CN102417749B - Environmentally friendly putty - Google Patents

Environmentally friendly putty Download PDF

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Publication number
CN102417749B
CN102417749B CN201110366911.2A CN201110366911A CN102417749B CN 102417749 B CN102417749 B CN 102417749B CN 201110366911 A CN201110366911 A CN 201110366911A CN 102417749 B CN102417749 B CN 102417749B
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parts
weight
main body
following composition
solidifying agent
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Expired - Fee Related
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CN201110366911.2A
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Chinese (zh)
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CN102417749A (en
Inventor
卢齐元
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Shanghai Zhong Zhong Construction Engineering Co., Ltd.
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TIANCHANG CITY TONGTIAN CHEMICAL CO Ltd
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  • Macromonomer-Based Addition Polymer (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses environmentally friendly putty. The putty comprises a main body and a curing agent, wherein the main body comprises the following components, by weight, 56-60 parts of an air-dried aqueous unsaturated polyester resin, 2-5 parts of styrene, 0.5-0.8 parts of triethylenetetramine, 0.8-1.2 parts of dimethylaniline, 1.2-1.5 parts of polymethyl methacrylate, 1.2-1.6 parts of BYK-980, 0.01-0.02 parts of dimethylglyoxime, 0.015-0.025 parts of polyamide wax, 0.2-0.3 parts of methylparaben, 4-8 parts of hollow glass bead, 1-3 parts of bentonite, 5-7 parts of calcium carbonate, 10-15 parts of titanium dioxide, 1-2 parts of a glass fiber, and 3-5 parts of barium sulfate; and the curing agent comprises, by weight, 60-64 parts of benzoyl peroxide, 20-24 parts of dibutyl phthalate, and 4-8 parts of silica.

Description

A kind of environmental protection atomized ash
Technical field
The present invention relates to chemistry painting industry field, particularly a kind of environmental protection atomized ash.
Background technology
Along with improving constantly that social progress and people require daily life tools, the material that more and more can be convenient for people to daily life occurs in a large number.The goods that can be convenient for people to daily life along with social progress is various appear in people's life in a large number, such as, automobile and various vessel, but due to the limitation of present industrial technology means, these products were all some parts in bulk or plate bodys before processed production becomes finished product.And in the process of the parts that these are in bulk or plate body splicing all-in-one-piece product, connection all parts or plate body become one and just become critical processing step.If these processing step processing is good, the whole structure of product can reach more satisfactory state, once these processing step processing is bad, the whole structure of product just there will be larger drop.
As mentioned above, splicing process between processing element or plate body is the important means that embodies product appearance effect, and especially important with seam technique in such technique, and the integral part that determines seam processing quality has been exactly joint filler that manufacturer adopts.If joint filler select good, the part of seam is comparatively level and smooth, is smaller to the appearance effects of product entirety, if but joint filler select bad, so often the appearance effect of product entirety is had to larger impact.
With regard to present people's life, automobile has entered into the daily life of people as a kind of commonplace vehicles are very general, and the outward appearance of the automobile aspect that people relatively pay close attention to often, its appearance effect of new automobile is reasonable often, but after driver drives a car generation traffic accident, due to impact effect each other, must cause damaged on car surface shell.How repairing so damaged outward appearance that makes automobile and return to the state before collision, is the problem that vast car steering person pays close attention to the most.
Along with a kind of seam repair materials of social progress is invented by people, Here it is is atomized ash, the effect that its seam that is mainly used in producing between metal, nonmetal and other materials in the process of splicing is repaired, filled and led up.
Atomized ash is as a kind of more novel material, and it is taking unsaturated polyester as main component, adds other associated materials simultaneously and stirs and to make.It is higher etc. that its major advantage has the fast and intensity of curing speed.But with regard to traditional atomized ash, it is just more powerful than the characteristic of traditional putty, but due to the restriction of its formula materials, its performance does not still reach people's requirement.
Particularly; in the more and more higher situation of the performance requriements of atomized ash product surface decoration; along with user's improving constantly environmental protection concept understanding level; the enhancing of the environmental protection concept to use and workmen's protection simultaneously; especially at high-grade motor vehicle repair, high-grade house decoration, decoration industry, people are to having good workability and to meet the atomized ash product demand of environmental requirement huge.
Summary of the invention
For the deficiencies in the prior art, one of object of the present invention is to provide a kind of environmental protection atomized ash.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of environmental protection atomized ash, described atomized ash is made up of main body and two kinds of components of solidifying agent, is main body by weight: solidifying agent=100 when use: 2, mix, described main body is made up of following composition by weight: air drying type water-based unsaturated polyester resin 56-60 part, vinylbenzene 2-5 part, Triethylenetetramine (TETA) 0.5-0.8 part, xylidine 0.8-1.2 part, polymethylmethacrylate 1.2-1.5 part, BYK-9801.2-1.6 part, dimethylglyoxime 0.01-0.02 part, polyamide wax 0.015-0.025 part, Tegosept M 0.2-0.3 part, hollow glass micropearl 4-8 part, wilkinite 1-3 part, calcium carbonate 5-7 part, titanium dioxide 10-15 part, glass fibre 1-2 part, barium sulfate 3-5 part, solidifying agent is made up of by weight following composition: benzoyl peroxide 60-64 part, dibutyl phthalate 20-24 part, silicon-dioxide 4-8 part.
Preferably, described main body is made up of following composition by weight: air drying type water-based unsaturated polyester resin 57-59 part, vinylbenzene 3-4 part, Triethylenetetramine (TETA) 0.6-0.7 part, xylidine 0.9-1.1 part, polymethylmethacrylate 1.3-1.4 part, BYK-9801.3-1.5 part, dimethylglyoxime 0.014-0.016 part, polyamide wax 0.018-0.022 part, Tegosept M 0.22-0.28 part, hollow glass micropearl 5-7 part, wilkinite 1.5-2.5 part, calcium carbonate 5.5-6.5 part, titanium dioxide 12-14 part, glass fibre 1.4-1.6 part, barium sulfate 3.5-4.5 part, solidifying agent is made up of by weight following composition: benzoyl peroxide 61-63 part, dibutyl phthalate 21-23 part, silicon-dioxide 5-7 part.
Most preferably, described main body is made up of following composition by weight: 58 parts of air drying type water-based unsaturated polyester resins, 3.5 parts of vinylbenzene, 0.65 part of Triethylenetetramine (TETA), 1.0 parts of xylidines, 1.35 parts of polymethylmethacrylates, BYK-9801.4 part, 0.015 part of dimethylglyoxime, 0.020 part of polyamide wax, 0.25 part of Tegosept M, 6 parts of hollow glass micropearls, 2 parts of wilkinites, 6 parts, calcium carbonate, 13 parts of titanium dioxides, 1.5 parts, glass fibre, 4 parts, barium sulfate, solidifying agent is made up of by weight following composition: 62 parts of benzoyl peroxides, 22 parts of dibutyl phthalates, 6 parts of silicon-dioxide.
The present invention, compared with existing other atomized ash, has following beneficial effect:
1) atomized ash that prepared by the present invention reduces the content of volatile organic compounds, and smell is little, toxicity is low, therefore good environmental protection.
2) the present invention is on the basis of lot of experiments, optimize the design of atomized ash each component, make the excellent combination property of the atomized ash of preparation: construction use properties is good, fillibility and the anti-contracility of product are improved, film forming defensive position sense exquisiteness, smooth densification are scraped in painting, and good with the matching performance of main flow paint on the market.
Embodiment
Embodiment mono-
A kind of environmental protection atomized ash, described atomized ash is made up of main body and two kinds of components of solidifying agent, is main body by weight: solidifying agent=100 when use: 2, mix, described main body is made up of following composition by weight: 56 parts of air drying type water-based unsaturated polyester resins, 5 parts of vinylbenzene, 0.5 part of Triethylenetetramine (TETA), 1.2 parts of xylidines, 1.2 parts of polymethylmethacrylates, BYK-9801.6 part, 0.01 part of dimethylglyoxime, 0.025 part of polyamide wax, 0.2 part of Tegosept M, 8 parts of hollow glass micropearls, 1 part of wilkinite, 7 parts, calcium carbonate, 10 parts of titanium dioxides, 2 parts, glass fibre, 3 parts, barium sulfate, solidifying agent is made up of by weight following composition: 64 parts of benzoyl peroxides, 20 parts of dibutyl phthalates, 8 parts of silicon-dioxide.
Embodiment bis-
A kind of environmental protection atomized ash, described atomized ash is made up of main body and two kinds of components of solidifying agent, is main body by weight: solidifying agent=100 when use: 2, mix, described main body is made up of following composition by weight: 60 parts of air drying type water-based unsaturated polyester resins, 2 parts of vinylbenzene, 0.8 part of Triethylenetetramine (TETA), 0.8 part of xylidine, 1.5 parts of polymethylmethacrylates, BYK-9801.2 part, 0.02 part of dimethylglyoxime, 0.015 part of polyamide wax, 0.3 part of Tegosept M, 4 parts of hollow glass micropearls, 3 parts of wilkinites, 5 parts, calcium carbonate, 15 parts of titanium dioxides, 1 part, glass fibre, 5 parts, barium sulfate, solidifying agent is made up of by weight following composition: 60 parts of benzoyl peroxides, 24 parts of dibutyl phthalates, 4 parts of silicon-dioxide.
Embodiment tri-
A kind of environmental protection atomized ash, described atomized ash is made up of main body and two kinds of components of solidifying agent, is main body by weight: solidifying agent=100 when use: 2, mix, described main body is made up of following composition by weight: 57 parts of air drying type water-based unsaturated polyester resins, 4 parts of vinylbenzene, 0.6 part of Triethylenetetramine (TETA), 1.1 parts of xylidines, 1.3 parts of polymethylmethacrylates, BYK-9801.5 part, 0.014 part of dimethylglyoxime, 0.022 part of polyamide wax, 0.22 part of Tegosept M, 7 parts of hollow glass micropearls, 1.5 parts of wilkinites, 6.5 parts, calcium carbonate, 12 parts of titanium dioxides, 1.6 parts, glass fibre, 3.5 parts, barium sulfate, solidifying agent is made up of by weight following composition: 63 parts of benzoyl peroxides, 21 parts of dibutyl phthalates, 7 parts of silicon-dioxide.
Embodiment tetra-
A kind of environmental protection atomized ash, described atomized ash is made up of main body and two kinds of components of solidifying agent, is main body by weight: solidifying agent=100 when use: 2, mix, described main body is made up of following composition by weight: 59 parts of air drying type water-based unsaturated polyester resins, 3 parts of vinylbenzene, 0.7 part of Triethylenetetramine (TETA), 0.9 part of xylidine, 1.4 parts of polymethylmethacrylates, BYK-9801.3 part, 0.016 part of dimethylglyoxime, 0.018 part of polyamide wax, 0.28 part of Tegosept M, 5 parts of hollow glass micropearls, 2.5 parts of wilkinites, 5.5 parts, calcium carbonate, 14 parts of titanium dioxides, 1.4 parts, glass fibre, 4.5 parts, barium sulfate, solidifying agent is made up of by weight following composition: 61 parts of benzoyl peroxides, 23 parts of dibutyl phthalates, 7 parts of silicon-dioxide.
Embodiment five
A kind of environmental protection atomized ash, described atomized ash is made up of main body and two kinds of components of solidifying agent, is main body by weight: solidifying agent=100 when use: 2, mix, described main body is made up of following composition by weight: 58 parts of air drying type water-based unsaturated polyester resins, 3.5 parts of vinylbenzene, 0.65 part of Triethylenetetramine (TETA), 1.0 parts of xylidines, 1.35 parts of polymethylmethacrylates, BYK-9801.4 part, 0.015 part of dimethylglyoxime, 0.020 part of polyamide wax, 0.25 part of Tegosept M, 6 parts of hollow glass micropearls, 2 parts of wilkinites, 6 parts, calcium carbonate, 12.5 parts of titanium dioxides, 1.5 parts, glass fibre, 4 parts, barium sulfate, solidifying agent is made up of by weight following composition: 62 parts of benzoyl peroxides, 22 parts of dibutyl phthalates, 6 parts of silicon-dioxide.
Applicant's statement, the present invention illustrates detailed process equipment and process flow process of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed process equipment and process flow process, do not mean that the present invention must rely on above-mentioned detailed process equipment and process flow process and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, and the selections of the equivalence replacement to the each raw material of product of the present invention and the interpolation of ancillary component, concrete mode etc., within all dropping on protection scope of the present invention and open scope.

Claims (3)

1. an environmental protection atomized ash, described atomized ash is made up of main body and two kinds of components of solidifying agent, is main body by weight: solidifying agent=100 when use: 2, mix, it is characterized in that, described main body is made up of following composition by weight: air drying type water-based unsaturated polyester resin 56-60 part, vinylbenzene 2-5 part, Triethylenetetramine (TETA) 0.5-0.8 part, xylidine 0.8-1.2 part, polymethylmethacrylate 1.2-1.5 part, BYK-9801.2-1.6 part, dimethylglyoxime 0.01-0.02 part, polyamide wax 0.015-0.025 part, Tegosept M 0.2-0.3 part, hollow glass micropearl 4-8 part, wilkinite 1-3 part, calcium carbonate 5-7 part, titanium dioxide 10-15 part, glass fibre 1-2 part, barium sulfate 3-5 part, solidifying agent is made up of by weight following composition: benzoyl peroxide 60-64 part, dibutyl phthalate 20-24 part, silicon-dioxide 4-8 part.
2. a kind of environmental protection atomized ash as claimed in claim 1, it is characterized in that, described main body is made up of following composition by weight: air drying type water-based unsaturated polyester resin 57-59 part, vinylbenzene 3-4 part, Triethylenetetramine (TETA) 0.6-0.7 part, xylidine 0.9-1.1 part, polymethylmethacrylate 1.3-1.4 part, BYK-9801.3-1.5 part, dimethylglyoxime 0.014-0.016 part, polyamide wax 0.018-0.022 part, Tegosept M 0.22-0.28 part, hollow glass micropearl 5-7 part, wilkinite 1.5-2.5 part, calcium carbonate 5.5-6.5 part, titanium dioxide 12-14 part, glass fibre 1.4-1.6 part, barium sulfate 3.5-4.5 part, solidifying agent is made up of by weight following composition: benzoyl peroxide 61-63 part, dibutyl phthalate 21-23 part, silicon-dioxide 5-7 part.
3. a kind of environmental protection atomized ash as claimed in claim 2, it is characterized in that, described main body is made up of following composition by weight: 58 parts of air drying type water-based unsaturated polyester resins, 3.5 parts of vinylbenzene, 0.65 part of Triethylenetetramine (TETA), 1.0 parts of xylidines, 1.35 parts of polymethylmethacrylates, BYK-9801.4 part, 0.015 part of dimethylglyoxime, 0.020 part of polyamide wax, 0.25 part of Tegosept M, 6 parts of hollow glass micropearls, 2 parts of wilkinites, 6 parts, calcium carbonate, 13 parts of titanium dioxides, 1.5 parts, glass fibre, 4 parts, barium sulfate, solidifying agent is made up of by weight following composition: 62 parts of benzoyl peroxides, 22 parts of dibutyl phthalates, 6 parts of silicon-dioxide.
CN201110366911.2A 2011-11-18 2011-11-18 Environmentally friendly putty Expired - Fee Related CN102417749B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103497666A (en) * 2013-09-03 2014-01-08 蚌埠市英路光电有限公司 Noctilucent powdery paint
CN104212281B (en) * 2014-09-22 2016-08-24 句容亿格纳米材料厂 A kind of nanometer decorative coveringn and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101250256A (en) * 2008-03-28 2008-08-27 武汉理工大学 Method for synthesizing unsaturated polyester resin
CN101284959A (en) * 2008-06-02 2008-10-15 中山市三和气雾有限公司 Atomic ash special for wood decoration
CN101519566A (en) * 2008-09-17 2009-09-02 陈杰新 Method for producing automobil putty

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101250256A (en) * 2008-03-28 2008-08-27 武汉理工大学 Method for synthesizing unsaturated polyester resin
CN101284959A (en) * 2008-06-02 2008-10-15 中山市三和气雾有限公司 Atomic ash special for wood decoration
CN101519566A (en) * 2008-09-17 2009-09-02 陈杰新 Method for producing automobil putty

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Inventor after: Liu Jun

Inventor before: Lu Qiyuan

TR01 Transfer of patent right

Effective date of registration: 20170502

Address after: 226600 Haian, Jiangsu, Haian Town, No. South Dam Road, No. 18

Patentee after: Jiangsu Suzhong Construction Group Co., Ltd.

Address before: 239361 Chuzhou, Tianchang, Datong Town, Ping Qiao Road, No. 88, No.

Patentee before: Tianchang City Tongtian Chemical Co.,Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20191231

Address after: 200086 room 702-705, No. 3, Lane 900, Quyang Road, Hongkou District, Shanghai

Patentee after: Shanghai Zhong Zhong Construction Engineering Co., Ltd.

Address before: 226600, 18 South Road, Haian Town, Haian County, Jiangsu, Nantong

Patentee before: Jiangsu Suzhong Construction Group Co., Ltd.

TR01 Transfer of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140604

Termination date: 20201118

CF01 Termination of patent right due to non-payment of annual fee