CN104920412A - Insecticide composite comprising flufenoxuron and cyhalodiamide - Google Patents
Insecticide composite comprising flufenoxuron and cyhalodiamide Download PDFInfo
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- CN104920412A CN104920412A CN201510361748.9A CN201510361748A CN104920412A CN 104920412 A CN104920412 A CN 104920412A CN 201510361748 A CN201510361748 A CN 201510361748A CN 104920412 A CN104920412 A CN 104920412A
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- flufenoxuron
- chlorine fluorine
- insect amide
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- cyanogen insect
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Abstract
The invention provides an insecticide composite, comprising flufenoxuron and cyhalodiamide, for agricultural pests. The weight ratio of the flufenoxuron to the cyhalodiamide is (1-50): (20-1). The insecticide composite has the advantages of high efficiency, low poison, long effect preserving period and capability of effectively controlling the pests such as red spiders, leaf rollers, cabbage worms, cotton bollworms and locusts.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Pesticidal combination containing flufenoxuron and chlorine fluorine cyanogen insect amide.
Background technology
The resistance problem of pest is global problems.Along with Chemical Control of Harmful Insects continuity, the increase of Pesticide use amount and not scientifical use agricultural chemicals, pest resistance is day by day serious, and the pest species producing resistance is on the increase.Particularly to the Lepidoptera class pest that agricultural production is caused harm serious, resistance level is higher, and resistance development speed is relatively very fast.Meanwhile, the use agricultural chemicals of high strength, causes Practice for Pesticide Residue in Agricultural Products to exceed standard, environmental pollution and the increase of peasant's drug cost etc., is unfavorable for agricultural sustainable development.Therefore, the pesticide of efficient, the low toxicity of research and development, environmental protection has positive effect to agricultural sustainable development.
Flufenoxuron (flufenoxuron) act as suppression chitin synthesis to insect, better to the effect of immature mite and insect.Flufenoxuron is mainly used in preventing and treating the insect on the fruit tree such as apple, oranges and tangerines and the plant such as vegetables, cotton, harmful mite, all has good control efficiency to insects such as spider mite kind, rust mite class (rust mite), leaf miner, diamond-back moth, cabbage caterpillar, cotton bollworm, heart-eating worm class, nocturnal moth class and locustamigratorias.
Chlorine fluorine cyanogen insect amide is the novel pesticide that Zhejiang Provincial Chemical Engineering Research Inst is developed voluntarily, code name ZJ4042, and chemical name is: the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, shown in structural formula following (I):
This insecticide belongs to Novel ortho benzenedicarboxamide insecticides, by activating calcium release channel in blue Buddhist nun's alkali recipient cell, causing the runaway release of storing calcium ion, is the compounds acting on blue Buddhist nun's alkali (Ryanodine) acceptor of insect cell few in number at present.Wide spectrum preventive effect is had to lepidoptera pest.
When flufenoxuron and chlorine fluorine cyanogen insect amide are used alone, drug cost is higher, limits it to a certain extent and applies, and is used alone for a long time and easily causes pest resistance degree constantly to increase.Therefore, flufenoxuron and chlorine fluorine cyanogen insect amide being carried out mixture, is a kind of effective ways preventing and treating agriculture resistant insect.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of efficient, low toxicity and the lasting period is long, the Pesticidal combination that effectively can prevent and treat crop pests, is conducive to the comprehensive regulation of insect.
For solving the problem, the technical solution adopted in the present invention is:
For a Pesticidal combination for pest, it is characterized in that described Pesticidal combination contains flufenoxuron and chlorine fluorine cyanogen insect amide, and the weight ratio of flufenoxuron and chlorine fluorine cyanogen insect amide is 1 ~ 50:20 ~ 1.
The chlorine fluorine cyanogen insect amide that the present invention uses, is the compound shown in structure above (I).
Pesticidal combination of the present invention, flufenoxuron and chlorine fluorine cyanogen insect amide are as active component.Preferably, the weight ratio of flufenoxuron and chlorine fluorine cyanogen insect amide is 1 ~ 10:10 ~ 1.Further preferably, the weight ratio of flufenoxuron and chlorine fluorine cyanogen insect amide is 1 ~ 5:5 ~ 1.
Present invention also offers a kind of insecticide for pest, by weight containing 5 ~ 90% above-mentioned Pesticidal combinations, all the other are agriculturally acceptable carrier and auxiliary agent.As preferred embodiment, the above-mentioned Pesticidal combination preferably containing 5 ~ 40% in insecticide.
Carrier of the present invention can be solid or liquid, and any carrier being generally used for preparing insecticides all can use.
Suitable solid carrier comprises: mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance comprises silicates, carbonate, Sulfates and oxide-based.Silicates is kaolin such as, sepiolite, nacrite, imvite, mica, vermiculite, pyrophyllite, talcum.Carbonate is such as: calcium carbonate, dolomite.Sulfates as ammonium sulfate, sodium sulphate, calcium sulphate.Oxide-based as quicklime, magnesium lime, diatomite.Plant is such as: citrus pulp, corncob cellulose, rice husk powder, rice husk, large soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class as winnofil hydrate, winnofil, white carbon.Inorganic salts is potassium chloride such as, sodium chloride.
Liquid-carrier comprises water and organic solvent.When active ingredient is suspension emulsion, organic solvent plays solubilising and antifreeze effect.Suitable organic solvent comprises aromatic hydrocarbons, such as benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chlorinated aliphatic hydrocarbon, such as vinyl chloride, chloroform, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, such as petroleum distillate, cyclohexane, light mineral oil and paraffin.Alcohols is methyl alcohol such as, ethanol, isopropyl alcohol, butanols, isobutanol, ethylene glycol, propane diols, glycerine, fatty alcohol etc.; Ethers is Propylene Glycol ether such as, ethohexadiol ether, benzinum.Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and different fluorine that ketone, N-methyl-pyrrolidon such as; Special solvent also has dimethyl formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile; Vegetable oil and methylated vegetable oils.Above-mentioned organic solvent both can be used alone, also can be used in combination, can also mix together with water.
Auxiliary agent of the present invention can comprise one or more in surfactant, defoamer, thickener, suspending agent and antifreezing agent as required, can also comprise other auxiliary agents that the industry is conventional as required.
Surfactant can be emulsifier, dispersant, stabilizing agent or wetting agent; Can be ionic or nonionic.Suitable surfactant comprises: the sodium salt of polyacrylic acid and lignin sulfonic acid and calcium salt; The polycondensation product of the fatty acid containing at least 12 carbon atoms in molecule or fatty amine and oxirane and/expoxy propane; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In the molecule at least containing the sulfuric acid of 10 carbon atoms or the alkali metal of sulfonic acid or alkali salt, be preferably sodium salt, as the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, alkylaryl sodium sulfonate and neopelex; The copolymer of the polymer of oxirane, oxirane and expoxy propane.
Emulsifier comprises nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonylphenol ether of nonionic emulsifier, fatty alcohol-polyoxyethylene ether, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether, styrylphenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.Anionic emulsifier mainly comprises calcium dodecyl benzene sulfonate, triphen ethyl phenol polyoxy ether phosphate amine salt, thermally coupled distillation columns amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention comprises: acrylate homopolymer sodium salt, maleic acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, triphen ethyl phenol polyoxyethylene ether phosphate, fatty alcohol-polyoxyethylene ether phosphoric acid, to one or more in hydroxyphenyl lignin sulfonic acid sodium salt.
Wetting agent of the present invention comprises: fatty alcohol-polyoxyethylene ether, naphthalene sulfonate, lauryl sodium sulfate, one or more combinations in alkyl phenol resin polyoxyethylene ether sulfate.
Thickener of the present invention comprises xanthans, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, gum Arabic, gelatin, one or more in polyvinyl alcohol.Defoamer of the present invention is preferably: bubble enemy, silicone, C
8 ~ 10fatty alcohol, C
10 ~ 20saturated fat acids and acid amides etc.
Pesticidal combination of the present invention can be mixed with missible oil, oil suspending agent, suspending agent, wetting powder or water dispersible granules according to the method that this area is general.
Pesticidal combination of the present invention and insecticide are suitable for pest control, and described insect comprises two spotted spider mite, leaf roller, cabbage caterpillar, cotton bollworm and locust.As preferred mode, Pesticidal combination provided by the invention and insecticide are suitable for preventing and treating the insect in fruit and vegetables, and described insect comprises two spotted spider mite, leaf roller, cabbage caterpillar, cotton bollworm and locust.
Pesticidal combination of the present invention has following advantage compared to existing technology:
(1) in composition, two kinds of active components are composite shows excellent synergistic effect in certain ratio range, and the insecticidal effect of mixed composition comparatively its single dose is significantly improved, and has the advantages that the good and lasting effect of quick-acting grows;
(2) reduce using dosage, reduce peasant's drug cost;
(3) utilize two kinds of active components to carry out reasonably mixture to the different mode of action of insect, the different mechanism of action, both extended the Pesticide use life-span, delayed again the generation of pest resistance to insecticide.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these embodiments.One skilled in the art would recognize that all alternatives, improvement project and the equivalents that present invention encompasses and may comprise in Claims scope.
In following embodiment, unless otherwise indicated, all percentage is all weight percentage.
The present inventor has carried out Toxicity Determination test to flufenoxuron and chlorine fluorine cyanogen insect amide mixture.
Test evaluates SOP (insecticide volume) with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and initiative pesticide bioactivity, adopts infusion process.
Synergy adopts following method to calculate:
The content (%) of toxicity index × A in using with of theoretical mixed toxicity index (TTI)=A
The content (%) of toxicity index × B in using with of+B
If co-toxicity coefficient is greater than 120, show there is synergistic effect; If be less than 80, be indicated as antagonism; If be greater than 80 to be less than 120, be indicated as summation action.
Embodiment 1: chlorine fluorine cyanogen insect amide and flufenoxuron mixture
Table 1, chlorine fluorine cyanogen insect amide and flufenoxuron are to cabbage pieris (Pieris rapae) synergy effect
| Proportioning | LC 50(mg/L) | Actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Flufenoxuron | 0.62 | 19.35 |
| Chlorine fluorine cyanogen insect amide | 0.12 | 100.00 | ||
| Flufenoxuron: chlorine fluorine cyanogen insect amide=50:1 | 0.35 | 34.29 | 20.94 | 163.76 |
| Flufenoxuron: chlorine fluorine cyanogen insect amide=20:1 | 0.35 | 34.29 | 23.20 | 147.81 |
| Flufenoxuron: chlorine fluorine cyanogen insect amide=1:1 | 0.12 | 100.00 | 59.68 | 167.57 |
| Flufenoxuron: chlorine fluorine cyanogen insect amide=1:10 | 0.08 | 150.00 | 92.67 | 161.87 |
| Flufenoxuron: chlorine fluorine cyanogen insect amide=1:20 | 0.08 | 150.00 | 96.16 | 155.99 |
Table 2, chlorine fluorine cyanogen insect amide and flufenoxuron are to the effect of citrus red mite Panonychus citri synergy
| Proportioning | LC 50(mg/L) | Actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Flufenoxuron | 3.68 | 2951.09 | ||
| Chlorine fluorine cyanogen insect amide | 108.6 | 100.00 | ||
| Flufenoxuron: chlorine fluorine cyanogen insect amide=50:1 | 2.38 | 4563.03 | 2895.18 | 157.61 |
| Flufenoxuron: chlorine fluorine cyanogen insect amide=20:1 | 2.51 | 4326.69 | 2815.32 | 153.68 |
| Flufenoxuron: chlorine fluorine cyanogen insect amide=1:1 | 3.98 | 2728.64 | 1525.54 | 178.86 |
| Flufenoxuron: chlorine fluorine cyanogen insect amide=1:10 | 18.5 | 587.03 | 359.19 | 163.43 |
| Flufenoxuron: chlorine fluorine cyanogen insect amide=1:20 | 27.5 | 394.91 | 235.77 | 167.50 |
As can be seen from result of the test table 1,2, flufenoxuron and chlorine fluorine cyanogen insect amide are in the scope of 1 ~ 50:20 ~ 1 (by weight), and co-toxicity coefficient is all greater than 120, all show as synergistic effect to cabbage red spider and cotton cabbage caterpillar.Flufenoxuron and chlorine fluorine cyanogen insect amide mixture have reasonability and feasibility.
Embodiment 2 (20% flufenoxuron chlorine fluorine cyanogen insect amide suspending agent)
By flufenoxuron 18%, chlorine fluorine cyanogen insect amide 2%, emulsifier 1601# (styrylphenol polyoxyethylene poly-oxygen propylene aether) 10%, dispersant SOPA-270 4%, bentonite 2%, xanthans 0.1%, silicone defoaming agent 0.4%, glycerine 5%, surplus are the formula of deionized water, each component is first pulverized in advance, add in sand mill again and grind, obtained 20% flufenoxuron chlorine fluorine cyanogen insect amide suspending agent after high shear mixing.
20% obtained flufenoxuron chlorine fluorine cyanogen insect amide suspending agent is used for apple skin worm control.20% flufenoxuron chlorine fluorine cyanogen insect amide suspending agent is watered even spraying by the amount of 10 mg/kg at apple skin worm larva occurance peak, and after medicine, the preventive effect of 3 days and 7 days is respectively 91.5% and 93.9%.By same method dispenser, contrast single dose 50 grams per liter flufenoxuron dispersible agent (formulation rate is 75 mg/kg) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 mg/kg), after medicine, the preventive effect of 3 days is respectively 70.1% and 84.9%, and after medicine, the preventive effect of 7 days is respectively 72.9% and 85.9%.After flufenoxuron and chlorine fluorine cyanogen insect amide mixture, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 3 (40% flufenoxuron chlorine fluorine cyanogen insect amide water-dispersible granules)
Be kaolinic formula by flufenoxuron 35%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus, each component carried out dry pulverization process, granulation, drying, screening obtained 40% flufenoxuron chlorine fluorine cyanogen insect amide water-dispersible granules afterwards.
40% obtained flufenoxuron chlorine fluorine cyanogen insect amide water-dispersible granules is used for citrus red mite control.40% flufenoxuron chlorine fluorine cyanogen insect amide water-dispersible granules is watered even spraying by the amount of 20 mg/kg at larva occurrence in peak period, and after medicine, 3 days and 7 days preventive effects are respectively 90.6% and 93.2%.By same method dispenser, contrast single dose 50 grams per liter flufenoxuron dispersible agent (formulation rate is 75 mg/kg) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 mg/kg), after medicine, the preventive effect of 3 days is respectively 76.3% and 46.8%, and after medicine, the preventive effect of 7 days is respectively 78.8% and 59.2%.After flufenoxuron and chlorine fluorine cyanogen insect amide mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose, and dosage reduces than single dose.
Embodiment 4 (70% flufenoxuron chlorine fluorine cyanogen insect amide water-dispersible granules)
Be kaolinic formula by flufenoxuron 55%, chlorine fluorine cyanogen insect amide 15%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus, each component carried out dry pulverization process, granulation, drying, screening obtained 70% flufenoxuron chlorine fluorine cyanogen insect amide water-dispersible granules afterwards.
70% obtained flufenoxuron chlorine fluorine cyanogen insect amide water-dispersible granules is used for cabbage pieris control.70% flufenoxuron chlorine fluorine cyanogen insect amide water-dispersible granules is contained at cabbage caterpillar low instar larvae the phase of sending out by the amount of 10 grams/acre and is watered even spraying, and after medicine, the preventive effect of 7 days and 14 days is respectively 91.8% and 95.7%.By same method dispenser, contrast single dose 50 grams per liter flufenoxuron dispersible agent (formulation rate is 15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), after medicine, the preventive effect of 7 days is respectively 81.6% and 84.2%, and after medicine, the preventive effect of 14 days is respectively 82.8% and 86.4%.After flufenoxuron and chlorine fluorine cyanogen insect amide mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 5 (40% flufenoxuron chlorine fluorine cyanogen insect amide wetting powder)
Be kaolinic formula by flufenoxuron 35%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus, each component carried out dry pulverization process, granulation, drying, screening obtained 40% flufenoxuron chlorine fluorine cyanogen insect amide wetting powder afterwards.
40% obtained flufenoxuron chlorine fluorine cyanogen insect amide wetting powder is used for cabbage pieris control.40% flufenoxuron chlorine fluorine cyanogen insect amide wetting powder is watered even spraying by the amount of 10 grams/acre at cabbage caterpillar low instar larvae occurrence in peak period, and after medicine, the preventive effect of 7 days and 14 days is respectively 92.5% and 94.7%.By same method dispenser, contrast single dose 50 grams per liter flufenoxuron dispersible agent (formulation rate is 15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), after medicine, the preventive effect of 7 days is respectively 72.7% and 81.9%, and after medicine, the preventive effect of 14 days is respectively 73.7% and 83.6%.After flufenoxuron and chlorine fluorine cyanogen insect amide mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 6 (20% flufenoxuron chlorine fluorine cyanogen insect amide oil suspending agent)
By the formula of flufenoxuron 15%, chlorine fluorine cyanogen insect amide 5%, castor oil polyoxyethylene ether 13%, tristyrylphenol polyoxyethylene ether phosphate 3%, organobentonite 1%, methyl oleate benefit to 100%, each component is mixed, after sand milling to certain particle diameter, obtains 20% flufenoxuron chlorine fluorine cyanogen insect amide oil suspending agent.
20% obtained flufenoxuron chlorine fluorine cyanogen insect amide oil suspending agent is used for grasshoppers control.20% flufenoxuron chlorine fluorine cyanogen insect amide oil suspending agent is watered even spraying by the amount of 10 grams/acre in the egg hatching phase of containing, and after medicine, 3 days and 7 days preventive effects are respectively 85.2% and 89.6%.By same method dispenser, contrast single dose 50 grams per liter flufenoxuron dispersible agent (formulation rate is 15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), after medicine, the preventive effect of 3 days is respectively 73.1% and 59.8%, and after medicine, the preventive effect of 7 days is 78.2% and 65.5%.After flufenoxuron and chlorine fluorine cyanogen insect amide mixture, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 7 (20% flufenoxuron chlorine fluorine cyanogen insect amide missible oil)
Be the formula of dimethylbenzene by flufenoxuron 15%, chlorine fluorine cyanogen insect amide 5%, calcium dodecyl benzene sulfonate 6%, triphen ethyl phenol APEO 6%, NMP 8%, surplus, 20% flufenoxuron chlorine fluorine cyanogen insect amide missible oil will be obtained after each component mixing and stirring.
20% obtained flufenoxuron chlorine fluorine cyanogen insect amide missible oil is used for cotton cotton bollworm control.20% flufenoxuron chlorine fluorine cyanogen insect amide missible oil is watered even spraying by the amount of 10 grams/acre at larva occurance peak, and after medicine, the preventive effect of 3 days and 7 days is respectively 95.9% and 96.8%.By same method dispenser, contrast single dose 50 grams per liter flufenoxuron dispersible agent (formulation rate is 15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), after medicine, the preventive effect of 3 days is respectively 75.7% and 81.8%, and after medicine, the preventive effect of 7 days is 79.2% and 85.7%.After flufenoxuron and chlorine fluorine cyanogen insect amide mixture, synergistic effect is obvious, and preventive effect is better than single dose.
Claims (8)
1., for a Pesticidal combination for pest, it is characterized in that described Pesticidal combination is containing flufenoxuron and chlorine fluorine cyanogen insect amide, and the weight ratio of flufenoxuron and chlorine fluorine cyanogen insect amide is 1 ~ 50:20 ~ 1.
2., according to Pesticidal combination according to claim 1, it is characterized in that the weight ratio of described flufenoxuron and chlorine fluorine cyanogen insect amide is 1 ~ 10:10 ~ 1.
3., according to Pesticidal combination according to claim 2, it is characterized in that the weight ratio of described flufenoxuron and chlorine fluorine cyanogen insect amide is 1 ~ 5:5 ~ 1.
4. for an insecticide for pest, it is characterized in that described insecticide by weight containing 5 ~ 90% Pesticidal combination, all the other are agriculturally acceptable carrier and auxiliary agent.
5., according to the insecticide for pest according to claim 4, it is characterized in that described insecticide contains the Pesticidal combination of 5 ~ 40% by weight.
6., according to the insecticide for pest according to claim 4, it is characterized in that described insecticide is missible oil, oil suspending agent, suspending agent, wetting powder or water dispersible granules.
7., according to Pesticidal combination according to claim 1, it is characterized in that described Pesticidal combination is for pest control, described insect comprises two spotted spider mite, leaf roller, cabbage caterpillar, cotton bollworm and locust.
8., according to Pesticidal combination according to claim 7, it is characterized in that described Pesticidal combination is for preventing and treating the insect in fruit and vegetables.
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| CN106577709A (en) * | 2015-10-20 | 2017-04-26 | 浙江省化工研究院有限公司 | Pesticide compound containing cyhalodiamide and hexaflumuron |
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