CN102493189B - Anti-bloodiness clothing finishing agent and emergency clothes - Google Patents
Anti-bloodiness clothing finishing agent and emergency clothes Download PDFInfo
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- CN102493189B CN102493189B CN 201110361317 CN201110361317A CN102493189B CN 102493189 B CN102493189 B CN 102493189B CN 201110361317 CN201110361317 CN 201110361317 CN 201110361317 A CN201110361317 A CN 201110361317A CN 102493189 B CN102493189 B CN 102493189B
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- finishing agent
- clothing
- blood stains
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Abstract
The invention discloses an anti-bloodiness clothing finishing agent and an emergency clothes. The finishing agent is prepared from raw materials comprising a main material, an auxiliary material, an assistant agent, a cross-linking agent and an initiator. The fabric of the emergency clothes is the fabric treated by using the finishing agent. The finishing agent and the emergency clothes of the present invention have the following advantages that: on the basis that the finishing agent truly maintains the original performances of the fabric, the finished fabric has an anti-bloodiness effect; the finishing agent is a nanoscale material, such that the original air permeability of the fabric is not affected; the components of the raw materials are simple; the preparation method is simple.
Description
Technical field
The present invention relates to a kind of emergency clothing, specifically a kind of anti-blood stains clothing finishing agent and the emergency clothing that uses this finishing agent, belong to medical field.
Background technology
At medical field, in order to rescue in time, the doctor can change the clothes of oneself and puts on emergency clothing and take the emergency tender noneffectives is carried out simple first aid process before receiving 120 urgent ambulance calls, emergency clothing is that the doctor is when implementing first aid, be through outermost clothes, wrap up patient's wound in first aid process, lift the simple action such as patient.Traditional emergency clothing adopts the materials such as nonwoven fabric, cotton to make more, when first aid, if there are the spots such as blood stains to be infected with on emergency clothing, just is difficult to wipe, and also is not easy to wash.
Summary of the invention
In order to address the above problem, the emergency clothing that the object of the present invention is to provide a kind of anti-blood stains clothing finishing agent and used this finishing agent.
Technical scheme of the present invention is:
A kind of anti-blood stains clothing finishing agent is prepared from by the raw material of following weight portion:
Major ingredient: 90 parts of fluorocarbon resins;
Auxiliary material: 8 parts of titanium dioxide, 7 parts of APP, 5 parts of zirconium carbides;
Auxiliary agent: 5 parts of dodecafluoroheptyl methacrylates;
Crosslinking agent: 1 part of cycloaliphatic polyisocyanate;
Initator: 0.5 part of dibutyl tin laurate;
It is that granular size is 0.1~1 * 10 that above-mentioned each raw material is nanoscale
-9m;
Described preparation method is: major ingredient and auxiliary material mix, the deionized water of quality such as then add, pour into and carry out emulsification in emulsion tank, splash into reactor after emulsification is complete under 74~78 ℃, drip simultaneously auxiliary agent, crosslinking agent and initator, time for adding is 3 hours, controls temperature in the dropping process between 74~78 ℃, after being added dropwise to complete, 74~78 ℃ are incubated l hour, then be cooled to 30 ℃, carry out the nanofiltration device and filter, obtain nano level finishing agent product.
Further, described emulsion tank is the JP600 type ultrasonic emulsification tank that Wuhan Jiapeng Electronics Co., Ltd. produces;
Described nanofiltration device is the 1T/H model nanofiltration device that Dongguan Wojiesen Water Treatment Co., Ltd. produces;
Described cycloaliphatic polyisocyanate is the WB-905 enclosed type water-based cycloaliphatic polyisocyanate that vast and boundless firm Chemical Industry Science Co., Ltd produces.
A kind of anti-blood stains emergency clothing, the fabric of described emergency clothing is the fabric after processing through above-mentioned anti-blood stains clothing finishing agent, described processing method comprises the following steps:
(1) fabric preliminary treatment: the fabric process of emergency clothing is soaped, and the temperature of soaping is 88-92 ℃, and the time of soaping is 16-19 minute, removes the surfactant of fabric;
(2) with above-mentioned finishing agent thin up, mix according to the volume ratio ratio of 1: 15, obtain the pH=5 dressing liquid;
(3) the pretreated fabric of above-mentioned steps (1) is flooded with the dressing liquid that step (2) obtains, 20-22 ℃ of condition temperature, time 70-90 minute, then squeeze obtain liquid carrying rate (be on fabric panel with the maceration extract quality account for the percentage of dry fabric fabric quality) 68~73% fabric;
(4) fabric with above-mentioned steps (3) gained carries out drying and shaping, 190 ℃ of temperature, 1 minute time.
The invention has the advantages that: described finishing agent is on the basis that has really kept the original performance of fabric panel, make the fabric panel after arrangement have the effect of anti-blood stains, simultaneously, because finishing agent is nanometer materials, thereby do not affect the original gas permeability of fabric, material composition is simple, and the preparation method is easy.
The specific embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein only is used for description and interpretation the present invention, is not intended to limit the present invention.
Except as otherwise noted, the percentage that adopts in the present invention is percetage by weight.
Embodiment 1
A kind of anti-blood stains clothing finishing agent,
Raw material by following weight portion is prepared from:
Major ingredient: 90 parts of fluorocarbon resins;
Auxiliary material: 8 parts of titanium dioxide, 7 parts of APP, 5 parts of zirconium carbides;
Auxiliary agent: 5 parts of dodecafluoroheptyl methacrylates;
Crosslinking agent: 1 part of cycloaliphatic polyisocyanate;
Initator: 0.5 part of dibutyl tin laurate;
It is that granular size is 0.1~1 * 10 that above-mentioned each raw material is nanoscale
-9m;
the preparation method is: major ingredient and auxiliary material mix, the deionized water that the quality such as then adds, pour in emulsion tank (the JP600 type ultrasonic emulsification tank that Wuhan Jiapeng Electronics Co., Ltd. produces) and carry out emulsification, in splashing into reactor after emulsification is complete under 74 ℃, drip simultaneously auxiliary agent, crosslinking agent and initator, time for adding is 3 hours, control temperature in the dropping process at 74 ℃, after being added dropwise to complete, 74 ℃ are incubated l hour, then be cooled to 30 ℃, carry out nanofiltration device (the 1T/H model nanofiltration device that Dongguan Wojiesen Water Treatment Co., Ltd. produces filters), obtain nano level finishing agent product.
Described cycloaliphatic polyisocyanate is the WB-905 enclosed type water-based cycloaliphatic polyisocyanate that vast and boundless firm Chemical Industry Science Co., Ltd produces.
A kind of anti-blood stains emergency clothing, the fabric of described emergency clothing is the fabric after processing through above-mentioned anti-blood stains clothing finishing agent, described processing method comprises the following steps:
(1) fabric preliminary treatment: the fabric process of emergency clothing is soaped, and the temperature of soaping is 88 ℃, and the time of soaping is 16 minutes, removes the surfactant of fabric;
(2) with above-mentioned finishing agent thin up, be mixed to get the pH=5 dressing liquid according to the volume ratio ratio of 1: 15;
(3) the pretreated fabric of above-mentioned steps (1) is flooded with the dressing liquid that step (2) obtains, 20 ℃ of condition temperature, 70 minutes time, then squeeze obtain liquid carrying rate (be on fabric panel with the maceration extract quality account for the percentage of dry fabric fabric quality) 68% fabric;
(4) fabric with above-mentioned steps (3) gained carries out drying and shaping, 190 ℃ of temperature, 1 minute time.
Result: the fabric panel after above-mentioned processing is placed in the blood stains immersion takes out after 15 minutes, have not a particle of blood stains and be infected with; Compare with the identical fabric fabric of non-processor, gas permeability is identical.
Embodiment 2
A kind of anti-blood stains clothing finishing agent,
Raw material by following weight portion is prepared from:
Major ingredient: 90 parts of fluorocarbon resins;
Auxiliary material: 8 parts of titanium dioxide, 7 parts of APP, 5 parts of zirconium carbides;
Auxiliary agent: 5 parts of dodecafluoroheptyl methacrylates;
Crosslinking agent: 1 part of cycloaliphatic polyisocyanate;
Initator: 0.5 part of dibutyl tin laurate;
It is that granular size is 0.1~1 * 10 that above-mentioned each raw material is nanoscale
-9m;
the preparation method is: major ingredient and auxiliary material mix, the deionized water that the quality such as then adds, pour in emulsion tank (the JP600 type ultrasonic emulsification tank that Wuhan Jiapeng Electronics Co., Ltd. produces) and carry out emulsification, in splashing into reactor after emulsification is complete under 74~78 ℃, drip simultaneously auxiliary agent, crosslinking agent and initator, time for adding is 3 hours, control temperature in the dropping process at 78 ℃, after being added dropwise to complete, 74 ℃ are incubated l hour, then be cooled to 30 ℃, carry out nanofiltration device (the 1T/H model nanofiltration device that Dongguan Wojiesen Water Treatment Co., Ltd. produces filters), obtain nano level finishing agent product.
Described cycloaliphatic polyisocyanate is the WB-905 enclosed type water-based cycloaliphatic polyisocyanate that vast and boundless firm Chemical Industry Science Co., Ltd produces.
A kind of anti-blood stains emergency clothing, the fabric of described emergency clothing is the fabric after processing through above-mentioned anti-blood stains clothing finishing agent, described processing method comprises the following steps:
(1) fabric preliminary treatment: the fabric process of emergency clothing is soaped, and the temperature of soaping is 92 ℃, and the time of soaping is 19 minutes, removes the surfactant of fabric;
(2) with above-mentioned finishing agent thin up, be mixed to get the pH=5 dressing liquid according to the volume ratio ratio of 1: 15;
(3) the pretreated fabric of above-mentioned steps (1) is flooded with the dressing liquid that step (2) obtains, 22 ℃ of condition temperature, 90 minutes time, then squeeze obtain liquid carrying rate (be on fabric panel with the maceration extract quality account for the percentage of dry fabric fabric quality) 73% fabric;
(4) fabric with above-mentioned steps (3) gained carries out drying and shaping, 190 ℃ of temperature, 1 minute time.
Result: the fabric panel after above-mentioned processing is placed in the blood stains immersion takes out after 10 minutes, have not a particle of blood stains and be infected with; Compare with the identical fabric fabric of non-processor, gas permeability is identical.
Embodiment 3
A kind of anti-blood stains clothing finishing agent,
Raw material by following weight portion is prepared from:
Major ingredient: 90 parts of fluorocarbon resins;
Auxiliary material: 8 parts of titanium dioxide, 7 parts of APP, 5 parts of zirconium carbides;
Auxiliary agent: 5 parts of dodecafluoroheptyl methacrylates;
Crosslinking agent: 1 part of cycloaliphatic polyisocyanate;
Initator: 0.5 part of dibutyl tin laurate;
It is that granular size is 0.1~1 * 10 that above-mentioned each raw material is nanoscale
-9m;
the preparation method is: major ingredient and auxiliary material mix, the deionized water that the quality such as then adds, pour in emulsion tank (the JP600 type ultrasonic emulsification tank that Wuhan Jiapeng Electronics Co., Ltd. produces) and carry out emulsification, in splashing into reactor after emulsification is complete under 74~78 ℃, drip simultaneously auxiliary agent, crosslinking agent and initator, time for adding is 3 hours, control temperature in the dropping process at 76 ℃, after being added dropwise to complete, 76 ℃ are incubated l hour, then be cooled to 30 ℃, carry out nanofiltration device (the 1T/H model nanofiltration device that Dongguan Wojiesen Water Treatment Co., Ltd. produces filters), obtain nano level finishing agent product.
Described cycloaliphatic polyisocyanate is the WB-905 enclosed type water-based cycloaliphatic polyisocyanate that vast and boundless firm Chemical Industry Science Co., Ltd produces.
A kind of anti-blood stains emergency clothing, the fabric of described emergency clothing is the fabric after processing through above-mentioned anti-blood stains clothing finishing agent, described processing method comprises the following steps:
(1) fabric preliminary treatment: the fabric process of emergency clothing is soaped, and the temperature of soaping is 90 ℃, and the time of soaping is 18 minutes, removes the surfactant of fabric;
(2) with above-mentioned finishing agent thin up, be mixed to get the pH=5 dressing liquid according to the volume ratio ratio of 1: 15;
(3) the pretreated fabric of above-mentioned steps (1) is flooded with the dressing liquid that step (2) obtains, 20 ℃ of condition temperature, 80 minutes time, then squeeze obtain liquid carrying rate (be on fabric panel with the maceration extract quality account for the percentage of dry fabric fabric quality) 70% fabric;
(4) fabric with above-mentioned steps (3) gained carries out drying and shaping, 190 ℃ of temperature, 1 minute time.
Result: the fabric panel after above-mentioned processing is placed in the blood stains immersion takes out after 20 minutes, have not a particle of blood stains and be infected with; Compare with the identical fabric fabric of non-processor, gas permeability is identical.
In each embodiment of the present invention, chemical industry material used is material used in the production of this area, all can obtain from market, and can not exert an influence for the production result; The equipment of using in each operation all adopts conventional equipment used in current production, there is no special feature.
It should be noted that at last: the above only is the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment, the present invention is had been described in detail, for a person skilled in the art, it still can be modified to the technical scheme that aforementioned each embodiment puts down in writing, and perhaps part technical characterictic wherein is equal to replacement.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (5)
1. anti-blood stains clothing finishing agent, it is characterized in that: the raw material by following weight portion is prepared from:
Major ingredient: 90 parts of fluorocarbon resins;
Auxiliary material: 8 parts of titanium dioxide, 7 parts of APP, 5 parts of zirconium carbides;
Auxiliary agent: 5 parts of dodecafluoroheptyl methacrylates;
Crosslinking agent: 1 part of cycloaliphatic polyisocyanate;
Initator: 0.5 part of dibutyl tin laurate;
Above-mentioned each feedstock particle size is 0.1~1 * 10
-9m;
The preparation method is: major ingredient and auxiliary material mix, the deionized water of quality such as then add, pour into and carry out emulsification in emulsion tank, splash into reactor after emulsification is complete under 74~78 ℃, drip simultaneously auxiliary agent, crosslinking agent and initator, time for adding is 3 hours, controls temperature in the dropping process between 74~78 ℃, after being added dropwise to complete, 74~78 ℃ are incubated l hour, then be cooled to 30 ℃, carry out the nanofiltration device and filter, obtain nano level finishing agent product.
2. anti-blood stains clothing finishing agent according to claim 1 is characterized in that: described emulsion tank is the JP600 type ultrasonic emulsification tank that Wuhan Jiapeng Electronics Co., Ltd. produces.
3. anti-blood stains clothing finishing agent according to claim 1 is characterized in that: described nanofiltration device is the 1T/H model nanofiltration device that Dongguan Wojiesen Water Treatment Co., Ltd. produces.
4. anti-blood stains clothing finishing agent according to claim 1 is characterized in that: described cycloaliphatic polyisocyanate is the WB-905 enclosed type water-based cycloaliphatic polyisocyanate that vast and boundless firm Chemical Industry Science Co., Ltd produces.
5. anti-blood stains emergency clothing is characterized in that: the fabric of described emergency clothing is the fabric after processing through the described anti-blood stains clothing finishing agent of any one in the claims 1-4;
Processing method comprises the following steps:
(1) fabric preliminary treatment: the fabric process of emergency clothing is soaped, and the temperature of soaping is 88-92 ℃, and the time of soaping is 16-19 minute, removes the surfactant of fabric;
(2) with the described anti-blood stains clothing finishing agent thin up of any one in claim 1-4, mix according to the volume ratio ratio of 1: 15, obtain the pH=5 dressing liquid;
(3) the pretreated fabric of above-mentioned steps (1) is flooded with the dressing liquid that step (2) obtains, then 20-22 ℃ of condition temperature, time 70-90 minute squeeze the fabric that obtains liquid carrying rate 68~73%;
(4) fabric with above-mentioned steps (3) gained carries out drying and shaping, 190 ℃ of temperature, 1 minute time.
Priority Applications (1)
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CN 201110361317 CN102493189B (en) | 2011-11-15 | 2011-11-15 | Anti-bloodiness clothing finishing agent and emergency clothes |
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CN 201110361317 CN102493189B (en) | 2011-11-15 | 2011-11-15 | Anti-bloodiness clothing finishing agent and emergency clothes |
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CN102493189A CN102493189A (en) | 2012-06-13 |
CN102493189B true CN102493189B (en) | 2013-06-26 |
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CN 201110361317 Expired - Fee Related CN102493189B (en) | 2011-11-15 | 2011-11-15 | Anti-bloodiness clothing finishing agent and emergency clothes |
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CN103103789A (en) * | 2012-12-14 | 2013-05-15 | 常熟市张桥雪松印花厂 | Preparation method for blood-resistant clothing finishing agent |
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US7244371B2 (en) * | 2003-09-11 | 2007-07-17 | Xinggao Fang | Compositions and methods for treating a textile using such compositions |
US20060292324A1 (en) * | 2004-03-26 | 2006-12-28 | Robert Roberts | Uniaxially and biaxially-oriented polytetrafluoroethylene structures |
TWI306130B (en) * | 2004-10-22 | 2009-02-11 | Formosa Taffeta Co Ltd | Preparation of fabrics having lotus leaf effect and fabrics having lotus leaf effect |
US7695807B2 (en) * | 2006-04-04 | 2010-04-13 | E.I. Du Pont De Nemours And Company | Non-stick finish |
CN101349010A (en) * | 2008-08-28 | 2009-01-21 | 苏州大学 | Silk broadcloth anti-water anti-oil dressing agent, preparation method and uses thereof |
CN101560731A (en) * | 2009-05-19 | 2009-10-21 | 青岛中泰化纤丝绸有限责任公司 | Washable, oil repellent and water repellent finishing agent suitable for synthetic fiber fabric |
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Granted publication date: 20130626 Termination date: 20131115 |