CN108342904A - A kind of creasing anti-bacterial processing method of real silk fabric - Google Patents
A kind of creasing anti-bacterial processing method of real silk fabric Download PDFInfo
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- CN108342904A CN108342904A CN201810192484.2A CN201810192484A CN108342904A CN 108342904 A CN108342904 A CN 108342904A CN 201810192484 A CN201810192484 A CN 201810192484A CN 108342904 A CN108342904 A CN 108342904A
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- 239000004744 fabric Substances 0.000 title claims abstract description 90
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 29
- 238000003672 processing method Methods 0.000 title claims abstract description 16
- 229920001661 Chitosan Polymers 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 20
- 238000012986 modification Methods 0.000 claims abstract description 18
- 230000004048 modification Effects 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 9
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 52
- 238000001035 drying Methods 0.000 claims description 36
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- 238000002386 leaching Methods 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 235000007164 Oryza sativa Nutrition 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 230000010355 oscillation Effects 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 235000009566 rice Nutrition 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 230000000845 anti-microbial effect Effects 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 238000007605 air drying Methods 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000008236 heating water Substances 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 210000000481 breast Anatomy 0.000 claims 1
- 229910001882 dioxygen Inorganic materials 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 230000007547 defect Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000011160 research Methods 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 abstract description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 241000209094 Oryza Species 0.000 description 4
- 241000588724 Escherichia coli Species 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000001153 anti-wrinkle effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- PXFBZOLANLWPMH-UHFFFAOYSA-N 16-Epiaffinine Natural products C1C(C2=CC=CC=C2N2)=C2C(=O)CC2C(=CC)CN(C)C1C2CO PXFBZOLANLWPMH-UHFFFAOYSA-N 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 239000000823 artificial membrane Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention provides a kind of creasing anti-bacterial processing methods of real silk fabric, chitosan itself has apparent antibacterial effect, biocompatibility is further enhanced after modification, secondly, modified organic silicone finishing agent can further be also easy to produce the shortcomings that fold, antibacterial fabric performance is enhanced after oxygen-containing group in graphene is combined with fabric fibre, and various finishing agent macromoleculars can more fully be attached to fabric surface.In terms of research technique, by suitable concentration proportioning, suitable bath temperature and time is adjusted, in conjunction with best impregnation-squeezing technology so that test best results are most suitable for human body.The method of the present invention is simple for process, it is at low cost, safety and environmental protection, the finishing agent of use is modification agent, take full advantage of the defect that the modified outstanding advantages of finishing agent compensate for silk fabric itself, the creasing anti-bacterial performance of real silk fabric can be effectively improved, and so that real silk fabric is kept original feel and toughness without any damage in fabric.
Description
Technical field
The present invention relates to a kind of fabrics, and in particular to a kind of processing method of real silk fabric.
Background technology
Real silk fabric is a kind of fabric made of natural mulberry silk fiber, and smooth bright and clean, bright in luster pure, feel is soft
Soft, appearance is slim and graceful, and drapability is good, and since its is comfortable and easy to wear, moisture absorption is ventilative, raw material sources are in natural, affine to human skin
Power is good, is favored by people from ancient times to the present.
Real silk fabric has many excellent performances, but it easy tos produce fold and shrinkage phenomenon in rinse cycle, this is
Its exemplary shortcomings.With continuing to bring out for new chemical fiber in recent years, the shortcomings that real silk fabric is more aobvious to be protruded, so improving
Its wrinkle resistance simultaneously assigns its a variety of specific function and is of great significance.In addition, containing a large amount of fine in natural fiber in silk
Dimension element and protein, are conducive to the growth and breeding of bacterium, therefore it is necessary to carry out antimicrobial treatment to real silk fabric, make its
Safe healthcare effect is had more in dress.
Invention content
Goal of the invention：In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of the crease-resistant anti-of real silk fabric
Bacterium processing method can effectively improve creasing anti-bacterial performance, and lossless to fabric using this method treated real silk fabric
Wound makes it keep original feel and toughness.
Technical solution：The present invention provides a kind of creasing anti-bacterial processing methods of real silk fabric, include the following steps：
（1）Compound concentration is the MgCl of the modified organic silicon aqueous finish solution and a concentration of 2~10g/L of 2~10g/L respectively2▪
6H2Two kinds of aqueous solutions are uniformly mixed by O aqueous catalyst solutions, and the volumetric concentration of wherein modified organic silicon aqueous finish solution exists
30% ~ 70% range；
（2）Take step（1）100 ~ 200ml solution is placed under 20 ~ 50 DEG C of water bath after heating 5min and is put into very in container
Silk fabrics makes real silk fabric be totally submerged, and continues heating water bath 5min；
（3）Real silk fabric is taken out, in step（1）Two leachings two are rolled in the solution of preparation, are then dried, drying temperature 110~130
DEG C, 1~3min of drying time；
（4）Real silk fabric after drying rinses in the liquid soap that volume fraction is 2 ~ 10%, 30 ~ 50 DEG C of temperature, and the time 20 ~
It is taken out after 50min, clear water is dry after cleaning；
（5）It is received by the modification of chitosan solution of solvent configuration quality score 0.1%~1% of 0.2mol/L acetic acid solutions as antibacterial
Rice finishing agent；
（6）By step（4）In it is dry after real silk fabric be put into antimicrobial nano finishing agent, and vibrated in 50 DEG C of water-baths
40min；
（7）Real silk fabric is taken out, is washed with deionized water only, by fabric drying；
（8）Fabric after drying is immersed in graphene dispersing solution after 2h and is taken out, two leachings two is then carried out again and rolls operation, most
Air blast dries up fabric under room temperature afterwards.
Further, step（1）The modified organic silicon finishing agent uses polyethers base silane and amino silane for primary raw material,
Using 1:Amino modified organic silicon solution is made up of emulsion polymerization under room temperature for 3 volume ratio.
Further, step（3）The three roller laboratory mangles using pick-up rate 100% are rolled in two leachings two.
Further, step（5）The modification of chitosan solution uses acetic acid solution with chitosan for primary raw material, using 2:
Modified chitosan solution is obtained by the reaction under room temperature in 3 volume ratio.
Further, step（6）The oscillation rate of water-bath is 100r/min.
Further, step（7）In drying temperature be 100 DEG C ~ 120 DEG C, drying time 1min.
Further, step（8）In graphene dispersing solution be to be prepared by Hummers methods, be graphene oxide first
It prepares, is uniformly mixed with 10 ~ 20ml of the concentrated sulfuric acid, potassium permanganate 4g, graphite 1g, reacts 30min at a temperature of 40 DEG C ~ 50 DEG C, add
The hydrogen peroxide of 30% volume fractions of 5ml ~ 10ml, then washed with the dilute hydrochloric acid of 10% volume fraction of 200ml ~ 300ml, after washing
Forced air drying at room temperature obtains graphene oxide；Graphene oxide is pulverized again, be heated rapidly under microwave 700 DEG C ~
1000 DEG C of redox graphenes, then by the powder after heating up and water with mass ratio 10:7 ratio is uniformly mixed.
Inventive principle：1, in the active silicone hydroxyl and cellulose in the amino-modified silicone finishing agent that the present invention uses
Hydroxyl reaction form cross-linked structure, reach anti-wrinkle effect, be added after amino that then the water-soluble of organosilicon is improved, be conducive to
The abundant progress of reaction.2, the modification of chitosan finishing agent used can be combined with the immobilized artificial membrane on cell membrane, and memebrane protein is caused to become
Property, membrane structure is destroyed, and reaches antibacterial effect, it is acylated after chitosan biological compatibility more preferably.3, graphene nano material
Being dissolved into silk fiber can not only make fabric anti-bacterial effect more preferable, and the ability of the superpower absorption macromolecular of itself can more make organic
Silicon molecule is preferably attached to above fabric with chitosan molecule.Even if making treated real silk fabric after multiple washing still
So there is preferable antibacterial anti-wrinkle effect.
Advantageous effect：There is chitosan itself apparent antibacterial effect, biocompatibility further to be carried after modification
Height, secondly, the shortcomings that modified organic silicone finishing agent can further be also easy to produce fold, by graphene oxygen-containing group with
Antibacterial fabric performance is enhanced after fabric fibre combines, and various finishing agent macromoleculars can more fully be attached to fabric table
Face.In terms of research technique, by suitable concentration proportioning, suitable bath temperature and time is adjusted, is padded in conjunction with best
Technology so that test best results are most suitable for human body.The method of the present invention simple process and low cost, safety and environmental protection, use it is whole
It is modification agent to manage agent, takes full advantage of the defect that the modified outstanding advantages of finishing agent compensate for silk fabric itself,
The creasing anti-bacterial performance of real silk fabric can be effectively improved, and so that real silk fabric is kept original hand without any damage in fabric
Sense and toughness.
Specific implementation mode
Technical solution of the present invention is described in detail below, but protection scope of the present invention is not limited to the implementation
Example.
Embodiment 1：A kind of creasing anti-bacterial processing method of real silk fabric, includes the following steps：
The first step：Modified organic silicon finishing agent is configured to the aqueous solution of a concentration of 3g/L, by 2:1 volume ratio is added a concentration of
The MgCl2 6H2O aqueous catalyst solutions of 6g/L are uniformly mixed；
Second step：It takes above-mentioned part solution in beaker, is placed under 30 DEG C of water bath after carrying out heating 5min and is put into silk
Fabric continues water-bath 5min；
Third walks：Real silk fabric is taken out, fabric is disseminated using solution is configured in the first step, then uses three roller of laboratory
Laboratory mangle（Pick-up rate 100%）Two leachings two are carried out to the fabric after dip dyeing to roll, and are then dried, wherein 130 DEG C of drying temperature,
Drying time 3min；
4th step：Fabric after drying takes out after rinsing 30min in 40 DEG C of waters bath with thermostatic control in 5% liquid soap, and clear water is washed several
It is dry after secondary；
5th step：It is received by the modification of chitosan solution of solvent configuration quality score 0.6% of 0.2mol/L acetic acid solutions as antibacterial
Rice finishing agent, is found by experiment that Escherichia coli and staphylococcus aureus need 50h-60h in 0.6% modification of chitosan
Inside can be only achieved growth vertex, and without modification of chitosan solution again for 24 hours in can reach growth peak；
6th step：Take chitosan solution in beaker, will be dry in the 4th step after real silk fabric be put into wherein, and in 50 DEG C of water
40min is vibrated in bath, the wherein oscillation rate of water-bath is 100r/min；
7th step：Fabric is taken out, deionized water is cleaned several times, and last time cleaning solution is taken to measure pH value, if neutral then table
Show that acetic acid is cleaned, by fabric drying, drying temperature is 100 DEG C ~ 120 DEG C, drying time 1min；
8th step：Fabric after drying is immersed in graphene oxide dispersion after 2h and is taken out, then rolls behaviour by two leachings two
It is more firm that work makes the oxygen-containing group in graphene be combined with silk fiber, air blast drying fabric under last room temperature；
9th step：It by the adhesion condition of scanning electron microscopic observation fabric surface molecule, finds compared with before cleaning, overall big point
The adhesion amount of son only reduces 5%, maintains 95% or more adhesion amount.
Embodiment 2：A kind of creasing anti-bacterial processing method of real silk fabric, includes the following steps：
The first step：Modified organic silicon finishing agent is configured to the aqueous solution of a concentration of 6g/L, by 1:1 volume ratio is added a concentration of
The MgCl2 6H2O aqueous catalyst solutions of 6g/L are uniformly mixed；
Second step：It takes above-mentioned part solution in beaker, is placed under 30 DEG C of water bath after carrying out heating 5min and is put into silk
Fabric continues water-bath 5min；
Third walks：Real silk fabric is taken out, fabric is disseminated using solution is configured in the first step, then uses three roller of laboratory
Laboratory mangle（Pick-up rate 100%）Two leachings two are carried out to the fabric after dip dyeing to roll, and are then dried, wherein 130 DEG C of drying temperature,
Drying time 3min；
4th step：Fabric after drying takes out after rinsing 30min in 40 DEG C of waters bath with thermostatic control in 5% liquid soap, and clear water is washed several
It is dry after secondary；
5th step：It is received by the modification of chitosan solution of solvent configuration quality score 0.6% of 0.2mol/L acetic acid solutions as antibacterial
Rice finishing agent, is found by experiment that Escherichia coli and staphylococcus aureus need 50h-60h in 0.6% modification of chitosan
Inside can be only achieved growth vertex, and without modification of chitosan solution again for 24 hours in can reach growth peak；
6th step：Take chitosan solution in beaker, will be dry in the 4th step after real silk fabric be put into wherein, and in 50 DEG C of water
40min is vibrated in bath, the wherein oscillation rate of water-bath is 100r/min；
7th step：Fabric is taken out, deionized water is cleaned several times, and last time cleaning solution is taken to measure pH value, if neutral then table
Show that acetic acid is cleaned, by fabric drying, drying temperature is 100 DEG C ~ 120 DEG C, drying time 1min；
8th step：Fabric after drying is immersed in graphene oxide dispersion after 2h and is taken out, the oxygen-containing group in graphene is made
Group is combined more firm with cocoon fiber；
9th step：It by the adhesion condition of scanning electron microscopic observation fabric surface molecule, finds compared with before cleaning, overall big point
The adhesion amount of son reduces 10%, maintains 90% or more adhesion amount.
Embodiment 3：A kind of creasing anti-bacterial processing method of real silk fabric, includes the following steps：
The first step：Modified organic silicon finishing agent is configured to the aqueous solution of a concentration of 6g/L, by 1:2 volume ratio is added a concentration of
The MgCl2 6H2O aqueous catalyst solutions of 9g/L are uniformly mixed；
Second step：It takes above-mentioned part solution in beaker, is placed under 30 DEG C of water bath after carrying out heating 5min and is put into silk
Fabric continues water-bath 5min；
Third walks：Real silk fabric is taken out, fabric is disseminated using solution is configured in the first step, then uses three roller of laboratory
Laboratory mangle（Pick-up rate 100%）Two leachings two are carried out to the fabric after dip dyeing to roll, and are then dried, wherein 130 DEG C of drying temperature,
Drying time 3min；
4th step：Fabric after drying takes out after rinsing 30min in 40 DEG C of waters bath with thermostatic control in 5% liquid soap, and clear water is washed several
It is dry after secondary；
5th step：It is received by the modification of chitosan solution of solvent configuration quality score 0.6% of 0.2mol/L acetic acid solutions as antibacterial
Rice finishing agent, is found by experiment that Escherichia coli and staphylococcus aureus need 50h-60h in 0.6% modification of chitosan
Inside can be only achieved growth vertex, and without modification of chitosan solution again for 24 hours in can reach growth peak；
6th step：Take chitosan solution in beaker, will be dry in the 4th step after real silk fabric be put into wherein, and in 50 DEG C of water
40min is vibrated in bath, the wherein oscillation rate of water-bath is 100r/min；
7th step：Fabric is taken out, deionized water is cleaned several times, and last time cleaning solution is taken to measure pH value, if neutral then table
Show that acetic acid is cleaned, by fabric drying, drying temperature is 100 DEG C ~ 120 DEG C, drying time 1min..8th step：After drying
Fabric is immersed in graphene oxide dispersion and is taken out after 2h, and then drying makes graphite oxide at a high temperature of 700 DEG C ~ 1000 DEG C
Alkene is restored, and so that the oxygen-containing group in graphene is combined with cocoon fiber more firm；
9th step：It by the adhesion condition of scanning electron microscopic observation fabric surface molecule, finds compared with before cleaning, overall big point
The adhesion amount of son only reduces 8%, maintains 92% or more adhesion amount.
Claims (7)
1. a kind of creasing anti-bacterial processing method of real silk fabric, it is characterised in that：Include the following steps：
（1）Compound concentration is the MgCl of the modified organic silicon aqueous finish solution and a concentration of 2~10g/L of 2~10g/L respectively2▪
6H2Two kinds of aqueous solutions are uniformly mixed by O aqueous catalyst solutions, and the volumetric concentration of wherein modified organic silicon aqueous finish solution exists
30% ~ 70% range；
（2）Take step（1）100 ~ 200ml solution is placed under 20 ~ 50 DEG C of water bath after heating 5min and is put into very in container
Silk fabrics makes real silk fabric be totally submerged, and continues heating water bath 5min；
（3）Real silk fabric is taken out, in step（1）Two leachings two are rolled in the solution of preparation, are then dried, drying temperature 110~130
DEG C, 1~3min of drying time；
（4）Real silk fabric after drying rinses in the liquid soap that volume fraction is 2 ~ 10%, 30 ~ 50 DEG C of temperature, and the time 20 ~
It is taken out after 50min, clear water is dry after cleaning；
（5）It is received by the modification of chitosan solution of solvent configuration quality score 0.1%~1% of 0.2mol/L acetic acid solutions as antibacterial
Rice finishing agent；
（6）By step（4）In it is dry after real silk fabric be put into antimicrobial nano finishing agent, and vibrated in 50 DEG C of water-baths
40min；
（7）Real silk fabric is taken out, is washed with deionized water only, by fabric drying；
（8）Fabric after drying is immersed in graphene dispersing solution after 2h and is taken out, two leachings two is then carried out again and rolls operation, most
Air blast dries up fabric under room temperature afterwards.
2. the creasing anti-bacterial processing method of real silk fabric according to claim 1, it is characterised in that：Step（1）It is described to change
Property organic silicone finishing agent uses polyethers base silane and amino silane for primary raw material, using 1:3 volume ratio passes through breast under room temperature
Amino modified organic silicon solution is made in liquid polymerization.
3. the creasing anti-bacterial processing method of real silk fabric according to claim 1, it is characterised in that：Step（3）Two leachings two
Roll the three roller laboratory mangles using pick-up rate 100%.
4. the creasing anti-bacterial processing method of real silk fabric according to claim 1, it is characterised in that：Step（5）It is described to change
Property chitosan solution use acetic acid solution and chitosan for primary raw material, using 2:Modification is obtained by the reaction under room temperature in 3 volume ratio
Chitosan solution.
5. the creasing anti-bacterial processing method of real silk fabric according to claim 1, it is characterised in that：Step（6）Water-bath
Oscillation rate be 100r/min.
6. the creasing anti-bacterial processing method of real silk fabric according to claim 1, it is characterised in that：Step（7）In baking
Dry temperature is 100 DEG C ~ 120 DEG C, drying time 1min.
7. according to the creasing anti-bacterial processing method of real silk fabric as described in the claims, it is characterised in that：Step（8）In
Graphene dispersing solution is prepared by Hummers methods, is the preparation of graphene oxide first, with 10 ~ 20ml of the concentrated sulfuric acid, permanganic acid
Potassium 4g, graphite 1g are uniformly mixed, and are reacted 30min at a temperature of 40 DEG C ~ 50 DEG C, are added the dioxygen of 30% volume fractions of 5ml ~ 10ml
Water, then washed with the dilute hydrochloric acid of 10% volume fraction of 200ml ~ 300ml, forced air drying at room temperature after washing, obtain oxidation stone
Black alkene；Graphene oxide is pulverized again, 700 DEG C ~ 1000 DEG C redox graphenes are heated rapidly under microwave, then will
Powder after heating up is with water with mass ratio 10:7 ratio is uniformly mixed.
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