CN102504637A - Unsaturated polyester putty for automobile repair - Google Patents
Unsaturated polyester putty for automobile repair Download PDFInfo
- Publication number
- CN102504637A CN102504637A CN2011103850517A CN201110385051A CN102504637A CN 102504637 A CN102504637 A CN 102504637A CN 2011103850517 A CN2011103850517 A CN 2011103850517A CN 201110385051 A CN201110385051 A CN 201110385051A CN 102504637 A CN102504637 A CN 102504637A
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- CN
- China
- Prior art keywords
- parts
- powder
- white carbon
- unsaturated polyester
- following component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 230000008439 repair process Effects 0.000 title claims abstract description 11
- 229920006305 unsaturated polyester Polymers 0.000 title abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000006229 carbon black Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 16
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 10
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 9
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000010941 cobalt Substances 0.000 claims abstract description 8
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 8
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 claims abstract description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 3
- 235000019241 carbon black Nutrition 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 13
- CDULGHZNHURECF-UHFFFAOYSA-N 2,3-dimethylaniline 2,4-dimethylaniline 2,5-dimethylaniline 2,6-dimethylaniline 3,4-dimethylaniline 3,5-dimethylaniline Chemical group CC1=CC=C(N)C(C)=C1.CC1=CC=C(C)C(N)=C1.CC1=CC(C)=CC(N)=C1.CC1=CC=C(N)C=C1C.CC1=CC=CC(N)=C1C.CC1=CC=CC(C)=C1N CDULGHZNHURECF-UHFFFAOYSA-N 0.000 claims description 8
- 238000007605 air drying Methods 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 7
- 239000001038 titanium pigment Substances 0.000 claims description 7
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 claims description 6
- -1 cyclohexanone peroxides Chemical class 0.000 claims description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexyloxide Natural products O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 5
- 229960000892 attapulgite Drugs 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- DSCFFEYYQKSRSV-UHFFFAOYSA-N 1L-O1-methyl-muco-inositol Natural products COC1C(O)C(O)C(O)C(O)C1O DSCFFEYYQKSRSV-UHFFFAOYSA-N 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- XESZUVZBAMCAEJ-UHFFFAOYSA-N 4-tert-butylcatechol Chemical compound CC(C)(C)C1=CC=C(O)C(O)=C1 XESZUVZBAMCAEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005498 polishing Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses unsaturated polyester putty for automobile repair, which comprises base stock and curing agent. The base stock comprises, by weight, 100 parts of air-dry unsaturated polyester resin, 0.5-1 part of cobalt iso-octoate, 5-7 parts of dimethylaniline, 0.8-1.0 part of 4-tert-butylcatechol, 6-8 parts of white carbon black, 8-10 parts of titanium dioxide, 45-55 parts of -325-mesh pulvistalci, 25-35 parts of -325-mesh diatomite powder, 3-5 parts of gaseous SiO2 powder, 8-10 parts of palygouskite, and 0.5-1 part of ultramarine. The curing agent comprises, by weight, 35-45 parts of cyclohexanone peroxide, 35-45 parts of benzoyl peroxide, 2-3 parts of acetone, and 13-15 parts of white carbon black.
Description
Technical field
The present invention relates to chemical field, particularly a kind of motor vehicle repair is with the atom ash.
Background technology
The formal name of atom ash is called polymerization putty, i.e. unsaturated polyester resin putty.Unique advantages such as solidifying fast because of it has, be prone to polishing, organic solvent discharging is few, bonding strength by force, does not ftracture becomes at present that research both at home and abroad is very active, development is exceedingly fast, ideal material for repairing comparatively.Be widely used in automobile making, machinery, shipbuilding, locomotive, vehicle manufacturing, repairing trades.The atom ash is a kind of Compositional type product; Be made up of host and solidifying agent two portions, host is generally formed through mix, grinding by unsaturated polyester resin, color stuffing, promotor (like cobalt naphthenate, xylidine) and thixotropic agent (like aerosil, organobentonite).Solidifying agent is made up of organo-peroxide (like cyclohexanone peroxide, methylethyl ketone peroxide etc.), pigment.The atom ash of excellent property should have the multinomial performances such as grinability, thermotolerance and stability in storage of good air-drying property, snappiness and shock-resistance, excellence.
Compare with traditional oil putty; The atom ash have can thickly be coated with, normal temperature fast setting, strong adhesion, advantage such as be prone to polish, do not ftracture, and it does not contain volatile solvent, can 100% participates in curing; Can also regulate curing speed with solidifying agent, the fast setting film forming.In the time of 1h, just can polish, paint, receive the great kindness of domestic and international auto vendor and machinofacture producer deeply.
Abroad, the production of atom ash starts from the mid-1970s, and the eighties, the atom ash was just applied rapidly in the automotive industry of developed country.Now, " GG " board atom ash of producing with Japanese Kansai Paint Co., Ltd is the most famous.China took up to carry out development and the trial production that the atom ash domesticizes in the latter stage eighties, had obtained significant effect.Particularly in recent years between, constantly enlarges and increase in the application and the alternative import volume of automobile, but that homemade atom ash solidifies back hardness is bigger; Be difficult to polishing, shrinking percentage is also high, causes the coating easy of crack and peels off; And production technique is unstable, has influenced the quality and the use properties of homemade atom ash.
Summary of the invention
To the deficiency of prior art, one of the object of the invention is to provide a kind of motor vehicle repair with the atom ash.
For realizing above-mentioned purpose, the technical scheme that the present invention adopts is following:
A kind of motor vehicle repair is with the atom ash, and described atom ash is made up of base-material and the two components of solidifying agent, and wherein base-material is made up of following component in weight part; 100 parts of air drying type unsaturated polyester resins, cobalt iso-octoate 0.5-1 part, xylidine 5-7 part; T-butyl catechol 0.8-1.0 part, WHITE CARBON BLACK 6-8 part, white titanium pigment 8-10 part;-325 order talcum powder 45-55 parts ,-325 order diatomite in powder 25-35 parts, gas phase SiO
2Powder 3-5 part, protruding Attapulgite 8-10 part, ultramarine 0.5-1 part, wherein solidifying agent is made up of following component in weight part: be cyclohexanone peroxide 35-45 part, Lucidol 35-45 part, acetone 2-3 part, WHITE CARBON BLACK 13-15 part.
Preferably, wherein base-material is made up of following component in weight part, 100 parts of air drying type unsaturated polyester resins, 0.8 part of cobalt iso-octoate; 6 parts of xylidines, 0.9 part of t-butyl catechol, 7 parts of WHITE CARBON BLACKs, 9 parts of white titanium pigments; 50 parts of-325 order talcum powder, 30 parts of-325 order diatomites in powder, gas phase SiO
24 parts in powder, 9 parts of protruding Attapulgites, 0.8 part in ultramarine, wherein solidifying agent is made up of following component in weight part: be 40 parts of cyclohexanone peroxides, 40 parts of Lucidols, 2.5 parts in acetone, 14 parts of WHITE CARBON BLACKs.
Beneficial effect of the present invention is:
1) on the bases of a large amount of experiments,, cooperate protruding Attapulgite to solve in the prior art that people want to solve for a long time and unsolved intensity height causes the contradiction that snappiness is poor, grinability is also poor through selecting-325 order talcum powder and the combination of-325 zeyssatite for use.The collocation of above-mentioned filler has realized raising intensity, improves snappiness, is prone to the effect of polishing.
2) intensity, sticking power after atom ash of the present invention solidifies obviously are superior to prior art products, and do effective soon.
Embodiment
Embodiment one
A kind of motor vehicle repair is with the atom ash, and described atom ash is made up of base-material and the two components of solidifying agent, and wherein base-material is made up of following component in weight part; 100 parts of air drying type unsaturated polyester resins, 0.5 part of cobalt iso-octoate, 7 parts of xylidines; 0.8 part of t-butyl catechol, 8 parts of WHITE CARBON BLACKs, 8 parts of white titanium pigments; 55 parts of-325 order talcum powder, 25 parts of-325 order diatomites in powder, gas phase SiO
25 parts in powder, 8 parts of protruding Attapulgites, 1 part in ultramarine, wherein solidifying agent is made up of following component in weight part: be 35 parts of cyclohexanone peroxides, 45 parts of Lucidols, 2 parts in acetone, 15 parts of WHITE CARBON BLACKs.
Embodiment two
A kind of motor vehicle repair is with the atom ash, and described atom ash is made up of base-material and the two components of solidifying agent, and wherein base-material is made up of following component in weight part; 100 parts of air drying type unsaturated polyester resins, 1 part of cobalt iso-octoate, 5 parts of xylidines; 1.0 parts of t-butyl catechols, 6 parts of WHITE CARBON BLACKs, 10 parts of white titanium pigments; 45 parts of-325 order talcum powder, 35 parts of-325 order diatomites in powder, gas phase SiO
23 parts in powder, 10 parts of protruding Attapulgites, 0.5 part in ultramarine, wherein solidifying agent is made up of following component in weight part: be 45 parts of cyclohexanone peroxides, 35 parts of Lucidols, 3 parts in acetone, 13 parts of WHITE CARBON BLACKs.
Embodiment three
A kind of motor vehicle repair is with the atom ash, and described atom ash is made up of base-material and the two components of solidifying agent, and wherein base-material is made up of following component in weight part; 100 parts of air drying type unsaturated polyester resins, 0.8 part of cobalt iso-octoate, 6 parts of xylidines; 0.9 part of t-butyl catechol, 7 parts of WHITE CARBON BLACKs, 9 parts of white titanium pigments; 50 parts of-325 order talcum powder, 30 parts of-325 order diatomites in powder, gas phase SiO
24 parts in powder, 9 parts of protruding Attapulgites, 0.8 part in ultramarine, wherein solidifying agent is made up of following component in weight part: be 40 parts of cyclohexanone peroxides, 40 parts of Lucidols, 2.5 parts in acetone, 14 parts of WHITE CARBON BLACKs.
Applicant's statement; The present invention explains detailed process equipment of the present invention and technical process through the foregoing description; But the present invention is not limited to above-mentioned detailed process equipment and technical process, does not mean that promptly the present invention must rely on above-mentioned detailed process equipment and technical process could be implemented.The person of ordinary skill in the field should understand, and to any improvement of the present invention, to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (2)
1. a motor vehicle repair is characterized in that with the atom ash, and described atom ash is made up of base-material and the two components of solidifying agent, and wherein base-material is made up of following component in weight part; 100 parts of air drying type unsaturated polyester resins, cobalt iso-octoate 0.5-1 part, xylidine 5-7 part; T-butyl catechol 0.8-1.0 part, WHITE CARBON BLACK 6-8 part, white titanium pigment 8-10 part;-325 order talcum powder 45-55 parts ,-325 order diatomite in powder 25-35 parts, gas phase SiO
2Powder 3-5 part, protruding Attapulgite 8-10 part, ultramarine 0.5-1 part, wherein solidifying agent is made up of following component in weight part: be cyclohexanone peroxide 35-45 part, Lucidol 35-45 part, acetone 2-3 part, WHITE CARBON BLACK 13-15 part.
2. a kind of motor vehicle repair as claimed in claim 1 is characterized in that with the atom ash wherein base-material is made up of following component in weight part; 100 parts of air drying type unsaturated polyester resins, 0.8 part of cobalt iso-octoate, 6 parts of xylidines; 0.9 part of t-butyl catechol, 7 parts of WHITE CARBON BLACKs, 9 parts of white titanium pigments; 50 parts of-325 order talcum powder, 30 parts of-325 order diatomites in powder, gas phase SiO
24 parts in powder, 9 parts of protruding Attapulgites, 0.8 part in ultramarine, wherein solidifying agent is made up of following component in weight part: be 40 parts of cyclohexanone peroxides, 40 parts of Lucidols, 2.5 parts in acetone, 14 parts of WHITE CARBON BLACKs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110385051.7A CN102504637B (en) | 2011-11-28 | 2011-11-28 | Unsaturated polyester putty for automobile repair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110385051.7A CN102504637B (en) | 2011-11-28 | 2011-11-28 | Unsaturated polyester putty for automobile repair |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102504637A true CN102504637A (en) | 2012-06-20 |
| CN102504637B CN102504637B (en) | 2014-08-06 |
Family
ID=46216774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110385051.7A Expired - Fee Related CN102504637B (en) | 2011-11-28 | 2011-11-28 | Unsaturated polyester putty for automobile repair |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102504637B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103756394A (en) * | 2014-01-02 | 2014-04-30 | 河南科技大学 | Nano modified high temperature resisting unsaturated polyester putty filling material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04198369A (en) * | 1990-11-28 | 1992-07-17 | Process Planning Kk | Putty composition |
| CN1145384A (en) * | 1995-09-13 | 1997-03-19 | 西安近代化学研究所 | High-strength quick-drying putty |
-
2011
- 2011-11-28 CN CN201110385051.7A patent/CN102504637B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04198369A (en) * | 1990-11-28 | 1992-07-17 | Process Planning Kk | Putty composition |
| CN1145384A (en) * | 1995-09-13 | 1997-03-19 | 西安近代化学研究所 | High-strength quick-drying putty |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103756394A (en) * | 2014-01-02 | 2014-04-30 | 河南科技大学 | Nano modified high temperature resisting unsaturated polyester putty filling material and preparation method thereof |
| CN103756394B (en) * | 2014-01-02 | 2016-01-13 | 河南科技大学 | A kind of nano modification HIGH-TEMPERATURE RESISTANT PUT-TY packing material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102504637B (en) | 2014-08-06 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Li Xinying Inventor before: Lu Qiyuan |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170523 Address after: Xiongxian Zan Gang Zhen Duan Gang Cun 071800 Hebei city in Baoding province 4 Group No. 065 Patentee after: Li Xinying Address before: 239361 Chuzhou, Tianchang, Datong Town, Ping Qiao Road, No. 88, No. Patentee before: Tianchang City Tongtian Chemical Co.,Ltd. |
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| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Li Xinying Inventor after: Xiao Wei Inventor before: Li Xinying |
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| TR01 | Transfer of patent right | ||
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Effective date of registration: 20171016 Address after: Xiongxian Zan Gang Zhen Duan Gang Cun 071800 Hebei city in Baoding province 4 Group No. 065 Co-patentee after: Xiao Wei Patentee after: Li Xinying Address before: Xiongxian Zan Gang Zhen Duan Gang Cun 071800 Hebei city in Baoding province 4 Group No. 065 Patentee before: Li Xinying |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140806 Termination date: 20171128 |