CN103271077B - A kind of Compositional type farmland, fruit tree miticide - Google Patents
A kind of Compositional type farmland, fruit tree miticide Download PDFInfo
- Publication number
- CN103271077B CN103271077B CN201310248469.2A CN201310248469A CN103271077B CN 103271077 B CN103271077 B CN 103271077B CN 201310248469 A CN201310248469 A CN 201310248469A CN 103271077 B CN103271077 B CN 103271077B
- Authority
- CN
- China
- Prior art keywords
- miticide
- mite
- present
- azacyclotin
- fruit tree
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The present invention relates to field of pesticide preparation, disclose a kind of Compositional type farmland, fruit tree miticide.Acaricidal activity composition of the present invention is made up of second mite azoles and azacyclotin, and the percentage by weight of described second mite azoles and azacyclotin is 1 ~ 99:1 ~ 99.Wherein, described miticide composition accounts for described acaricidal percentage by weight is 1% ~ 99%.Miticide composition of the present invention has notable synergistic effect, improves preventive effect, reduces the consumption of active ingredient, delays the generation of pest resistance to insecticide, and reduces the pollution to environment.Miticide of the present invention can prevent and treat farmland and fruit tree evil mite effectively.
Description
The application is the applying date is on December 01st, 2010, and application number is 201010568461.0, and invention and created name is the divisional application of " a kind of Compositional type farmland, fruit tree miticide ".
Technical field
The present invention relates to field of pesticide preparation, relate to a kind of Compositional type farmland, fruit tree miticide specifically.
Background technology
The Agricultural Mites kind of China has kind more than 500, wherein endanger serious about kind more than 40, as tetranychid, Tetranychus urticae, goitre mite, Panonychus citri etc., their field-crops such as main harm fruit tree and cotton, wheat class, vegetables, tobacco, tealeaves, corn, soybean, peanut.Agricultural Mites volume is little, breeding is fast, strong adaptability, easily produces resistance, and under the suitableeest condition, 1 female one-tenth mite, 1 month breeding limit can, up to 10,000 bulls, be the pest communities of the most difficult generally acknowledged control.
Evil mite main harm crop and fruit tree leaf, the harmful characteristics of most Agricultural Mites is quite similar, all punctures plant epidermis cell with its elongated lancet, suck juice during harm, make part of damage chlorosis, withered or lopsided, only there is chlorosis spot in leaf initial stage of being injured, expand gradually, blade large area chlorosis near vein later, become brown, when mite mouth density is large, killed leaf is covered with silk screen, comes off in advance.After goitre mite harm fruit tree, the blade of crops or fruit, the position that is injured also can be stimulated to form mite goitre.Except directly endangering, some kinds or the communication media of the viroses of plant, the many mite classes as Eriophyoidea can propagate the viroses of plant, and the part mite class that Pyemotidae fringe mite belongs to Siteroptesspp. can propagate fungal disease.Warehouse evil mite casting off a skin and excreta can pollute the agricultural product of storage, make it generate heat to go mouldy, variable color with bad smell, after the agricultural product of band mite and contact human skin, also can bring out fash.
Of a great variety for preventing and treating the harmful miticide hidden from market, have crop unsafe amidine class, organic phosphates, the contour malicious miticide of organochlorine class; Have low to person poultry toxicity, to mite class effective chrysanthemum ester class miticide, but the lasting period is short, repeatedly will use, and produce cross resistance.At present hide agent from for killing of preventing and treating that evil hides from and mostly be selectivity miticide, toxicity is low, to people and animals, natural enemies security, it is long to kill the mite lasting period, as pyridaben (sweeping mite clean), propargite (mite must gram), Hexythiazox, Avermectin (Long Weikang) etc., but some optimum control state are single, and some costs are high, the residual height had is unsatisfactory to Agricultural Mites control efficiency.
Summary of the invention
In view of this, the object of the invention is to provide a kind of Compositional type farmland, fruit tree miticide efficiently.
For realizing object of the present invention, the present invention adopts following technical scheme:
A kind of miticide composition, is made up of second mite azoles and azacyclotin.
The research and development of Yi Manzuoshi SUMITOMO CHEMICAL KCC, belong to the miticide of diphenyloxazole quinoline derivant, its mechanism of action suppresses the formation of mite class embryo and young mite to the molting process becoming mite, if all there is remarkable control efficiency to the ovum of mite pest, young mite mite, be mainly used in control citrus red mite, hawthron spider mite, Tetranychus urticae etc.In addition, second mite azoles using dosage is low, registration using dosage 5000-7500 times of liquid; Rain fastness is strong, and the lasting period reaches 50 days; To crop and Environmental security, on beneficial insect almost without impact, the needs of the harmful pests comprehensive regulation can be met; To female one-tenth mite, there is good sterile effect, though directly mite can not be killed into, effectively can reduce follow-on insect population radix.
Azacyclotin is the strong broad spectrum acaricides of a kind of action of contace poison, moderate toxicity, if can kill mite, become mite and summer egg, invalid to winter egg.Azacyclotin is stablized light, and the longevity of residure is long, to crop safety, is applicable to the multiple harmful mites such as the citrus red mite on control fruit tree, vegetables, apple tetranychus, grape tetranychid and eggplant two spotted spider mite.
Wherein, as preferably, the percentage by weight of second mite azoles of the present invention and azacyclotin is 1 ~ 99:1 ~ 99.
After different acaricidal activity component mixing, each active component is due to the difference of composition, structure, physicochemical property, makes the synergy between each active component be typically expressed as synergistic effect, summation action or antagonism.So-called synergistic effect is exactly the mutual synergism between different material, and its effect produced is greater than the sum total of each composition effect; And summation action is exactly the sum total that its effect produced equals each composition effect; When antagonism refers to that two kinds of materials act on living organism, a kind of material disturbs the effect of another kind of material, or the effect of interfering with an opponent each other, makes the phenomenon that general effect declines.
Evaluate the mixed interaction of two kinds of different acaricidal activity components and usually adopt calculating co-toxicity coefficient method, wherein, co-toxicity coefficient is obviously greater than 100 for synergistic effect, and co-toxicity coefficient is significantly less than 100 for antagonism, and co-toxicity coefficient=100 are summation action.The present invention, according to Sun Yunpei (SunY-P) method, calculates co-toxicity coefficient and evaluates second mite azoles effect mixed with azacyclotin, result display, and the percentage by weight of second mite azoles and azacyclotin is that the co-toxicity coefficient of 1 ~ 99:1 ~ 99 is all greater than 100.By indoor and outdoors biological activity determination test find, described second mite azoles and azacyclotin composite, so that the ratio of 1 ~ 99:1 ~ 99 is used in combination, there is notable synergistic effect.
It is further preferred that the percentage by weight of described second mite azoles and azacyclotin is 1:7 ~ 10.
Present invention also offers a kind of miticide, its active component is made up of miticide composition of the present invention.
Wherein, as preferably, it is 1% ~ 99% that miticide composition of the present invention accounts for described acaricidal percentage by weight.
Miticide of the present invention can make wetting powder, missible oil, suspending agent, microcapsule suspending agent or water dispersible granules by miticide composition of the present invention and customary adjuvant as required.
Experiment shows, miticide of the present invention can prevent and treat farmland and fruit tree evil mite effectively, therefore, present invention also offers the application of described miticide in control farmland, fruit tree evil mite.
Embodiment
The embodiment of the invention discloses a kind of Compositional type farmland, fruit tree miticide.Those skilled in the art can use for reference present disclosure, and suitable improving technique parameter realizes.Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the art, they are all deemed to be included in the present invention.Product of the present invention is described by preferred embodiment, related personnel obviously can not depart from content of the present invention, spirit and scope product as herein described is changed or suitably change with combination, realize and apply the technology of the present invention.
For realizing object of the present invention, the present invention adopts following technical scheme:
A kind of miticide composition, is made up of second mite azoles and azacyclotin.
Wherein, as preferably, the percentage by weight of second mite azoles of the present invention and azacyclotin is 1 ~ 99:1 ~ 99.
More preferably, the percentage by weight of described second mite azoles and azacyclotin is 1:7 ~ 10.
The present invention is found by the test of indoor and outdoors biological activity determination, and miticide composition of the present invention has notable synergistic effect so that certain proportion is used in combination.
The former medicine of agricultural chemicals and active component generally can not directly use, and must process and be mixed with various types of preparation, could use.Therefore, the present invention also provides a kind of miticide, and its active component is made up of miticide composition of the present invention.
Wherein, miticide composition of the present invention accounts for described acaricidal percentage by weight is 1% ~ 99%.
The form of preparation claims formulation, and what current Pesticide use was more is pulvis, aqua, wetting powder, missible oil, suspending agent, microcapsule suspending agent, water dispersible granules etc. more than ten plant formulation.Miticide of the present invention comprises wetting powder, missible oil, suspending agent, microcapsule suspending agent and water dispersible granules.
Wherein, wetting powder of the present invention comprises miticide composition, wetting agent, dispersant, carrier and inserts.Missible oil of the present invention comprises miticide composition, benzene or dimethylbenzene and surfactant.Suspending agent of the present invention comprises miticide composition, wetting dispersing agent, viscosity modifier, antifreezing agent and defoamer.Microcapsule suspending agent of the present invention comprises miticide composition, solvent, curing agent and viscosity modifier.Water dispersible granules of the present invention comprises miticide composition, wetting agent, disintegrant, dispersant, adhesive, interleaving agent and carrier.
Miticide of the present invention can also make the conventional multiple formulation such as granule, fumicants, aerosol, ultra low volume preparation, fumigant except above-mentioned formulation as required, to be applied to agricultural production.
Auxiliary agent, surfactant, carrier and other auxiliary materials that more than preparation various preparation is used are and well known to a person skilled in the art, if wetting agent is sulfonated oil, Nekal BX, soybean lecithin, thio-alcohol, hydrazides class, mercaptan acetals and polyethylene glycol oxide alkanisation ether etc.; Dispersant is sodium phosphate trimer, sodium pyrophosphate, lauryl sodium sulfate, cellulose derivatives, polyacrylamide, fatty acid polyethylene glycol ester and fatty alcohol oxirane etc.; Disintegrant is dried starch, sodium carboxymethyl starch, low substituted hydroxy-propyl methylcellulose, crospolyvinylpyrrolidone etc.; Adhesive is polyurethane, polystyrene, polyacrylate, vinyl acetate resin etc.; Solvent can be various aromatic hydrocarbons, aliphatic hydrocarbon, ketone etc.
Experiment shows, miticide of the present invention can prevent and treat farmland and fruit tree evil mite effectively, as citrus red mite, Tetranychus urticae etc.Miticide composition of the present invention is made up of second mite azoles and azacyclotin, has notable synergistic effect, improves preventive effect, reduces the consumption of active ingredient, delays the generation of pest resistance to insecticide, and reduces the pollution to environment.
In order to understand the present invention further, below in conjunction with embodiment, a kind of Compositional type farmland provided by the invention, fruit tree miticide are described in detail.
Embodiment 1:78% second mite azoles Avermectin wetting powder
60% second mite azoles, 18% Avermectin, 5% alkylphenol polyoxyethylene fully mix in proportion with 7% fatty alcohol oxirane, and diatomite is mended to 100%, obtained wetting powder after ultra-fine pulverizer disintegrating.
Embodiment 2:60% second mite azoles abamectin emulsifiable concentrate
40% second mite azoles, 24% Avermectin, 10% benzene and 15% dimethylbenzene and 11% dodecyl sodium sulfate fully mix in proportion, successively through mix and blend processing, obtain cream preparation.
Embodiment 3:80% second mite azoles azocyclotin dispersant
10% second mite azoles, 70% azacyclotin, 2% xylonic acid sodium sulfonate, 3% alumina silicate, 5% ethylene glycol, 1% isopropyl alcohol, water benefit obtains suspending agent to 100% common process.
Embodiment 4:55% second mite azoles azacyclotin wetting powder
5% second mite azoles, 50% azacyclotin, 10% alkylphenol polyoxyethylene fully mix in proportion with 15% fatty alcohol oxirane, and silica is mended to 100%, obtained wetting powder after ultra-fine pulverizer disintegrating.
Embodiment 5:42% second mite azoles propargite microcapsule suspending agent
2% second mite azoles, 40% propargite, 13% benzene, 30% curing agent, by after proportioning mixing, is directly scattered in 11% polyvinyl alcohol, then adds other solvent benefit to 100%, makes microcapsule suspending agent after slow reaction.
Embodiment 6:78% second mite azoles propargite suspending agent
3% second mite azoles, 75% propargite, 5% Nongru-700 #, 8% Sodium Polyacrylate, 5% propane diols, 1% tributyl phosphate, water benefit obtains suspending agent to 100% common process.
Embodiment 7:91% second mite azoles clofentezine missible oil
13% second mite azoles, 78% clofentezine, 3% benzene and 5% dimethylbenzene and 1% polyoxyethylene fatty amine fully mix, and successively through mix and blend processing, obtain cream preparation.
Embodiment 8:30% second mite azoles clofentezine water dispersible granule
3% second mite azoles, 27% clofentezine, 8% sulfonated oil, 17% sodium carboxymethyl starch, 24% sodium phosphate trimer and polystyrene, 14% calcium carbonate, 7% carrier mix, wetting powder is made after pulverizing, add a certain amount of water mixing extruder grain afterwards, obtained water dispersible granules after drying screening.
Embodiment 9:25% second mite azoles and Damanling suspension agent
5% second mite azoles, 20% propargite, 5% agriculture breast BY110,10% alumina silicate, 5% propane diols, 1% bubble enemy, water benefit obtains suspending agent to 100% common process.
Embodiment 10:32% second mite azoles and water dispersible granules
20% second mite azoles, 12% pyridaben, 8% polyethylene glycol oxide alkanisation ether, 15% crospolyvinylpyrrolidone, 26% fatty alcohol oxirane and polyacrylate, 11% talcum powder stearate soap, 8% carrier mix in proportion, wetting powder is made after pulverizing, add a certain amount of water mixing extruder grain afterwards, obtained water dispersible granules after drying screening.
Embodiment 11: control citrus red mite field control effectiveness test
Test and carry out in Zhengzhou, henan one peasant household orchard, active ingredient second mite azoles and Avermectin, azacyclotin, propargite, clofentezine or pyridaben mixture, test process and formulation rate are in table 1, as processed 8 for second mite azoles and the use of Avermectin mixture, reagent agent is second mite azoles and Avermectin, and formulation rate is containing reagent agent 13mg in every 1kg water, wherein, second mite azoles is 10mg, and Avermectin is 3mg.
Table 1 tests process and formulation rate
4 strain tree of the same size is selected in each process, every strain tree select east, south, west, north, in the blade in 5 orientation, often process repetition 4 times, respectively before dispenser and the quantity of dispenser " Invest, Then Investigate " record two spotted spider mite, calculate control efficiency, the results are shown in Table 2.
Table 2 control efficiency
| Process | Red spider radix | Borer population alive | Revision insect recluced rate (%) | Preventive effect (%) |
| 1 | 77 | 107 | -38.96 | 0.00 |
| 2 | 70 | 9 | 87.14 | 90.75 |
| 3 | 53 | 8 | 84.91 | 89.14 |
| 4 | 59 | 10 | 83.05 | 87.80 |
| 5 | 81 | 13 | 83.95 | 88.45 |
| 6 | 74 | 12 | 83.78 | 88.33 |
| 7 | 86 | 13 | 84.88 | 89.12 |
| 8 | 77 | 4 | 94.81 | 96.26 |
| 9 | 69 | 2 | 97.10 | 97.91 |
| 10 | 58 | 3 | 94.83 | 96.28 |
| 11 | 62 | 2 | 96.77 | 97.68 |
| 12 | 67 | 4 | 94.03 | 95.70 |
| 13 | 75 | 3 | 96.00 | 97.12 |
| 14 | 83 | 3 | 96.39 | 97.40 |
| 15 | 59 | 1 | 98.31 | 98.78 |
| 16 | 71 | 4 | 94.37 | 95.95 |
| 17 | 67 | 2 | 97.01 | 97.85 |
As seen from the results in Table 2, a kind of mixture in active ingredient second mite azoles and Avermectin, azacyclotin, propargite, clofentezine or pyridaben, compared with single dose, after reducing consumption, borer population of living is low, and Revision insect recluced rate is high, preventive effect is used alone higher than single dose, shows citrus red mite preventive effect desirable.As processed 12 for second mite azoles and the use of propargite mixture, formulation rate is second mite azoles 10mg in every 1kg water, propargite 200mg, and borer population of living is 4, and Revision insect recluced rate is 94.03%, and preventive effect is 95.70%.Be used alone with process 2 second mite azoles single dose and process 5 propargite single doses and be used alone and compare, decrease formulation rate, and borer population of living reduces, Revision insect recluced rate and preventive effect improve, and show that second mite azoles and propargite mixture reduce consumption, improve preventive effect.
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
Claims (5)
1. a miticide composition, is characterized in that, is made up of second mite azoles and azacyclotin, and the percentage by weight of described second mite azoles and azacyclotin is 1:7.
2. a miticide, is characterized in that, active component is made up of miticide composition described in claim 1.
3. miticide according to claim 2, it is characterized in that, it is 1% ~ 99% that described miticide composition accounts for described acaricidal percentage by weight.
4. miticide according to claim 2, is characterized in that, make wetting powder, missible oil, suspending agent, microcapsule suspending agent or water dispersible granules by described miticide composition and standard adjuvant.
5. the application of miticide described in Claims 2 or 3 in control farmland, fruit tree evil mite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310248469.2A CN103271077B (en) | 2010-12-01 | 2010-12-01 | A kind of Compositional type farmland, fruit tree miticide |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310248469.2A CN103271077B (en) | 2010-12-01 | 2010-12-01 | A kind of Compositional type farmland, fruit tree miticide |
| CN2010105684610A CN102484990A (en) | 2010-12-01 | 2010-12-01 | Composite miticide for farmland and fruit trees |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105684610A Division CN102484990A (en) | 2010-12-01 | 2010-12-01 | Composite miticide for farmland and fruit trees |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103271077A CN103271077A (en) | 2013-09-04 |
| CN103271077B true CN103271077B (en) | 2016-03-23 |
Family
ID=46150588
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310248469.2A Active CN103271077B (en) | 2010-12-01 | 2010-12-01 | A kind of Compositional type farmland, fruit tree miticide |
| CN201310251194.8A Active CN103271041B (en) | 2010-12-01 | 2010-12-01 | A kind of Compositional type farmland, fruit tree miticide |
| CN2010105684610A Pending CN102484990A (en) | 2010-12-01 | 2010-12-01 | Composite miticide for farmland and fruit trees |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310251194.8A Active CN103271041B (en) | 2010-12-01 | 2010-12-01 | A kind of Compositional type farmland, fruit tree miticide |
| CN2010105684610A Pending CN102484990A (en) | 2010-12-01 | 2010-12-01 | Composite miticide for farmland and fruit trees |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN103271077B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102007922A (en) * | 2011-01-01 | 2011-04-13 | 陕西上格之路生物科学有限公司 | Acaricide composition containing etoxazole and propargite |
| CN102302011A (en) * | 2011-04-27 | 2012-01-04 | 陕西韦尔奇作物保护有限公司 | Pesticide composition containing etoxazole |
| CN102210321A (en) * | 2011-05-04 | 2011-10-12 | 陕西韦尔奇作物保护有限公司 | Pesticide composite containing etoxazole |
| JP2013095740A (en) * | 2011-11-04 | 2013-05-20 | Sumitomo Chemical Co Ltd | Aqueous suspension agrochemical composition and aqueous suspension agrochemical formulation |
| CN102696631B (en) * | 2012-05-09 | 2015-07-08 | 广东中迅农科股份有限公司 | Synergistic acaricidal composition containing etoxazole and chlorfenapyr |
| CN103798278B (en) * | 2014-01-26 | 2016-04-20 | 上海艳紫化工科技有限公司 | Avermectin and the composite agricultural chemicals suspension agent of azacyclotin |
| CN105123714A (en) * | 2015-09-25 | 2015-12-09 | 安徽美兰农业发展股份有限公司 | Abamectin and etoxazole compound suspending agent and preparation method thereof |
| CN107318861A (en) * | 2016-04-28 | 2017-11-07 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN106035367B (en) * | 2016-06-16 | 2018-06-08 | 永春锐拓信息技术中心 | A kind of composition pesticide containing azacyclotin and propargite |
| CN109042694A (en) * | 2018-06-28 | 2018-12-21 | 安徽瑞然生物药肥科技有限公司 | A kind of etoxazole AVM hereinafter suspending agent |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1391810A (en) * | 2002-07-04 | 2003-01-22 | 胡凡 | Insecticide and acaricide composition containing abamectin |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3428112B2 (en) * | 1993-12-21 | 2003-07-22 | 八洲化学工業株式会社 | Composite acaricide composition |
| CN102283216B (en) * | 2010-06-19 | 2013-04-03 | 海利尔药业集团股份有限公司 | Acaricidal composition containing abamectin and etoxazole |
| CN101856029B (en) * | 2010-07-07 | 2013-01-30 | 浙江威尔达化工有限公司 | Pesticide combination containing etoxazole and abamectin |
-
2010
- 2010-12-01 CN CN201310248469.2A patent/CN103271077B/en active Active
- 2010-12-01 CN CN201310251194.8A patent/CN103271041B/en active Active
- 2010-12-01 CN CN2010105684610A patent/CN102484990A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1391810A (en) * | 2002-07-04 | 2003-01-22 | 胡凡 | Insecticide and acaricide composition containing abamectin |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103271041A (en) | 2013-09-04 |
| CN103271041B (en) | 2015-07-29 |
| CN103271077A (en) | 2013-09-04 |
| CN102484990A (en) | 2012-06-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103271077B (en) | A kind of Compositional type farmland, fruit tree miticide | |
| CN101715777B (en) | Pesticide composition containing ethirimol and thiophanate-methyl, and application thereof | |
| CN103283746B (en) | One planting fruit-trees, forest trunk disease therapeutic agent | |
| CN104322558A (en) | Sterilization composition and applications thereof | |
| CN104522054A (en) | Biological source synergistic compound insecticide, preparation method and application thereof | |
| CN104082300B (en) | Insecticide acaricide composition containing pyriproxyfen and spirodiclofen | |
| CN102669157B (en) | Mite-killing composition and preparation thereof | |
| CN104115861A (en) | Insect and mite killing composition containing xiaochongthion and cyflumetofen | |
| CN106689186A (en) | Efficient insecticidal composition containing bifenthrin and pyriproxyfen | |
| CN102657216A (en) | Use of pesticide mixed preparation containing chlorpyrifos and high-efficiency cypermethrin in control of Athetis lepigone Moschler | |
| CN102334488B (en) | Insect-killing and disease-preventing suspension seed coating formulation | |
| CN104115850A (en) | Insect and mite killing composition containing etoxazole and spirotetramat | |
| CN101473828B (en) | Agricultural chemical composition for disinsection and use thereof | |
| CN101380002A (en) | Insecticide and acaricide composition containing spirodiclofen | |
| CN103070186A (en) | Insecticidal composition containing thiamethoxam and application of insecticidal composition | |
| CN105010383A (en) | Insecticidal composition containing dinotefuran and indoxacarb and preparation method thereof | |
| CN102239891A (en) | Enhanced compound pesticide containing toosedarin plant source and preparation method thereof | |
| CN106900757B (en) | A kind of bitter pueraria root extract and the Pesticidal combination of Osthole and application thereof for preventing and treating agricultural pests | |
| CN101491251A (en) | Pesticide combination and use thereof | |
| CN104115833A (en) | Insect and mite killing composition containing pyriproxyfen and cyflumetofen | |
| CN104094963A (en) | Insecticide-acaricide composite with synergistic effect | |
| CN103719115A (en) | Insecticidal composition | |
| CN102972425A (en) | Monosultap and acetamiprid compounded insecticide | |
| CN103300013A (en) | Compounded acaricide for farmlands and fruit trees | |
| CN106973949B (en) | A kind of Pesticidal combination and application thereof comprising bitter pueraria root extract and matrine |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20220207 Granted publication date: 20160323 |