Summary of the invention
The purpose of this invention is to provide a kind of SE Wood plastic boards, product uses has similar wood appearance, and higher than plastics hardness, the life-span is long, but thermoplastic shaping, intensity height and save energy, the present invention provides its preparation method simultaneously.
Described SE Wood plastic boards is made up of the raw material of following parts by weight, and raw material gross weight umber is 100 parts:
Described coupling agent is silane coupling agent, titanate coupling agent or aluminate coupling agent.
Described stablizer is compound Pb stabilizer, calcium zinc class stablizer or organotin stabilizer.
Described alkyl-acrylates modifier is the ACR modifier.
Described weighting agent is lime carbonate, talcum powder, calcinated argil or permanent white.
Described lubricant is Triple Pressed Stearic Acid, stearate, Solsperse 2000 compound, stearic amide class, fatty acid metal soap class, polyethylene wax, paraffin or oxidic polyethylene.
Described whipping agent is yellow whipping agent and white hair infusion, and yellow whipping agent is that Cellmic C 121, azo two isobutyls are fine, nitroso group foaming agent or hydrazides class whipping agent; The white hair infusion is sodium hydrogencarbonate, bicarbonate of ammonia, volatile salt or triazo-compound, and the mass ratio of yellow whipping agent and white hair infusion is 1: 1~1: 5.
Described toughner is chlorinatedpolyethylene, alkyl acrylate or ethylene-vinyl acetate polymkeric substance, and the granularity of described wood powder is 20~80 orders.
The preparation method of described SE Wood plastic boards: at first the raw material with formula ratio adds in the high-speed mixer, is heated to 105~120 ℃ through oil jacket heating and self-friction, puts into cold mixing;, puts into material storage bunker when being cooled to below 50 ℃; Lean on level gage automatic control material loading through the spring feeder, this storage bunker compound gets into 80/156 conical double-screw and extrudes processing, and the temperature control of screw rod oil is between 80~120 ℃; Barrel temperature temperature control is between 130~190 ℃; Molten materials gets into merging core through screw rod and branches to special-purpose rack-style foaming mould, and the merging core temperature is between 130~160 ℃, and die temperature is between 150~180 ℃; The die lip temperature is passed through die heater thermal oil temperature control between 130~160 ℃; Molten materials expands from the mould post-foaming and gets into typified form simultaneously, gets into edge-neatening apparatus through cooling and shaping and controls width, gets into automatic cutting machine then and is cut into finished product automatically by sl..
The invention has the beneficial effects as follows:
Tap density≤the 700kg/m of SE Wood plastic boards of the present invention
3, having excellent flame-retardant performance and smoke-suppressing, hardness is high simultaneously, and woodiness touch is strong; The same with log, have performances such as can following closely, can bore, can dig, can glue, smooth surface is fine and smooth, and water-fast, corrosion-resistant, fire prevention, mildew-resistant, do not damaged by worms, pollution-free.
Embodiment
Below in conjunction with embodiment the present invention is described further.
Embodiment 1
Described SE Wood plastic boards prescription is following: the 50 weight part polymerization degree are 1000 polyvinyl chloride resin powder, the compound Pb stabilizer of 2 weight parts, the ACR modifier of 5 weight parts; The lime carbonate of 2 weight parts, the polyethylene wax of 1 weight part, the Cellmic C 121 of 0.4 weight part; 0.6 the sodium hydrogencarbonate of weight part, the chlorinatedpolyethylene of 3.9 weight parts, 35 weight parts, 40 purpose wood powders; 0.1 the silane coupling agent of weight part, total weight parts are 100 parts.
The preparation method of described SE Wood plastic boards: at first the above-mentioned raw materials with formula ratio adds in the high-speed mixer, is heated to 110 ℃ through oil jacket heating and self-friction, puts into cold mixing; When material is cooled to 50 ℃, put into storage bunker, lean on level gage automatic control material loading through the spring feeder, this storage bunker compound gets into 80/156 conical double-screw and extrudes processing; 17 rev/mins of control screw speeds; The temperature control of screw rod oil is at 95 ℃, 180 ℃, 175 ℃, 170 ℃, 160 ℃ of barrel temperature temperature controls, and molten materials gets into merging core through screw rod and branches to special-purpose rack-style foaming mould; The merging core temperature is between 130 ℃; Die temperature is between 170 ℃, and between 140 ℃, molten materials expands from the mould post-foaming and gets into typified form simultaneously the die lip temperature through die heater thermal oil temperature control; Get into edge-neatening apparatus through cooling and shaping and control width, get into automatic cutting machine then and be cut into finished product automatically by sl..
The product that present embodiment is prepared is the sheet material of 15mm, and density is 650kg/m
3, sheet material hardness (shore hardness) D=65.
Embodiment 2
Described SE Wood plastic boards prescription is that the polyvinyl chloride resin powder polymerization degree with embodiment 1 changes 700 into, component and preparation method such as embodiment 1 in all the other prescriptions.
The product that present embodiment is prepared is the sheet material of 15mm, and density is 600kg/m
3, sheet material hardness (shore hardness) D=60.
Embodiment 3
Described SE Wood plastic boards prescription is following: the 50 weight part polymerization degree are 700 polyvinyl chloride resin powder, the compound Pb stabilizer of 2 weight parts, the ACR modifier of 5 weight parts; The lime carbonate of 5 weight parts, the polyethylene wax of 1 weight part, the azo acid amides of 0.4 weight part; 0.6 the sodium hydrogencarbonate of weight part, the chlorinatedpolyethylene of 3.9 weight parts, the wood powder of 32 weight parts; 0.1 the silane coupling agent of weight part, 100 parts of total weight parts.
The preparation method of described SE Wood plastic boards such as embodiment 1.
The product that present embodiment is prepared is the sheet material of 15mm, and density is 580kg/m
3, sheet material hardness (shore hardness) D=55.
Embodiment 4
The polyvinyl chloride resin powder polymerization degree that described SE Wood plastic boards prescription is embodiment 3 changes 1000 into, component and preparation method such as embodiment 3 in all the other prescriptions.
The product that present embodiment is prepared is the sheet material of 15mm, and the gained panel density is 600kg/m
3, sheet material hardness (shore hardness) D=62.
Embodiment 5
Described SE Wood plastic boards prescription is following: the 50 weight part polymerization degree are 1000 SE, the organotin stabilizer of 2 weight parts, the lime carbonate of 2 weight parts; The ACR modifier of 4 weight parts, the polyethylene wax of 1 weight part, the Cellmic C 121 of 0.4 weight part; 0.6 the sodium hydrogencarbonate of weight part, the chlorinatedpolyethylene of 3.9 weight parts, the wood powder of 36 weight parts; 0.1 the silane coupling agent of weight part, 100 parts of total weight parts.
The preparation method of described SE Wood plastic boards such as embodiment 1.
The product that present embodiment is prepared is the sheet material of 15mm, and density is 680kg/m
3, sheet material hardness (shore hardness) D=68.
Embodiment 6
Described SE Wood plastic boards prescription is following: the 50 weight part polymerization degree are 1000 polyvinyl chloride resin powder, the compound Pb stabilizer of 2 weight parts, the lime carbonate of 2 weight parts; The ACR modifier of 5 weight parts, the polyethylene wax of 1 weight part, the Cellmic C 121 of 0.2 weight part; The volatile salt of 1 weight part, the chlorinatedpolyethylene of 3.9 weight parts, the wood powder of 34.8 weight parts; 0.1 the silane coupling agent of weight part, the component of total weight parts 100, gained panel density are 650kg/m
3, sheet material hardness (shore hardness) D=70, the preparation method is identical with embodiment 1.
Embodiment 7
Described SE Wood plastic boards prescription is following: the 48 weight part polymerization degree are 700 polyvinyl chloride resin powder, the compound Pb stabilizer of 2 weight parts, the ACR modifier of 6 weight parts, the permanent white of 3 weight parts; The oxidic polyethylene of 1 weight part, azo two isobutyls of 0.4 weight part are fine, the sodium hydrogencarbonate of 0.6 weight part; 3.9 the chlorinatedpolyethylene of weight part, the wood powder of 35 weight parts, the silane coupling agent of 0.1 weight part; Total weight parts is 100 parts, through the cold conical double screw extruder of infiltrating into 80/156 of heat, and 17 rev/mins of control screw speeds; The barrel Heating temperature is respectively 180 ℃, 175 ℃, 170 ℃, 160 ℃, 95 ℃ of screw rod oil temperature, 170 ℃ of die temperatures; 140 ℃ of die lip temperature are the sheet material of 15mm through foaming and setting, and density is 580kg/m
3, sheet material hardness (shore hardness) D=55, all the other are embodiment 1.
Several important components and sheet material index are as shown in table 1 below in the prescription:
Table 1 embodiment performance table
Can find out by above table 1:
1, sheet material increases with the increase density of the polyvinyl chloride resin powder polymerization degree.
2, under the constant situation of panel density, sheet material hardness increases with the increase of SE molecular weight.
3, suitably strengthen the consumption of white hair infusion in the prescription, sheet material hardness can improve.
4, panel density reduces with the increase of properties-correcting agent.
5, sheet material hardness reduces with the minimizing or the weighting agent increase of wood powder.