CN102469838A - Work glove - Google Patents

Work glove Download PDF

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Publication number
CN102469838A
CN102469838A CN2010800283369A CN201080028336A CN102469838A CN 102469838 A CN102469838 A CN 102469838A CN 2010800283369 A CN2010800283369 A CN 2010800283369A CN 201080028336 A CN201080028336 A CN 201080028336A CN 102469838 A CN102469838 A CN 102469838A
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CN
China
Prior art keywords
filament
gloves
composite filament
silk
conducting fibre
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Granted
Application number
CN2010800283369A
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Chinese (zh)
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CN102469838B (en
Inventor
岸原英敏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Showa Glove Co
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Showa Glove Co
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Application filed by Showa Glove Co filed Critical Showa Glove Co
Publication of CN102469838A publication Critical patent/CN102469838A/en
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Publication of CN102469838B publication Critical patent/CN102469838B/en
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    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/015—Protective gloves
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/0055—Plastic or rubber gloves
    • A41D19/0058—Three-dimensional gloves
    • A41D19/0065—Three-dimensional gloves with a textile layer underneath
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/26—Electrically protective, e.g. preventing static electricity or electric shock
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Gloves (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)

Abstract

Disclosed is a work glove which has been entirely or partly knitted from a composite yarn comprising a filament yarn and a conductive fiber, characterized in that the filament yarn contained in the composite yarn has a recovery from stretch of 0-10%.

Description

Gloves are used in work
Technical field
The present invention relates to semiconductor manufacturing process with cover with paint, lacquer, colour wash, etc. that operation or dustless office operation etc. have the composite filament that uses in the field of electric conductivity and low dusting property requirement and manufacturing approach thereof, the work that obtains with this composite filament is with gloves and cloth and silk, this work manufacturing approach with gloves and cloth and silk.
Background technology
In semiconductor manufacturing process, covering with paint operation or dustless office operation etc., need to use work to use gloves with electric conductivity.Such work is blended into the conducting fibre that obtains in polyester or the nylon fiber with having used in the gloves with carbon.In addition, such work is with also using in the gloves coating acrylic fiber and the conducting fibre that obtains enrolls the composite filament that obtains in the long filaments such as a mao nylon, simulate wool polyester capillaries etc. with copper sulfide with acrylic fiber dyeing or with polypyrrole.And, for the anti-skidding finger tip part that will such gloves, palm portion has been carried out coating with polyurethane resin or synthetic rubber etc. work also used with gloves etc.
For example, disclose the gloves of partly having sewed on the electric conductivity wire rod at finger part and the back of the hand among the JP2009-102779A, this electric conductivity wire rod is on the surface of synthetic fibers, to have formed metallicity by the wire rod of rete.Record a kind of conducting fibre cloth in No. 3042096, the Japan registration utility model, Yi Bian this conducting fibre cloth is from being that main component has been mixed the fibrous silk thread raw material of electromagnetic wave that the material of mineral such as silica or aluminium oxide obtains and the fibrous silk thread raw material of the copper ion property conducting fibre cloth that inweaves of winding each other on one side with platinum.But also the gloves made with this conducting fibre cloth or cloth and silk etc. are disclosed.A kind of gloves that use the electric conductivity silk thread are disclosed among the JP2006-63456A.The openly flat 6-54720 communique of Japan registration utility model discloses a kind of finger part at the formation gloves and has used resistance value 10 9The gloves of the electric conductivity strand below Ω/cm.In above-mentioned any one gloves, all can obtain the electric conductivity and the low dusting property of prescribed level.
Yet, in above-mentioned known gloves, used conducting fibre intactly enrolled the composite fibre that obtains in the long filament.Result from the physical property of conducting fibre, such gloves can't obtain enough to be used for when wearing, having the retractility about fit sense.In addition, owing to conducting fibre costs an arm and a leg, so, the problem that resulting composite filament and gloves etc. also exist cost to raise.
In order to prevent or to suppress static, perhaps reduce cost, there is a kind of scheme to propose a kind of composite filament that obtains through looping conducting fibre on long filaments such as hair nylon fiber or simulate wool polyester fiber and used the work of this composite filament to use gloves.So-called looping is to twine the method that becomes the silk thread of wrap wire and obtain composite filament in the periphery of the silk thread that becomes core with the interval of regulation.The situation that obtains composite filament with pass through and sth. made by twisting etc. is compared, and the length of the needed silk thread of looping is shorter, therefore can expect the advantage of cost aspect.In addition, compare with doubler twister, therefore the extensive listing of the machine of looping and being widely used also is effective from productive viewpoint.
, when having on the gloves of processing with such composite filament and carry out operation, the problem that exists the conducting fibre in these gloves to come off owing to the friction and wear in the operation.For this reason, in for example semiconductor manufacturing process etc., have the situation that the faults such as insulation breakdown of semiconductor substrate take place to cause because of the conducting fibre that comes off.
The reason that conducting fibre in the gloves comes off is inferred as follows.In order to improve the fit of gloves; Existing static countermeasure with gloves all be to use usually the flexible return rate of measuring according to the JIS of Japanese Industrial Standards (Japanese Industrial Standard) L1013 be 20%～50% warp curl processing long filament (for example; Hair nylon yarn etc.) as heart yearn, use conducting fibre as wrap wire.In the occasion of having used such long filament, when obtaining composite filament, perhaps when making gloves, carry out operation with tension force while on technology, need give silk thread with this composite filament through looping.This tension force is eliminated after operation.So, along with this long filament restores to the original state, by looping the little conducting fibre of recovery extent outwards bloat from the surface of composite filament.And, can infer that the conducting fibre that outwards bloats comes off because of friction and wear easily.Particularly in the thickness of the conducting fibre occasion also thinner than the thickness of long filament, the phenomenon that conducting fibre bloats from the surface of composite filament just becomes more remarkable.
Summary of the invention
Invent problem to be solved
Therefore, the coming off of the conducting fibre that the friction and wear in order to prevent by operation causes is even after having eliminated tension force after the looping or after the manufacturing at gloves, also must suppress the little conducting fibre of recovery extent and bloat laterally.
Problem of the present invention is, a kind of composite filament that comes off, has concurrently electric conductivity and low dusting property that can prevent conducting fibre for a long time is provided in view of the above problems and the work that obtains with this composite filament with gloves and cloth and silk.
Be used to solve the means of problem
The inventor has carried out with keen determination research repeatedly in order to solve above-mentioned problem, the situation that the result has found to let restorative (nerve) and quilt constitutes the long filament of composite filament with this conducting fibre combination restorative (nerve) of conducting fibre to be close.Its result, discovery can obtain to prevent the composite filament that comes off of conducting fibre and the work that obtains with this composite filament with gloves and cloth and silk, thereby accomplished the present invention.In addition, long filament is to be wound onto as the looping silk on the conducting fibre of heart yearn, to be used as heart yearn that the conducting fibre of looping silk reels, to be added in as the interpolation silk of the conducting fibre of heart yearn, with conducting fibre and twist with the fingers and become and the silk thread of twisted filament etc.
That is, the present invention is the technical scheme of purport with following (1)～(16).
(1) gloves are used in a kind of work, and a gloves integral body or a part form so that the composite filament that contains long filament and conducting fibre is knitting, it is characterized in that, the whole flexible return rate of long filament that is included in the said composite filament is 0-10%.
(2) use gloves like (1) described work, it is characterized in that, long filament is a heart yearn, and conducting fibre is the looping silk on every side that is wound onto said heart yearn.
(3) use gloves like (1) described work, it is characterized in that, long filament is a heart yearn, and conducting fibre is the interpolation silk that makes an addition to said heart yearn, and these heart yearns and interpolation silk are by looping silk looping.
(4) use gloves like (1) described work, it is characterized in that, conducting fibre is a heart yearn, and long filament is the looping silk on every side that is wound onto said heart yearn.
(5) use gloves like (1) described work, it is characterized in that, composite filament is with long filament and conducting fibre and twist with the fingers and form.
(6) use gloves like any described work in (1) to (5), it is characterized in that, conducting fibre is and the form of twisted filament.
(7) use gloves like any described work in (1) to (6), it is characterized in that, the integral body on finger tip part, palm portion or surface is synthesized rubber or resin-coated.
(8) a kind of work is characterized in that with the manufacturing approach of gloves, has:
Make the operation of the flexible return rate reduction of the processing silk that curls;
Obtain to contain in the part at least curling processing silk, whole flexible return rate after flexible return rate is reduced and be the operation of 0～10% long filament;
Obtain the operation of composite filament with said long filament and conducting fibre;
Said composite filament is knitted into the operation of gloves.
(9) a kind of composite filament contains long filament and conducting fibre, it is characterized in that, the whole flexible return rate of long filament that is included in the said composite filament is 0-10%.
Like (9) described composite filament, it is characterized in that (10) long filament is a heart yearn, conducting fibre is the looping silk on every side that is wound onto said heart yearn.
Like (9) described composite filament, it is characterized in that (11) long filament is a heart yearn, conducting fibre is the interpolation silk that is added in said heart yearn, and these heart yearns and interpolation silk are by looping silk looping.
Like (9) described composite filament, it is characterized in that (12) conducting fibre is a heart yearn, long filament is the looping silk on every side that is wound onto said heart yearn.
Like (9) described composite filament, it is characterized in that (13) this composite filament is with long filament and conducting fibre and twist with the fingers and form.
Like any described composite filament in (9) to (13), it is characterized in that (14) conducting fibre is and the form of twisted filament.
(15) a kind of manufacturing approach of composite filament is characterized in that, has:
Make the operation of the flexible return rate reduction of the processing silk that curls;
Obtain to contain in the part at least curling processing silk, whole flexible return rate after flexible return rate is reduced and be the operation of 0～10% long filament;
Obtain the operation of composite filament with said long filament and conducting fibre.
(16) a kind of cloth and silk is characterized in that, the whole or part of this cloth and silk forms with any described composite filament in (9) to (15).
The invention effect
Among the present invention, be defined as 0～10% to the flexible return rate of measuring according to the JIS L1013 of Japanese Industrial Standards that is incorporated into the long filament that constitutes composite filament in the conducting fibre.Its result make conducting fibre restorative (nerve) be incorporated into conducting fibre in constitute the long filament of composite filament restorative (nerve) roughly conform to and become possibility.Thus; Any one occasion in the occasion that conducting fibre is used as heart yearn, the occasion of using as the looping silk, the occasion used as the interpolation silk of heart yearn; After looping, eliminate in the tension force, can both prevent that the little conducting fibre of reinstatement degree from outwards bloating.Its result, the coming off of the conducting fibre that can suppress to cause because of friction and wear.Also have, even in long-term actual the use, also can suppress coming off of conducting fibre effectively.The work of therefore, can obtain to have concurrently the composite filament of electric conductivity and low dusting property, processing with this composite filament is with gloves and cloth and silk.
Description of drawings
Fig. 1 is that the expression heart yearn is that long filament, looping silk are the skeleton diagram of the contrast of the occasion after composite filament and the tension force on this composite filament of conducting fibre is eliminated.
The skeleton diagram of the contrast of the occasion of Fig. 2 after to be expression as the heart yearn of long filament with as the interpolation silk of conducting fibre be eliminated with the composite filament of long filament looping and the tension force on this composite filament.
The skeleton diagram of the contrast of the occasion after Fig. 3 composite filament that to be the heart yearn that constituted by align of expression plurality of threads formed by the conducting fibre looping and the tension force on this composite filament are eliminated.
The skeleton diagram of the contrast of the occasion after Fig. 4 composite filament that to be expression form with the long filament looping as the conducting fibre of heart yearn and the tension force on this composite filament are eliminated.
The skeleton diagram of the contrast of the occasion after Fig. 5 composite filament that to be the heart yearn that constituted by align of many conducting fibres of expression form with the conducting fibre looping and the tension force on this composite filament are eliminated.
Fig. 6 is the skeleton diagram of the of the present invention work of expression palm portion after by resin-coated with gloves.
Fig. 7 is when being illustrated in the flexible return rate of measuring long filament, will hang the skeleton diagram of the state in the sample 6 vertical entry 10 of load 8 of load 7 and (8.82mN * 20 * demonstration tex) of (0.176mN * 20 * demonstrations tex (expression テ Star Network ス number)).
The specific embodiment
Work of the present invention is that gloves are whole or a part of with the knitting gloves of composite filament with gloves.This composite filament be contain conducting fibre and with the silk thread of this conducting fibre combination (that is, be wound onto as the looping silk on the conducting fibre of heart yearn, be used as heart yearn that the conducting fibre of looping silk reels, be added in as the interpolation silk of the conducting fibre of heart yearn, quilt and conducting fibre and twist with the fingers and silk thread such as twisted filament) composite filament.
From the viewpoint of low dusting property, conducting fibre used in the present invention is preferably long filament (long fibre in other words).
As conducting fibre; Can enumerate metallic fibers such as stainless steel (for example, diameter is the metallic fiber of 20～50 μ m), on synthetic fibers surfaces such as acrylic fiber polymerization pyrroles's etc. fiber, on the acrylic fiber surface, coated the fiber of copper sulfide etc., carbon admixed fiber that obtains in polyester fiber or the nylon fiber etc.
Wherein, on synthetic fibers surfaces such as acrylic fiber, coated fibers such as copper sulfide, carbon admixed the fiber in polyester fiber or the nylon fiber from improving viewpoint, being preferably as the requirement of the liquor style of gloves and static countermeasure aspect.
From reducing the viewpoint of the dust yield and the amount of coming off, be preferably conducting fibre and be also twisted filament.In this occasion, can be that conducting fibre and non-conductive fiber are also twisted with the fingers the also twisted filament that forms, also can be only conducting fibre also to be twisted with the fingers the also twisted filament that forms.Wherein, if conducting fibre and non-conductive fiber are also twisted with the fingers the also twisted filament that forms, also can not produce insulation breakdown even then come off, be safe, uses this and twisted filament so be preferably.
Conducting fibre is occasion conducting fibre and non-conductive fiber and twisted filament; Then be preferably with the flexible return rate of measuring according to the JIS L1013 of Japanese Industrial Standards be 0～10% long filament with conducting fibre and twist with the fingers form and twisted filament, further be preferably the also twisted filament that to be 0～7% long filament form with conducting fibre and sth. made by twisting of flexible return rate.Quilt surpasses at 10% o'clock with the flexible return rate of the long filament of conducting fibre and sth. made by twisting, has the dust yield and the many situation of quantitative change that come off, and is not therefore praised highly.In addition, the long filament of flexible return rate less than 0% is actually non-existent.
Flexible return rate among the present invention uses as the index of restorative (nerve) of silk thread, and its assay method will be described in the embodiment of back.
With conducting fibre and long filament and twist with the fingers and obtain and the occasion of twisted filament, be preferably every meter 50 be twisted to 700 twist with the fingers and twist with the fingers form and twisted filament, further be preferably 100～500 twist with the fingers and twist with the fingers form and twisted filament.And twist with the fingers twisting count less than 50 when twisting with the fingers, and poor as the yield behavior of silk thread, can not further carry out well and twist with the fingers with doubler twister, have the situation of productivity decline.On the other hand, and twist with the fingers twisting count and surpass 700 when twisting with the fingers, resulting and twisted filament has the situation really up to the mark and unpractical that becomes.
From preventing the viewpoint that composite filament bloats from wire ends, quilt is compound with conducting fibre and silk thread that constitute composite filament must be a long filament, i.e. long fibre.As long filament, can use the fiber that forms by polyester, acrylic acid, reinforcement polyethylene, aromatic polyamides, nylon etc. separately, perhaps also can be also with two or more fibers.
As the heart yearn of composite filament or the occasion of adding the silk use, preferably its rugosity is every 50d～450d, further is preferably 50d～200d with this long filament.During rugosity deficiency 50d, the sense of stability when having as heart yearn or interpolation silk and the situation of intensity difference on the other hand, when rugosity surpasses 450d, have and become too stiff, as the liquor style of composite filament or the situation of sense of touch difference.
With the occasion of this long filament as the looping silk use of composite filament, being preferably its rugosity is every 2d～5d, further is preferably 1.3d～2.9d.During rugosity deficiency 2d, have the dust yield and the many situation of quantitative change that come off, on the other hand, when rugosity surpasses 5d, have the situation of liquor style variation.
If wait the silk thread that obtains through the processing of curling, the flexible return rate of long filament is usually about 20～50%.Among the present invention, the value of the flexible return rate of the long filament that flexible return rate and the quilt that need make conducting fibre and this conducting fibre are compound is approaching.Owing to make the value of flexible return rate of the two approaching, so must suppress to be used as the coming off of conducting fibre of the occasion of composite filament.Because the flexible return rate of conducting fibre is generally about 1～5%, so be necessary for 0～10% by the flexible return rate of compound long filament, is preferably 0.1～10%, further is preferably 1～7%.Note, by the occasion that the flexible different multi-filament line of return rate constitutes, must make the whole flexible return rate of long filament satisfy above-mentioned scope at this long filament.
Generally speaking,, for example can consider in order to make conducting fibre and roughly to conform to restorative (nerve) of (that is) other silk threads of this conducting fibre combination usefulness by compound, can be to the processing of curling of this conducting fibre.Yet if Tongran color fibre or admixed the conducting fibre of carbon, because the raw material properties aspect, the curling processing of giving retractility is difficult.Even if obtained retractility, its flexible return rate is about 2～3% low value only, owing to can't obtain as the fit sense of work during with gloves, so there is not practicality.Therefore, must be as the present invention, making the whole flexible return rate of long filament that uses with the conducting fibre combination is 0～10%.
As long filament, even if so long as just can use for its flexible return rate of state of raw silk also satisfies above-mentioned scope.Yet owing to slightly a retractility is arranged, the fit sense when putting on one's gloves can promote, so be preferably the flexible return rate of the processing silk that curls is reduced, and uses as long filament.
Long filament can use the commodity of selling on the flexible market of return rate in above-mentioned scope, and the flexible return rate that also can make flexible return rate exceed the long filament of above-mentioned scope is reduced to back use in the above-mentioned scope.As the method that the flexible return rate that makes long filament reduces, the following method of can giving an example.
At first, with long filament so that its rolling density becomes 0.2～0.3g/cm 3Mode loosely be wound on the bobbin, carry out hot wash in 0.17～1 hour at about 70～100 ℃.Next, dewatered 1～30 minute, 60～100 ℃ of dryings of carrying out 40～300 minutes.Through heat-treating like this, the flexible return rate of long filament is reduced.Can be used for carrying out such processing to for example known overflow dyeing machine.
Notice that above-mentioned condition can be carried out suitable adjustment according to the material that constitutes long filament etc.
As the employed looping silk of looping, can use for example above-mentioned conducting fibre, also can use polyester, strengthen polyethylene, the raw silk of aromatic polyamides, nylon, acrylic acid system fiber, perhaps it has been carried out the curling processing thread etc. after the curling processing.
As the formation of the composite filament among the present invention, can enumerate following (i)～(v).The formation (i)～(v) of composite filament is described with Fig. 1～Fig. 5.
(i) being is heart yearn with the long filament, and conducting fibre is wound on the formation on every side of said heart yearn as the looping silk.Fig. 1 (a) is the figure of composite filament that expression has the formation of (i).That is, expression is a heart yearn with long filament 1, through the composite filament that this heart yearn is obtained with conducting fibre 2 loopings.After the looping or after having carried out the manufacturing of gloves etc., even under the situation after tension force is eliminated, shown in Fig. 1 (b), the situation that the conducting fibre 2 that the reinstatement degree is little bloats has laterally also obtained inhibition.
(ii) be to be heart yearn with the long filament, as the interpolation silk that makes an addition to said heart yearn, these heart yearns and interpolation silk are by the formation of looping silk looping with conducting fibre.Fig. 2 (a) is the figure that expression has the composite filament of formation (ii).That is, expression is a heart yearn with long filament 1, serves as to add silk with conducting fibre 2, through the composite filament that said heart yearn and interpolation silk are obtained with long filament 1 looping.After the looping or after having carried out the manufacturing of gloves etc., even under the situation after tension force is eliminated, shown in Fig. 2 (b), the situation that the conducting fibre 2 that the reinstatement degree is little bloats has laterally also obtained inhibition.
(iii) be that long filament with many align is a heart yearn, conducting fibre as the looping silk be wound onto said heart yearn around formation.In other words, be that heart yearn is a many formation in the occasion of above-mentioned formation (i).Fig. 3 (a) is the figure that representes formation (iii).That is, the expression with after plurality of threads 1 align as heart yearn, through the composite filament that said heart yearn is obtained with conducting fibre 2 loopings.After the looping or after having carried out the manufacturing of gloves etc., even under the situation after tension force is eliminated, shown in Fig. 3 (b), the situation that little conducting fibre 2 bloats laterally about reinstatement has also obtained inhibition.
(iv) be to be heart yearn with the conducting fibre, long filament is wound onto the formation on every side of said heart yearn as the looping silk.Fig. 4 (a) is the figure that expression has the composite filament of formation (iv).That is, expression is a heart yearn with conducting fibre 2, through the composite filament that said heart yearn is obtained with long filament 1 looping.After the looping or after having carried out the manufacturing of gloves etc., even under the situation after tension force is eliminated, shown in Fig. 4 (b), the situation that little conducting fibre 2 bloats laterally about reinstatement has also obtained inhibition.
(v) be many conducting fibres with align as heart yearn, conducting fibre as the looping silk be wound onto said heart yearn around formation.In other words, be that heart yearn is a many formation in above-mentioned occasion (iv).Fig. 5 (a) is that expression has the (figure of the composite filament of formation v).That is, the expression with after many conducting fibres 2 align as heart yearn, through the composite filament that said heart yearn is obtained with long filament 1 looping.After the looping or after having carried out the manufacturing of gloves etc., even under the situation after tension force eliminated, shown in Fig. 5 (b), the situation that the conducting fibre 2 that the reinstatement degree is little bloats has laterally also obtained inhibition.
When the whole flexible return rate of the long filament in the composite filament surpasses 10%, to compare with Fig. 1 (b), Fig. 2 (b), Fig. 3 (b), Fig. 4 (b), Fig. 5 (b), the phenomenon that conducting fibre is surperficial from composite filament or glove surface bloats becomes remarkable.That is, among the present invention,, bloat from composite filament surface or glove surface so can suppress conducting fibre because the flexible return rate that the long filament in the composite filament is whole is defined as 0～10%.
Even if it is in above-mentioned composite filament,, the most preferred in order that have the composite filament of the formation of (i) from the viewpoint that comes off that suppresses conducting fibre effectively.
The looping number of turns is preferably about core 50～700 circles of every 1m, is more preferably 100～500 circles, further is preferably 200～400 circles.When the looping number of turns surpassed 700 circles, the composite filament hardening was difficult to knittingly, has the situation as the liquor style variation of gloves.During looping number of turns less than 50 circles, can not carry out looping with machine, have the situation that to carry out the production of composite filament with known habitual looping.
When carrying out looping, can enumerate S word coiling and Z word coiling etc. as its method for winding.Note; When carrying out looping, through carry out the coiling reverse with heart yearn (in other words, if heart yearn reel then the method for winding of Z-shaped coiling looping silk for S shape; If heart yearn is Z-shaped coiling then the method for winding of S shape coiling looping silk); The twisting of composite filament and knit goods disappears, and becomes good finished product, so be preferably the coiling reverse with heart yearn.
Notice that if conducting fibre or itself and twisted filament are used as the looping silk, then the conducting fibre area that exposes composite filament surface and glove surface can become big.Consequently, the effect that reduces surface resistivity improves.Yet, on the other hand, become big because conducting fibre exposes the area of composite filament surface and glove surface, so the quantitative change that comes off of conducting fibre is many.Therefore,, be preferably conducting fibre or itself and twisted filament and do not use as the looping silk from the viewpoint of the amount of coming off that suppresses conducting fibre, and the silk that is used as heart yearn, adds silk, carries out and twist with the fingers.
Having the composite filament that constitutes as stated can obtain through following method.
That is, obtain: make the flexible return rate of long filament be reduced to 0～10% operation through said method through following operation; Obtain as required to contain in the part at least that to make the long filament after flexible return rate reduces, whole flexible return rate be the operation of 0～10% long filament; With said long filament and conducting fibre, through looping or and twist with the fingers to wait the operation of acquisition composite filament.
Through the knitting composite filament that as above-mentioned, obtains, can access work of the present invention with gloves and cloth and silk.Notice that among the present invention, so-called cloth and silk is the appellation of knitted fabric, yarn fabric, nonwoven etc.
As the knitting method of composite filament, can use known customary way and device, only with the whole method of above-mentioned composite filament knitted gloves, perhaps also can select the part of gloves, for example finger tip is knitting with composite filament.With the occasion of the knitting work of above-mentioned composite filament with the part of gloves, be preferably again, for example (コ-ス) carried out knitting (that is, with knitting 1 row of composite filament, being right after capable with knitting 1 row～10 of long filament thereafter) with 1: 1～1: 10 row with composite filament and long filament.Contain conducting fibre in the composite filament and compare the retractility reduction with the situation that does not contain conducting fibre.Therefore, knitting through composite filament and long filament are carried out with 1: 1～1: 10 row, only can optionally comprise with high (for example about 50%) long filament or the knitting part of polyurethane elastic filament of flexible return rate.Its result can make as fit sense and the liquor style of work with gloves and cloth and silk etc. and improve.Have again, the work of can giving with gloves and cloth and silk integral body with uniform charging property.
Using composite filament to obtain the occasion of work of the present invention with gloves and cloth and silk, being preferably its sheet resistance value is 1 * 10 5～1 * 10 10Ω/seq. is more preferably 1 * 10 6～1 * 10 8Ω/seq..Because sheet resistance value can make static spread lentamente in this scope the time, so be preferably sheet resistance value in this scope.Sheet resistance value less than 1 * 10 5During Ω/seq.,, have and get an electric shock or the situation of short circuit in the occasion that conducting fibre comes off.On the other hand, sheet resistance value surpasses 1 * 10 10During Ω/seq., find static discharge is arranged and the situation of the insulation breakdown that causes.Through the knitting method (in other words, the ratio of composite filament and loops of filament line number) of the occasion of knitting composite filament, conducting fibre and the mixed fine rate of long filament in the composite filament are carried out suitable adjustment, can sheet resistance value be controlled in the above-mentioned scope.
The work that obtains through knitting composite filament with gloves or the cloth and silk that obtains through knitting composite filament made the work that obtains with gloves in; Can use enforcements such as synthetic rubber or resin with anti-skidding processing to finger tip part, palm portion, or whole surface as purpose.
As anti-skidding processing, can enumerate, for example in finger tip part or palm portion, form the processing of anti-skidding protuberance with anti-skidding tunicles of formation such as polyurethane resin or synthetic rubber, with synthetic rubber or PVC based polymer etc.For example, the gloves that obtain are enclosed within on the impregnation mold of the shape that is rendered as hand, are immersed in the polyurethane system resin solution etc., carry out water displacement, drying.Through such method, can form anti-skidding tunicle with polyurethane resin or synthetic rubber etc. in finger tip part or palm portion, perhaps form anti-skidding protuberance with synthetic rubber or PVC based polymer etc.
The figure that Fig. 6 (a) is seen when being the gloves after the back of the hand is partly observed the anti-skidding processing of having been implemented above-mentioned that kind.The figure that Fig. 6 (b) is seen when being the gloves after anti-skidding processing has been implemented in the palm portion observation.In the gloves 3, palm portion is coated by resin 4.
As synthetic rubber, can enumerate acrylonitrile-butadiene rubber, neoprene, acrylic acid, polyurethane, vinyl acetate resin-PVC copolymer, the single polymers of PVC etc.
In addition, also can be through implementing anti-skidding processing to synthetic rubber compound or vinyl acetate resin-PVC copolymer, the single polymers of PVC with squeegee in the porous printing that the metacarpus of gloves carries out convex.
In addition, on resulting gloves, implement in the above-mentioned anti-skidding processing, surperficial in order to prevent oversteeping such as resin to gloves, can carry out eyelet and fill up (order ends め).Particularly, can carry out eyelet and fill up through fingerprint tool dipping, drying, leaching, the sulfuration in synthetic rubber compounds such as acrylonitrile-butadiene rubber, neoprene, acrylic acid, polyurethane that will be stained with pernitric acid calcium coagulating agent.Perhaps, as the additive method that eyelet is filled up, also can adopt dipping, drying after, make the method for the goods demoulding, leaching, dehydration, sulfuration.
Composite filament of the present invention, the work that obtains with this composite filament is with gloves and cloth and silk, is specially adapted in semiconductor manufacturing process, covering with paint operation or dustless office operation etc. have the field of electric conductivity and low dusting property requirement, use.
Embodiment
Below, enumerate embodiment further explain the present invention.These embodiment and indefinite the present invention's meaning.
The employed evaluation method of embodiment and comparative example is represented as follows.
1. sheet resistance value
The circular knitting cloth that cuts out the about 8cm of diameter from the gloves that embodiment and comparative example, obtain is as test film.This test film is arranged on sheet resistance value determinator (MONROEELECTRONICS manufactured, " 272A type ") (making alive: 10V), read value after 15 seconds as sheet resistance value.The occasion of the value after reading 15 seconds has partly been followed EN1149-1.Condition determination is set at 23 ℃ of room temperatures, humidity 45%.
2. the amount of coming off of conducting fibre
2.1 dusting property test
Each 1000 on the gloves that preparation obtains in embodiment and comparative example.It is that activating agent (Black Warrior (ゲ Application Block) manufactured, trade name " super L (ス-パ-L) ") added in the washing lotion in the 113L pure water washing 15 minutes that the gloves that prepared are put into nonionic with 50g, next, cleans with ultra-pure water and to clean washing 3 times.After the cleaning washing, according to the JIS B9923 of Japanese Industrial Standards (tumbling (タ Application Block リ Application グ method)), to the 1cft behind 10 gloves dustings 3The above particle number (the particle numbers of 10 gloves) of the 0.5 μ m that is swimming in the gas is measured.With measured value as estimating with the amount of coming off of fiber is corresponding.
Among the present invention, being defined as of 10 of the particle number less thaies that will swim can be stood actual use.
2.2 adhesive tape forcible separation method
Each 3 on the gloves that preparation obtains in embodiment and comparative example.In the gloves that prepared, 1 cotton calico of usefulness rubs 100 times, and 1 cotton calico of usefulness rubs 300 times in addition.Next; (the smart device of Daiei science is made manufacturing with learning the shape color fastness testing machine that shakes; Trade name " RT-200 "), with the load of 300g with adhesive tape ((the ニ チ バ Application) manufactured of stumbling day, " cellophane adhesive tape (セ ロ Ha Application テ-プ) ") (size: 20mm * 20mm) sticks on the gloves that do not rub respectively, on rubbed 100 times gloves, 300 times the gloves of having rubbed; Take off after 5 seconds, such operation has been repeated 5 times with same adhesive tape.After this, observe the adhesive tape surface, the radical of the conducting fibre that adhered to is counted with microscope (KEYENCE manufactured, trade name " VHX-900 ").With the measured value of this radical as estimating with the corresponding value of the amount of coming off of fiber.
Among the present invention, being defined as of 10 of the radical deficiencies of the conducting fibre that is adhered to can be stood actual use.
3. flexible return rate
Below with Fig. 7 the flexible return rate determination method according to the JIS L1013 of Japanese Industrial Standards definition is described.
From the composite filament of the formation gloves that embodiment and comparative example, obtain, choose long filament; Volume hangs on the hook 5; The load 7 of suspension (0.176mN * demonstration tex), the making Guang is about 40cm, winding number is the line of the little one-tenth Guang of 10 circles, has processed the sample 6 that adds up to 20 rhizoid bundles.Next, in 60 ℃ water, flood draining after 20 minutes, on filter paper, made its air dry 24 hours.With this sample 6, as shown in Figure 7, on the load 7 of (0.176mN * 20 * demonstration tex), hang up again under the state of load 8 of (8.82mN * 20 * demonstration tex), left standstill dipping in the water 9 that the temperature of hanging down is 20 ± 2 ℃ 2 minutes.After this, from water, take out and to measure Guang long, at once with the load dismounting with encircle 10 remove (8.82mN * 20 * demonstration tex) load 8, place after 2 minutes, once more to Guang progress row measurement.Calculated flexible return rate Er (%) with following formula then.
Er＝[(a-b)/a]×100
A: on the load 7 of (0.176mN * 20 * demonstration tex), the Guang when having added the load 8 of (8.82mN * 20 * demonstration tex) again long (mm)
B: the Guang when having hung the load 7 of (0.176mN * 20 * demonstration tex) long (mm)
Note, measure and carried out 5 times, with its mean value as flexible return rate.
Next, the material that uses in embodiment and the comparative example is represented as follows.
(A) long filament
(A-1) hair nylon (70d-24f, flexible return rate 24%) (east beautiful (eastern レ) manufactured)
(A-2) hair nylon (70d-24f, flexible return rate 7%)
(A-1) loosely is wound on the bobbin with hair nylon, and rolling density is adjusted into 0.2～0.3g/cm 3Next; Hair nylon (A-1) by will loosely being wound on the bobbin is put into overflow dyeing machine (day slope making institute (day slope is made institute) manufactured; Trade name " LLCD-50/90 ") in,, dewatered 15 minutes through about 90 ℃ * about 1 hour hot wash; Carry out 70 ℃ * 200 minutes drying, make flexible return rate be reduced to 7% back and use.
(A-3) polyester system (50d-36f raw silk, flexible return rate 1.5%) (generation joins (KB セ-レ Application) manufactured)
(A-4) hair nylon (70d-24f, flexible return rate 10.0%)
(A-1) loosely is wound on the bobbin with hair nylon, and rolling density is adjusted into 0.2～0.3g/cm 3Next; Hair nylon (A-1) by will loosely being wound on the bobbin is put into overflow dyeing machine (day slope making institute (day slope is made institute) manufactured; Trade name " LLCD-50/90 ") in,, dewatered 15 minutes through about 75 ℃ * about 1 hour hot wash; Carry out 70 ℃ * 200 minutes drying, make flexible return rate be reduced to 10% back and use.
(A-5) hair nylon (70d-24f, flexible return rate 5%)
(A-1) loosely is wound on the bobbin with hair nylon, and rolling density is adjusted into 0.2～0.3g/cm 3Next; Hair nylon (A-1) by will loosely being wound on the bobbin is put into overflow dyeing machine (day slope making institute (day slope is made institute) manufactured; Trade name " LLCD-50/90 ") in,, dewatered 15 minutes through about 100 ℃ * about 1 hour hot wash; Carry out 70 ℃ * 200 minutes drying, make flexible return rate be reduced to 5% back and use.
(A-6) simulate wool polyester capillaries (75d-36f, flexible return rate 1.2%)
Simulate wool polyester capillaries (300d-144f, flexible return rate 20%) loosely is wound on the bobbin, rolling density is adjusted into 0.2～0.3g/cm 3Next; Said hair nylon by will loosely being wound on the bobbin is put into overflow dyeing machine (day slope making institute (day slope is made institute) manufactured; Trade name " LLCD-50/90 ") in,, dewatered 15 minutes through about 95 ℃ * about 1 hour hot wash; Carry out 70 ℃ * 200 minutes drying, make flexible return rate be reduced to 1.2% back and use.
· (A-7) high strength polyethylene (100d-36f, telescopic recovery rate of 2%) (Toyobo (Toyobo) manufactured)
(A-8) aramid fibre (200d raw silk, flexible return rate 2.5%)
(B) conducting fibre
(B-1) Tongran color fibre silk (50d-30f, flexible return rate 3.0%) (Japanese silkworm hair (Japanese silkworm hair) manufactured, trade name " サ Application ダ-ロ Application ").
(B-2) carbon fiber wire (20d-3f, flexible return rate 2.9%) (generation joins (KB セ-レ Application) manufactured, trade name " 9R1 ").
(B-3) stainless steel fibre (32.7d, flexible return rate 1.2%) (Japanese smart line (Japanese smart line) manufactured, trade name " Na ス ロ Application ").
· (B-4) Copper dyed fibers (75d-18f, telescopic recovery rate of 3.0%) (Showa Gloves (Shin Yong - Waku bag ro - sleeve) Ltd., trade name "copper sulfide compound Fiber (copper sulfide composite fiber)").
(B-5) Tongran color fibre silk (40d-13f, flexible return rate 2.5%) (Japanese silkworm hair (Japanese silkworm hair) manufactured, trade name " サ Application ダ-ロ Application ").
(B-6) Tongran color fibre silk (40d-13f, flexible return rate 3.0%) (Japanese silkworm hair (Japanese silkworm hair) manufactured, trade name " サ Application ダ-ロ Application ").
(embodiment 1)
With 4 (A-2) is core, has obtained composite filament with 1 (B-1) with 300T/M coiling looping.Carried out looping (and the back is described and sth. made by twisting) with hammer two-wire looping machine (カ キ ノ キ manufactured, trade name " KC5D108 ").With resulting composite filament be used for gloves integral body (from the finger tip to the end) knitting gloves.The knitting making of gloves is to carry out with 13G knitting machine (the smart machine manufactured in island, trade name " New SFG ").
(embodiment 2)
Be used in the composite filament that obtains among the embodiment 1 with (A-1), with composite filament: (A-1)=ratio of 1: 2 row is knitting gloves.
(embodiment 3)
Be used in the composite filament that obtains among the embodiment 1 with (A-1), with composite filament: (A-1)=ratio of 1: 10 row is knitting gloves.
(embodiment 4)
With 1 (A-2) is core, and 1 (B-1) obtained composite filament with core and interpolation silk with 300T/M coiling looping with 2 (A-2) for adding silk.The whole flexible return rate of long filament in the resulting composite filament is 7.1%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 5)
With 4 (A-2) is core, and 1 (B-1) obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 7.3%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 6)
With 2 (A-2) is core, and 1 (B-2) obtained composite filament with core and interpolation silk with 300T/M coiling looping with 2 (A-2) for adding silk.The whole flexible return rate of long filament in the resulting composite filament is 7.3%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 7)
With 3 (A-2) is core, with 300T/M coiling looping in advance with 1 (B-1) and 1 (A-3) with 200T/M and twist with the fingers and obtain and twisted filament, obtained composite filament.The whole flexible return rate of long filament in the resulting composite filament is 6.3%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 8)
Replace (B-1) and used 1 (B-2), in addition, use with embodiment 7 same methods and obtained composite filament.The whole flexible return rate of long filament in the resulting composite filament is 6.7%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 9)
With 1 (A-2) is core, with in advance with 1 (B-1) and 1 (A-3) with 200T/M and twist with the fingers and obtain and twisted filament (flexible return rate 2.9%) serve as to add silk, with 2 (A-1) core and interpolation thread have been obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 5.2%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 10)
Replace (B-1) and used 1 (B-2), in addition, use with embodiment 9 same methods and obtained composite filament.The whole flexible return rate of long filament in the resulting composite filament is 5.7%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 11)
Obtain so that 3 (B-1) are also twisted with the fingers with 200T/M and twisted filament is a core, and 2 (A-2) have been obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 5.5%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 12)
With 1 (A-2) is core, serves as to add silk with the silk thread that in advance 2 (B-1) has been carried out with 200T/M and twist with the fingers, and with 2 (A-2) core and interpolation silk has been obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 6.2%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 13)
2 (B-1) have been obtained composite filament with also twisted filament and 2 (A-2) that 300T/M and sth. made by twisting obtain with further also sth. made by twisting of 300T/M.The whole flexible return rate of long filament in the resulting composite filament is 5.9%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 14)
To be heart yearn with the also twisted filament that 300T/M and sth. made by twisting obtain, obtained composite filament with the 300T/M looping with 1 (A-2) with 1 (B-1) and 1 (A-2).The whole flexible return rate of long filament in the resulting composite filament is 6.9%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 15)
The gloves that will in embodiment 1, obtain are coated on the metal impregnation mold; Only palm impregnated in and make polyurethane (DIC manufactured; Trade name " Network リ ス ボ Application MP-812 ") is dissolved in N; Solution in the N dimethyl formamide (solid portion concentration: quality 10%), to carry out the warm water displacement in 50 ℃ * 1 hour.After this, carry out drying with 100 ℃ * 30 minutes, obtained the gloves after palm portion coats with polyurethane resin.
(embodiment 16)
With 2 (A-4) is core, and 1 (B-1) obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 8.5%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 17)
With 2 (A-6) is core, and 1 (B-1) obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 2.2%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 18)
With 2 (A-7) is core, and 1 (B-1) obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 2.7%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 19)
With 1 (A-8) is core, has obtained composite filament with (B-1) with the 300T/M looping of reeling.The whole flexible return rate of long filament in the resulting composite filament is 3.2%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 20)
With 1 (B-3) and 2 (A-6) is core, has obtained composite filament with (B-1) with the 300T/M looping of reeling.The whole flexible return rate of long filament in the resulting composite filament is 2.2%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 21)
With 4 (A-5) is core, and 1 (B-4) obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 5.0%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 22)
With 4 (A-5) is core, and 1 (B-5) obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 5.2%.Resulting composite filament is used for the whole knitting gloves of gloves.
(embodiment 23)
With 1 hair nylon 30d, utilize circular knitter (vertical manufactured, the trade name " MA100 " compiled in eight fields) to obtain warp-knitting cloth (cloth and silk).In the warp knitted fabric as a whole, used in Example 1 to obtain composite yarn, with a single needle lockstitch electronic serrated lock seam automatic cutting machine (a needle of the sewing Kei electronic plover seam Kei automatic Shito cut ri sewing) (brother ( Getting sleeve ザ -) Ltd., trade name "LZ2-B856E-301"), to a sewing 1cm intervals.After this, be cut into glove form, make.
(comparative example 1)
With 3 (A-1) is core, and 1 (B-1) obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 20.5%.Resulting composite filament is used for the whole knitting gloves of gloves.
(comparative example 2)
With 4 (A-1) is core, replaces (B-1) and has used (B-2), in addition, uses with comparative example 1 same method and has obtained composite filament.The whole flexible return rate of long filament in the resulting composite filament is 23.2%.Resulting composite filament is used for the whole knitting gloves of gloves.
(comparative example 3)
With 1 (A-1) is core, and 1 (B-1) obtained composite filament with 2 (A-2) with 300T/M coiling looping with core and interpolation silk for adding silk.The whole flexible return rate of long filament in the resulting composite filament is 11.7%.Resulting composite filament is used for the whole knitting gloves of gloves.
(comparative example 4)
Replace (B-1) and used 1 serve as a composite filament that adds thread with (B-2), in addition, use with the same method of comparative example 3 knitting gloves.The whole flexible return rate of long filament in the resulting composite filament is 12.6%.
(comparative example 5)
With 2 (A-1) is core, reels with 300T/M with 1 (B-1), uses 1 (A-1) oppositely to reel with 300T/M above that, further uses 1 (A-1) oppositely to reel with 300T/M above that, has obtained the composite filament that conducting fibre stashes.The whole flexible return rate of long filament in the resulting composite filament is 21.7%.Resulting composite filament is used for the whole knitting gloves of gloves.
(comparative example 6)
Replace (B-1) and used (B-2), in addition, use with comparative example 5 same methods and obtained composite filament.The whole flexible return rate of long filament in the resulting composite filament is 23.4%.Resulting composite filament is used for the whole knitting gloves of gloves.
(comparative example 7)
With 4 (A-1) and twist with the fingers the silk obtain, be used for the whole knitting gloves of gloves.The whole flexible return rate of long filament in the resulting composite filament is 24.5%.
(comparative example 8)
Replace (A-2) and used (A-1), in addition, use with embodiment 13 same methods and obtained composite filament.The whole flexible return rate of long filament in the resulting composite filament is 15.8%.Resulting composite filament is used for the whole knitting gloves of gloves.
(comparative example 9)
Replace (A-2) and used (A-1), in addition, use with embodiment 14 same methods and obtained composite filament.The whole flexible return rate of long filament in the resulting composite filament is 13.1%.Resulting composite filament is used for the whole knitting gloves of gloves.
(comparative example 10,11)
The gloves that in having used comparative example 1,2, obtained, use with embodiment 15 same methods and obtained the gloves after palm portion coats with mylar.
(comparative example 12)
With 3 (B-6) is core, and 2 (A-1) have obtained composite filament with 300T/M coiling looping.The whole flexible return rate of long filament in the resulting composite filament is 14.8%.Resulting composite filament is used for the whole knitting gloves of gloves.
(comparative example 13)
With 1 hair nylon 30d, utilize circular knitter (vertical manufactured, the trade name " MA100 " compiled in eight fields) to obtain warp-knitting cloth (cloth and silk).At this warp-knitting cloth on the whole; Be used in the composite filament that obtains in the comparative example 1; With single needle flush joint electronic sawtooth eyelet automatic tangent sewing machine (brother's (Block ラ ザ-) manufactured, trade name " LZ2-B856E-301 "), sew with the interval of 1cm.After this, be cut into glove form, prepare to make, but the line that splits taken place composite filament, making does not have and can go on.
Physical property to the gloves that in embodiment and comparative example, obtain is tested.The evaluation result of embodiment 1～12 is shown in table 1, and the evaluation result of embodiment 13～23 is shown in table 2, and the evaluation result of comparative example 1～13 is shown in table 3.
(table 1)
Figure BDA0000124636000000211
(table 2)
Figure BDA0000124636000000221
(table 3)
Figure BDA0000124636000000222
Can know from the result of embodiment 1～23, in order to reduce the amount of coming off of conducting fibre, must make the coiling conducting fibre heart yearn, add silk or carry out and twists with the fingers thread flexible return rate be 0～10%.Making flexible return rate is that 0%～10% effect is compared with comparative example and can be understood.
In addition, can know that conducting fibre has the few more tendency of the dawn number amount of coming off of 1 rhizoid more from embodiment 21,22.In addition, can know from the contrast of embodiment 9 and embodiment 10, with the amount of coming off of carbon fiber than lacking with the amount of coming off of Tongran color fibre.
Have again, can know following situation from the result of embodiment 7～14.In other words, in the adhesive tape forcible separation method, learn: carbon fiber, Tongran color fibre the two, can through with conducting fibre each other and twist with the fingers, perhaps with polyester capillaries etc. and twist with the fingers and become and be difficult to more come off.Learn in addition, use the occasion of conducting fibre,, then can reduce the amount of coming off of conducting fibre if conducting fibre is used each other and after twisting with the fingers at core.Learn in addition; With conducting fibre and other fibers; Be that raw silk or flexible return rate are the occasion that polyester, reinforcement polyethylene, aromatic polyamides, nylon, acrylic acid system fiber below 10% have carried out and twisted with the fingers, also can reduce the amount of coming off of conducting fibre.
Can know from comparative example 5, in the gloves that used conducting fibre,, also not change on the amount of coming off even conducting fibre is hidden.
Work of the present invention is to satisfy the gloves that static countermeasure and low dusting property requirement are arranged with gloves, is of value to semiconductor manufacturing process, covers with paint, lacquer, colour wash, etc. the use in operation, the dustless office operation etc.

Claims (16)

1. gloves are used in a job, it is characterized in that, a gloves integral body or a part form so that the composite filament that contains long filament and conducting fibre is knitting, and the whole flexible return rate of long filament that is included in the said composite filament is 0-10%.
2. gloves are used in work as claimed in claim 1, it is characterized in that, long filament is a heart yearn, and conducting fibre is the looping silk on every side that is wound onto said heart yearn.
3. gloves are used in work as claimed in claim 1, it is characterized in that, long filament is a heart yearn, and conducting fibre is the interpolation silk that makes an addition to said heart yearn, and these heart yearns and interpolation silk are by looping silk looping.
4. gloves are used in work as claimed in claim 1, it is characterized in that, conducting fibre is a heart yearn, and long filament is the looping silk on every side that is wound onto said heart yearn.
5. gloves are used in work as claimed in claim 1, it is characterized in that, composite filament is with long filament and conducting fibre and twist with the fingers and form.
6. use gloves like any described work in the claim 1 to 5, it is characterized in that, conducting fibre is and the form of twisted filament.
7. use gloves like any described work in the claim 1 to 6, it is characterized in that, the integral body on finger tip part, palm portion or surface is synthesized rubber or resin-coated.
8. work with the manufacturing approach of gloves for one kind, it is characterized in that having:
Make the operation of the flexible return rate reduction of the processing silk that curls;
Obtain to contain in the part at least curling processing silk, whole flexible return rate after flexible return rate is reduced and be the operation of 0～10% long filament;
Obtain the operation of composite filament with said long filament and conducting fibre;
Said composite filament is knitted into the operation of gloves.
9. a composite filament contains long filament and conducting fibre, it is characterized in that, the whole flexible return rate of long filament that is included in the said composite filament is 0-10%.
10. composite filament as claimed in claim 9 is characterized in that, long filament is a heart yearn, and conducting fibre is the looping silk on every side that is wound onto said heart yearn.
11. composite filament as claimed in claim 9 is characterized in that, long filament is a heart yearn, and conducting fibre is the interpolation silk that is added in said heart yearn, and these heart yearns and interpolation silk are by looping silk looping.
12. composite filament as claimed in claim 9 is characterized in that, conducting fibre is a heart yearn, and long filament is the looping silk on every side that is wound onto said heart yearn.
13. composite filament as claimed in claim 9 is characterized in that, this composite filament is with long filament and conducting fibre and twist with the fingers and form.
14. any described composite filament as in the claim 9 to 13 is characterized in that, conducting fibre is and the form of twisted filament.
15. the manufacturing approach of a composite filament is characterized in that, has:
Make the operation of the flexible return rate reduction of the processing silk that curls;
Obtain to contain in the part at least curling processing silk, whole flexible return rate after flexible return rate is reduced and be the operation of 0～10% long filament;
Obtain the operation of composite filament with said long filament and conducting fibre.
16. a cloth and silk is characterized in that, the whole or part of said cloth and silk forms with any described composite filament in the claim 9 to 15.
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CN105113074A (en) * 2015-09-10 2015-12-02 南通强生安全防护科技有限公司 Environment-friendly yarn, and manufacturing method and use thereof
CN105305293A (en) * 2015-11-19 2016-02-03 国家电网公司 Antistatic protection plate for electric power overhauling
CN105342040A (en) * 2015-11-19 2016-02-24 国家电网公司 Antistatic glove for power equipment maintenance
CN106124568A (en) * 2016-08-29 2016-11-16 广州市博顿运动装备有限公司 A kind of method testing glove touch-control performance
CN107268131A (en) * 2017-06-07 2017-10-20 丹阳市斯鲍特体育用品有限公司 A kind of fencing metallic plastron fabric is twisted thread with conductive silver fiber

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6016399B2 (en) * 2012-03-23 2016-10-26 東レ・デュポン株式会社 Gloves and manufacturing method thereof
EP3023018B1 (en) * 2013-07-19 2017-09-13 Showa Glove Co. Glove
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JP7419410B2 (en) * 2021-01-15 2024-01-22 ユニチカトレーディング株式会社 conductive composite yarn

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03829A (en) * 1989-05-30 1991-01-07 Unitika Ltd Dyed yarn of synthetic fiber and production thereof
JPH06136603A (en) * 1992-10-22 1994-05-17 Keitaro Yamanaka Production of glove having antibacterial and deodorizing functions
CN1190444A (en) * 1995-06-07 1998-08-12 赫希斯特人造丝公司 Filled thermoplastic cut-resistant fiber
JP2006063456A (en) * 2004-08-24 2006-03-09 Morito Co Ltd Electrostatic charge eliminating glove
CN1280940C (en) * 2004-08-12 2006-10-18 河北工业大学 Lithium/polyparrole secondary button cell and its preparation method
JP2007039839A (en) * 2005-08-03 2007-02-15 Du Pont Toray Co Ltd Composite yarn and woven or knitted fabric using the same
CN2909876Y (en) * 2006-01-25 2007-06-13 黄建华 Conducting gloves contg. silver fiber
CN201073012Y (en) * 2007-08-31 2008-06-18 中国石油天然气股份有限公司 Gloves capable of releasing electrostatic
JP2009046785A (en) * 2007-08-22 2009-03-05 Toray Ind Inc Crimped conductive yarn
JP2009102779A (en) * 2007-10-25 2009-05-14 Fellenca Ltd Glove

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57167425A (en) * 1981-04-03 1982-10-15 Kanebo Ltd Production of bulky yarn with silk like feeling
JPH0421772Y2 (en) * 1986-04-18 1992-05-19
JPS6324221U (en) * 1986-07-29 1988-02-17
JPH0342096A (en) 1989-04-21 1991-02-22 Shigenobu Kasamatsu Method for removing phosphate ion and sulfate ion in water
JPH0654720U (en) 1993-01-11 1994-07-26 東洋紡績株式会社 Conductive gloves
JP3000829B2 (en) * 1993-08-11 2000-01-17 サンケン電気株式会社 DC-DC converter parallel connection device
JPH108340A (en) * 1996-06-22 1998-01-13 Shimono Shikimono Kk Antistatic pile yarn
KR100497179B1 (en) * 2002-12-31 2005-06-23 주식회사 메스토 Core yarn containing silver yarn and fabric woven thereby and towel manufactured thereby
US7135227B2 (en) * 2003-04-25 2006-11-14 Textronics, Inc. Electrically conductive elastic composite yarn, methods for making the same, and articles incorporating the same
JP4923174B2 (en) * 2006-07-05 2012-04-25 ユニチカトレーディング株式会社 Conductive composite yarn and conductive fabric

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03829A (en) * 1989-05-30 1991-01-07 Unitika Ltd Dyed yarn of synthetic fiber and production thereof
JPH06136603A (en) * 1992-10-22 1994-05-17 Keitaro Yamanaka Production of glove having antibacterial and deodorizing functions
CN1190444A (en) * 1995-06-07 1998-08-12 赫希斯特人造丝公司 Filled thermoplastic cut-resistant fiber
CN1280940C (en) * 2004-08-12 2006-10-18 河北工业大学 Lithium/polyparrole secondary button cell and its preparation method
JP2006063456A (en) * 2004-08-24 2006-03-09 Morito Co Ltd Electrostatic charge eliminating glove
JP2007039839A (en) * 2005-08-03 2007-02-15 Du Pont Toray Co Ltd Composite yarn and woven or knitted fabric using the same
CN2909876Y (en) * 2006-01-25 2007-06-13 黄建华 Conducting gloves contg. silver fiber
JP2009046785A (en) * 2007-08-22 2009-03-05 Toray Ind Inc Crimped conductive yarn
CN201073012Y (en) * 2007-08-31 2008-06-18 中国石油天然气股份有限公司 Gloves capable of releasing electrostatic
JP2009102779A (en) * 2007-10-25 2009-05-14 Fellenca Ltd Glove

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105113074A (en) * 2015-09-10 2015-12-02 南通强生安全防护科技有限公司 Environment-friendly yarn, and manufacturing method and use thereof
CN105113076A (en) * 2015-09-17 2015-12-02 南通强生安全防护科技有限公司 Preparation method of anti-static yarn and gloves
CN105305293A (en) * 2015-11-19 2016-02-03 国家电网公司 Antistatic protection plate for electric power overhauling
CN105342040A (en) * 2015-11-19 2016-02-24 国家电网公司 Antistatic glove for power equipment maintenance
CN105342040B (en) * 2015-11-19 2016-11-30 国家电网公司 A kind of antistatic gloves for electric power apparatus examination
CN106124568A (en) * 2016-08-29 2016-11-16 广州市博顿运动装备有限公司 A kind of method testing glove touch-control performance
CN107268131A (en) * 2017-06-07 2017-10-20 丹阳市斯鲍特体育用品有限公司 A kind of fencing metallic plastron fabric is twisted thread with conductive silver fiber

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