CN102493189A - Anti-bloodiness clothing finishing agent and emergency clothes - Google Patents

Anti-bloodiness clothing finishing agent and emergency clothes Download PDF

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Publication number
CN102493189A
CN102493189A CN2011103613174A CN201110361317A CN102493189A CN 102493189 A CN102493189 A CN 102493189A CN 2011103613174 A CN2011103613174 A CN 2011103613174A CN 201110361317 A CN201110361317 A CN 201110361317A CN 102493189 A CN102493189 A CN 102493189A
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Prior art keywords
lining
finishing agent
blood stains
parts
agent
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CN2011103613174A
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CN102493189B (en
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王国栋
韩晓丽
张光芳
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Abstract

The invention discloses an anti-bloodiness clothing finishing agent and an emergency clothes. The finishing agent is prepared from raw materials comprising a main material, an auxiliary material, an assistant agent, a cross-linking agent and an initiator. The fabric of the emergency clothes is the fabric treated by using the finishing agent. The finishing agent and the emergency clothes of the present invention have the following advantages that: on the basis that the finishing agent truly maintains the original performances of the fabric, the finished fabric has an anti-bloodiness effect; the finishing agent is a nanoscale material, such that the original air permeability of the fabric is not affected; the components of the raw materials are simple; the preparation method is simple.

Description

A kind of anti-blood stains clothing finishing agent and first aid clothes
Technical field
The present invention relates to a kind of first aid clothes, specifically a kind of anti-blood stains clothing finishing agent and the first aid clothes that use this finishing agent belong to medical field.
Background technology
At medical field; In order to rescue in time; The doctor can change oneself before receiving 120 urgent ambulance calls clothes is put on the first aid clothes and is taken the emergency tender noneffectives is carried out simple first aid process, the first aid clothes be the doctor when implementing first aid, be through outermost clothes; In first aid process, wrap up patient's wound, lift simple action such as patient.The traditional first aid clothes materials such as nonwoven fabric, cotton that adopt are processed more, when first aid, if there is spot such as blood stains to be infected with on the first aid clothes, just are difficult to wipe, and also are not easy to wash.
Summary of the invention
In order to address the above problem, the first aid clothes that the object of the present invention is to provide a kind of anti-blood stains clothing finishing agent and used this finishing agent.
Technical scheme of the present invention is:
A kind of anti-blood stains clothing finishing agent is formed by the feedstock production of following weight portion:
Major ingredient: 90 parts of fluorocarbon resins;
Auxiliary material: 8 parts of titanium dioxide, 7 parts of APPs, 5 parts of zirconium carbides;
Auxiliary agent: 5 parts of methacrylic acid ten difluoro heptyl esters;
Crosslinking agent: 1 part of cycloaliphatic polyisocyanate;
Initator: 0.5 part of dibutyl tin laurate;
It is that granular size is 0.1~1 * 10 that above-mentioned each raw material is nanoscale -9M;
Described preparation method is: major ingredient and auxiliary material mix, and the deionized water of quality such as add then, pour into and carry out emulsification in the emulsion tank; Under 74~78 ℃, splash in the agitated reactor after emulsification finishes, drip auxiliary agent, crosslinking agent and initator simultaneously, the dropping time is 3 hours; The control temperature is between 74~78 ℃ in the dropping process, and after being added dropwise to complete, 74~78 ℃ are incubated l hour; Be cooled to 30 ℃ then, carry out the nanofiltration device and filter, obtain nano level finishing agent product.
Further, described emulsion tank is the JP600 type ultrasonic emulsification jar that Wuhan Jiapeng Electronics Co., Ltd. produces;
Described nanofiltration device is the 1T/H model nanofiltration device that Dongguan Wojiesen Water Treatment Co., Ltd. produces;
Described cycloaliphatic polyisocyanate is the WB-905 enclosed type water-based cycloaliphatic polyisocyanate that vast and boundless firm Chemical Industry Science Co., Ltd produces.
A kind of anti-blood stains first aid clothes, the lining of said first aid clothes is the lining after handling through above-mentioned anti-blood stains clothing finishing agent, described processing method may further comprise the steps:
(1) lining preliminary treatment: the lining process of first aid clothes is soaped, and the temperature of soaping is 88-92 ℃, and the time of soaping is 16-19 minute, removes the surfactant of lining;
(2),, obtain the pH=5 dressing liquid according to 1: 15 mixed of volume ratio with above-mentioned finishing agent thin up;
(3) the pretreated lining of above-mentioned steps (1) is flooded with the dressing liquid that step (2) obtains; 20-22 ℃ of condition temperature, time 70-90 minute, squeeze then obtain liquid carrying rate (be on the fabric panel with the maceration extract quality account for the percentage of dry fabric fabric quality) 68~73% lining;
(4) lining with above-mentioned steps (3) gained carries out drying and shaping, 190 ℃ of temperature, 1 minute time.
The invention has the advantages that: said finishing agent is on the basis that has really kept the original performance of fabric panel; Make the fabric panel after the arrangement have the effect of anti-blood stains; Simultaneously, because of finishing agent is nanometer materials, thereby do not influence the original gas permeability of fabric; Material composition is simple, and the preparation method is easy.
The specific embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein only is used for explanation and explains the present invention, and be not used in qualification the present invention.
Except as otherwise noted, the percentage that is adopted among the present invention is percetage by weight.
Embodiment 1
A kind of anti-blood stains clothing finishing agent,
Feedstock production by following weight portion forms:
Major ingredient: 90 parts of fluorocarbon resins;
Auxiliary material: 8 parts of titanium dioxide, 7 parts of APPs, 5 parts of zirconium carbides;
Auxiliary agent: 5 parts of methacrylic acid ten difluoro heptyl esters;
Crosslinking agent: 1 part of cycloaliphatic polyisocyanate;
Initator: 0.5 part of dibutyl tin laurate;
It is that granular size is 0.1~1 * 10 that above-mentioned each raw material is nanoscale -9M;
The preparation method is: major ingredient and auxiliary material mix, and the deionized water of quality such as add then, pour into and carry out emulsification in the emulsion tank (the JP600 type ultrasonic emulsification jar that Wuhan Jiapeng Electronics Co., Ltd. produces); Under 74 ℃, splash in the agitated reactor after emulsification finishes, drip auxiliary agent, crosslinking agent and initator simultaneously, the dropping time is 3 hours; The control temperature is at 74 ℃ in the dropping process; After being added dropwise to complete, 74 ℃ are incubated l hour, are cooled to 30 ℃ then; Carry out nanofiltration device (the 1T/H model nanofiltration device that Dongguan Wojiesen Water Treatment Co., Ltd. produces filters), obtain nano level finishing agent product.
Described cycloaliphatic polyisocyanate is the WB-905 enclosed type water-based cycloaliphatic polyisocyanate that vast and boundless firm Chemical Industry Science Co., Ltd produces.
A kind of anti-blood stains first aid clothes, the lining of said first aid clothes is the lining after handling through above-mentioned anti-blood stains clothing finishing agent, described processing method may further comprise the steps:
(1) lining preliminary treatment: the lining process of first aid clothes is soaped, and the temperature of soaping is 88 ℃, and the time of soaping is 16 minutes, removes the surfactant of lining;
(2), obtain the pH=5 dressing liquid according to 1: 15 mixed of volume ratio with above-mentioned finishing agent thin up;
(3) the pretreated lining of above-mentioned steps (1) is flooded with the dressing liquid that step (2) obtains; 20 ℃ of condition temperature, 70 minutes time, squeeze then obtain liquid carrying rate (be on the fabric panel with the maceration extract quality account for the percentage of dry fabric fabric quality) 68% lining;
(4) lining with above-mentioned steps (3) gained carries out drying and shaping, 190 ℃ of temperature, 1 minute time.
Result: place the blood stains immersion to take out after 15 minutes the fabric panel after the above-mentioned processing, have not a particle of blood stains and be infected with; Compare with the identical fabric lining of non-processor, gas permeability is identical.
Embodiment 2
A kind of anti-blood stains clothing finishing agent,
Feedstock production by following weight portion forms:
Major ingredient: 90 parts of fluorocarbon resins;
Auxiliary material: 8 parts of titanium dioxide, 7 parts of APPs, 5 parts of zirconium carbides;
Auxiliary agent: 5 parts of methacrylic acid ten difluoro heptyl esters;
Crosslinking agent: 1 part of cycloaliphatic polyisocyanate;
Initator: 0.5 part of dibutyl tin laurate;
It is that granular size is 0.1~1 * 10 that above-mentioned each raw material is nanoscale -9M;
The preparation method is: major ingredient and auxiliary material mix, and the deionized water of quality such as add then, pour into and carry out emulsification in the emulsion tank (the JP600 type ultrasonic emulsification jar that Wuhan Jiapeng Electronics Co., Ltd. produces); Under 74~78 ℃, splash in the agitated reactor after emulsification finishes, drip auxiliary agent, crosslinking agent and initator simultaneously, the dropping time is 3 hours; The control temperature is at 78 ℃ in the dropping process; After being added dropwise to complete, 74 ℃ are incubated l hour, are cooled to 30 ℃ then; Carry out nanofiltration device (the 1T/H model nanofiltration device that Dongguan Wojiesen Water Treatment Co., Ltd. produces filters), obtain nano level finishing agent product.
Described cycloaliphatic polyisocyanate is the WB-905 enclosed type water-based cycloaliphatic polyisocyanate that vast and boundless firm Chemical Industry Science Co., Ltd produces.
A kind of anti-blood stains first aid clothes, the lining of said first aid clothes is the lining after handling through above-mentioned anti-blood stains clothing finishing agent, described processing method may further comprise the steps:
(1) lining preliminary treatment: the lining process of first aid clothes is soaped, and the temperature of soaping is 92 ℃, and the time of soaping is 19 minutes, removes the surfactant of lining;
(2), obtain the pH=5 dressing liquid according to 1: 15 mixed of volume ratio with above-mentioned finishing agent thin up;
(3) the pretreated lining of above-mentioned steps (1) is flooded with the dressing liquid that step (2) obtains; 22 ℃ of condition temperature, 90 minutes time, squeeze then obtain liquid carrying rate (be on the fabric panel with the maceration extract quality account for the percentage of dry fabric fabric quality) 73% lining;
(4) lining with above-mentioned steps (3) gained carries out drying and shaping, 190 ℃ of temperature, 1 minute time.
Result: place the blood stains immersion to take out after 10 minutes the fabric panel after the above-mentioned processing, have not a particle of blood stains and be infected with; Compare with the identical fabric lining of non-processor, gas permeability is identical.
Embodiment 3
A kind of anti-blood stains clothing finishing agent,
Feedstock production by following weight portion forms:
Major ingredient: 90 parts of fluorocarbon resins;
Auxiliary material: 8 parts of titanium dioxide, 7 parts of APPs, 5 parts of zirconium carbides;
Auxiliary agent: 5 parts of methacrylic acid ten difluoro heptyl esters;
Crosslinking agent: 1 part of cycloaliphatic polyisocyanate;
Initator: 0.5 part of dibutyl tin laurate;
It is that granular size is 0.1~1 * 10 that above-mentioned each raw material is nanoscale -9M;
The preparation method is: major ingredient and auxiliary material mix, and the deionized water of quality such as add then, pour into and carry out emulsification in the emulsion tank (the JP600 type ultrasonic emulsification jar that Wuhan Jiapeng Electronics Co., Ltd. produces); Under 74~78 ℃, splash in the agitated reactor after emulsification finishes, drip auxiliary agent, crosslinking agent and initator simultaneously, the dropping time is 3 hours; The control temperature is at 76 ℃ in the dropping process; After being added dropwise to complete, 76 ℃ are incubated l hour, are cooled to 30 ℃ then; Carry out nanofiltration device (the 1T/H model nanofiltration device that Dongguan Wojiesen Water Treatment Co., Ltd. produces filters), obtain nano level finishing agent product.
Described cycloaliphatic polyisocyanate is the WB-905 enclosed type water-based cycloaliphatic polyisocyanate that vast and boundless firm Chemical Industry Science Co., Ltd produces.
A kind of anti-blood stains first aid clothes, the lining of said first aid clothes is the lining after handling through above-mentioned anti-blood stains clothing finishing agent, described processing method may further comprise the steps:
(1) lining preliminary treatment: the lining process of first aid clothes is soaped, and the temperature of soaping is 90 ℃, and the time of soaping is 18 minutes, removes the surfactant of lining;
(2), obtain the pH=5 dressing liquid according to 1: 15 mixed of volume ratio with above-mentioned finishing agent thin up;
(3) the pretreated lining of above-mentioned steps (1) is flooded with the dressing liquid that step (2) obtains; 20 ℃ of condition temperature, 80 minutes time, squeeze then obtain liquid carrying rate (be on the fabric panel with the maceration extract quality account for the percentage of dry fabric fabric quality) 70% lining;
(4) lining with above-mentioned steps (3) gained carries out drying and shaping, 190 ℃ of temperature, 1 minute time.
Result: place the blood stains immersion to take out after 20 minutes the fabric panel after the above-mentioned processing, have not a particle of blood stains and be infected with; Compare with the identical fabric lining of non-processor, gas permeability is identical.
Among each embodiment of the present invention, used chemical industry material is used material in the production of this area, all can from market, obtain, and can not exert an influence for the production result; The equipment of in each operation, using all adopts conventional equipment used in the current production, does not have special feature.
What should explain at last is: the above is merely the preferred embodiments of the present invention; Be not limited to the present invention; Although the present invention has been carried out detailed explanation with reference to previous embodiment; For a person skilled in the art, it still can be made amendment to the technical scheme that aforementioned each embodiment put down in writing, and perhaps part technical characterictic wherein is equal to replacement.All within spirit of the present invention and principle, any modification of being done, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (5)

1. anti-blood stains clothing finishing agent, it is characterized in that: the feedstock production by following weight portion forms:
Major ingredient: 90 parts of fluorocarbon resins;
Auxiliary material: 8 parts of titanium dioxide, 7 parts of APPs, 5 parts of zirconium carbides;
Auxiliary agent: 5 parts of methacrylic acid ten difluoro heptyl esters;
Crosslinking agent: 1 part of cycloaliphatic polyisocyanate;
Initator: 0.5 part of dibutyl tin laurate;
Above-mentioned each feedstock particle size is 0.1~1 * 10 -9M;
Described preparation method is: major ingredient and auxiliary material mix, and the deionized water of quality such as add then, pour into and carry out emulsification in the emulsion tank; Under 74~78 ℃, splash in the agitated reactor after emulsification finishes, drip auxiliary agent, crosslinking agent and initator simultaneously, the dropping time is 3 hours; The control temperature is between 74~78 ℃ in the dropping process, and after being added dropwise to complete, 74~78 ℃ are incubated l hour; Be cooled to 30 ℃ then, carry out the nanofiltration device and filter, obtain nano level finishing agent product.
2. anti-blood stains clothing finishing agent according to claim 1 is characterized in that: described emulsion tank is the JP600 type ultrasonic emulsification jar that Wuhan Jiapeng Electronics Co., Ltd. produces.
3. anti-blood stains clothing finishing agent according to claim 1 is characterized in that: described nanofiltration device is the 1T/H model nanofiltration device that Dongguan Wojiesen Water Treatment Co., Ltd. produces.
4. anti-blood stains clothing finishing agent according to claim 1 is characterized in that: described cycloaliphatic polyisocyanate is the WB-905 enclosed type water-based cycloaliphatic polyisocyanate that vast and boundless firm Chemical Industry Science Co., Ltd produces.
5. an anti-blood stains first aid is obeyed, and it is characterized in that: the lining of said first aid clothes is for requiring the lining after each described anti-blood stains clothing finishing agent processing among the 1-4 through aforesaid right;
Described processing method may further comprise the steps:
(1) lining preliminary treatment: the lining process of first aid clothes is soaped, and the temperature of soaping is 88-92 ℃, and the time of soaping is 16-19 minute, removes the surfactant of lining;
(2) with described anti-blood stains clothing finishing agent thin up,, obtain the pH=5 dressing liquid according to 1: 15 mixed of volume ratio;
(3) the pretreated lining of above-mentioned steps (1) is flooded with the dressing liquid that step (2) obtains, 20-22 ℃ of condition temperature, time 70-90 minute are squeezed the lining that obtains liquid carrying rate 68~73% then;
(4) lining with above-mentioned steps (3) gained carries out drying and shaping, 190 ℃ of temperature, 1 minute time.
CN 201110361317 2011-11-15 2011-11-15 Anti-bloodiness clothing finishing agent and emergency clothes Expired - Fee Related CN102493189B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN102493189B CN102493189B (en) 2013-06-26

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103103789A (en) * 2012-12-14 2013-05-15 常熟市张桥雪松印花厂 Preparation method for blood-resistant clothing finishing agent

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050056805A1 (en) * 2003-09-11 2005-03-17 Xinggao Fang Compositions and methods for treating a textile using such compositions
US20060085921A1 (en) * 2004-10-22 2006-04-27 Formosa Taffeta Co., Ltd. Method of preparing fabrics having lotus leaf effect and fabrics having lotus leaf effect
US20060292324A1 (en) * 2004-03-26 2006-12-28 Robert Roberts Uniaxially and biaxially-oriented polytetrafluoroethylene structures
CN101349010A (en) * 2008-08-28 2009-01-21 苏州大学 Silk broadcloth anti-water anti-oil dressing agent, preparation method and uses thereof
CN101415763A (en) * 2006-04-04 2009-04-22 纳幕尔杜邦公司 Non-stick finish
CN101560731A (en) * 2009-05-19 2009-10-21 青岛中泰化纤丝绸有限责任公司 Washable, oil repellent and water repellent finishing agent suitable for synthetic fiber fabric

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050056805A1 (en) * 2003-09-11 2005-03-17 Xinggao Fang Compositions and methods for treating a textile using such compositions
US20060292324A1 (en) * 2004-03-26 2006-12-28 Robert Roberts Uniaxially and biaxially-oriented polytetrafluoroethylene structures
US20060085921A1 (en) * 2004-10-22 2006-04-27 Formosa Taffeta Co., Ltd. Method of preparing fabrics having lotus leaf effect and fabrics having lotus leaf effect
CN101415763A (en) * 2006-04-04 2009-04-22 纳幕尔杜邦公司 Non-stick finish
CN101349010A (en) * 2008-08-28 2009-01-21 苏州大学 Silk broadcloth anti-water anti-oil dressing agent, preparation method and uses thereof
CN101560731A (en) * 2009-05-19 2009-10-21 青岛中泰化纤丝绸有限责任公司 Washable, oil repellent and water repellent finishing agent suitable for synthetic fiber fabric

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103103789A (en) * 2012-12-14 2013-05-15 常熟市张桥雪松印花厂 Preparation method for blood-resistant clothing finishing agent

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