell mite dibasic acid esters 5 grams, phoxim 25 grams, lauryl sodium sulfate 3 grams, sodium lignin sulfonate 4 grams, ethylene glycol 2 grams, gum Arabic 1 gram, deionized water complement to 100 grams.Above-mentioned each component is fully mixed porphyrize processing in the adding sand milling still, promptly obtain 30% spiral shell mite dibasic acid esters phoxim suspending agent.

Claims (9)

1. one kind contains organic Phosphorus mixed insecticide preparation, it is characterized in that, active ingredient is spiral shell mite dibasic acid esters and organophosphorus insecticides; Spiral shell mite dibasic acid esters by weight 1~40%; Organophosphorus insecticides by weight 1~40%, all the other are auxiliary agents, the each component total amount is 100%; Organophosphorus insecticide wherein is chlopyrifos, Profenofos, phoxim, pyridaphethione or orthene.
2. a kind of organic Phosphorus mixed insecticide preparation that contains according to claim 1 is characterized in that said spiral shell mite dibasic acid esters is 1~20% by weight, and organophosphorus insecticides is 1~20% by weight.
3. a kind of organic Phosphorus mixed insecticide preparation that contains according to claim 1 is characterized in that, processes missible oil, microemulsion, aqueous emulsion, water dispersible granules or suspending agent.
4. a kind of organic Phosphorus mixed insecticide preparation that contains according to claim 1 and 2, it is characterized in that: process spiral shell mite dibasic acid esters chlorpyrifos micro emulsion, the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 4%,
Chlopyrifos is 1%,
N-Methyl pyrrolidone 9%,
Calcium dodecyl benzene sulfonate 6%,
Nonyl phenol polyethenoxy ether 5%,
Water is 75%.
5. a kind of organic Phosphorus mixed insecticide preparation that contains according to claim 1 and 2 is characterized in that: process spiral shell mite dibasic acid esters chlopyrifos water dispersible granules, the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 5%,
Chlopyrifos is 40%,
Sodium methylene bis-naphthalene sulfonate is 7%,
Lauryl sodium sulfate is 3%,
Ammonium sulfate is 6%,
Precipitated calcium carbonate is 39%.
6. according to claim 1 or the described a kind of organic Phosphorus mixed insecticide preparation that contains of claim 2, it is characterized in that: process spiral shell mite dibasic acid esters Profenofos missible oil, the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 10%,
Profenofos is 30%,
N-Methyl pyrrolidone is 10%,
Calcium dodecyl benzene sulfonate is 8%,
Xylol is 42%.
7. a kind of organic Phosphorus mixed insecticide preparation that contains according to claim 1 and 2 is characterized in that: process spiral shell mite dibasic acid esters orthene missible oil, the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 40%,
Orthene is 8%,
N-Methyl pyrrolidone is 5%,
Dimethyl formamide is 5%,
Calcium dodecyl benzene sulfonate is 6%,
Xylol is 36%.
8. a kind of organic Phosphorus mixed insecticide preparation that contains according to claim 1 and 2 is characterized in that: process spiral shell mite dibasic acid esters pyridaphethione aqueous emulsion, the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 6%,
Pyridaphethione is 24%,
N-Methyl pyrrolidone is 10%,
Octyl group alkane phenol polyethenoxy ether is 5%,
Ethylene glycol is 3%,
Dimethyl silicone polymer 0.3%,
Water is 51.7%.
9. a kind of organic Phosphorus mixed insecticide preparation that contains according to claim 1 and 2 is characterized in that: process spiral shell mite dibasic acid esters phoxim suspending agent, the weight proportion of each component is:
Spiral shell mite dibasic acid esters is 5%,
Phoxim is 25%,
Sodium lignin sulfonate is 4%,
Lauryl sodium sulfate 3%,
Ethylene glycol is 2%,
Gum Arabic 1%,
Water is 60%.
CN2011104349802A 2011-12-22 2011-12-22 Combined pesticide preparation containing organic phosphorus Pending CN102511494A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011104349802A CN102511494A (en) 2011-12-22 2011-12-22 Combined pesticide preparation containing organic phosphorus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011104349802A CN102511494A (en) 2011-12-22 2011-12-22 Combined pesticide preparation containing organic phosphorus

Publications (1)

Publication Number Publication Date
CN102511494A true CN102511494A (en) 2012-06-27

Family

ID=46282802

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2011104349802A Pending CN102511494A (en) 2011-12-22 2011-12-22 Combined pesticide preparation containing organic phosphorus

Country Status (1)

Country Link
CN (1) CN102511494A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103749525A (en) * 2013-12-25 2014-04-30 江苏龙灯化学有限公司 Insecticidal composition
CN103783043A (en) * 2014-02-28 2014-05-14 浙江农林大学 Compound pest/mite killing composition containing spirodiclofen double ester and application of compsition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103749525A (en) * 2013-12-25 2014-04-30 江苏龙灯化学有限公司 Insecticidal composition
CN103749525B (en) * 2013-12-25 2015-10-28 江苏龙灯化学有限公司 A kind of Pesticidal combination
CN103783043A (en) * 2014-02-28 2014-05-14 浙江农林大学 Compound pest/mite killing composition containing spirodiclofen double ester and application of compsition
CN103783043B (en) * 2014-02-28 2016-04-13 浙江农林大学 Containing the compound insecticidal/miticide composition and uses thereof of spiral shell mite dibasic acid esters

Similar Documents

Publication Publication Date Title
CN104839157A (en) Insecticidal composition containing chitosan oligosaccharide and flubendiamide and application
CN103250720B (en) A kind of containing chlorfluazuron and ZJ4042 agricultural pesticide composition
CN103039501B (en) Agricultural insecticidal composition containing beta cypermethrin and ZJ4042
CN102511494A (en) Combined pesticide preparation containing organic phosphorus
CN103918678A (en) Seed coating agent with functions of repelling birds and rats
CN104522010A (en) Synergistic acaricidal composition containing cyenopyrafen and bifenazate
CN103039490B (en) Weeding composite containing fentrazamide and pyridate
CN102246811B (en) Insecticidal composition containing ZJ3265 and profenofos
CN103053523B (en) Synergistic insecticidal composition containing flonicamid and pyridalyl and application thereof
CN102246814A (en) Apholate-chlorpyrifos microemulsion
CN106577709A (en) Pesticide compound containing cyhalodiamide and hexaflumuron
CN1951192A (en) Kresoxim-methyl and nimbin mixed microemulsion and preparation method thereof
CN104145963B (en) A kind of Pesticidal combination containing ether chrysanthemum ester and ZJ4042
CN101961016A (en) Insecticidal microemulsion compounded by chlorantraniliprole and azadirachtin and preparation method thereof
CN102017984A (en) Synergy disinfection composite containing nitenpyram and cypermethrin and application thereof
CN102613236B (en) Farm chemical composition containing chlorpyrifos and ZJ3265
CN103053604A (en) Synergistic insecticidal composition containing flonicamid and silafluofen and application thereof
CN103053545B (en) Agricultural pesticide combination containing pymetrozine
CN102017985A (en) Synergistic pesticidal composition containing nitenpyram and high-efficient cypermethrin and application thereof
CN102550584A (en) Compound herbicide composition for wheat field
CN104365645A (en) Insecticidal composition containing acetamiprid and cyhalodiamide
CN104920412A (en) Insecticide composite comprising flufenoxuron and cyhalodiamide
CN102630690A (en) Insect-killing composite containing indoxacarb and ZJ3265
CN106259343A (en) A kind of pyriproxyfen-containing and the Pesticidal combination of chlorine fluorine cyanogen insect amide
CN107148973A (en) A kind of Pesticidal combination containing Bifenazate and chlorine fluorine cyanogen insect amide

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20120627

WD01 Invention patent application deemed withdrawn after publication