CN102484990A - Composite miticide for farmland and fruit trees - Google Patents
Composite miticide for farmland and fruit trees Download PDFInfo
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- CN102484990A CN102484990A CN2010105684610A CN201010568461A CN102484990A CN 102484990 A CN102484990 A CN 102484990A CN 2010105684610 A CN2010105684610 A CN 2010105684610A CN 201010568461 A CN201010568461 A CN 201010568461A CN 102484990 A CN102484990 A CN 102484990A
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Abstract
The invention, relating to the field of pesticide preparations, discloses a composite miticide for farmland and fruit trees. The active components of the miticide comprise 1-99 wt% of etoxazole and 1-99 wt% of one component selected from avermectin, azocylotin, propargite, clofentezine or pyridaben, wherein an acaricidal composition comprises the active components, and the acaricidal composition accounts for 1-99 wt% of the miticide. The acaricidal composition has obvious synergistic effect, increases the control effect, reduces the dosage of the active components, delays the generation of pest resistance, and reduces the environmental pollution. The miticide disclosed herein can effectively control farmland and fruit tree mites.
Description
Technical field
The present invention relates to the pesticidal preparations field, relate to a kind of Compositional type farmland, fruit tree miticide specifically.
Background technology
The agricultural evil mite kind of China has kind more than 500; Wherein endanger serious about kind more than 40; Like tetranychid, Tetranychus urticae, goitre mite, Panonychus citri etc., field-crop such as their main harm fruit trees and cotton, wheat class, vegetables, tobacco, tealeaves, corn, soybean, peanut.Agricultural evil mite volume is little, breeding is fast, adaptability is strong, is prone to produce resistance, and under the righttest condition, 1 female one-tenth mite breeding in 1 month limit can be up to 10,000 bulls, be the pest group of the most difficult control of generally acknowledging.
Evil mite main harm crop and fruit tree leaf, the harm characteristics of most agricultural evil mites are quite similar, all puncture the plant epidermis cell with its elongated lancet during harm; Suck juice, make part of damage chlorosis, withered or lopsided, the chlorosis spot only appears in the leaf initial stage of being injured near vein; Enlarge gradually later on, blade large tracts of land chlorosis becomes brown; When mite mouth density was big, killed leaf was covered with silk screen, comes off in advance.Behind the blade or fruit of goitre mite harm fruit tree, crops, also can stimulate the position that is injured to form the mite goitre.Except direct harm, the kind that has still is the communication media of the viroses of plant, can propagate the viroses of plant like many mite classes of goitre mite Superfamily, and Pyemotidae fringe mite belongs to the part mite class of Siteroptes spp. can propagate fungal disease.Cast off a skin and the excreta of warehouse evil mite can pollute the agricultural product of storage, make that its heating is gone mouldy, variable color and have stench flavor, and the agricultural product of band mite also can bring out fash with after human body skin contacts.
It is of a great variety to be used to prevent and treat the harmful miticide of hiding from the market, and high malicious miticides such as the unsafe amidine class of pair crop, organic phosphates, organochlorine class are arranged; Have couple person poultry toxicity low, to the effective chrysanthemum ester of mite class class miticide, but the lasting period is short, repeatedly use, and produce cross resistance.Be used to prevent and treat the harmful agent of hiding from of hiding from extremely at present and mostly be the selectivity miticide, toxicity is low, to people and animals, natural enemies security; The mite lasting period is long extremely; Like pyridaben (it is clean to sweep mite), alkynes mite special (mite must restrain), Hexythiazox, AVM (Long Weikang) etc., but the control worm attitude that has is single, and the cost that has is high; The residual height that has is unsatisfactory to agriculture control of pest mite effect.
Summary of the invention
In view of this, the object of the invention provides a kind of Compositional type efficiently farmland, fruit tree miticide.
For realizing the object of the invention, the present invention adopts following technical scheme:
A kind of miticide composition is by a kind of composition the in second mite azoles and AVM, azacyclotin, alkynes mite spy, four mite piperazines or the pyridaben.
Second mite azoles is the research and development of SUMITOMO CHEMICAL KCC; The miticide that belongs to the diphenyl oxazoline derivative; Its mechanism of action is to suppress mite class embryo's formation and young mite to the process of casting off a skin that becomes mite; To the ovum of mite pest, young mite, if mite all has remarkable control efficiency, be mainly used in control citrus red mite, hawthron spider mite, Tetranychus urticae etc.In addition, second mite azoles using dosage is low, 5000-7500 times of liquid of registration using dosage; Rain fastness is strong, and the lasting period reaches 50 days; To crop and Environmental security, useful insect almost there is not influence, can satisfy the needs of harmful insect comprehensive regulation; Female one-tenth mite is had good sterile effect,, can effectively reduce follow-on insect population radix though can not directly kill into mite.
AVM is a kind of macrolide disaccharide class native compound that from edaphon, separates.The mite class had tag and stomach poison function and faint fumigation action is arranged, no systemic action, its mechanism of action is to disturb the neurophysiology activity; Stimulate and discharge the r-reanal; Arthropodan nerve conduction is had inhibitory action, the mite class becomes, if mite with paralysis symptom promptly appears after medicament contacts, inertia is not got food; Dead after 2-4 days, can effectively prevent and treat tetranychid, goitre mite, the yellow tea mite of crops such as fruit tree, vegetables, grain.AVM has very strong osmosis to blade, can kill subepidermal insect, and the longevity of residure is long, though predatism and parasite are had direct killing effect, but because of plant surface residual little to the damage of beneficial insect less.
Azacyclotin is the strong wide spectrum miticide of a kind of action of contace poison, and moderate toxicity can be killed if mite, one-tenth mite and summer egg are invalid to winter egg.Azacyclotin is stable to light, and the longevity of residure is long, to crop safety, is applicable to the multiple harmful mites such as citrus red mite, apple tetranychus, grape tetranychid and eggplant two spotted spider mite on control fruit tree, the vegetables.
Alkynes mite spy is a kind of wide spectrum organosulfur acaricide; To becoming mite, all better as if mite, young mite and mite ovum effect; Also can kill the harmful mite that other insecticide has been developed immunity to drugs, can be used for preventing and treating cotton, vegetables, apple, citrus, tea, the various harmful mites of flowers and other crops.Alkynes mite spy has selectivity, and safer to honeybee and natural enemy, residual effect is lasting, and toxicity is very low, and is little to people and animals and natural environment harm, is the desirable miticide of integrated control.
Four mite piperazines are the very high organic nitrogen heterocyclic contact killing type acaricide agent of a kind of activity, to children, active if mite has preferably, suppress the children, if the process of casting off a skin of mite; Its medicament has stronger penetration; To temperature-insensitive, the four seasons are all available, and drug effect is slower; But the lasting period is longer, is applicable to the multiple harmful mite on the crops such as fruits and vegetables, cotton.
Pyridaben is wide spectrum, tagging property miticide, and each worm attitude of whole growth phase of mite is all had good effect, has tangible speed to kill effect equally to the one-tenth mite of moving the phase.This medicine is not acted upon by temperature changes, and no matter uses in early spring or autumn, all can reach promising result.Medicament can be used for preventing and treating multiple food vegetalitas evil mite, is applicable to citrus, apple, pears, hawthorn, cotton, tobacco, vegetables (except the eggplant) and ornamental plants, as is used to prevent and treat citrus and blister mites such as European red mite, pears and hawthorn.
Wherein, As preferably; The percentage by weight of second mite azoles according to the invention and AVM, azacyclotin, alkynes mite spy, four mite piperazines or pyridaben is 1～99: 1～99, and promptly the percentage by weight of second mite azoles and AVM, second mite azoles and azacyclotin, second mite azoles and alkynes mite spy, second mite azoles and four mite piperazines and second mite azoles and pyridaben is respectively 1～99: 1～99.
Different miticide active components mix each active component of back because the difference of composition, structure, physicochemical property makes that the synergy between each active component is typically expressed as synergistic effect, summation action or antagonism.So-called synergistic effect is exactly the mutual synergism between different material, and the effect of its generation is greater than the sum total of each composition effect; And being exactly the effect of its generation, summation action equals the sum total of each composition effect; Antagonism is meant that a kind of material disturbed the effect of another kind of material when two kinds of materials acted on living organism, or the effect of interfering with an opponent each other, the phenomenon that general effect is descended.
Estimate the mixed interaction of two kinds of different miticide active components and adopt the co-toxicity coefficient method of calculating usually, wherein, co-toxicity coefficient obviously is synergistic effect greater than 100, and co-toxicity coefficient is significantly less than 100 and is antagonism, and co-toxicity coefficient=100 are summation action.The present invention is according to Sun Yunpei (Sun Y-P) method; Calculate co-toxicity coefficient evaluation second mite azoles and AVM, azacyclotin, alkynes mite spy, four mite piperazines or pyridaben and use effect with; The result shows, the percentage by weight of second mite azoles and AVM, azacyclotin, alkynes mite spy, four mite piperazines or pyridaben is that 1～99: 1～99 co-toxicity coefficient is all greater than 100.Find through the test of indoor and outdoors biological activity determination; Said second mite azoles and AVM, azacyclotin, alkynes mite are special, four mite piperazines or pyridaben are composite, are about to that second mite azoles is special with AVM, azacyclotin, alkynes mite respectively, four mite piperazines or pyridaben be with 1～99: 1～99 mixed is used has the notable synergistic effect.
More preferably, the percentage by weight of said second mite azoles and AVM is 10: 3～6, promptly 10: 3～10: 6; The percentage by weight of said second mite azoles and azacyclotin is 1: 7～10; The special percentage by weight of said second mite azoles and alkynes mite is 1: 20～25; The percentage by weight of said second mite azoles and four mite piperazines is 1: 6～9; The percentage by weight of said second mite azoles and pyridaben is 1: 4～6.
The present invention also provides a kind of miticide, and its active component is made up of miticide composition according to the invention.
Wherein, as preferably, it is 1%～99% that miticide composition according to the invention accounts for said acaricidal percentage by weight.
Miticide according to the invention can be processed wetting powder, missible oil, suspending agent, microcapsule suspending agent or water dispersible granules by miticide composition according to the invention and conventional auxiliary material as required.
Experiment shows that miticide according to the invention can be prevented and treated farmland and fruit tree evil mite effectively, and therefore, the present invention also provides the application of said miticide in control farmland, fruit tree evil mite.
Embodiment
The embodiment of the invention discloses a kind of Compositional type farmland, fruit tree miticide.Those skilled in the art can use for reference this paper content, suitably improve technological parameter and realize.Special needs to be pointed out is that all similarly replace and change apparent to those skilled in the art, they all are regarded as and are included in the present invention.Product of the present invention is described through preferred embodiment, and the related personnel obviously can change or suitably change and combination product as herein described in not breaking away from content of the present invention, spirit and scope, realizes and use technology of the present invention.
For realizing the object of the invention, the present invention adopts following technical scheme:
A kind of miticide composition is by a kind of composition the in second mite azoles and AVM, azacyclotin, alkynes mite spy, four mite piperazines or the pyridaben.
Wherein, as preferably, second mite azoles according to the invention and AVM, azacyclotin, alkynes mite are special, the percentage by weight of four mite piperazines or pyridaben is 1～99: 1～99.
More preferably, the percentage by weight of said second mite azoles and AVM is 10: 3～6; The percentage by weight of said second mite azoles and azacyclotin is 1: 7～10; The special percentage by weight of said second mite azoles and alkynes mite is 1: 20～25; The percentage by weight of said second mite azoles and four mite piperazines is 1: 6～9; The percentage by weight of said second mite azoles and pyridaben is 1: 4～6.
The present invention finds through indoor and outdoors biological activity determination test, and miticide composition according to the invention is about to that second mite azoles is special with AVM, azacyclotin, alkynes mite respectively, four mite piperazines or pyridaben mix use with certain proportion and have the notable synergistic effect.
The former medicine of agricultural chemicals is that active component generally can not directly be used, and must process and be mixed with various types of preparations, could use.Therefore, the present invention also provides a kind of miticide, and its active component is made up of miticide composition according to the invention.
Wherein, to account for said acaricidal percentage by weight be 1%～99% to miticide composition according to the invention.
The form of preparation is claimed formulation, and at present to use more be kind of formulation surplus pulvis, aqua, wetting powder, missible oil, suspending agent, microcapsule suspending agent, the water dispersible granules etc. ten to agricultural chemicals.Miticide according to the invention comprises wetting powder, missible oil, suspending agent, microcapsule suspending agent and water dispersible granules.
Wherein, wetting powder according to the invention comprises miticide composition, wetting agent, dispersant, carrier and inserts.Missible oil according to the invention comprises miticide composition, benzene or xylol and surfactant.Suspending agent according to the invention comprises miticide composition, wetting dispersing agent, viscosity modifier, antifreezing agent and antifoaming agent.Microcapsule suspending agent according to the invention comprises miticide composition, solvent, curing agent and viscosity modifier.Water dispersible granules according to the invention comprises miticide composition, wetting agent, disintegrant, dispersant, adhesive, interleaving agent and carrier.
Miticide according to the invention can also be processed multiple formulations such as granule commonly used except that above-mentioned formulation, fumicants, aerosol, ultra low volume preparation, fumigant as required, to be applied to agricultural production.
Used auxiliary agent, surfactant, carrier and other auxiliary materials of various preparations is and well known to a person skilled in the art more than the preparation, is sulfonated oil, Nekal BX, soybean lecithin, thio-alcohol, hydrazides class, mercaptan acetals and polyethylene glycol oxide alkanisation ether etc. like wetting agent; Dispersant is sodium phosphate trimer, sodium pyrophosphate, lauryl sodium sulfate, cellulose derivatives, polyacrylamide, fatty acid polyethylene glycol ester and fatty alcohol oxirane etc.; Disintegrant is dried starch, sodium carboxymethyl starch, low substituted hydroxy-propyl methylcellulose, PVPP etc.; Adhesive is polyurethane, polystyrene, polyacrylate, vinyl acetate resin etc.; Solvent can be various aromatic hydrocarbons, aliphatic hydrocarbon, ketone etc.
Experiment shows that miticide according to the invention can be prevented and treated farmland and fruit tree evil mite effectively, like citrus red mite, Tetranychus urticae etc.Miticide composition according to the invention is made up of second mite azoles and AVM, azacyclotin, alkynes mite spy, four mite piperazines or pyridaben; Have the notable synergistic effect, improved preventive effect, reduce the consumption of active ingredient; Delay the generation of pest resistance to insecticide, and reduce pollution environment.
In order further to understand the present invention, a kind of Compositional type provided by the invention farmland, fruit tree miticide are elaborated below in conjunction with embodiment.
Embodiment 1:78% second mite azoles AVM wetting powder
60% second mite azoles, 18% AVM, 5% APES fully mix with 7% fatty alcohol oxirane in proportion, and diatomite is mended to 100%, and ultrafine crusher makes wetting powder after pulverizing.
Embodiment 2:60% second mite azoles abamectin emulsifiable concentrate
40% second mite azoles, 24% AVM, 10% benzene and 15% xylol and 11% dodecyl sodium sulfate fully mix in proportion, through the mix stirring and processing, obtain cream preparation successively.
Embodiment 3:80% second mite azoles azacyclotin suspending agent
10% second mite azoles, 70% azacyclotin, 2% xylonic acid sodium sulfonate, 3% alumina silicate, 5% ethylene glycol, 1% isopropyl alcohol, water benefit to 100% common process makes suspending agent.
Embodiment 4:55% second mite azoles azacyclotin wetting powder
5% second mite azoles, 50% azacyclotin, 10% APES fully mix with 15% fatty alcohol oxirane in proportion, and silica is mended to 100%, and ultrafine crusher makes wetting powder after pulverizing.
The special microcapsule suspending agent of embodiment 5:42% second mite azoles alkynes mite
2% second mite azoles, special, 13% benzene of 40% alkynes mite, 30% curing agent directly is scattered in 11% polyvinyl alcohol after mixing by proportioning, adds other solvent again and mends to 100%, processes microcapsule suspending agent behind the slow reaction.
The special suspending agent of embodiment 6:78% second mite azoles alkynes mite
3% second mite azoles, 75% alkynes mite spy, 5% Nongru-700 #, 8% Sodium Polyacrylate, 5% propane diols, 1% tributyl phosphate, water benefit to 100% common process makes suspending agent.
Embodiment 7:91% second mite azoles four mite piperazine missible oil
13% second mite azoles, 78% 4 mite piperazine, 3% benzene and 5% xylol and 1% polyoxyethylene fatty amine fully mix, and through the mix stirring and processing, obtain cream preparation successively.
Embodiment 8:30% second mite azoles clofentezine water dispersible granule
3% second mite azoles, 27% 4 mite piperazine, 8% sulfonated oil, 17% sodium carboxymethyl starch, 24% sodium phosphate trimer and polystyrene, 14% calcium carbonate, 7% carrier mix; Process wetting powder after the pulverizing; Add the granulation of a certain amount of water extrusion afterwards, after dry screened, make water dispersible granules.
Embodiment 9:25% second mite azoles and Damanling suspension agent
5% second mite azoles, 20% alkynes mite spy, 5% agricultural newborn BY110,10% alumina silicate, 5% propane diols, 1% bubble enemy, water benefit to 100% common process makes suspending agent.
Embodiment 10:32% second mite azoles and water dispersible granules
20% second mite azoles, 12% pyridaben, 8% polyethylene glycol oxide alkanisation ether, 15% PVPP, 26% fatty alcohol oxirane and polyacrylate, 11% talcum powder stearate soap, 8% carrier mix in proportion; Process wetting powder after the pulverizing; Add the granulation of a certain amount of water extrusion afterwards, after dry screened, make water dispersible granules.
Embodiment 11: control citrus red mite field control effectiveness test
Test in one peasant household orchard, Zhengzhou, Henan and carry out, active ingredient second mite azoles and AVM, azacyclotin, alkynes mite spy, four mite piperazines or pyridaben are mixed, and test is handled and formulation rate is seen table 1; As handle 8 and be the use that is mixed of second mite azoles and AVM; Supplying the reagent agent is second mite azoles and AVM, and formulation rate is to contain in every 1kg water to supply reagent agent 13mg, wherein; Second mite azoles is 10mg, and AVM is 3mg.
Table 1 test is handled and formulation rate
4 strains tree of the same size is selected in each processing, every strain tree choosing east, south, west, north, in the blade in 5 orientation, every processing repetition 4 times, respectively before dispenser and the dispenser " Invest, Then Investigate " write down the quantity of two spotted spider mite, the calculating control efficiency, the result sees table 2.
Table 2 control efficiency
| Handle | Red spider radix | Borer population alive | The insect population rate (%) that goes down | Preventive effect (%) |
| 1 | 77 | 107 | -38.96 | 0.00 |
| 2 | 70 | 9 | 87.14 | 90.75 |
| 3 | 53 | 8 | 84.91 | 89.14 |
| 4 | 59 | 10 | 83.05 | 87.80 |
| 5 | 81 | 13 | 83.95 | 88.45 |
| 6 | 74 | 12 | 83.78 | 88.33 |
| 7 | 86 | 13 | 84.88 | 89.12 |
| 8 | 77 | 4 | 94.81 | 96.26 |
| 9 | 69 | 2 | 97.10 | 97.91 |
| 10 | 58 | 3 | 94.83 | 96.28 |
| 11 | 62 | 2 | 96.77 | 97.68 |
| 12 | 67 | 4 | 94.03 | 95.70 |
| 13 | 75 | 3 | 96.00 | 97.12 |
| 14 | 83 | 3 | 96.39 | 97.40 |
| 15 | 59 | 1 | 98.31 | 98.78 |
| 16 | 71 | 4 | 94.37 | 95.95 |
| 17 | 67 | 2 | 97.01 | 97.85 |
Can know that by table 2 result a kind of being mixed in active ingredient second mite azoles and AVM, azacyclotin, alkynes mite spy, four mite piperazines or the pyridaben compared with single agent; After reducing consumption, the borer population of living is low, the insect population rate height that goes down; Preventive effect is higher than single agent to be used separately, shows the citrus red mite preventive effect desirable.As handle 12 and be second mite azoles and alkynes mite spy uses that be mixed, formulation rate is second mite azoles 10mg in every 1kg water, alkynes mite spy 200mg, and the work borer population is 4, and the insect population rate of going down is 94.03%, and preventive effect is 95.70%.Use separately and handle the special single agent of 5 alkynes mites and use separately and compare with handling 2 second mite azoles list agent, reduced formulation rate, and the borer population of living has reduced, go down rate and preventive effect of insect population improved, and shows that second mite azoles and alkynes mite spy are mixed to have reduced consumption, improved preventive effect.
The explanation of above embodiment just is used for helping to understand method of the present invention and core concept thereof.Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention, can also carry out some improvement and modification to the present invention, these improvement and modification also fall in the protection domain of claim of the present invention.
Claims (11)
1. a miticide composition is characterized in that, by a kind of composition the in second mite azoles and AVM, azacyclotin, alkynes mite spy, four mite piperazines or the pyridaben.
2. according to the said miticide composition of claim 1, it is characterized in that the percentage by weight of said second mite azoles and AVM, azacyclotin, alkynes mite spy, four mite piperazines or pyridaben is 1～99: 1～99.
3. according to the said miticide composition of claim 2, it is characterized in that the percentage by weight of said second mite azoles and AVM is 10: 3～6.
4. according to the said miticide composition of claim 2, it is characterized in that the percentage by weight of said second mite azoles and azacyclotin is 1: 7～10.
5. according to the said miticide composition of claim 2, it is characterized in that the special percentage by weight of said second mite azoles and alkynes mite is 1: 20～25.
6. according to the said miticide composition of claim 2, it is characterized in that the percentage by weight of said second mite azoles and four mite piperazines is 1: 6～9.
7. according to the said miticide composition of claim 2, it is characterized in that the percentage by weight of said second mite azoles and pyridaben is 1: 4～6.
8. a miticide is characterized in that, active component is made up of the said miticide composition of claim 1.
9. said according to Claim 8 miticide is characterized in that it is 1%～99% that said miticide composition accounts for said acaricidal percentage by weight.
10. said according to Claim 8 miticide is characterized in that, processes wetting powder, missible oil, suspending agent, microcapsule suspending agent or water dispersible granules by said miticide composition and conventional adjuvant.
11. claim 8 or the 9 said miticides application in control farmland, fruit tree evil mite.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010105684610A CN102484990A (en) | 2010-12-01 | 2010-12-01 | Composite miticide for farmland and fruit trees |
| CN201310248469.2A CN103271077B (en) | 2010-12-01 | 2010-12-01 | A kind of Compositional type farmland, fruit tree miticide |
| CN201310251194.8A CN103271041B (en) | 2010-12-01 | 2010-12-01 | A kind of Compositional type farmland, fruit tree miticide |
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| CN2010105684610A CN102484990A (en) | 2010-12-01 | 2010-12-01 | Composite miticide for farmland and fruit trees |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2013102517465A Division CN103300013A (en) | 2010-12-01 | 2010-12-01 | Compounded acaricide for farmlands and fruit trees |
| CN201310248469.2A Division CN103271077B (en) | 2010-12-01 | 2010-12-01 | A kind of Compositional type farmland, fruit tree miticide |
| CN201310251194.8A Division CN103271041B (en) | 2010-12-01 | 2010-12-01 | A kind of Compositional type farmland, fruit tree miticide |
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| CN2010105684610A Pending CN102484990A (en) | 2010-12-01 | 2010-12-01 | Composite miticide for farmland and fruit trees |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102007922A (en) * | 2011-01-01 | 2011-04-13 | 陕西上格之路生物科学有限公司 | Acaricide composition containing etoxazole and propargite |
| CN102210321A (en) * | 2011-05-04 | 2011-10-12 | 陕西韦尔奇作物保护有限公司 | Pesticide composite containing etoxazole |
| CN102302011A (en) * | 2011-04-27 | 2012-01-04 | 陕西韦尔奇作物保护有限公司 | Pesticide composition containing etoxazole |
| CN102696631A (en) * | 2012-05-09 | 2012-10-03 | 广东中迅农科股份有限公司 | Synergistic acaricidal composition containing etoxazole and chlorfenapyr |
| WO2013065874A1 (en) * | 2011-11-04 | 2013-05-10 | Sumitomo Chemical Company, Limited | Aqueous agrochemical suspension composition and aqueous agrochemical suspension formulation |
| CN103798278A (en) * | 2014-01-26 | 2014-05-21 | 上海艳紫化工科技有限公司 | Pesticide suspension concentrate compounding abamectin and azacyclotin |
| CN105123714A (en) * | 2015-09-25 | 2015-12-09 | 安徽美兰农业发展股份有限公司 | Abamectin and etoxazole compound suspending agent and preparation method thereof |
| CN106035367A (en) * | 2016-06-16 | 2016-10-26 | 李祥英 | Pesticide composition containing azocylotin and propargite |
| CN107318861A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN109042694A (en) * | 2018-06-28 | 2018-12-21 | 安徽瑞然生物药肥科技有限公司 | A kind of etoxazole AVM hereinafter suspending agent |
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| CN101856029A (en) * | 2010-07-07 | 2010-10-13 | 吴明龙 | Pesticide combination containing etoxazole and abamectin |
| CN102283216A (en) * | 2010-06-19 | 2011-12-21 | 海利尔药业集团股份有限公司 | Acaricidal composition containing abamectin and etoxazole |
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- 2010-12-01 CN CN201310251194.8A patent/CN103271041B/en not_active Expired - Fee Related
- 2010-12-01 CN CN2010105684610A patent/CN102484990A/en active Pending
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102283216A (en) * | 2010-06-19 | 2011-12-21 | 海利尔药业集团股份有限公司 | Acaricidal composition containing abamectin and etoxazole |
| CN101856029A (en) * | 2010-07-07 | 2010-10-13 | 吴明龙 | Pesticide combination containing etoxazole and abamectin |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102007922A (en) * | 2011-01-01 | 2011-04-13 | 陕西上格之路生物科学有限公司 | Acaricide composition containing etoxazole and propargite |
| CN102302011A (en) * | 2011-04-27 | 2012-01-04 | 陕西韦尔奇作物保护有限公司 | Pesticide composition containing etoxazole |
| CN102210321A (en) * | 2011-05-04 | 2011-10-12 | 陕西韦尔奇作物保护有限公司 | Pesticide composite containing etoxazole |
| US9000019B2 (en) | 2011-11-04 | 2015-04-07 | Sumitomo Chemical Company, Limted | Aqueous agrochemical suspension composition and aqueous agrochemical suspension formulation |
| EP2773194A4 (en) * | 2011-11-04 | 2015-08-12 | Sumitomo Chemical Co | Aqueous agrochemical suspension composition and aqueous agrochemical suspension formulation |
| WO2013065874A1 (en) * | 2011-11-04 | 2013-05-10 | Sumitomo Chemical Company, Limited | Aqueous agrochemical suspension composition and aqueous agrochemical suspension formulation |
| CN103906430A (en) * | 2011-11-04 | 2014-07-02 | 住友化学株式会社 | Aqueous agrochemical suspension composition and aqueous agrochemical suspension formulation |
| CN102696631B (en) * | 2012-05-09 | 2015-07-08 | 广东中迅农科股份有限公司 | Synergistic acaricidal composition containing etoxazole and chlorfenapyr |
| CN102696631A (en) * | 2012-05-09 | 2012-10-03 | 广东中迅农科股份有限公司 | Synergistic acaricidal composition containing etoxazole and chlorfenapyr |
| CN103798278A (en) * | 2014-01-26 | 2014-05-21 | 上海艳紫化工科技有限公司 | Pesticide suspension concentrate compounding abamectin and azacyclotin |
| CN103798278B (en) * | 2014-01-26 | 2016-04-20 | 上海艳紫化工科技有限公司 | Avermectin and the composite agricultural chemicals suspension agent of azacyclotin |
| CN105123714A (en) * | 2015-09-25 | 2015-12-09 | 安徽美兰农业发展股份有限公司 | Abamectin and etoxazole compound suspending agent and preparation method thereof |
| CN107318861A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN106035367A (en) * | 2016-06-16 | 2016-10-26 | 李祥英 | Pesticide composition containing azocylotin and propargite |
| CN106035367B (en) * | 2016-06-16 | 2018-06-08 | 永春锐拓信息技术中心 | A kind of composition pesticide containing azacyclotin and propargite |
| CN109042694A (en) * | 2018-06-28 | 2018-12-21 | 安徽瑞然生物药肥科技有限公司 | A kind of etoxazole AVM hereinafter suspending agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103271077A (en) | 2013-09-04 |
| CN103271077B (en) | 2016-03-23 |
| CN103271041B (en) | 2015-07-29 |
| CN103271041A (en) | 2013-09-04 |
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Application publication date: 20120606 |