CN102504633B - Putty with good sanding property - Google Patents
Putty with good sanding property Download PDFInfo
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- CN102504633B CN102504633B CN201110366810.5A CN201110366810A CN102504633B CN 102504633 B CN102504633 B CN 102504633B CN 201110366810 A CN201110366810 A CN 201110366810A CN 102504633 B CN102504633 B CN 102504633B
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 44
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 24
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 13
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 13
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 13
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 12
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 12
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 239000004250 tert-Butylhydroquinone Substances 0.000 claims abstract description 12
- 235000019281 tert-butylhydroquinone Nutrition 0.000 claims abstract description 12
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 5
- CDULGHZNHURECF-UHFFFAOYSA-N 2,3-dimethylaniline 2,4-dimethylaniline 2,5-dimethylaniline 2,6-dimethylaniline 3,4-dimethylaniline 3,5-dimethylaniline Chemical group CC1=CC=C(N)C(C)=C1.CC1=CC=C(C)C(N)=C1.CC1=CC(C)=CC(N)=C1.CC1=CC=C(N)C=C1C.CC1=CC=CC(N)=C1C.CC1=CC=CC(C)=C1N CDULGHZNHURECF-UHFFFAOYSA-N 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000003849 aromatic solvent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000012795 verification Methods 0.000 description 2
- 206010009866 Cold sweat Diseases 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
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- Macromonomer-Based Addition Polymer (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses putty with a good sanding property, which is formed through the hybrid reaction of main agent and curing agent. The mass ratio of the main agent to the curing agent is 100:2; the main agent comprises the following components by part by weight: 56 to 64 parts of unsaturated polyester resin, 4 to 8 parts of phenethylene, 10 to 15 parts of talcum powder, 5 to 8 parts of barium sulphate, 2 to 3 parts of titanium dioxide, 6 to 9 parts of heavy calcium carbonate, 0.5 to 1 parts of tertiary butyl hydroquinone, 1.4 to 1.8 parts of anti-settling agent, and 0.2 to 0.4 part of accelerating agent; and the curing agent comprises the following components by part by weight: 80 to 84 parts of benzoyl peroxide, 5 to 8 parts of pigment, 10 to 12 parts of filling material, and 5 to 6 parts of 10 percent dimethyl aniline.
Description
Technical field
The present invention relates to chemical field, particularly the good atomized ash of a kind of sanding property.
Background technology
Repairing and application bottoming that atomized ash is mainly used in various vehicles, lathe, boats and ships, instrument, meter case and furniture are used, the production technology of current atom ash is mature on the whole, and whether easily polish after atomized ash film forming, become an important indicator evaluating atomized ash manufacturer quality product.
At present, in order to improve the sanding property after atomized ash film forming, many producers have adopted various way: the viscosity that for example reduces unsaturated polyester resin, and the viscosity of reduction resin, risk is higher, easily causes the activity decreased of resin, even atomized ash film forming cracking; What have adds single acid or fumaric acid class material in resin, and sanding property has improved, but easily causes that the atomized ash quality guaranteed period is short, the film formation surface phenomenon such as be clamminess; Also the employing having is fusion alcohol alcohol resin in resin, has improved the sanding property of atomized ash, but can cause having in atomized ash paste cellular, easily causes the suspection of client to quality product.
Chinese patent application publication number be CN101698755 Patent Application Publication a kind of aromatic solvent putty, described aromatic solvent putty each component and content thereof are: (by weight): unsaturated polyester, 34-40 part; Vinylbenzene, 2-8 part; Aromatic solvent, 2-5 part; Light calcium carbonate, 5-8 part; Water-ground limestone, 10-20 part; Talcum powder, 35-55 part; Cobalt iso-octoate, 0.8-2 part; Xylidine, 0.1-0.5 part; Titanium dioxide, 1.5-2.5 part; Wilkinite, 2-5 part.Although claim its sanding property excellence in its patent documentation, through verification experimental verification, its effect is unsatisfactory, still can not meet the demand of every profession and trade.
Summary of the invention
For the deficiencies in the prior art, the atomized ash that provides sanding property good is provided one of object of the present invention, and this atomized ash has advantages of quick-drying and easy blade coating.
For achieving the above object, the technical solution used in the present invention is as follows:
The atomized ash that sanding property is good, is formed by host and solidifying agent hybrid reaction, and the mass ratio of described host and solidifying agent is: 100: 2, wherein this host was made up of following component by weight: unsaturated polyester resin: 56-64 part; Vinylbenzene: 4-8 part; Talcum powder: 10-15 part; Barium sulfate: 5-8 part; Titanium dioxide: 2-3 part; Water-ground limestone: 6-9 part; Tertiarybutylhydroquinone: 0.5-1 part; Anti-settling agent: 1.4-1.8 part; Promotor: 0.2-0.4 part; Wherein this solidifying agent is made up of following component by weight: benzoyl peroxide 80-84 part; Pigment: 5-8 part; Filler: 10-12 part; Promotor: 10% xylidine: 5-6 part.
Preferably, wherein this host is made up of following component by weight: unsaturated polyester resin: 58-62 part; Vinylbenzene: 5-7 part; Talcum powder: 12-14 part; Barium sulfate: 6-7 part; Titanium dioxide: 2.2-2.8 part; Water-ground limestone: 7-8 part; Tertiarybutylhydroquinone: 0.6-0.8 part; Anti-settling agent: 1.5-1.7 part; Promotor: 0.25-0.35 part; Wherein this solidifying agent is made up of following component by weight: benzoyl peroxide 81-83 part; Pigment: 6-7 part; Filler: 10.5-11.5 part; Promotor: 10% xylidine: 5.2-5.8 part.
Most preferably, wherein this host is made up of following component by weight: unsaturated polyester resin: 60 parts; Vinylbenzene: 6 parts; Talcum powder: 13 parts; Barium sulfate: 6.5 parts; Titanium dioxide: 2.5 parts; Water-ground limestone: 7.5 parts; Tertiarybutylhydroquinone: 0.7 part; Anti-settling agent: 1.6 parts; Promotor: 0.3 part; Wherein this solidifying agent is made up of following component by weight: 82 parts of benzoyl peroxides; Pigment: 6.5 parts; Filler: 11 parts; Promotor: 10% xylidine: 5.5 parts.
Beneficial effect of the present invention is:
1) the present invention, by the optimization design to atomized ash each component, makes the content proportioning of each component reach best, thereby obtains the excellent especially technique effect of sanding property, not scab paper when polishing, and after polishing, polishing is level and smooth, without honeycomb.
2) except sanding property excellence, atomized ash normal temperature of the present invention just can be polished for lower about 12 minutes, and therefore its quick-drying performance is good, and blade coating processing ease.
Embodiment
Embodiment mono-
The atomized ash that sanding property is good, is formed by host and solidifying agent hybrid reaction, and the mass ratio of described host and solidifying agent is: 100: 2, wherein this host was made up of following component by weight: unsaturated polyester resin: 56 parts; Vinylbenzene: 8 parts; Talcum powder: 10 parts; Barium sulfate: 8 parts; Titanium dioxide: 2 parts; Water-ground limestone: 9 parts; Tertiarybutylhydroquinone: 0.5 part; Anti-settling agent: 1.8 parts; Promotor: 0.2 part; Wherein this solidifying agent is made up of following component by weight: 80 parts of benzoyl peroxides; Pigment: 8 parts; Filler: 10 parts; Promotor: 10% xylidine: 6 parts.
Embodiment bis-
The atomized ash that sanding property is good, is formed by host and solidifying agent hybrid reaction, and the mass ratio of described host and solidifying agent is: 100: 2, wherein this host was made up of following component by weight: unsaturated polyester resin: 64 parts; Vinylbenzene: 4 parts; Talcum powder: 15 parts; Barium sulfate: 5 parts; Titanium dioxide: 3 parts; Water-ground limestone: 6 parts; Tertiarybutylhydroquinone: 1 part; Anti-settling agent: 1.4 parts; Promotor: 0.4 part; Wherein this solidifying agent is made up of following component by weight: 84 parts of benzoyl peroxides; Pigment: 5 parts; Filler: 12 parts; Promotor: 10% xylidine: 5 parts.
Embodiment tri-
The atomized ash that sanding property is good, is formed by host and solidifying agent hybrid reaction, and the mass ratio of described host and solidifying agent is: 100: 2, wherein this host was made up of following component by weight: unsaturated polyester resin: 58 parts; Vinylbenzene: 7 parts; Talcum powder: 12 parts; Barium sulfate: 7 parts; Titanium dioxide: 2.2 parts; Water-ground limestone: 8 parts; Tertiarybutylhydroquinone: 0.6 part; Anti-settling agent: 1.7 parts; Promotor: 0.25 part; Wherein this solidifying agent is made up of following component by weight: 81 parts of benzoyl peroxides; Pigment: 7 parts; Filler: 10.5 parts; Promotor: 10% xylidine: 5.8 parts.
Embodiment tetra-
The atomized ash that sanding property is good, is formed by host and solidifying agent hybrid reaction, and the mass ratio of described host and solidifying agent is: 100: 2, wherein this host was made up of following component by weight: unsaturated polyester resin: 62 parts; Vinylbenzene: 5 parts; Talcum powder: 14 parts; Barium sulfate: 6 parts; Titanium dioxide: 2.8 parts; Water-ground limestone: 7 parts; Tertiarybutylhydroquinone: 0.8 part; Anti-settling agent: 1.5 parts; Promotor: 0.35 part; Wherein this solidifying agent is made up of following component by weight: 83 parts of benzoyl peroxides; Pigment: 6 parts; Filler: 11.5 parts; Promotor: 10% xylidine: 5.2 parts.
Embodiment five
The atomized ash that sanding property is good, is formed by host and solidifying agent hybrid reaction, and the mass ratio of described host and solidifying agent is: 100: 2, wherein this host was made up of following component by weight: unsaturated polyester resin: 60 parts; Vinylbenzene: 6 parts; Talcum powder: 13 parts; Barium sulfate: 6.5 parts; Titanium dioxide: 2.5 parts; Water-ground limestone: 7.5 parts; Tertiarybutylhydroquinone: 0.7 part; Anti-settling agent: 1.6 parts; Promotor: 0.3 part; Wherein this solidifying agent is made up of following component by weight: 82 parts of benzoyl peroxides; Pigment: 6.5 parts; Filler: 11 parts; Promotor: 10% xylidine: 5.5 parts.
Applicant's statement, the present invention illustrates detailed process equipment and process flow process of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed process equipment and process flow process, do not mean that the present invention must rely on above-mentioned detailed process equipment and process flow process and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, and the selections of the equivalence replacement to the each raw material of product of the present invention and the interpolation of ancillary component, concrete mode etc., within all dropping on protection scope of the present invention and open scope.
Claims (3)
1. the good atomized ash of sanding property, is characterized in that, is formed by host and solidifying agent hybrid reaction, and the mass ratio of described host and solidifying agent is: 100: 2, wherein this host was made up of following component by weight: unsaturated polyester resin: 56-64 part; Vinylbenzene: 5-8 part; Talcum powder: 10-15 part; Barium sulfate: 5-8 part; Titanium dioxide: 2.2-3 part; Water-ground limestone: 6-9 part; Tertiarybutylhydroquinone: 0.5-1 part; Anti-settling agent: 1.4-1.8 part; Promotor: 0.2-0.4 part; Wherein this solidifying agent is made up of following component by weight: benzoyl peroxide 80-84 part; Pigment: 5-8 part; Filler: 10-12 part; Promotor: 10% xylidine: 5-6 part.
2. the good atomized ash of a kind of sanding property as claimed in claim 1, is characterized in that, wherein this host is made up of following component by weight: unsaturated polyester resin: 58-62 part; Vinylbenzene: 5-7 part; Talcum powder: 12-14 part; Barium sulfate: 6-7 part; Titanium dioxide: 2.2-2.8 part; Water-ground limestone: 7-8 part; Tertiarybutylhydroquinone: 0.6-0.8 part; Anti-settling agent: 1.5-1.7 part; Promotor: 0.25-0.35 part; Wherein this solidifying agent is made up of following component by weight: benzoyl peroxide 81-83 part; Pigment: 6-7 part; Filler: 10.5-11.5 part; Promotor: 10% xylidine: 5.2-5.8 part.
3. the good atomized ash of a kind of sanding property as claimed in claim 2, is characterized in that, wherein this host is made up of following component by weight: unsaturated polyester resin: 60 parts; Vinylbenzene: 6 parts; Talcum powder: 13 parts; Barium sulfate: 6.5 parts; Titanium dioxide: 2.5 parts; Water-ground limestone: 7.5 parts; Tertiarybutylhydroquinone: 0.7 part; Anti-settling agent: 1.6 parts; Promotor: 0.3 part; Wherein this solidifying agent is made up of following component by weight: 82 parts of benzoyl peroxides; Pigment: 6.5 parts; Filler: 11 parts; Promotor: 10% xylidine: 5.5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110366810.5A CN102504633B (en) | 2011-11-18 | 2011-11-18 | Putty with good sanding property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110366810.5A CN102504633B (en) | 2011-11-18 | 2011-11-18 | Putty with good sanding property |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102504633A CN102504633A (en) | 2012-06-20 |
| CN102504633B true CN102504633B (en) | 2014-08-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110366810.5A Expired - Fee Related CN102504633B (en) | 2011-11-18 | 2011-11-18 | Putty with good sanding property |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102504633B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109867997A (en) * | 2019-03-29 | 2019-06-11 | 广州雅克化工有限公司 | A kind of high-performance fiber poly-putty base and preparation method thereof |
| CN109867998A (en) * | 2019-03-29 | 2019-06-11 | 广州雅克化工有限公司 | A kind of high-performance elastic poly-putty base and preparation method thereof |
| CN114316548A (en) * | 2021-11-24 | 2022-04-12 | 东莞长盈精密技术有限公司 | Repairing composition and method for repairing shot hole defect of die-cast picture frame |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041751A (en) * | 2006-11-02 | 2007-09-26 | 董善刚 | Highly dynamic cracking resistant type elastic putty |
| CN101525507A (en) * | 2008-03-11 | 2009-09-09 | 陈杰新 | All-purpose alloy environment-friendly atomic ash |
| CN101775245A (en) * | 2010-01-21 | 2010-07-14 | 中华制漆（深圳）有限公司 | Multifunctional putty and preparation method thereof |
-
2011
- 2011-11-18 CN CN201110366810.5A patent/CN102504633B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041751A (en) * | 2006-11-02 | 2007-09-26 | 董善刚 | Highly dynamic cracking resistant type elastic putty |
| CN101525507A (en) * | 2008-03-11 | 2009-09-09 | 陈杰新 | All-purpose alloy environment-friendly atomic ash |
| CN101775245A (en) * | 2010-01-21 | 2010-07-14 | 中华制漆（深圳）有限公司 | Multifunctional putty and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102504633A (en) | 2012-06-20 |
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| C14 | Grant of patent or utility model | ||
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Inventor after: Zou Hu Inventor before: Lu Qiyuan |
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| TR01 | Transfer of patent right |
Effective date of registration: 20170807 Address after: 541001 No. 27, Diecai, Guangxi District, Guilin, Zhongshan North Road Patentee after: Zou Hu Address before: 239361 Chuzhou, Tianchang, Datong Town, Ping Qiao Road, No. 88, No. Patentee before: Tianchang City Tongtian Chemical Co.,Ltd. |
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Effective date of registration: 20170926 Address after: 541001 No. 27, Diecai, Guangxi District, Guilin, Zhongshan North Road Co-patentee after: Long Maoming Patentee after: Zou Hu Co-patentee after: Liu Lili Co-patentee after: Li Huanhuan Co-patentee after: Huang Yanfeng Address before: 541001 No. 27, Diecai, Guangxi District, Guilin, Zhongshan North Road Patentee before: Zou Hu |
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