CN102444021A - Intelligent waterproof and moisture permeable fabric - Google Patents
Intelligent waterproof and moisture permeable fabric Download PDFInfo
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- CN102444021A CN102444021A CN2011102425197A CN201110242519A CN102444021A CN 102444021 A CN102444021 A CN 102444021A CN 2011102425197 A CN2011102425197 A CN 2011102425197A CN 201110242519 A CN201110242519 A CN 201110242519A CN 102444021 A CN102444021 A CN 102444021A
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Abstract
The invention provides an intelligent waterproof and moisture permeable fabric and a preparation method thereof and relates to a preparation method of a waterproof and moisture permeable fabric. The preparation method comprises the following steps: carrying out surface modification on fiber by utilizing a plasma technique capable of realizing low-frequency normal-voltage corona discharging so as to generate plasma on the surface of the fiber; introducing hydrogel into surface of the fabric by chemical grafting modification; and adding a pore-forming agent so as to form a large amount of micropore structures in the gel. By using the preparation method, the stimulus response speed of the gel material on environment is obviously improved, the waterproof and moisture permeable properties of the fabric are enhanced, and the hand feeling and comfort level of the fabric are improved.
Description
Technical field
The present invention relates to a kind of waterproof moisture permeating fabric, especially aquogel is incorporated in the fabric, obtain a kind of intelligent waterproof moisture permeating fabric and preparation method thereof.
Background technology
Along with the continuous change of human habitat, people improve constantly the demand of fabric multifunctional.Waterproof moisture permeating fabric is one of high value added product of developing successively of people in recent years, also is a focus of current research.Waterproof moisture permeating fabric is meant that fabric can not seen through or soaks into by water under certain hydraulic pressure; But the sweat steam that human body distributes but can or be delivered to the external world through the fabric diffusion; Rather than between body surface and fabric, gather condensation and make the people feel glutinous wet and sultry, thereby realized the unification of textile water-proof performance and water vapour permeability.Thereby the clothes made from waterproof moisture permeating fabric can not only satisfy the needs of wearing in the bad weathers such as cold, sleet, strong wind; And under big labour intensity, also can perspire pass through wet; Comfortable and easy to wear, can also in chemical, poisonous and infection environment, play isolated, the effect of filtering and wet thoroughly.Therefore, developed countries such as the U.S., West Europe, Japan all classify waterproof moisture permeating fabric as one of high-tech product geared to the 21st century.
For a long time, the product of waterproof moisture permeating fabric has following several kinds: 1. polyurethane coating (PU) waterproof moisture permeating fabric has unique pliability, ABRASION RESISTANCE, low temperature properties, wettability, cohesiveness, glossiness and high cohesion and curing rate etc.; The PU lining also has good apparel construction, the designability of annex except having good block-water performance, to guarantee dress fast and the sealing in water.Yet present this PU fabric still is in the research and development stage at home and abroad.2. multiple product adopts neoprene coated fabric or micropore PTFE film as the anti-layer material that soaks; 3. mostly RIPSTOP, institutional framework are that the Oxford spins, and make the ABRASION RESISTANCE that can improve the lining surface like this, protect anti-dip-coating layer or the anti-film that soaks.
In recent years, many researchers have carried out deep research to waterproof moisture permeating fabric.Balance [balance; The development and the performance study of temperature sense type loomage water proof and moisture permeable dressing agent. Tianjin University of Technology's academic dissertation; 2005] through making the phase crystallization of flexible polyurethane section and to wherein introducing method such as crosslinked in the chemistry; Prepared critical transition temperature and be about 20～26 ℃ high poisture-penetrability shape memory polyurethane material, a little higher than human body of this temperature range is 15.6～21.0 ℃ of comfortable environment temperature the most.[Xu Xufan such as Xu Xufan; The research [J] of polyurethane PU coated fabric waterproofing and moisture-penetration performances. printing and dyeing assistant, 2003,20 (6): 23-25] PU resin N; Dinethylformamide (DMF) solution coat is on base cloth; Put it into then with DMF affinity interaction to be arranged and do not have in the water-bath of affinity interaction and flood, prepared the porous matter skin membrane of continuity pore, improved the waterproofing and moisture-penetration performances of PU film with polyurethane resin.[Yun J.K such as Yun J.K; Preparation and properties of water borne polyurethaneurea/sodium alginate blends for high water vapor permeable coating materials [J] .Journal of Applied Polymer Science; 2007; 105:1168-1176] adopt among the synthetic water-based PU of IPDI (IPDI), PTMG (PTMG), dihydromethyl propionic acid (DMPA) and add mosanom; With its coating film forming on the nylon cloth fabric, and then water significantly increases the vapor transfer rate of coating the mosanom stripping.[Hua Mingyang such as Hua Mingyang; The preparation method of aqueous polyurethane grafted siloxane wear-resistant soft finishing agent; Chinese patent; CN101161918A] in the raw material of synthetic waterproof moisture-penetrating urethane, added the hydroxyl polysiloxanes, improved the flexibility and the ABRASION RESISTANCE of waterproof moisture-penetrating urethane coating to a great extent.Sun Jun etc. [Sun Jun, a kind of waterproof moisture permeating fabric, Chinese patent, CN2526168Y] utilize the tetrafluoroethylene microporous barrier of better water resistance to be covered by the fiber fabric layer the inside, have obtained the good fabric of resistance to water and water proofing property.[Hao Xinmin such as Hao Xinmin; A kind of preparation method of polytetrafluoroethylwaterproof waterproof moisture permeating fabric; Chinese patent; CN101135115A] in polyurethane coating solution, add a small amount of natural plants powder, dry after-contraction has increased the porosity of polyurethane film, thereby has increased the water vapour permeability of the thin polyurethane rete of fabric face.
To sum up, more than mostly research is polyurethane coating (PU) waterproof moisture permeating fabric.
Intellectual material is meant that material can perception environmental change, realization instruction and action execution through self-judgement.Aquogel is the swelling body of the cross-linked structure that forms with chemical bond or physical force between a kind of macromolecular chain, and the compound system by water and macromolecule network are formed does not promptly dissolve yet not fusion, and small-molecule substance can permeate or spread therein.Discover that some gel can make different responses and show distinctive intelligent multiple signal such as pH, temperature, magnetic field, electric field, light, chemical substance.Wherein, researcher's synthetic water gel monomer is the most common with acrylamide and derivative, acrylic acid and derivative thereof etc.In recent years, people have synthesized many kinds of novel high polymer gels, and this gellike is released at cellular incubation, medicine and had a good application prospect aspect control, the fabric-modifying.
Plasma is called the electricity slurry again, is at first proposed in 1879 by Britain physicist William Crookes, and he has studied the character of ionized gas in the vacuum tube, points out the existence of material the 4th attitude.The ionized gas shape material that the positron-electron that is produced after by ionization by the atom after depriving and atom by portions of electronics is formed.The plasma that generates through gas discharge can roughly be divided into two types.One type is high-temperature plasma, and its temperature is up to more than ten thousand degrees centigrade, and gas particle all is Ionized.Another kind of is low temperature plasma, relatively the former, it is suitable for carrying out the preparation and the processing of high purity material through electrodeless discharge, process efficiency is high, for process choice provides more spaces.
Summary of the invention
The object of the invention aims to provide a kind of intelligent waterproof moisture permeating fabric and preparation method thereof.
Using plasma treatment technology of the present invention utilizes air as the discharge carrier, through low frequency normal pressure corona discharge, on fiber surface, produces free radical; Initiation grafting reaction again is incorporated into aquogel in the fabric, makes fabric face form the intelligent gel layer; Have the ability of " dry state-hygrometric state " environmental change being made response, that is: in the environment of dry state, gel molecular is in contraction state; Hole in the fabric is open, and moisture-penetrable ventilated property is good; In a single day fabric immerses in the water, and gel layer is instant rapidly to expand, and with the pore closure at different levels in the fabric, stops water to permeate to fabric, the anti-function of soaking of performance.
The preparation method of intelligent waterproof moisture permeating fabric is following:
1, takes by weighing 1 part of fabric, fiber is carried out surface modification with plasma technique.
2,0.0063～0.252 part of nitric acid and 0.0055～0.106 part of ammonium ceric nitrate are joined in the redistilled water; Then the surface is contained in the fabric adding ceric ammonium nitrate solution of plasma; Take out after soaking 0.5～2h; Then at the unreacted reactant of removing under the effect of roll on the fabric; Again fabric is put into the mixed solution of 5.6～113 parts of N-NIPAs (NIPAM), 18.5～115 parts of methacrylic acid diethyl ethyl esters (DEAEMA), 5～20 parts of pore-foaming agents, 0.315～0.63 part of nitric acid, 8.16～40.8 parts of ethanol, added 32～100 parts of mass fractions again in its mixed liquor and be 5%～10% cross-linking agent aqueous solution, fill N fast
215～60min, reaction 8～24h.
3, after reaction finished, fabric obtained intelligent waterproof moisture permeating fabric through cleaning removal of impurities, drying.
Fabric of the present invention can be natural fabric or synthetic fiber.Natural fabric such as natural plant fibre (comprising cotton, fiber crops, fibre and soya etc.) silk, hair etc.Synthetic fiber such as terylene, nylon, acrylic fibers, polyvinyl, polypropylene fibre, polyvinyl chloride fibre, spandex etc.
The spendable working gas of apparatus for low-temperature plasma treatment of the present invention includes but not limited to following gas: O
2, H
2, N
2, NH
3, C
2H
4, CH
3, CF
4, C
2F
6Deng.In the research of low temperature plasma, study the more two kinds of discharge types that mainly contain: high-frequency discharge and corona discharge to material surface modifying.High-frequency discharge plasma treatment technology is the common technology in the textile industry.High-frequency discharge need be carried out under the condition of high vacuum degree condition.When high-frequency discharge is carried out graft modification to material, adopt inert gas such as He, Ar etc. as the discharge carrier usually, discharge back matrix contacts with monomer solution.
Preferably, the present invention adopts the corona discharge low temp plasma technology.Low frequency corona discharge corona discharge in air atmosphere, can carry out under the normal pressure usually.Electronics has that sufficiently high energy makes that reactant excites, disassociation and ionization, and whole reaction system remains on the lower temperature levels on the other hand, the destruction of having avoided high temperature possibly cause matrix.Low temperature plasma is easy to obtain simultaneously, and cost is lower.The matrix top layer can form free radical and trapped radical under the effect of various particles, after oxygen contacts, form peroxy-radical; In addition, also can follow reactions such as crosslinked, degraded.These effects make matrix surface that marked change can take place.Through can make things convenient for, intuitively understand the variation of surface polarity in the matrix surface measurement of contact angle to water.After the modification, the polar group of matrix surface is many more, and surface energy is high more, and water droplet is just sprawled more easily, and contact angle is more little.
More preferably; Plasma surface of the present invention is modified as: after destarch, kiering, vacuum drying treatment; Be placed on power then and be 5KW, frequency and be on the apparatus for low-temperature plasma treatment of 2.45GHz and handle 10～40s, obtain the fabric that plasma is contained on the surface.
Above-mentioned said crosslinking agent is polyethylene glycol (200) double methacrylate (PEGDA), polyethylene glycol (400) double methacrylate (PEGDA) or N, the N-methylene-bisacrylamide.
Said pore-foaming agent is (molecular weight is 400 or 600) polyethylene glycol or sodium chloride particle (average grain diameter is at 800～2500 orders).
Reacted fabric is put into distilled water soak 12～24h, change distilled water therebetween three times; Boil 6～12h, remove the foreign material on the fabric; Then fabric is immersed in the hydrochloric acid solution of 0.1mol/L behind 4～10h, distilled water rinsing 3～8h is used in its taking-up again, behind vacuumize 6～12h, obtain the intelligent waterproof moisture permeating fabric after the aquogel modification.
The effect of ammonium ceric nitrate is as a kind of initator, on fabric face, causes methacrylic acid diethyl ethyl ester and NIPA glycerol polymerization initiation reaction.
The prepared intelligent waterproof moisture permeating fabric of the present invention has the following advantages:
(1) utilize the plasma treatment technology of low frequency normal pressure corona discharge that fiber is carried out surface modification; Produce plasma in its surface; Make fiber surface produce more long-life free radical; Increase its surface energy, help aquogel, also reduced the technology cost simultaneously in its surperficial grafting.
(2) select NIPA and methacrylic acid diethyl ester monomer to be prepared into aquogel, formation has higher swelling ability and to temperature, the pH value macromolecule hydrogel than highly-responsive, has improved the feel and the comfort level of fabric; Add pore-foaming agent in the gel forming process simultaneously,, significantly improve the response speed of gel rubber material, the waterproofing and moisture-penetration performances of reinforced fiber environmental stimulus at a large amount of microcellular structures of the inner formation of gel.
(3) NIPA and methacrylic acid diethyl ester aquogel are the weak polyelectrolyte aquogel, have ionogenic functional group on the strand.Under the condition that electrolyte exists, the swelling behavior of the interaction partners gel between the electric charge has very big influence, and the stability of the state of water and hydration hydrogen bond can be affected in the aquogel in addition.Sodium chloride in the solution or polyglycols particle can make in the modified fabric grafting strand become to curl, and the chain interphase interaction strengthens, thereby causes its interaction with water to weaken, and the gel swelling degree descends, after the modified fabric hydrolysis, and the permeability rate raising.
Description of drawings
Fig. 1 is the Waterproof Breathable principle of intelligent waterproof moisture permeating fabric: unmodified fabric unit; Through after the plasma surface modification; Fabric face covers the closely knit plasma of one deck; Adopt graft-modification method again, add the monomer initiated polymerization, form the modified fabric unit of progress in Intelligent Hydrogel with responsive to temperature performance.When fabric is in the moist environment, gel layer is instant rapidly to expand, and with the pore closure at different levels in the fabric, stops water to permeate to fabric, realizes the anti-function of soaking; When fabric is in the environment of dry state, gel molecular is in contraction state, and the hole in the fabric is open, and moisture infiltrates from hole, realizes breathable moisture permeability.
The specific embodiment
Through embodiment the present invention is further specified below.
Embodiment 1:
Step 1, take by weighing 1g fabric (nylon fiber); After destarch, kiering, vacuum drying treatment; Being placed on power then is that 5KW, frequency are on the apparatus for low-temperature plasma treatment of 2.45GHz, through low frequency Corona discharge Treatment 10s, obtains the fabric that plasma is contained on the surface.
Step 2,6.3mg nitric acid and 5.48mg ammonium ceric nitrate are joined in the redistilled water (100mL); Then the surface is contained in the fabric adding ceric ammonium nitrate solution of plasma; Take out after soaking 0.5h; Then at the unreacted reactant of removing under the effect of roll on the fabric; Again fabric is put into the mixed solution of 5.6gN-NIPA (NIPAM), 18.5g methacrylic acid diethyl ethyl ester (DEAEMA), 5g (molecular weight is 400) polyethylene glycol, 0.315g nitric acid, 8.16g ethanol, added the 32g mass fraction again in its mixed liquor and be 5% polyethylene glycol (200) double methacrylate (PEGDA) aqueous solution, fill N fast
215min, reaction 8h.
After step 3, reaction finish, reacted fabric is put into distilled water soak 12h, change distilled water therebetween three times; Boil 6h, remove the foreign material on the fabric; Then fabric is immersed in the hydrochloric acid solution of 0.1mol/L behind the 4h, distilled water rinsing 3h is used in its taking-up again, behind the vacuumize 6h, obtain the intelligent waterproof moisture permeating fabric after the aquogel modification.
Embodiment 2:
Step 1, take by weighing 1g fabric (cotton fabric), after destarch, kiering, vacuum drying treatment, be placed on power then and be 5KW, frequency and be on the apparatus for low-temperature plasma treatment of 2.45GHz and handle 20s, obtain the fabric that plasma is contained on the surface.
Step 2,0.0076g nitric acid and 0.0548g ammonium ceric nitrate are joined in the redistilled water (140mL); Then the surface is contained in the fabric adding ceric ammonium nitrate solution of plasma; Take out after soaking 50min; Then at the unreacted reactant of removing under the effect of roll on the fabric; Again fabric is put into the mixed solution of 28.4g N-NIPA (NIPAM), 36.7g methacrylic acid diethyl ethyl ester (DEAEMA), 14g (molecular weight is 600) polyethylene glycol, 0.41g nitric acid, 20.4g ethanol, added the 48g mass fraction again in its mixed liquor and be 6% polyethylene glycol (400) double methacrylate (PEGDA) aqueous solution, fill N fast
220min, reaction 10h.
After step 3, reaction finish, reacted fabric is put into distilled water soak 16h, change distilled water therebetween three times; Boil 8h, remove the foreign material on the fabric; Then fabric is immersed in the hydrochloric acid solution of 0.1mol/L behind the 5h, distilled water rinsing 4h is used in its taking-up again, behind the vacuumize 8h, obtain the intelligent waterproof moisture permeating fabric after the aquogel modification.
Embodiment 3:
Step 1, take by weighing 1g fabric (natural flax fibre), after destarch, kiering, vacuum drying treatment, be placed on power then and be 5KW, frequency and be on the apparatus for low-temperature plasma treatment of 2.45GHz and handle 28s, obtain the fabric that plasma is contained on the surface.
Step 2,0.164g nitric acid and 0.082g ammonium ceric nitrate are joined in the redistilled water (160mL); Then the surface is contained in the fabric adding ceric ammonium nitrate solution of plasma; Take out after soaking 1h; At the unreacted reactant of removing under the effect of roll on the fabric, fabric is put into the mixed solution of 63.4g N-NIPA (NIPAM), 74.5g methacrylic acid diethyl ethyl ester (DEAEMA), 16g sodium chloride particle, 0.428g nitric acid, 26.1g ethanol then, adding 78.5g mass fraction is 7% N in its mixed liquor more again; The N-methylene-bisacrylamide aqueous solution fills N fast
245min, reaction 16h.
After step 3, reaction finish, reacted fabric is put into distilled water soak 18h, change distilled water therebetween three times; Boil 9h, remove the foreign material on the fabric; Then fabric is immersed in the hydrochloric acid solution of 0.1mol/L behind the 8.5h, distilled water rinsing 5h is used in its taking-up again, behind the vacuumize 9h, obtain the intelligent waterproof moisture permeating fabric after the aquogel modification.
Embodiment 4:
Step 1, take by weighing 1g fabric (terylene), after destarch, kiering, vacuum drying treatment, be placed on power then and be 5KW, frequency and be on the apparatus for low-temperature plasma treatment of 2.45GHz and handle 35s, obtain the fabric that plasma is contained on the surface.
Step 2,38g nitric acid and 16g ammonium ceric nitrate are joined in the redistilled water (180mL); Then the surface is contained in the fabric adding ceric ammonium nitrate solution of plasma; Take out after soaking 1.5h; Then at the unreacted reactant of removing under the effect of roll on the fabric; Again fabric is put into the mixed solution of 88.6gN-NIPA (NIPAM), 96.5g methacrylic acid diethyl ethyl ester (DEAEMA), 18.6g (molecular weight 600) polyethylene glycol, 0.252g nitric acid, 36.7g ethanol, added the 65g mass fraction again in its mixed liquor and be 8% polyethylene glycol (400) double methacrylate (PEGDA) aqueous solution, fill N fast
245min, reaction 18h.
After step 3, reaction finish, reacted fabric is put into distilled water soak 20h, change distilled water therebetween three times; Boil 10h, remove the foreign material on the fabric; Then fabric is immersed in the hydrochloric acid solution of 0.1mol/L behind the 8h, distilled water rinsing 6h is used in its taking-up again, behind the vacuumize 10h, obtain the intelligent waterproof moisture permeating fabric after the aquogel modification.
Embodiment 5:
Step 1, take by weighing 1g fabric (polyvinyl), after destarch, kiering, vacuum drying treatment, be placed on power then and be 5KW, frequency and be on the apparatus for low-temperature plasma treatment of 2.45GHz and handle 40s, obtain the fabric that plasma is contained on the surface.
2,252mg nitric acid and 109.6mg ammonium ceric nitrate are joined in the redistilled water (200mL); Then the surface is contained in the fabric adding ceric ammonium nitrate solution of plasma; Take out after soaking 2h; At the unreacted reactant of removing under the effect of roll on the fabric, fabric is put into the mixed solution of 113gN-NIPA (NIPAM), 115g methacrylic acid diethyl ethyl ester (DEAEMA), 20g sodium chloride particle, 0.63g nitric acid, 40.8g ethanol then, adding 100g mass fraction is 10% N in its mixed liquor more again; The N-methylene-bisacrylamide aqueous solution aqueous solution fills N fast
260min, reaction 24h.
3, after reaction finishes, reacted fabric is put into distilled water soak 24h, change distilled water therebetween three times; Boil 12h, remove the foreign material on the fabric; Then fabric is immersed in the hydrochloric acid solution of 0.1mol/L behind the 10h, distilled water rinsing 8h is used in its taking-up again, behind the vacuumize 12h, obtain the intelligent waterproof moisture permeating fabric after the aquogel modification.
Table 1 is implemented the waterproofing and moisture-penetration performances test result of each sample
Annotate: the tension failure strength retention is meant the ratio of tensile break strength and the tensile break strength of the preceding fabric of modification behind the fabric-modifying.
Claims (7)
1. intelligent waterproof moisture permeating fabric and preparation method thereof is characterized in that concrete steps are following:
Step 1, take by weighing 1 part of fabric, fiber is carried out surface modification with plasma technique;
Step 2,0.0063～0.252 part of nitric acid and 0.0055～0.106 part of ammonium ceric nitrate are joined in the redistilled water (100～200 parts); Then the surface is contained in the fabric adding ceric ammonium nitrate solution of plasma; Take out after soaking 0.5～2h; Then at the unreacted reactant of removing under the effect of roll pressed on the fabric; Again fabric is put into the mixed solution of 5.6～113 parts of N-NIPAs, 18.5～115 parts of methacrylic acid diethyl ethyl esters, 5～20 parts of pore-foaming agents, 0.315～0.63 part of nitric acid, 8.16～40.8 parts of ethanol; Add 32～100 parts of mass fractions again in its mixed liquor and be 5%～10% cross-linking agent aqueous solution, fill N fast
215～60min, reaction 8～24h;
After step 3, reaction finished, fabric obtained intelligent waterproof moisture permeating fabric through cleaning removal of impurities, drying.
2. a kind of intelligent waterproof moisture permeating fabric as claimed in claim 1 and preparation method thereof, it is characterized in that: the described plasma technique of step (1) is the corona discharge plasma technology.
3. a kind of intelligent waterproof moisture permeating fabric as claimed in claim 1 and preparation method thereof; It is characterized in that: the described surface modification of step (1) is: fabric is through after destarch, kiering, the vacuum drying treatment; Be placed on power then and be 5KW, frequency and be on the apparatus for low-temperature plasma treatment of 2.45GHz and handle 10～40s, obtain the fabric that plasma is contained on the surface.
4. a kind of intelligent waterproof moisture permeating fabric as claimed in claim 1 and preparation method thereof, it is characterized in that: said crosslinking agent is polyethylene glycol double methacrylate or N, a kind of or its combination in the N-methylene-bisacrylamide.
5. a kind of intelligent waterproof moisture permeating fabric as claimed in claim 1 and preparation method thereof, it is characterized in that: said pore-foaming agent is a kind of or its combination in polyethylene glycol or the sodium chloride particle.
6. a kind of intelligent waterproof moisture permeating fabric as claimed in claim 4 and preparation method thereof, it is characterized in that: described pore-foaming agent average grain diameter is at 800～2500 orders.
7. a kind of intelligent waterproof moisture permeating fabric as claimed in claim 1 and preparation method thereof is characterized in that: being operating as of described step (3): reacted fabric is put into distilled water soak 12～24h, change distilled water therebetween three times; Boil 6～12h, remove the foreign material on the fabric; Then fabric is immersed in the hydrochloric acid solution of 0.1mol/L behind 4～10h, distilled water rinsing 3～8h is used in its taking-up again, behind vacuumize 6～12h, obtain the intelligent waterproof moisture permeating fabric after the aquogel modification.
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102877285A (en) * | 2012-10-25 | 2013-01-16 | 愉悦家纺有限公司 | Desizing method of fabric |
| CN103271471A (en) * | 2013-06-13 | 2013-09-04 | 太仓协大申泰羊毛衫有限公司 | Antistatic, hygroscopic and degradable woolen sweater |
| CN103696088A (en) * | 2013-12-19 | 2014-04-02 | 吴江明敏制衣有限公司松陵分公司 | Water-proof and moisture-proof fabric |
| CN104179000A (en) * | 2014-09-12 | 2014-12-03 | 王朗 | Manufacturing method of waterproof braided fabric |
| CN104264468A (en) * | 2014-10-22 | 2015-01-07 | 湖北久瑞核技术股份有限公司 | Preparation method for water-repellent textile |
| CN104264475A (en) * | 2014-10-10 | 2015-01-07 | 苏州印丝特纺织数码科技有限公司 | Preparation method for waterproof and moisture-permeable silk fabric |
| WO2015103988A1 (en) * | 2014-01-10 | 2015-07-16 | 中国人民解放军第三0二医院 | Medical dressing hydrogel composite fabric, and preparation method therefor and uses thereof |
| CN106498720A (en) * | 2016-11-18 | 2017-03-15 | 辽东学院 | A kind of temperature sensitive waterproof moisture permeable fabric and preparation method thereof |
| CN107201508A (en) * | 2016-03-16 | 2017-09-26 | 台湾神户电池股份有限公司 | The method for lifting the hydrophily and electric conductivity of carbon cloth |
| EP3470573A1 (en) * | 2017-10-16 | 2019-04-17 | Werner & Mertz GmbH | Method for producing a textile article with hydrophobised textile surface using plasma treatment and wet chemical processing |
| CN109778545A (en) * | 2019-01-22 | 2019-05-21 | 乐清市雅格狮丹服饰有限公司 | A kind of finishing technique of waterproof casings |
| CN111607893A (en) * | 2020-06-04 | 2020-09-01 | 浙江天晟信息技术有限公司 | Water-repellent non-woven fabric and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1328063A (en) * | 2001-06-29 | 2001-12-26 | 清华大学 | Process for preparing high-response porous sensitive aqueogel |
-
2011
- 2011-08-22 CN CN201110242519.7A patent/CN102444021B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1328063A (en) * | 2001-06-29 | 2001-12-26 | 清华大学 | Process for preparing high-response porous sensitive aqueogel |
Non-Patent Citations (1)
| Title |
|---|
| 牛家嵘: "智能型抗浸透湿织物的开发与研究", 《中国优秀博硕士学位论文全文数据库(博士)工程科技Ⅰ辑》 * |
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| CN102877285B (en) * | 2012-10-25 | 2014-12-17 | 愉悦家纺有限公司 | Desizing method of fabric |
| CN102877285A (en) * | 2012-10-25 | 2013-01-16 | 愉悦家纺有限公司 | Desizing method of fabric |
| CN103271471A (en) * | 2013-06-13 | 2013-09-04 | 太仓协大申泰羊毛衫有限公司 | Antistatic, hygroscopic and degradable woolen sweater |
| CN103696088A (en) * | 2013-12-19 | 2014-04-02 | 吴江明敏制衣有限公司松陵分公司 | Water-proof and moisture-proof fabric |
| CN105228658A (en) * | 2014-01-10 | 2016-01-06 | 中国人民解放军第三0二医院 | A kind of medical dressing hydrogel compound fabric and its preparation method and application |
| WO2015103988A1 (en) * | 2014-01-10 | 2015-07-16 | 中国人民解放军第三0二医院 | Medical dressing hydrogel composite fabric, and preparation method therefor and uses thereof |
| CN105228658B (en) * | 2014-01-10 | 2018-04-20 | 中国人民解放军第三0二医院 | A kind of medical dressing hydrogel compound fabric and its preparation method and application |
| CN104179000A (en) * | 2014-09-12 | 2014-12-03 | 王朗 | Manufacturing method of waterproof braided fabric |
| CN104264475A (en) * | 2014-10-10 | 2015-01-07 | 苏州印丝特纺织数码科技有限公司 | Preparation method for waterproof and moisture-permeable silk fabric |
| CN104264475B (en) * | 2014-10-10 | 2016-11-30 | 海门市彼维知识产权服务有限公司 | A kind of preparation method of Waterproof Breathable silk fabric |
| CN104264468A (en) * | 2014-10-22 | 2015-01-07 | 湖北久瑞核技术股份有限公司 | Preparation method for water-repellent textile |
| CN107201508A (en) * | 2016-03-16 | 2017-09-26 | 台湾神户电池股份有限公司 | The method for lifting the hydrophily and electric conductivity of carbon cloth |
| CN106498720A (en) * | 2016-11-18 | 2017-03-15 | 辽东学院 | A kind of temperature sensitive waterproof moisture permeable fabric and preparation method thereof |
| CN106498720B (en) * | 2016-11-18 | 2019-03-05 | 辽东学院 | A kind of temperature sensitive waterproof moisture permeable fabric and preparation method thereof |
| EP3470573A1 (en) * | 2017-10-16 | 2019-04-17 | Werner & Mertz GmbH | Method for producing a textile article with hydrophobised textile surface using plasma treatment and wet chemical processing |
| WO2019076823A1 (en) * | 2017-10-16 | 2019-04-25 | Werner & Mertz Gmbh | Process for producing a textile article having a water-repellent textile surface by plasma treatment and wet-chemical treatment |
| CN109778545A (en) * | 2019-01-22 | 2019-05-21 | 乐清市雅格狮丹服饰有限公司 | A kind of finishing technique of waterproof casings |
| CN111607893A (en) * | 2020-06-04 | 2020-09-01 | 浙江天晟信息技术有限公司 | Water-repellent non-woven fabric and preparation method thereof |
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