CN102766368A - Environment-friendly unsaturated polyester putty containing hollow glass beads - Google Patents
Environment-friendly unsaturated polyester putty containing hollow glass beads Download PDFInfo
- Publication number
- CN102766368A CN102766368A CN2012102287308A CN201210228730A CN102766368A CN 102766368 A CN102766368 A CN 102766368A CN 2012102287308 A CN2012102287308 A CN 2012102287308A CN 201210228730 A CN201210228730 A CN 201210228730A CN 102766368 A CN102766368 A CN 102766368A
- Authority
- CN
- China
- Prior art keywords
- parts
- environmental protection
- hollow glass
- atom ash
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to environment-friendly unsaturated polyester putty, which contains hollow glass beads, wherein the particle sizes of the hollow glass beads are 0.01 to 500 micrometers, the density is 0.1 to 1.2 g/cm<3>, and the wall thickness is 6 to 12 percent of the diameter of each hollow glass bead. According to the environment-friendly unsaturated polyester putty, the hollow glass beads are added, and the environment-friendly unsaturated polyester putty with low volatile organic compounds (VOC), good filling effect and high dispersity is obtained by optimizing each component.
Description
Technical field
The present invention relates to a kind of putty, be specifically related to a kind of environmental protection atom ash.
Background technology
Atom ash, the atom ash is claimed unsaturated polyester putty or senior size putty again, is mainly used in automobile, steamer, rolling stock, furniture, dial plate and precision machine tool etc. and fills and leads up processing before spraying paint.Two components that main putty that the atom ash is formed through agitation grinding by material such as unsaturated resin, talcum powder, vinylbenzene and solidifying agent are formed are filled and led up material; Have characteristics such as the fast strong adhesion of ambient cure rate of drying, easy polishing; Be widely used in automobile, locomotive, lathe, the manufacturing of concrete body class buildings and the top coat of repairing, also can be applicable to the exterior finish such as furniture, floor and the helmet, mould product.
The method of use of atom ash is:
1, basic ash and solidifying agent are cooperated, the lower hardener dose of temperature the more;
2, etc. greasy dirt, rust staining, old lacquer and moisture content should thoroughly be removed in the metallic surface that is coated with;
3, atom ash consumption is advisable with disposable using up, and base ash and solidifying agent are joined white silk in proportion, promptly joins completion to the color even unanimity.
CN 102408770A discloses a kind of furniture and finishing is grey with atom, and described atom ash is made up of main body and the two components of solidifying agent, and wherein main body is made up of following component in weight part, air drying type unsaturated polyester resin 70-80 part; Epoxy resin 5-7 part, paracril 0.8-1.2 part, cobalt iso-octoate 3.5-4.5 part; Xylidine 1.5-2.5 part, Resorcinol 0.8-1.0 part, WHITE CARBON BLACK 6-8 part; White titanium pigment 8-10 part, talcum powder 45-55 part, gas phase SiO
2Powder 3-5 part, polynite 8-10 part, permanent white 0.5-1 part, wherein solidifying agent is made up of following component in weight part: be Lucidol 75-85 part, acetone 2-3 part, WHITE CARBON BLACK 15-20 part.
CN 102504642A discloses a kind of plates of automobile with the atom ash; The host of said atom ash is made up of following component in weight part: 100 parts of unsaturated polyester resins; Dimethyl hydroxyethyl Tolylamine 5-7 part, vinylbenzene 1-2 part, tetrafluoroethylene wax 0.8-1.2 part; Resorcinol 0.5-1 part, gas phase SiO
21-2 part, white titanium pigment 4-6 part, hollow glass micropearl 1-2 part, talcum powder 5-8 part, expansion micro mist 5-6 part, initiator by following composition by weight forming: Lucidol 60-70 part, Witcizer 300 25-35 part, silicon-dioxide 2-8 part.
CN 102417749A discloses a kind of environmental protection atom ash, and said atom ash is made up of main body and two kinds of components of solidifying agent, gets final product by weight being main body: solidifying agent=100:2, mixing when using; Said main body is made up of following composition by weight: air drying type water-based unsaturated polyester resin 56-60 part, vinylbenzene 2-5 part, Triethylenetetramine (TETA) 0.5-0.8 part, xylidine 0.8-1.2 part; Polymethylmethacrylate 1.2-1.5 part, BYK-9801.2-1.6 part, dimethylglyoxime 0.01-0.02 part, polyamide wax 0.015-0.025 part; Tegosept M 0.2-0.3 part, hollow glass micropearl 4-8 part, wilkinite 1-3 part, lime carbonate 5-7 part; White titanium pigment 10-15 part, spun glass 1-2 part, permanent white 3-5 part; Solidifying agent by following composition by weight forming: Lucidol 60-64 part, Witcizer 300 20-24 part, silicon-dioxide 4-8 part.
CN 101775245A discloses a kind of multifunctional putty, is formed by host and solidifying agent hybrid reaction, and the mass ratio of said host and solidifying agent is 100:2, and wherein this host comprises following component by weight: unsaturated polyester resin: 25-38%; Dispersion moisture agent: 0.2-1.0%; Talcum powder: 35-45%; Permanent white: 20-30%; Thixotropic agent: 0.1-1.5%; Rutile type Titanium Dioxide: 0.5-2%; Anti-settling agent: 0.1-1%; Vinylbenzene: 2-4%; Stopper: 0.01-0.03%; Promotor: 0.02-0.04%; This solidifying agent comprises by weight: 50% Lucidol.
The main performance index of atom ash has: (1) is strong with the bonding force of metal, more than the sticking power l level, presses GB 9286-88 test; (2) fast drying promptly refers to atom gray surface time of drying and thorough assimilation time, presses the GB1728-79 test; (3) it is good to criticize ash property, freely smooth when referring to criticize grey operation with grey cutter, and sticking cutter is accessible, easy-formation, not crimping; (4) grinability is good, when referring to polish with dry sand paper, has been prone to ash, sticking ash or rare sticking ash on the sand paper, or be prone to polish with waterproof abrasive paper.
The technology content of atom ash is higher; In the existing atom ash; The ubiquity dispersiveness is bad, amalgamation, fillibility are bad, VOC content still is some high drawback, therefore demands developing the environmental protection atom ash that a kind of good dispersivity, amalgamation and fillibility are good and VOC further reduces urgently.
Summary of the invention
To the deficiency of prior art, one of the object of the invention is to provide the environmental protection atom that a kind of good dispersivity, amalgamation and fillibility are good and VOC further reduces ash.
Contain hollow glass micropearl in the environmental protection atom ash of the present invention.
Hollow glass micropearl is the small hollow glass spheroid of a kind of size, belongs to ceramic, and staple is SiO
2And Al
2O
3Hollow glass micropearl itself has that volume in light weight is big, thermal conductivity is low, ultimate compression strength is high; The advantage of dispersed, mobile, good stability also has insulation, self-lubricating, sound insulation, does not absorb water, fire-resistant, corrosion-resistant, radioprotective, excellent properties such as nontoxic.
Added the high-performance hollow glass micropearl in the atom ash according to the invention, hollow glass micropearl has minimum specific surface area and low oil absorbency, and he can have good dispersiveness in the atom ash; Be easy to compacted and fusion; Therefore he has very high filling properties, can reduce resin demand, reduce solvent load, increases the consumption of filler; Effectively reduce the VOC index, play the effect of environmental protection.
Preferably, the particle diameter of hollow glass micropearl according to the invention is 0.01-500 μ m, for example 0.02 μ m, 0.08 μ m, 0.26 μ m, 1.4 μ m, 28.7 μ m, 106 μ m, 323 μ m, 450 μ m, 480 μ m, 487 μ m etc., and density is 0.1-1.2g/cm
3, 0.14g/cm for example
3, 0.26g/cm
3, 0.57g/cm
3, 0.78g/cm
3, 0.85g/cm
3, 1.02g/cm
3, 1.16g/cm
3, 1.18g/cm
3Deng, wall thickness is the 6-12% of its diameter, for example 6.2%, 6.8%, 7.6%, 8.6%, 9.0%, 10.5%, 11.3%, 11.8% etc.Hollow glass micro-ball typical case but non-limiting instance have: the particle diameter of hollow glass micro-ball is 0.05-430 μ m, and density is 0.98g/cm
3, wall thickness is the 7.7-10.3% of its diameter; The particle diameter of hollow glass micro-ball is 0.5-330 μ m, and density is 1.05g/cm
3, wall thickness is the 8.2-11% of its diameter; The particle diameter of hollow glass micro-ball is 12-210 μ m, and density is 0.93g/cm
3, wall thickness is the 8.7-11.3% of its diameter; The particle diameter of hollow glass micro-ball is 20-150 μ m, and density is 0.80g/cm
3, wall thickness is the 8-10.2% of its diameter etc.
When the particle diameter of glass microsphere during less than 0.01 μ m, hollow chamber diminishes, and proportion increases, and wall thickness is not easy control, and when the particle diameter of glass microsphere during greater than 500 μ m, proportion can significantly reduce, but particle is obvious, and is dispersed bad; When the density of glass microsphere less than 0.1g/cm
3The time, must be because the particle diameter of glass microsphere becomes big, can cause dispersed bad problem equally, when the density of peeling off microballoon greater than 1.2g/cm
3The time, the purpose that reduces atom ash quality just is difficult to reach; For the wall thickness of peeling off microballoon, less than 6% of its diameter, glass microsphere intensity is low, and is not withstand voltage, and greater than 12%, then density is big.
Preferably, the particle diameter of hollow glass micropearl according to the invention is 0.01-400 μ m, and density is 0.1-0.9g/cm
3, wall thickness is the 7-11% of its diameter; Further preferable particle size is 0.2-400 μ m, and density is 0.2-0.75g/cm
3, wall thickness is the hollow glass micro-ball of the 7.5-10.5% of its diameter; Special preferable particle size is 15-150 μ m, and density is 0.4-0.5g/cm
3, wall thickness is the hollow glass micropearl of the 8-10% of its diameter.
In the present invention; The content of said environmental protection atom ash hollow core glass microballon is 2-17 by weight, and for example 3-15,5-10,9-14,2.2,4,6,13,15.2, weight parts such as 16.6 are preferably 3-15; Further preferred 5-10, preferred especially 6.2-8.4.The content of environmental protection atom ash hollow core glass microballon is less than 2 weight parts, and other components of interpolation become many, and especially the increase of the amount of organic solvent makes the VOC of product become big, not environmental protection, and dispersed improvement is not obvious; When the content of environmental protection atom ash hollow core glass microballon greater than 17 weight parts, though then VOC diminishes, other active principles, such as the content step-down of resin, filler etc., the adhesive property variation of the atom that is provided ash.
Environmental protection atom ash according to the invention can be realized through following technical scheme:
A kind of atom ash comprises following component by weight:
Preferably, a kind of environmental protection atom ash comprises following component by weight:
Wherein, said promotor is cobalt iso-octoate and/or cobalt naphthenate, preferred cobalt iso-octoate.
Promotor can promote atom ash fast doing in use.Wherein, cobalt naphthenate is generally 1% styrene solution, is called 1# promotor.But the cobalt salt color and luster is bad, and in the prior art field, people generally believe that the gel solidification effect of cobalt naphthenate and color can not satisfy the demand.And cobalt iso-octoate has good storing stability, compares with traditional cobalt naphthenate, and it is little to have a smell, urges the characteristics such as effective of doing.In light color paint, using, can reduce color and luster, the raising gloss of paint film, is the upgraded product of cobalt naphthenate.In the present invention, cobalt iso-octoate and cobalt naphthenate all can be independently or fit applications in the atom ash that provides, preferably use cobalt iso-octoate.
Preferably; Said resin is selected from the combination of any a kind or at least 2 kinds in Vilaterm, PS, tetrafluoroethylene, resol, vibrin, polyamide resin, polyoxymethylene resin, polyamide resin, polysulfone resin, polyether resin, the silicone resin; Said combination is Vilaterm/PS, silicone resin/vibrin, tetrafluoroethylene/polyamide resin, polysulfone resin/polyether resin/polyoxymethylene resin etc. for example, the combination of any a kind or at least 2 kinds in preferred polystyrene resin, resol, the silicone resin.
Resin known in the art all can be used for the present invention; And obtained performance is excellent under the cooperation of other components of atom provided by the invention ash; The environmental protection atom ash that VOC is low; Especially when selecting the combination of polystyrene resin/resol/silicone resin, obtain the synergistic function of rubber basis each component of glue.
White titanium pigment plays the effect of reinforcement, anti-aging and weighting agent in environmental protection atom ash of the present invention.Divided titanium dioxide is Rutile type Titanium Dioxide and anatase thpe white powder, and wherein Rutile type Titanium Dioxide is the most stable white titanium pigment, and anatase thpe white powder at high temperature can transform to Rutile type Titanium Dioxide.In the present invention, said white titanium pigment is selected from Rutile type Titanium Dioxide and/or anatase thpe white powder, preferred Rutile type Titanium Dioxide.
The effect of filler mainly is that the physicals adding filler that changes environmental protection atom ash of the present invention can play strengthening action, improves the mechanical property of atom ash, reduces string stress and thermal stresses, strengthens the stability to heat collapse, the reduction thermal expansivity.
Preferably; Said filler comprises the combination of any a kind or at least 2 kinds in lime carbonate, talcum powder, wilkinite, Calucium Silicate powder, asbestos powder, zeyssatite, carbon black or the kaolin; Said combination is wilkinite/talcum powder, lime carbonate/asbestos powder, wilkinite/zeyssatite, zeyssatite/talcum powder, kaolin/carbon black/lime carbonate, wilkinite/asbestos powder/talcum powder/zeyssatite etc. for example; Preferred lime carbonate and/or talcum powder; Further preferred light calcium carbonate and/or talcum powder, preferred wilkinite and/or talcum powder.
Preferably, the present invention realizes through following technical scheme:
A kind of environmental protection atom ash comprises following component by weight:
Preferably, said environmental protection atom ash by weight, comprises following component:
Preferably, said environmental protection atom ash comprises following component by weight:
Further preferably, said environmental protection atom ash comprises following component by weight:
Or said environmental protection atom ash comprises following component by weight:
Perhaps, said environmental protection atom ash comprises following component by weight:
Perhaps, as optional technical scheme, said environmental protection atom ash comprises following component by weight:
" comprising " of the present invention, mean it except that said component, can also comprise other components, these other components are given said environmental protection atom ash different characteristic, for example can add solvent, tensio-active agent etc.In addition, " comprising " of the present invention, can also replace with enclosed " being " or " by ... form ".
Another object of the present invention provides a kind of purposes of environmental protection atom of the present invention ash, and said atom ash can be used for that the automobile sheet metal is repaired, metallic substance is repaired, woodenware hair on the neck eye any a kind in filling up.
Compared with prior art, the present invention has following beneficial effect:
(1) is added with hollow glass micropearl; The amalgamation and the fillibility of atom ash have been improved; And reduced its VOC index; And dispersiveness is improved, and described these advantages have obtained raising further after the physical property (such as particle diameter, density, wall thickness etc.) of glass microballon is screened.
(2) through the optimization of a said atom ash component and component concentration, make the each side character of atom ash provided by the invention obtain the effect of synergy, obtained lower VOC, better filling effect and better dispersiveness.
Embodiment
For ease of understanding the present invention, it is following that the present invention enumerates embodiment.Those skilled in the art should understand, and said embodiment helps to understand the present invention, should not be regarded as concrete restriction of the present invention.
Embodiment 1
A kind of environmental protection atom ash comprises following component by weight:
5 parts of 17 parts of hollow glass micropearls, 16 parts of polyether resins, 7 parts of cobalt naphthenates, 0.05 part of xylidine, 8 parts of Rutile type Titanium Dioxides, zeyssatite 10, talcum powder 30, vinylbenzene;
Wherein, the particle diameter of hollow glass micropearl is 0.01-200 μ m, and density is 1.2g/cm
3, wall thickness is the 8-12% of its diameter.
Embodiment 2
A kind of environmental protection atom ash comprises following component by weight:
0.8 part of 2 parts of hollow glass micropearl, 45 parts of polysulfone resins, 1 part of cobalt iso-octoate, 0.7 part of xylidine, 1 part of anatase titanium dioxide type white titanium pigment, light calcium carbonate 5, talcum powder 20, kaolin 10, wilkinite 20, vinylbenzene;
Wherein, the particle diameter of hollow glass micropearl is 345-500 μ m, and density is 0.1g/cm
3, wall thickness is the 6-7.7% of its diameter.
Embodiment 3
A kind of environmental protection atom ash comprises following component by weight:
2 parts of hollow glass micropearls, 44.5 parts of polyvinyl resins, 1 part of cobalt iso-octoate, 0.7 part of xylidine, 1 part of white titanium pigment, 5 parts of wilkinites, 40 parts of talcum powder, 5 parts of vinylbenzene;
Wherein, the particle diameter of hollow glass micropearl is 34-300 μ m, and density is 0.54g/cm
3, wall thickness is the 7-9% of its diameter.
Embodiment 4
A kind of environmental protection atom ash comprises following component by weight:
17 parts of hollow glass micropearls, 16.1 parts of polystyrene resins, 7 parts of cobalt iso-octoates, 0.05 part of xylidine, 8 parts of white titanium pigments, 1 part of wilkinite, 50 parts of talcum powder, 0.5 part of vinylbenzene;
Wherein, the particle diameter of hollow glass micropearl is 34-300 μ m, and density is 0.54g/cm
3, wall thickness is the 7-9% of its diameter.
Embodiment 5
A kind of environmental protection atom ash comprises following component by weight:
5 parts of hollow glass micropearls, 40 parts of polyamide resins, 1 part of cobalt iso-octoate, 0.5 part of xylidine, 1 part of white titanium pigment, 3 parts of wilkinites, 40 parts of talcum powder, 3 parts of vinylbenzene;
Wherein, the particle diameter of hollow glass micropearl is 100-400 μ m, and density is 0.37g/cm
3, wall thickness is the 6-9% of its diameter.
Embodiment 6
A kind of environmental protection atom ash comprises following component by weight:
10 parts of hollow glass micropearls, 20 parts of polyamide resins, 5 parts of cobalt iso-octoates, 0.1 part of xylidine, 3 parts of white titanium pigments, 1 part of wilkinite, 50 parts of talcum powder, 1 part of vinylbenzene;
Wherein, the particle diameter of hollow glass micropearl is 120-404 μ m, and density is 0.38g/cm
3, wall thickness is the 6-9.1% of its diameter.
Embodiment 7
A kind of environmental protection atom ash comprises following component by weight:
7 parts of hollow glass micropearls, 30 parts of polyamide resins, 3.5 parts of cobalt iso-octoates, 0.32 part of xylidine, 2 parts of white titanium pigments, 2 parts of wilkinites, 45 parts of talcum powder, 2 parts of vinylbenzene;
Wherein, the particle diameter of hollow glass micropearl is 150-300 μ m, and density is 0.52g/cm
3, wall thickness is the 8-10% of its diameter.
Embodiment 8
A kind of environmental protection atom ash comprises following component by weight:
Particle diameter is 47 parts of 2.3 parts of 2.3 parts of 0.28 part of 3.7 parts of 33.3 parts of 6.5 parts of hollow glass micropearls, silicone resins, cobalt iso-octoates, xylidine, Rutile type Titanium Dioxides, wilkinites, talcum powder, 2.3 parts of the vinylbenzene of 50-200 μ m;
Wherein, the particle diameter of hollow glass micropearl is 120-320 μ m, and density is 0.66g/cm
3, wall thickness is the 8-9.8% of its diameter.
Applicant's statement; The present invention explains detailed prescription of the present invention and technical process through the foregoing description; But the present invention is not limited to above-mentioned detailed prescription and technical process, does not mean that promptly the present invention must rely on above-mentioned detailed prescription and technical process could be implemented.The person of ordinary skill in the field should understand, and to any improvement of the present invention, to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (10)
1. an environmental protection atom ash is characterized in that contain hollow glass micropearl in the said atom ash, the particle diameter of said hollow glass micropearl is 0.01-500 μ m, and density is 0.1-1.2g/cm
3, wall thickness is the 6-12% of its diameter.
2. environmental protection atom ash as claimed in claim 1 is characterized in that the particle diameter of said hollow glass micropearl is 0.01-400 μ m, and density is 0.1-0.9g/cm
3, wall thickness is the 7-11% of its diameter;
Preferably, the particle diameter of said hollow glass micropearl is 0.2-400 μ m, and density is 0.2-0.75g/cm
3, wall thickness is the 7.5-10.5% of its diameter; Further preferable particle size is 15-150 μ m, and density is 0.4-0.5g/cm
3, wall thickness is the hollow glass micropearl of the 8-10% of its diameter;
Preferably, the content of said environmental protection atom ash hollow core glass microballon is 2-17 by weight, is preferably 3-15, further preferred 5-10, preferred especially 6.2-8.4.
3. according to claim 1 or claim 2 environmental protection atom ash; It is characterized in that said atom ash comprises following component by weight: hollow glass micropearl 2-17 part, resin 16-45 part, promotor 1-7 part, xylidine 0.05-0.7 part, white titanium pigment 1-8 part, filler 40-55, vinylbenzene 0.8-5 part;
Preferably, said atom ash comprises following component by weight: hollow glass micropearl 5-10 part, resin 20-40 part, promotor 1-5 part, xylidine 0.1-0.5 part, white titanium pigment 1-3 part, filler 40-55, vinylbenzene 1-3 part.
4. like the described environmental protection atom ash of one of claim 1-3; It is characterized in that; Said resin is selected from the combination of any a kind or at least 2 kinds in Vilaterm, PS, tetrafluoroethylene, resol, vibrin, polyamide resin, polyoxymethylene resin, polyamide resin, polysulfone resin, polyether resin, the silicone resin, the combination of any a kind or at least 2 kinds in preferred polystyrene resin, resol, the silicone resin;
Preferably, said white titanium pigment is selected from Rutile type Titanium Dioxide and/or anatase thpe white powder, preferred Rutile type Titanium Dioxide;
Preferably, said promotor is cobalt iso-octoate and/or cobalt naphthenate, preferred cobalt iso-octoate;
Preferably, said filler comprises the combination of any a kind or at least 2 kinds in lime carbonate, talcum powder, wilkinite, Calucium Silicate powder, asbestos powder, zeyssatite, carbon black or the kaolin, preferred wilkinite and/or talcum powder.
5. like the described environmental protection atom ash of one of claim 1-4; It is characterized in that; Said environmental protection atom ash comprises following component by weight: hollow glass micropearl 2-17 part, resin 16.1-44.5 part, cobalt iso-octoate 1-7 part, xylidine 0.05-0.7 part, white titanium pigment 1-8 part, wilkinite 1-5 part, talcum powder 40-50 part, vinylbenzene 0.5-5 part.
6. like the described environmental protection atom ash of one of claim 1-5; It is characterized in that; Said environmental protection atom ash comprises following component by weight: hollow glass micropearl 5-10 part, resin 20-40 part, cobalt iso-octoate 1-5 part, xylidine 0.1-0.5 part, white titanium pigment 1-3 part, wilkinite 1-3 part, talcum powder 40-50 part, vinylbenzene 1-3 part.
7. like the described environmental protection atom ash of one of claim 1-6; It is characterized in that; Said environmental protection atom ash comprises following component by weight: hollow glass micropearl 5.3-10 part, resin 23-40 part, cobalt iso-octoate 2.2-5 part, xylidine 0.13-0.5 part, white titanium pigment 1-3 part, wilkinite 1-3 part, talcum powder 40-50 part, vinylbenzene 1-3 part.
8. like the described environmental protection atom ash of one of claim 1-7; It is characterized in that; Said environmental protection atom ash comprises following component by weight: 7 parts of hollow glass micropearls, 34 parts in resol, 3.1 parts of cobalt iso-octoates, 0.3 part of xylidine, 2 parts of white titanium pigments, 2 parts of wilkinites, 44.3 parts of talcum powder, 2.1 parts of vinylbenzene;
Preferably; Said environmental protection atom ash comprises following component by weight: particle diameter is 47 parts of 1.8 parts of 2.3 parts of 0.4 part of 4 parts of 37.4 parts of 8.2 parts of hollow glass micropearls, polystyrene resins, cobalt iso-octoates, xylidine, white titanium pigments, wilkinites, talcum powder, 1.6 parts of the vinylbenzene of 30-120 μ m.
9. like the described environmental protection atom ash of one of claim 1-8; It is characterized in that; Said environmental protection atom ash comprises following component by weight: particle diameter is 47 parts of 2.3 parts of 2.3 parts of 0.28 part of 3.7 parts of 33.3 parts of 6.5 parts of hollow glass micropearls, silicone resins, cobalt iso-octoates, xylidine, Rutile type Titanium Dioxides, wilkinites, talcum powder, 2.3 parts of the vinylbenzene of 50-200 μ m.
10. the purposes like the described environmental protection atom of one of claim 1-9 ash is characterized in that, said atom ash can be used for that the automobile sheet metal is repaired, metallic substance is repaired, woodenware hair on the neck eye any a kind in filling up.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102287308A CN102766368A (en) | 2012-07-04 | 2012-07-04 | Environment-friendly unsaturated polyester putty containing hollow glass beads |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102287308A CN102766368A (en) | 2012-07-04 | 2012-07-04 | Environment-friendly unsaturated polyester putty containing hollow glass beads |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102766368A true CN102766368A (en) | 2012-11-07 |
Family
ID=47093964
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012102287308A Pending CN102766368A (en) | 2012-07-04 | 2012-07-04 | Environment-friendly unsaturated polyester putty containing hollow glass beads |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102766368A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146241A (en) * | 2012-12-11 | 2013-06-12 | 亮克威泽(北京)涂料科技有限公司 | Unsaturated polyester putty base resin used for locomotive, preparation method of base resin and putty including base resin |
| CN106566307A (en) * | 2016-11-18 | 2017-04-19 | 清远永昌涂料有限公司 | Lightweight multifunctional putty and preparation method thereof |
| CN106752238A (en) * | 2016-11-18 | 2017-05-31 | 清远永昌涂料有限公司 | A kind of alloy fiber atomized ash and preparation method thereof |
| CN109735159A (en) * | 2019-03-06 | 2019-05-10 | 常州威斯敦粘合材料有限责任公司 | Photovoltaic back bi-component repairing putty and preparation method thereof, application method and application |
-
2012
- 2012-07-04 CN CN2012102287308A patent/CN102766368A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146241A (en) * | 2012-12-11 | 2013-06-12 | 亮克威泽(北京)涂料科技有限公司 | Unsaturated polyester putty base resin used for locomotive, preparation method of base resin and putty including base resin |
| CN103146241B (en) * | 2012-12-11 | 2015-12-02 | 亮克威泽(北京)涂料科技有限公司 | Unsaturated polyester putty host and preparation method thereof for railway locomotive and the putty containing this host |
| CN106566307A (en) * | 2016-11-18 | 2017-04-19 | 清远永昌涂料有限公司 | Lightweight multifunctional putty and preparation method thereof |
| CN106752238A (en) * | 2016-11-18 | 2017-05-31 | 清远永昌涂料有限公司 | A kind of alloy fiber atomized ash and preparation method thereof |
| CN109735159A (en) * | 2019-03-06 | 2019-05-10 | 常州威斯敦粘合材料有限责任公司 | Photovoltaic back bi-component repairing putty and preparation method thereof, application method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103319110B (en) | Artificial quartz stone and preparation method thereof | |
| CN106433537A (en) | Modified epoxy adhesive and preparing method thereof | |
| CN101602223B (en) | One-time forming high-strength decorative slab and manufacturing process thereof | |
| CN101544869A (en) | Packless ultraviolet curing transparent priming lacquer for woodenware | |
| CN102850878A (en) | Weather-resistant exterior wall paint and preparation method thereof | |
| CN101851483B (en) | Stone jointing adhesive | |
| CN102766368A (en) | Environment-friendly unsaturated polyester putty containing hollow glass beads | |
| CN101942234A (en) | Environment friendly dry powder emulsion paint and preparation method thereof | |
| CN107201159A (en) | A kind of cracking resistance, anti-dropout coating and preparation method | |
| CN101857790A (en) | Special color stone grout | |
| CN108314922A (en) | A kind of inner and external wall putty powder with enhanced water resistance and preparation method thereof, application | |
| CN101531875A (en) | Stone pointing adhesive | |
| CN104927740B (en) | Environment-friendly type stone material seamless binding glue and preparation method thereof | |
| CN102702919A (en) | Wear resistant epoxy resin primer-topcoat coating with high solid content and low toxicity | |
| CN101284973B (en) | Filling agent special for glued board adhesive | |
| CN104910847B (en) | Stone material seamless binding glue and preparation method thereof | |
| CN111961377A (en) | Water-based high-crack-resistance stone-like artistic coating and preparation method thereof | |
| CN101805581B (en) | Stone material caulking sealant | |
| CN207348307U (en) | A kind of fiberglass exterior wall cladding | |
| CN104927399A (en) | Corrosion resistant modified calcium carbonate with excellent overall performances and preparation method thereof | |
| CN104341936A (en) | Wear-resistant water-based paint for glass sliding doors and preparation method thereof | |
| CN110105854B (en) | Paint for antique coating of woodware and preparation method thereof | |
| CN103289539A (en) | Preparation method of modified fluorite slag-containing powdery paint | |
| CN102504635B (en) | Preparation method of environment-friendly putty | |
| KR102039313B1 (en) | The method for manufacturing and composition the same elastic paving material of eco-friendly water-soluble coating composition for surface enhancement of Cork Chips |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20121107 |