JPH04198369A - Putty composition - Google Patents
Putty compositionInfo
- Publication number
- JPH04198369A JPH04198369A JP32308990A JP32308990A JPH04198369A JP H04198369 A JPH04198369 A JP H04198369A JP 32308990 A JP32308990 A JP 32308990A JP 32308990 A JP32308990 A JP 32308990A JP H04198369 A JPH04198369 A JP H04198369A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- pts
- acid
- agent containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000003085 diluting agent Substances 0.000 claims abstract description 8
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 7
- 150000007519 polyprotic acids Polymers 0.000 claims abstract description 6
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 6
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 claims description 5
- 239000000463 material Substances 0.000 abstract description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 abstract description 7
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract description 6
- 239000004033 plastic Substances 0.000 abstract description 6
- 239000000454 talc Substances 0.000 abstract description 4
- 229910052623 talc Inorganic materials 0.000 abstract description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004342 Benzoyl peroxide Substances 0.000 abstract description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract description 3
- 239000001361 adipic acid Substances 0.000 abstract description 3
- 235000011037 adipic acid Nutrition 0.000 abstract description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract description 3
- 239000001530 fumaric acid Substances 0.000 abstract description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 abstract description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 abstract description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract description 2
- 229920006305 unsaturated polyester Polymers 0.000 abstract description 2
- 239000005977 Ethylene Substances 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000002075 main ingredient Substances 0.000 description 6
- 239000004575 stone Substances 0.000 description 5
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- -1 ethyl β-hydroxyacrylate Chemical compound 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 230000005856 abnormality Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- SMNNDVUKAKPGDD-UHFFFAOYSA-N 2-butylbenzoic acid Chemical group CCCCC1=CC=CC=C1C(O)=O SMNNDVUKAKPGDD-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- PDXRQENMIVHKPI-UHFFFAOYSA-N cyclohexane-1,1-diol Chemical compound OC1(O)CCCCC1 PDXRQENMIVHKPI-UHFFFAOYSA-N 0.000 description 1
- WMVRXDZNYVJBAH-UHFFFAOYSA-N dioxoiron Chemical compound O=[Fe]=O WMVRXDZNYVJBAH-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000012812 general test Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- ABMSPIUYLYKRLM-UHFFFAOYSA-N styrene hydrobromide Chemical compound Br.C=CC1=CC=CC=C1 ABMSPIUYLYKRLM-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、パテ組成物に関し、更に詳細には車輌用、建
築用等に使用可能であり、特にプラスチック材料及びア
ルミニウム等に対して優れた密着性等を有するパテ組成
物に関する。[Detailed Description of the Invention] <Industrial Application Field> The present invention relates to a putty composition, and more specifically, it can be used for vehicles, architecture, etc., and is particularly effective for plastic materials, aluminum, etc. The present invention relates to a putty composition having adhesive properties and the like.
〈従来の技術〉
従来、車輌用、建築用等に用いられるパテとしては、硝
化綿糸、アクリル系、アミノアルキッド系、ウレタン系
、不飽和ポリエステル系等を主剤とする組成物が種々提
案されており、様々な適応箇所に応じて使いわけられて
いる。<Prior art> Various compositions based on nitrified cotton thread, acrylic type, aminoalkyd type, urethane type, unsaturated polyester type, etc. have been proposed as putty used for vehicles, construction, etc. , are used depending on the various applications.
また近年、特に自動車、建築物等の材料として。In recent years, it has also been used as a material for automobiles, buildings, etc.
プラスチック材料及びアルミニウム材料等が多用される
ようになってきており、これらの材料の補修等に適する
パテの開発が要求されている。Plastic materials, aluminum materials, and the like have come into widespread use, and there is a demand for the development of putty suitable for repairing these materials.
しかしながら、従来提案され実施されているパテでは、
前記プラスチック材料及びアルミニウム材料等に対する
密着性が不十分であり、しかも、耐衝撃性、耐候性等に
問題が生じ、実用化されていないのが現状である。However, with the putty that has been proposed and implemented in the past,
At present, it has insufficient adhesion to the plastic materials, aluminum materials, etc., and also has problems with impact resistance, weather resistance, etc., and has not been put into practical use.
〈発明が解決しようとする課題〉
従って、本発明の目的は、プラスチック材料及びアルミ
ニウム材料に対しても優れた密着性を有し、且つ得られ
る硬化物が優れた耐衝撃性、耐オゾン性、耐候性等を有
するパテ組成物を提供することにある。<Problems to be Solved by the Invention> Therefore, an object of the present invention is to provide a cured product that has excellent adhesion to plastic materials and aluminum materials, and that the resulting cured product has excellent impact resistance, ozone resistance, An object of the present invention is to provide a putty composition having weather resistance.
〈課題を解決するための手段〉
本発明によれば、α、β−エチレン系不飽和ジカルボン
酸、飽和多塩基酸及び多価アルコールを重量比で1:2
〜4:3〜5の範囲で配合してなる必須成分を含む原料
成分を反応させて得られる不飽和ポリエステル樹脂(A
)100重量部に対して、重合性希釈剤(B)20〜6
0重量部及び充填剤(C)200〜250重量部を含有
する主剤と、有機過酸化物(D)を含む硬化剤とからな
ることを特徴とするパテ組成物が提供される。<Means for Solving the Problems> According to the present invention, α, β-ethylenically unsaturated dicarboxylic acid, saturated polybasic acid, and polyhydric alcohol are mixed in a weight ratio of 1:2.
~4: Unsaturated polyester resin (A
) 20 to 6 parts by weight of polymerizable diluent (B) per 100 parts by weight
There is provided a putty composition comprising a main ingredient containing 0 parts by weight and 200 to 250 parts by weight of a filler (C), and a curing agent containing an organic peroxide (D).
以下本発明を更に詳細に説明する。The present invention will be explained in more detail below.
本発明のパテ組成物は、特定の不飽和ポリエステル樹脂
(A)100重量部に対して、重合性希釈剤(B)及び
充填剤(C)を特定の配合割合で含有する主剤と、特定
の硬化剤とからなることを特徴とする。The putty composition of the present invention comprises a main ingredient containing a polymerizable diluent (B) and a filler (C) in a specific proportion to 100 parts by weight of a specific unsaturated polyester resin (A), and a specific unsaturated polyester resin (A). It is characterized by consisting of a curing agent.
本発明において用いる不飽和ポリエステル樹脂(A)は
、α、β−エチレン系不飽和ジカルボン酸、飽和多塩基
酸及び多価アルコールを特定割合で配合してなる必須成
分を含む原料成分を反応させて得られる樹脂であって、
好ましくは重量平均分子量1000〜10000、特に
好ましくは2000〜5000の樹脂である。前記α、
β−エチレン系不飽和ジカルボン酸としては、例えばフ
マル酸、無水マレイン酸、マレイン酸、イタコン酸等を
好ましく挙げることができ、使用に際しては単独若しく
は混合物として用いることができる。また前記飽和多塩
基酸としては、例えば無水フタル酸、フタル酸、アジピ
ン酸、イソフタル酸、テレフタル酸、セパチン酸、トリ
メリット酸、ピロメリット酸、テトラヒドロ無水フタル
酸、安息香酸、パラターシャリブチル安息香酸、3,6
−ニンドメチレンテトラヒドロ無水フタル酸、グルタル
酸等を好ましく挙げることができ、使用に際しては単独
若しくは混合物として用いることができる。更に前記多
価アルコールとしては、例え4fエチレングリコール、
プロピレングリコール、ジエチレングリコール、トリエ
チレングリコール、ジプロピレングリコール、1,3−
ブタンジオール、1,6−ヘキサンジオール、1,4−
シクロヘキサンジオール、ネオペンチルグリコール、グ
リセリン、トリメチロールプロパン、トリメチロールエ
タン、ペンタエリスリトール、ソルビトール、水素添加
ビスフェノールA、ポリブタジェングリコール等を好ま
しく挙げることができ、使用に際しては単独若しくは混
合物として用いることができる。The unsaturated polyester resin (A) used in the present invention is made by reacting raw material components containing essential components made by blending α, β-ethylenically unsaturated dicarboxylic acid, saturated polybasic acid, and polyhydric alcohol in specific proportions. A resin obtained,
Preferably, the resin has a weight average molecular weight of 1,000 to 10,000, particularly preferably 2,000 to 5,000. Said α,
Preferred examples of the β-ethylenically unsaturated dicarboxylic acid include fumaric acid, maleic anhydride, maleic acid, and itaconic acid, which can be used alone or as a mixture. Examples of the saturated polybasic acids include phthalic anhydride, phthalic acid, adipic acid, isophthalic acid, terephthalic acid, cepatic acid, trimellitic acid, pyromellitic acid, tetrahydrophthalic anhydride, benzoic acid, and paratertiary butylbenzoic acid. acid, 3,6
-Nindomethylenetetrahydrophthalic anhydride, glutaric acid and the like can be preferably mentioned, and they can be used alone or as a mixture. Further, examples of the polyhydric alcohol include 4f ethylene glycol,
Propylene glycol, diethylene glycol, triethylene glycol, dipropylene glycol, 1,3-
Butanediol, 1,6-hexanediol, 1,4-
Preferred examples include cyclohexanediol, neopentyl glycol, glycerin, trimethylolpropane, trimethylolethane, pentaerythritol, sorbitol, hydrogenated bisphenol A, and polybutadiene glycol, which can be used alone or as a mixture. .
前記不飽和ポリエステル樹脂の必須成分であるα、β−
エチレン系不飽和ジカルボン酸、飽和多塩基酸及び多価
アルコールの配合割合は、重量比で1:2〜4:3〜5
の範囲であり、好ましくは1:2.8〜3.3:3.8
〜4.3の範囲が望ましい。α, β- which are essential components of the unsaturated polyester resin
The mixing ratio of ethylenically unsaturated dicarboxylic acid, saturated polybasic acid, and polyhydric alcohol is 1:2 to 4:3 to 5 by weight.
The range is preferably 1:2.8 to 3.3:3.8
A range of ~4.3 is desirable.
前記不飽和ポリエステル樹脂を調製するには、例えば各
原料成分を混合し、公知の方法で具体的には、反応温度
100〜240℃で0.5〜15時間程時間熱重合する
ことにより得ることができる。In order to prepare the unsaturated polyester resin, for example, each raw material component is mixed and thermally polymerized by a known method, specifically, at a reaction temperature of 100 to 240°C for about 0.5 to 15 hours. I can do it.
本発明に用いる重合性希釈剤(B)は、前記不飽和ポリ
エステル樹脂(A)を溶解し、且つ架橋剤として作用す
る成分であって、例えばスチレン、クロルスチレン、ジ
ビニルベンゼン、ターシャリブチルスチレン、臭化スチ
レン、ジアリルフタレート、メタクリル酸メチル、メタ
クリル酸エチル、メタクリル酸ブチル、メタクリル酸イ
ソブチル、アクリル酸エチル、アクリル酸ブチル、アク
リル酸、β−ヒドロキシメタクリル酸エチル、β−ヒド
ロキシアクリル酸エチル等を好ましく挙げることができ
、使用に際しては単独若しくは混合物として用いること
ができる。前記重合性希釈剤(B)の主剤中における配
合割合は、不飽和ポリエステル樹脂(A)100重量部
に対して20〜60重量部の範囲であり、好ましくは3
0〜40重量部の範囲である。The polymerizable diluent (B) used in the present invention is a component that dissolves the unsaturated polyester resin (A) and acts as a crosslinking agent, such as styrene, chlorostyrene, divinylbenzene, tert-butylstyrene, Styrene bromide, diallyl phthalate, methyl methacrylate, ethyl methacrylate, butyl methacrylate, isobutyl methacrylate, ethyl acrylate, butyl acrylate, acrylic acid, ethyl β-hydroxymethacrylate, ethyl β-hydroxyacrylate, etc. are preferred. They can be used alone or as a mixture. The blending ratio of the polymerizable diluent (B) in the main resin is in the range of 20 to 60 parts by weight, preferably 3 parts by weight, based on 100 parts by weight of the unsaturated polyester resin (A).
The range is 0 to 40 parts by weight.
本発明において用いる充填剤(C)としては、例えばタ
ルク、酸化チタン、炭酸カルシウム、カオリン、クレー
、マイカ、微粉シリカ、アルミナ、硫酸バリウム、石膏
、パーライト、カーボンブラック、グラファイト、シア
ニンブルー、クロムイエロー、ウオッチングレッド、ベ
ンガラ、アニリンブラック、マンガンブルー、鉄黒、ウ
ルトラマリンブルー、ハンザレッド、クロムイニロー、
クロムグリーン、ステアリン酸亜鉛等の体質顔料及び顔
料等を好ましく挙げることができ、特に自動車補修用等
に用いる場合には、タルクを含有させるのが望ましい。Examples of the filler (C) used in the present invention include talc, titanium oxide, calcium carbonate, kaolin, clay, mica, finely divided silica, alumina, barium sulfate, gypsum, perlite, carbon black, graphite, cyanine blue, chrome yellow, Watching Red, Red Garla, Aniline Black, Manganese Blue, Iron Black, Ultramarine Blue, Hansa Red, Chrome Inirow,
Preferable examples include extender pigments and pigments such as chrome green and zinc stearate. In particular, when used for automobile repair, it is desirable to include talc.
前記充填剤(C)の主剤中における配合割合は、不飽和
ポリエステル樹脂(A)100重量部に対して、200
〜250重量部の範囲であり、好ましくは215〜23
0重量部の範囲である。また前記充填剤(C)は必要に
応じて後述する硬化剤に配合させることもできる。The blending ratio of the filler (C) in the main resin is 200 parts by weight per 100 parts by weight of the unsaturated polyester resin (A).
-250 parts by weight, preferably 215-23 parts by weight
It is in the range of 0 parts by weight. Further, the filler (C) can be added to a curing agent to be described later, if necessary.
本発明において、硬化剤成分として含有される有機過酸
化物(D)は、特に限定されるものではなく、公知の例
えば過酸化ベンゾイル、パーオキサイド等を用いること
ができる。また、硬化剤の貯蔵安定性及び取扱上の安全
性の点から、該有機過酸化物(D)に例えばジイソブチ
ルフタレート等の有機溶剤を添加することもでき、更に
は二三酸化鉄、シリカ等の無機成分を添加することもで
きる。該有機溶剤を使用する際の配合割合は、有−接遇
酸化物(D)100重量部に対して、50〜110重量
部、特に55〜70重量部の範囲が好ましく、また無機
成分の使用量は、0〜50重量部の範囲が望ましい。In the present invention, the organic peroxide (D) contained as a curing agent component is not particularly limited, and known examples such as benzoyl peroxide and peroxide can be used. In addition, from the viewpoint of storage stability and handling safety of the curing agent, an organic solvent such as diisobutyl phthalate may be added to the organic peroxide (D), and furthermore, iron dioxide, silica, etc. may be added to the organic peroxide (D). It is also possible to add other inorganic ingredients. The blending ratio when using the organic solvent is preferably in the range of 50 to 110 parts by weight, particularly 55 to 70 parts by weight, based on 100 parts by weight of the oxidized oxide (D). The amount is preferably in the range of 0 to 50 parts by weight.
本発明のパテ組成物においては、前記各成分の他に通常
使用されている硬化促進剤、遅延剤、硬化促進助剤等を
必要に応じて適宜含有させることができる。In the putty composition of the present invention, in addition to the above-mentioned components, commonly used curing accelerators, retarders, curing accelerating aids, etc. can be appropriately contained as necessary.
本発明のパテ組成物を調製するには、使用時に前記主剤
と硬化剤とを例えばニーダ−等により、好ましくは0.
5〜3分間程度混合し、予めサンドペーパー等により表
面処理した被塗物に所望の形状となるように付着させた
後、常温(20℃程度)で10〜30分間自然乾燥等を
行うことによって得ることができる。この際主剤と硬化
剤との配合割合は、重量比で1:0.03〜0.1、特
に好ましくは1:0.4〜0.7の範囲であるのが好ま
しい。In order to prepare the putty composition of the present invention, at the time of use, the main ingredient and the curing agent are mixed, for example, in a kneader or the like, preferably at a 0.
After mixing for about 5 to 3 minutes and applying it to the object to be coated, whose surface has been previously treated with sandpaper, etc., in the desired shape, the mixture is naturally dried for 10 to 30 minutes at room temperature (about 20°C). Obtainable. In this case, it is preferable that the blending ratio of the main ingredient and the curing agent is in the range of 1:0.03 to 0.1, particularly preferably 1:0.4 to 0.7 in terms of weight ratio.
〈発明の効果〉
本発明のパテ組成物は、特定の不飽和ポリエステル樹脂
(A)と重合性希釈剤(B)と充填剤(C)とを特定割
合で含有してなる主剤を必須成分として含むので、鉄、
ウレタン等はもとより、従来パテの密着性が十分でなか
った特にプラスチック材料及びアルミニウム材料に対し
ても優れた密着性を有し、且つ得られる硬化体は、永続
的な柔軟性を持ち、特に優れた耐衝撃性、耐オゾン性及
び耐候性等を有する。従って、車輌、建築用における補
修の成形、厚盛り、仕上げ用等に用いるパテとして極め
て有用である。<Effects of the Invention> The putty composition of the present invention has a main ingredient containing a specific unsaturated polyester resin (A), a polymerizable diluent (B), and a filler (C) in specific proportions as an essential component. Contains iron,
It has excellent adhesion not only to urethane, but also to plastic materials and aluminum materials, to which conventional putty has not had sufficient adhesion, and the resulting cured product has permanent flexibility, making it especially excellent. It has excellent impact resistance, ozone resistance, weather resistance, etc. Therefore, it is extremely useful as a putty for repair molding, thickening, finishing, etc. in vehicles and architecture.
〈実施例〉
以下本発明を実施例により更に詳細に説明するが本発明
はこれに限定されるものではない。<Examples> The present invention will be explained in more detail below with reference to Examples, but the present invention is not limited thereto.
失五孤上
撹拌機、温度計、窒素ガス吹込み管を備えたフラスコに
、フタル酸34重量部、フマル酸12重量部、アジピン
酸4重量部、ハイドロキノン0.1重量部及びジエチレ
ングリコール50重量部を仕込み、窒素ガスを導入しな
がら180〜200℃で4時間反応させて、重量平均分
子量3410の不飽和ポリエステル樹脂(A)を得た。In a flask equipped with an overhead stirrer, a thermometer, and a nitrogen gas blowing tube, add 34 parts by weight of phthalic acid, 12 parts by weight of fumaric acid, 4 parts by weight of adipic acid, 0.1 part by weight of hydroquinone, and 50 parts by weight of diethylene glycol. was charged and reacted at 180 to 200°C for 4 hours while introducing nitrogen gas to obtain an unsaturated polyester resin (A) having a weight average molecular weight of 3410.
次いで得られた不飽和ポリエステル樹脂(A)100重
量部と、スチレン35.7重量部と、タルク221.5
重量部とを均一に混合し、主剤を調製した。一方、別に
過酸化ベンゾイル48重量部とジイソブチルフタレート
30重量部と微量のシリカを含む二三酸化鉄22重量部
とをガラス製ビーカー中で混合撹拌し、硬化剤を調製し
た。次いで得られた主剤100重量部と硬化剤5重量部
とを混合し、パテ組成物を製造した後、ポリプロピレン
板(70X150X5mm)及びアルミニウム板(70
X150X5mm)夫々に硬化後の厚さが5mとなるよ
うに付着させ、室温で15分間硬化させ、試験片を作製
した。また試験片の端部をナイフで削って、厚さ2閣の
薄膜部を作製した。Next, 100 parts by weight of the obtained unsaturated polyester resin (A), 35.7 parts by weight of styrene, and 221.5 parts by weight of talc.
Parts by weight were uniformly mixed to prepare a main ingredient. Separately, 48 parts by weight of benzoyl peroxide, 30 parts by weight of diisobutyl phthalate, and 22 parts by weight of triferric oxide containing a trace amount of silica were mixed and stirred in a glass beaker to prepare a curing agent. Next, 100 parts by weight of the obtained main agent and 5 parts by weight of the curing agent were mixed to produce a putty composition, and then a polypropylene plate (70 x 150 x 5 mm) and an aluminum plate (70
x 150 x 5 mm) so that the thickness after curing would be 5 m, and was cured at room temperature for 15 minutes to prepare a test piece. In addition, the end of the test piece was shaved with a knife to prepare a thin film portion with a thickness of 2 mm.
得られた夫々の試験片について耐衝撃試験、密着性試験
、飛石試験、耐オゾン性試験及び促進耐候性試験を行っ
た。試験方法を以下に、また試験結果を表1に示す。Impact resistance tests, adhesion tests, flying stone tests, ozone resistance tests, and accelerated weather resistance tests were conducted on each of the obtained test pieces. The test method is shown below, and the test results are shown in Table 1.
[歇
JIS K5400 8.3,2.r塗料一般試験方
法」に従って行い、割れ及び剥れが生じた高さを結果と
して示す。[JIS K5400 8.3, 2. The height at which cracking and peeling occurred is shown as the result.
11作X監
JIS K5400 8.7 r塗料一般試験方法」
に従って行った。11 Works X Supervision JIS K5400 8.7 r Paint General Test Method”
I followed.
飛石試験
JASo 7320 rブレーキチューブ試験方法」
の5.4に従い、空気圧力1 kg/ad及び4kg/
dで行った。但し砕石の大きさは5〜13III11(
6号砕石)、砕石の使用量250gで行った。Flying stone test JASo 7320 r brake tube test method”
5.4, air pressure 1 kg/ad and 4 kg/ad
I went with d. However, the size of crushed stone is 5-13III11 (
No. 6 crushed stone), and the amount of crushed stone used was 250 g.
結果は薄膜部分(厚さ2m+)及び正常膜部分(厚さ5
mm)とも割れ及び剥れが認められなかったものをOl
わずかに認められたものを△、認められたものをXとし
た。The results are for the thin membrane part (thickness 2m+) and the normal membrane part (thickness 5m).
mm) with no cracks or peeling observed.
Those that were slightly observed were rated △, and those that were slightly observed were rated X.
1tJy作に監
JIS A 6021 5.8.2.r屋根用塗膜
防水剤」により7日間行った。但しオゾン濃度は75±
7.5pphm、温度は40±2℃で行った。結果は、
異常が認められなかったものをOとした。Created and supervised by 1tJy JIS A 6021 5.8.2. The test was carried out for 7 days using "Roof Paint Film Waterproofing Agent". However, the ozone concentration is 75±
The temperature was 7.5 pphm and 40±2°C. Result is,
Those in which no abnormality was observed were rated O.
促n候j」(1
JIS K5400 9.8.1.r塗料一般試験方
法」に従って300時間行った。結果は。The test was conducted for 300 hours in accordance with ``General Test Methods for Paints'' (1 JIS K5400 9.8.1.r).The results are as follows.
異常が認められなかったものをOとした。Those in which no abnormality was observed were rated O.
(以下余白)(Margin below)
Claims (1)
酸及び多価アルコールを重量比で1:2〜4:3〜5の
範囲で配合してなる必須成分を含む原料成分を反応させ
て得られる不飽和ポリエステル樹脂(A)100重量部
に対して、重合性希釈剤(B)20〜60重量部及び充
填剤(C)200〜250重量部を含有する主剤と、 有機過酸化物(D)を含む硬化剤とからなることを特徴
とするパテ組成物。[Claims] A raw material containing essential components made by blending α,β-ethylenically unsaturated dicarboxylic acid, saturated polybasic acid, and polyhydric alcohol in a weight ratio of 1:2 to 4:3 to 5. A base agent containing 20 to 60 parts by weight of a polymerizable diluent (B) and 200 to 250 parts by weight of a filler (C) based on 100 parts by weight of an unsaturated polyester resin (A) obtained by reacting the components; A putty composition comprising a curing agent containing an organic peroxide (D).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP32308990A JPH04198369A (en) | 1990-11-28 | 1990-11-28 | Putty composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP32308990A JPH04198369A (en) | 1990-11-28 | 1990-11-28 | Putty composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04198369A true JPH04198369A (en) | 1992-07-17 |
Family
ID=18150956
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP32308990A Pending JPH04198369A (en) | 1990-11-28 | 1990-11-28 | Putty composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04198369A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102408770A (en) * | 2011-11-28 | 2012-04-11 | 天长市通天化工有限责任公司 | Atomic ash for furniture and decoration |
CN102504637A (en) * | 2011-11-28 | 2012-06-20 | 天长市通天化工有限责任公司 | Unsaturated polyester putty for automobile repair |
CN102504634A (en) * | 2011-11-18 | 2012-06-20 | 天长市通天化工有限责任公司 | Preparation method of flame-retardant putty |
-
1990
- 1990-11-28 JP JP32308990A patent/JPH04198369A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102504634A (en) * | 2011-11-18 | 2012-06-20 | 天长市通天化工有限责任公司 | Preparation method of flame-retardant putty |
CN102504634B (en) * | 2011-11-18 | 2014-08-06 | 天长市通天化工有限责任公司 | Preparation method of flame-retardant putty |
CN102408770A (en) * | 2011-11-28 | 2012-04-11 | 天长市通天化工有限责任公司 | Atomic ash for furniture and decoration |
CN102504637A (en) * | 2011-11-28 | 2012-06-20 | 天长市通天化工有限责任公司 | Unsaturated polyester putty for automobile repair |
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