CN104231646B - The preparation method of a kind of high-intensity wood plastic composite and goods - Google Patents
The preparation method of a kind of high-intensity wood plastic composite and goods Download PDFInfo
- Publication number
- CN104231646B CN104231646B CN201410429256.4A CN201410429256A CN104231646B CN 104231646 B CN104231646 B CN 104231646B CN 201410429256 A CN201410429256 A CN 201410429256A CN 104231646 B CN104231646 B CN 104231646B
- Authority
- CN
- China
- Prior art keywords
- parts
- methacrylic acid
- plastic composite
- butyl acrylate
- wood plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000011155 wood-plastic composite Substances 0.000 title claims abstract description 48
- 229920001587 Wood-plastic composite Polymers 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 59
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 55
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 34
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 29
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000007822 coupling agent Substances 0.000 claims abstract description 27
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims abstract description 24
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 24
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920000573 polyethylene Polymers 0.000 claims abstract description 18
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 18
- 235000019394 potassium persulphate Nutrition 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003063 flame retardant Substances 0.000 claims abstract description 16
- 229960000935 dehydrated alcohol Drugs 0.000 claims abstract description 15
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 14
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 14
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 14
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 229920001577 copolymer Polymers 0.000 claims description 30
- 238000001035 drying Methods 0.000 claims description 12
- 239000008240 homogeneous mixture Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 230000004048 modification Effects 0.000 claims description 9
- 238000012986 modification Methods 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 7
- 238000010992 reflux Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000010790 dilution Methods 0.000 claims description 5
- 239000012895 dilution Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 abstract description 3
- 239000004698 Polyethylene Substances 0.000 description 18
- 239000000463 material Substances 0.000 description 17
- 229920003023 plastic Polymers 0.000 description 13
- 239000004033 plastic Substances 0.000 description 13
- 239000000203 mixture Substances 0.000 description 10
- 239000002023 wood Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 235000011149 sulphuric acid Nutrition 0.000 description 4
- 239000001117 sulphuric acid Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 229920002522 Wood fibre Polymers 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 239000011157 advanced composite material Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000003113 dilution method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
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- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
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CN201410429256.4A CN104231646B (en) | 2014-08-27 | 2014-08-27 | The preparation method of a kind of high-intensity wood plastic composite and goods |
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CN201410429256.4A CN104231646B (en) | 2014-08-27 | 2014-08-27 | The preparation method of a kind of high-intensity wood plastic composite and goods |
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CN104231646A CN104231646A (en) | 2014-12-24 |
CN104231646B true CN104231646B (en) | 2016-08-24 |
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CN201410429256.4A Expired - Fee Related CN104231646B (en) | 2014-08-27 | 2014-08-27 | The preparation method of a kind of high-intensity wood plastic composite and goods |
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Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105082303B (en) * | 2015-03-27 | 2017-08-08 | 西南林业大学 | A kind of preparation method of high-intensity wood plastic composite |
CN105949580A (en) * | 2016-06-22 | 2016-09-21 | 刘莹莹 | Waterproof anti-seepage wood-plastic material and preparation method thereof |
CN106084400A (en) * | 2016-06-23 | 2016-11-09 | 刘莹莹 | A kind of with fibrous reinforcement Wood-plastic material and preparation method thereof |
CN106009170A (en) * | 2016-06-23 | 2016-10-12 | 刘莹莹 | Flame-retardant wood-plastic material and preparation method thereof |
CN105968504A (en) * | 2016-06-23 | 2016-09-28 | 刘莹莹 | Heat-insulting wood-plastic material and preparation method thereof |
CN106117702A (en) * | 2016-06-23 | 2016-11-16 | 刘莹莹 | A kind of antioxidation Wood-plastic material and preparation method thereof |
CN105860230A (en) * | 2016-06-23 | 2016-08-17 | 刘莹莹 | Antibacterial anticorrosive wood-plastic material and preparation method thereof |
CN105860232A (en) * | 2016-06-23 | 2016-08-17 | 刘莹莹 | High-strength impact resistant wood-plastic material and preparation method thereof |
CN105885180A (en) * | 2016-06-23 | 2016-08-24 | 刘莹莹 | Polyamide-modified wood-plastic composite and preparation method thereof |
CN105860231A (en) * | 2016-06-23 | 2016-08-17 | 刘莹莹 | Hard anti-crack wood plastic material and preparation method thereof |
CN106336599A (en) * | 2016-08-28 | 2017-01-18 | 桐乡市美意家具有限公司 | Wood-plastic furniture material and preparation method thereof |
CN108752961A (en) * | 2018-06-26 | 2018-11-06 | 阜南县永兴工艺品有限公司 | A kind of rattan plaited Wood-plastic material of excellent in mechanical performance |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101812236A (en) * | 2010-04-02 | 2010-08-25 | 惠东美新塑木型材制品有限公司 | Long glass fiber reinforced plastic wood composite section and preparation method thereof |
CN101831112A (en) * | 2010-05-14 | 2010-09-15 | 金发科技股份有限公司 | Halogen-free flame-retardant type injection molding-class polyolefin wood plastic composite material and preparation method thereof |
CN101885231A (en) * | 2009-05-15 | 2010-11-17 | 上海交福新材料科技有限公司 | Preparation method of fully-degradable polymer wood plastic composite |
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2014
- 2014-08-27 CN CN201410429256.4A patent/CN104231646B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101885231A (en) * | 2009-05-15 | 2010-11-17 | 上海交福新材料科技有限公司 | Preparation method of fully-degradable polymer wood plastic composite |
CN101812236A (en) * | 2010-04-02 | 2010-08-25 | 惠东美新塑木型材制品有限公司 | Long glass fiber reinforced plastic wood composite section and preparation method thereof |
CN101831112A (en) * | 2010-05-14 | 2010-09-15 | 金发科技股份有限公司 | Halogen-free flame-retardant type injection molding-class polyolefin wood plastic composite material and preparation method thereof |
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CN104231646A (en) | 2014-12-24 |
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Date | Code | Title | Description |
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C06 | Publication | ||
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TA01 | Transfer of patent application right |
Effective date of registration: 20160728 Address after: 523000, Guangdong Province, Dongguan City, Dongcheng District province cattle Hill Industrial Park by the outer flame industrial zone Applicant after: GUANGDONG HONGYUN FURNITURE Co.,Ltd. Applicant after: GUANGDONG HONGQI FURNITURE Co.,Ltd. Applicant after: Guangdong Huasong Furniture Group Co.,Ltd. Applicant after: Guangdong Songtai Network Technology Co.,Ltd. Address before: 523000, Dongguan, Guangdong province Dongcheng District science and Technology Industrial Park, set up new cross Ling Industrial Zone Applicant before: GUANGDONG HONGQI FURNITURE Co.,Ltd. |
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C14 | Grant of patent or utility model | ||
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CP01 | Change in the name or title of a patent holder |
Address after: 523000, Guangdong Province, Dongguan City, Dongcheng District province cattle Hill Industrial Park by the outer flame industrial zone Co-patentee after: GUANGDONG HONGQI FURNITURE Co.,Ltd. Patentee after: GUANGDONG HONGYUN FURNITURE Co.,Ltd. Co-patentee after: Guangdong Huasong home furnishing Group Co.,Ltd. Co-patentee after: Guangdong Songtai Network Technology Co.,Ltd. Address before: 523000, Guangdong Province, Dongguan City, Dongcheng District province cattle Hill Industrial Park by the outer flame industrial zone Co-patentee before: GUANGDONG HONGQI FURNITURE Co.,Ltd. Patentee before: GUANGDONG HONGYUN FURNITURE Co.,Ltd. Co-patentee before: Guangdong Huasong Furniture Group Co.,Ltd. Co-patentee before: Guangdong Songtai Network Technology Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160824 |