CN102877285A - Desizing method of fabric - Google Patents

Desizing method of fabric Download PDF

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Publication number
CN102877285A
CN102877285A CN2012104134241A CN201210413424A CN102877285A CN 102877285 A CN102877285 A CN 102877285A CN 2012104134241 A CN2012104134241 A CN 2012104134241A CN 201210413424 A CN201210413424 A CN 201210413424A CN 102877285 A CN102877285 A CN 102877285A
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fabric
destarch
plasma
processed
pressure
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CN102877285B (en
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刘曰兴
王玉平
张国清
苏长智
夏玉
王涛
常国新
于秉清
宫成民
赵爱国
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Yuyue Home Textile Co Ltd
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Yuyue Home Textile Co Ltd
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Abstract

The invention provides a desizing method of fabric, and the desizing method comprises following steps that (a) plasma treatment is conducted on the fabric to be processed; and (b) desizing treatment is conducted on the fabric obtained in the step (a). Plasma treatment on the fabric is carried out before the desizing treatment is conducted on the fabric to be processed, high-energy particles in the plasma can produce an etching effect on the surface of the textile fabric, so that a continuous coverage state of fiber spreading mass and waxiness is oxidized and destructed, molecular chains of the spreading mass is cut off, and pores and cracks are formed on the surface of a size membrane, so that the penetration of desizing working liquid can be facilitated; and meanwhile, hydrophilic groups such as hydroxide radical, carboxyl group and the like are introduced into the plasma, the dissolving of the size membrane and the removal of impurities can be favored, so that the desizing rate of the fabric is improved. The experimental result shows that the desizing rate of the fabric can reach up to 85 percent or more by utilizing the desizing method, and the capillary and mechanical property of the obtained fabric can be improved.

Description

A kind of desizing method of fabric
Technical field
The present invention relates to the dyeing and finishing technique field, relate in particular to a kind of desizing method of fabric.
Background technology
The technical process that refers to remove appended impurity on textile sizing material and the fabric fibre is processed in the destarch of traditional textile printing and dyeing.The warp thread of the fabrics such as cotton, viscose glue and various synthetic fiber passes through mostly first sizing before weaving.Slurry in the sizing process can affect the wettability of fabric in dyeing and finishing process, and the obstruction chemicals contacts fiber.Therefore fabric is carrying out must carrying out the destarch processing before dyeing and finishing is processed.Desizing method commonly used comprises: alkali destarch method, enzyme desizing method, oxidant destarch method and alkaline oxygen bath destarch method.
Alkali destarch method is applicable to take starch or starch as the fabric main, that the rate of sizing is lower and the fabric of chemical sizwe (such as the polyacrylic slurry) and other slurry mixing starching.The advantage of this technique is that cost is low, and caustic soda can utilize kiering or mercerized waste alkali, does not damage again cotton fiber.But alkali destarch method is bad for the destarch effect of PVA slurry, and easily causes the PVA slurry that the slime spots that " cohesion " phenomenon sticks on the fabric or can form very difficult removal on the fabric guide roll occurs, and very easily produces the printing and dyeing fault; In addition, for the too late enzyme desizing method of the fabric alkali destarch effect of using the starch starching.Yet the enzyme desizing method is only applicable to pure starch slurry or take the fabric of starch slurry as slurry sizing main, that PVA content is lower.If mix PVA content fabric higher or that starch take the PVA slurry as the Your Majesty in the slurry, then must adopt other desizing method.Oxidant destarch method is applicable to PVA and closes fine blending and PURE YARN FABRIC take PVA as main and other slurry mixing starching, can strip all slurries.The oxidant that is used for destarch generally has sodium bromite, H 2O 2, NaClO, persulfate etc., at present main hydrogen peroxide and persulfate two classes of adopting.The characteristics of this technique are that destarch is rapid, and are effective, if also have the partial bleaching effect with the hydrogen peroxide destarch.The hydrogen peroxide destarch is not only to various types of starch, and the PVA slurry is also had preferably destarch effect, but to be high expensive, technology controlling and process bad easily goes out oxidation hole problem for the shortcoming that exists.If when adopting the persulfate destarch cellulose fibre is had damage, fabric falls strong serious, and the destarch effect of PVA is short of to some extent.
Because the scope of application of above-mentioned desizing method is narrower and have a more shortcoming, therefore, at present in industrial production take alkaline oxygen bath destarch method as main, this be since the method major advantage to be cost low and help the removal of cotton seed hulls and part fiber commensal, alleviate concise burden, semi-finished product whiteness, good penetrability after processing; And can both be suitable for all kinds of slurries.But use the method to have destarch rate problem on the low side, only can reach 50% ~ 70%.
Summary of the invention
The object of the present invention is to provide a kind of desizing method of fabric, method provided by the invention has improved the destarch quality of fabric so that fabric has higher destarch rate.
The invention provides a kind of desizing method of fabric, may further comprise the steps:
A) pending fabric is carried out Cement Composite Treated by Plasma;
B) fabric that described step a) is obtained carries out destarch to be processed.
Preferably, the frequency of described step a) Cement Composite Treated by Plasma applying plasma is 18000 hertz ~ 25000 hertz.
Preferably, the electrode in the described step a) Cement Composite Treated by Plasma and the distance between fabric are 1mm ~ 5mm.
Preferably, the number of times of described step a) applying plasma processing is 5 times ~ 10 times.
Preferably, the number of times fabric positive and negative of described step a) applying plasma processing respectively carries out 5 times ~ 10 times.
Preferably, the sparking electrode of described step a) applying plasma processing is 15 ~ 20.
Preferably, the speed of fabric is 25m/min ~ 50m/min in the described step a) Cement Composite Treated by Plasma.
Preferably, described step b) is specially:
B1) fabric that described step a) is obtained carries out the processing of the first hot water wash successively, the room temperature washing is processed and the first squezzing is processed;
B2) with described step b1) fabric that obtains immerses and carries out destarch in the destarch working solution and process;
B3) with described step b2) fabric that obtains rolls successively that material, decatize are processed, the second hot water wash is processed and the second squezzing is processed.
Preferably, the temperature of described the first hot water wash processing is 90 ℃ ~ 96 ℃;
The temperature that described the second hot water wash is processed is 93 ℃ ~ 95 ℃.
Preferably, the temperature of described decatize is 98 ℃ ~ 100 ℃;
The time of described decatize is 25min ~ 45min.
The invention provides a kind of desizing method of fabric, may further comprise the steps: a) pending fabric is carried out Cement Composite Treated by Plasma; B) fabric that described step a) is obtained carries out destarch to be processed.Before the present invention carries out destarch with pending fabric, it is carried out Cement Composite Treated by Plasma, high energy particle produces corrasion to the textile fabric surface in the plasma, make the continuous covering state of fiber spreading mass and wax oxidized and destroy, the strand of slurry is cut off, serosa surface forms hole and crack, is conducive to caustic soda and infiltrates; Plasma is introduced the hydrophilic radicals such as hydroxyl, carboxyl simultaneously, promotes the decomposition of slurry, the slurry solubility is improved, and the impurity that obtains also is easy to be removed; Cement Composite Treated by Plasma can also be carried out chemical modification to fiber surface: can generate ion and free group at fiber surface, the crystal region of the large molecular surface of fiber and the ratio of amorphous region are changed, thereby change water imbibition and the permeability of fiber surface.Therefore method provided by the invention has improved the destarch rate of fabric, and the raising that also obtains of the capillary effect of fabric and mechanical property.Experimental result shows, desizing method provided by the invention can reach more than 85% the destarch rate of fabric, and traditional handicraft has improved approximately 20% relatively, has guaranteed the quality of fabric in follow-up printing and dyeing, and has improved the feel of fabric, has improved level in kind.
The specific embodiment
The invention provides a kind of desizing method of fabric, may further comprise the steps:
A) pending fabric is carried out Cement Composite Treated by Plasma;
B) fabric that described step a) is obtained carries out destarch to be processed.
The present invention studies show that, slurry forms serous coat at fiber surface, in the process of the destarch of traditional handicraft, be difficult to remove because serous coat is comparatively complete, simultaneously destarch working solution also is difficult to enter yarn inside, cause the destarch working solution to be difficult to play a role, thereby so that the destarch effect is relatively poor.The invention provides a kind of desizing method of fabric, at first pending fabric is carried out Cement Composite Treated by Plasma, the fabric of the process Cement Composite Treated by Plasma that then will obtain carries out destarch to be processed, fabric is being carried out in the process of Cement Composite Treated by Plasma, high energy particle in the plasma produces corrasion to fabric face, makes the continuous covering state of fiber spreading mass and wax oxidized and destroy, and the strand of slurry is cut off, serosa surface forms hole and crack, is conducive to the destarch working solution and infiltrates; Plasma is introduced the hydrophilic radicals such as hydroxyl, carboxyl simultaneously, and destarch working solution Fast-swelling decomposes slurry, and the slurry solubility is improved, and contains the more wax of c h bond also oxidized, and the C=O linkage content is increased, and impurity is easy to be removed; Cement Composite Treated by Plasma can also be carried out chemical modification to fiber surface: can generate ion and free group at fiber surface, the crystal region of the large molecular surface of fiber and the ratio of amorphous region are changed, thereby change water imbibition and the permeability of fiber surface.So so that the fabric that method provided by the invention obtains has higher destarch rate, but also capillary effect and the intensity of fabric have been improved.
The present invention at first carries out Cement Composite Treated by Plasma with pending fabric, obtains the fabric through Cement Composite Treated by Plasma.The present invention further improves the quality of fabric in order to adapt to industrial needs, preferably pending fabric is carried out Cement Composite Treated by Plasma before, first described pending fabric turns over cloth, margin to seam and the processing of singing successively.The present invention does not have special restriction to the described method of turning over cloth, margin to seam and singing, and adopts the technical scheme of turning over cloth, margin to seam and singing well known to those skilled in the art to get final product.In the present invention, the described cloth that turns over the process that margin to seam is processed is: pending fabric is ploughed under in the step car according to positive and negative consistent principle, then the fabric that obtains is connected according to the mode of being end-to-end;
Obtain through behind the fabric that turns over the processing of cloth and margin to seam, the present invention is with the fabric that the obtains processing of singing, detailed process is: the fabric that obtains nuzzled up at flame or in red-hot metal surface, and the fine hair of the described fabric face of burning-off, fabric after processing obtains singing.The present invention does not have special restriction to conditions such as the kind of described flame or red-hot metal, temperature, adopts well known to those skilled in the art singing to adopt flame or red-hot metal to get final product in processing.
After finishing the processing of singing to described fabric, the present invention carries out Cement Composite Treated by Plasma with the fabric that obtains.The mode that plasma of the present invention produces does not have special restriction, adopts the producing method of plasma well known to those skilled in the art to get final product.In order to make cloth cover treatment effect uniformity, the present invention preferably carries out described fabric removing before the Cement Composite Treated by Plasma fold of cloth cover, the present invention does not have special restriction to the method for described removal fold, adopt the technical scheme of removal fold well known to those skilled in the art to get final product, the present invention preferably adopts the mode that applies spreading roll or roller to remove the fold of cloth cover; The present invention preferably passes through plasma apparatus with the fabric that obtains, and carries out Cement Composite Treated by Plasma.In the present invention, the plasma in the described Cement Composite Treated by Plasma is the plasma that excites air to obtain; The described voltage of air that excites is preferably 10000V ~ 15000V; The calibration of described Cement Composite Treated by Plasma applying plasma is 18000 hertz ~ 25000 hertz, more preferably 20000 hertz ~ 22000 hertz; The electrode of described generation plasma and the distance between fabric are preferably 1mm ~ 5mm, more preferably 1mm ~ 3mm; The sparking electrode that produces plasma in the described Cement Composite Treated by Plasma is preferably 15 ~ 20, more preferably 16; The number of times of described Cement Composite Treated by Plasma is preferably 5 times ~ 10 times, more preferably 6 times ~ 9 times, most preferably is 8 times; More preferably the tow sides with fabric carry out respectively 5 times ~ 10 times plasmas processing, most preferably are fabric and respectively carry out 5 times ~ 10 times plasmas processing according to positive reverse side mode once; The time of described Cement Composite Treated by Plasma is preferably 0.4 second ~ and 1 second;
The present invention can carry out Cement Composite Treated by Plasma by using plasma processor pair fabric, and its parameter setting is preferably: input voltage is preferably 380V ~ 400V; Input current is preferably 75A ~ 85A; Input power is preferably 28KW ~ 35KW; The speed of a motor vehicle is preferably 25m/min ~ 50m/min.The present invention is through broken hole fault on the fabric in order to prevent fabric by high-voltage electric shock, and the distance on the described plasma processor between sparking electrode and the electro-insulating rubber is preferably 2mm ~ 8mm, more preferably 3mm ~ 5mm.
After finishing the Cement Composite Treated by Plasma to pending fabric, the present invention carries out destarch with the fabric that obtains and processes, and finishes the destarch of pending fabric is processed.In the present invention, described destarch is processed and is preferably included following steps:
B1) fabric that described step a) is obtained carries out the processing of the first hot water wash successively, the room temperature washing is processed and the first squezzing is processed;
B2) with described step b2) fabric that obtains immerses in the destarch working solution;
B3) with described step b2) fabric that obtains rolls successively that material, decatize are processed, the second hot water wash is processed and the second squezzing is processed.
After finishing the Cement Composite Treated by Plasma to fabric, the present invention preferably carries out the fabric that obtains the processing of the first hot water wash successively, the room temperature washing is processed and the first squezzing is processed, the present invention does not have special restriction to the method that described the first hot water wash is processed, the room temperature washing is processed and the first squezzing is processed, and adopts the technical scheme that the first hot water wash well known to those skilled in the art is processed, the room temperature washing is processed and the first squezzing is processed to get final product.In the present invention, the temperature of hot water was preferably 90 ℃ ~ 96 ℃, more preferably 92 ℃ ~ 94 ℃ during described the first hot water wash was processed; Fabric is after washing, and moisture content is more on the fabric, should roll as far as possible and anhydrate minute, to raise the efficiency, saves steam, and in the present invention, preferably making the pick-up of the fabric that obtains after the described squezzing processing is 60% ~ 65%;
After described fabric processed through the first squezzing, the present invention enters the fabric that obtains and carries out the destarch processing in the destarch working solution, the present invention does not have special restriction to the composition of described destarch working solution, adopt destarch working solution well known to those skilled in the art to get final product, the present invention can adopt the alkali destarch working solution in the alkali lye destarch method, also can adopt the biology enzyme destarch working solution in the enzyme desizing method, in the present invention, if adopt the slurry working solution that goes down, it preferably includes the caustic soda of the component of following mass concentration: 2g/L ~ 12g/L and the refining agent of 2g/L ~ 3g/L; If adopt biology enzyme destarch working solution, it preferably includes the destarch biology enzyme of the component of following mass concentration: 2g/L ~ 5g/L, more preferably 3g/L ~ 4g/L; The bleeding agent of 1g/L ~ 2g/L.The present invention does not have special restriction to the kind of described destarch biology enzyme, bleeding agent and refining agent, adopt the refining agent that adopts in the destarch biology enzyme that adopts in the enzyme desizing method well known to those skilled in the art and bleeding agent, the alkali destarch method to get final product, the model that can adopt Zaozhuang City outstanding promise biology enzyme Co., Ltd to produce such as the destarch biology enzyme is the wide-temperature high-efficiency destarch enzyme of JN-160, the model that bleeding agent can adopt the chemical industry Co., Ltd of expounding one's ideas in writing to provide is the bleeding agent of CG, and refining agent can adopt the Suzhou connection to win the refining agent SA-23 that chemical Co., Ltd provides;
The present invention is when adopting alkali destarch working solution, and concentration of caustic soda wherein is lower, thereby has reduced the pH value of desized wastewater, so that its processing is simpler, has reduced the processing cost of waste water, is beneficial to environmental protection; And method provided by the invention can be carried out at normal temperatures and pressures, thereby avoids occurring " oxidation hole " fault owing to the metal impurities generation, has improved the mechanical property of fabric.
The present invention takes out fabric from the described destarch working solution of technique scheme, it is rolled material, decatize processing, the processing of the second hot water wash and the second squezzing successively processes, the present invention does not have special restriction to described method of rolling material, decatize processing, the processing of the second hot water wash and the second squezzing processing, adopts technical scheme of rolling material, decatize processing, the processing of the second hot water wash and the second squezzing processing well known to those skilled in the art to get final product.The present invention preferably will obtain fabric and expect that by rolling making its pick-up is 100% ~ 105%; In the present invention, the temperature of steam is preferably 98 ℃ ~ 100 ℃ in the described decatize processing procedure; The time of described decatize is preferably 25min ~ 45min, more preferably 30min ~ 40min; The temperature that described the second hot water wash is processed used hot water is preferably 93 ℃ ~ 95 ℃; The pick-up that described the second squezzing is processed is preferably 60% ~ 65%;
The present invention is preferably dried the fabric that obtains after the fabric that obtains is finished the second squezzing processing, finishes the destarch of fabric is processed.The present invention does not have special restriction to the method for described oven dry, adopts the technical scheme of oven dry well known to those skilled in the art to get final product.
After the present invention finishes the destarch of fabric is processed, destarch rate, capillary effect and the mechanical property of the fabric that detection obtains, the destarch rate represents a basic technical indicator of textile sizing material removal degree, and available following formula calculates: destarch rate=[fabric sizing percentage before (fabric sizing percentage after the front fabric sizing percentage-destarch of destarch)/destarch] * 100%.General Requirements fabric desizing rate is more than 80% in the production, or desizing grade is about 8 grades, and remaining residual slurry will be removed in next step concise operation.The present invention does not have special restriction to the detection method of described destarch rate, adopt the detection technique scheme of destarch rate well known to those skilled in the art to get final product, such as the disclosed chemical quantitative determination process of prior art or " TEGEWA " ranking method, the present invention adopts " TEGEWA " ranking method that the destarch rate of fabric is detected, and detailed process is as follows:
Tested fabric sample is dipped in continues 2min in the iodine solution of N/200, in water, blots with filter paper after the short time flushing subsequently, and under hygrometric state, place 5min, then with the judgement of grading of purple standard specimen card.It is 1 grade~9 grades that purple evaluation scale is divided into, and wherein 1 grade of destarch effect is the poorest, and 9 grades of destarch effects are best, and the relation of fabric desizing rate evaluation rank and quantitative assay sees Table 1, and table 1 is the relation of destarch rate evaluation rank and quantitative assay value among the present invention:
The relation of destarch rate evaluation rank and quantitative assay value among table 1 the present invention
Figure BDA00002308995500061
Capillary effect is that capillary effect also is an important technology index of evaluation fabric desizing effect, and General Requirements COTTON FABRIC capillary effect requires more than 8cm.Its mensuration is the sample cloth after the destarch vertically to be tightened fixedly be suspended on the support, the water storage case that fills deionized water or pure water is arranged below the support.Before the mensuration, be parallel to first tag line of water surface place mark in the cloth specimen lower end, then the cloth specimen lower end is immersed in deionized water or the pure water, tag line and the water surface are coincided together, at in setting time behind the certain altitude that deionized water or pure water rise to along capillary, make a Horizontal identification line from the extreme lower position (washmarking) that water arrives at cloth cover, then measure the distance the tag line of upper end from cloth specimen lower end tag line to cloth specimen with ruler, with centimetre being long measure metering, be the capillary effect value.The present invention does not have special restriction to the above-mentioned time, time used when adopting mensuration capillary effect well known to those skilled in the art gets final product, the present invention preferably adopts 30 minutes methods that the capillary effect of fabric is measured, namely be to measure liquid height along capillary rise in 30 minutes, represent with cm, sampling 30 * 5cm obtains the capillary effect of fabric;
Fabric strength generally is divided into two kinds of ultimate strength (or tensile strength) and tearing brute forces.Its assay method has a lot.In the prior art, ultimate strength has two kinds of methods to measure: galley proof method and grab method, tearing brute force comprises single tongue method and two tongue method, also can be according to the commercial detection standard method of relevant export market specified standard or client's appointment, such as execution such as AATCC, ASTM, ISO.The present invention is according to State Standard of the People's Republic of China GB/T 3923.1 " textile fabric tensile property " part 1: the fabric that the mensuration galley proof method of ultimate strength and elongation at break obtains the present invention carries out the mensuration of fabric strength;
The result shows that the destarch rate of the fabric that method provided by the invention obtains is more than 85%, is approximately higher than 25% of traditional handicraft, and the fabric that obtains has higher capillary effect and mechanical property, is beneficial to the carrying out of follow-up dyeing and printing process, has guaranteed follow-up printing quality; And improved the feel of fabric because of the removal of slurry, improved level in kind.
The invention provides a kind of desizing method of fabric, may further comprise the steps: a) pending fabric is carried out Cement Composite Treated by Plasma; B) fabric that described step a) is obtained carries out destarch to be processed.Before the present invention carries out destarch with pending fabric, it is carried out Cement Composite Treated by Plasma, high energy particle produces corrasion to the textile fabric surface in the plasma, make the continuous covering state of fiber spreading mass and wax oxidized and destroy, the strand of slurry is cut off, serosa surface forms hole and crack, is conducive to caustic soda and infiltrates; Plasma is introduced the hydrophilic radicals such as hydroxyl, carboxyl simultaneously, and the caustic soda Fast-swelling decomposes slurry, and the slurry solubility is improved, and contains the more wax of c h bond also oxidized, and the C=O linkage content is increased, and impurity is easy to be removed; Cement Composite Treated by Plasma can also be carried out chemical modification to fiber surface: can generate ion and free group at fiber surface, the crystal region of the large molecular surface of fiber and the ratio of amorphous region are changed, thereby change water imbibition and the permeability of fiber surface.Because of above-mentioned reason, lower NaOH consumption just can make the water imbibition of COTTON FABRIC obtain larger raising, is conducive to fabric and realizes cleaning destarch.Experimental result shows, desizing method provided by the invention can reach more than 85% the destarch rate of fabric, has guaranteed the quality of fabric in follow-up printing and dyeing, and has improved the feel of fabric, has improved level in kind.
In order to further specify the present invention, below in conjunction with embodiment the desizing method of fabric provided by the invention is described in detail, but they can not be interpreted as restriction to protection domain of the present invention.
In the following embodiments, plasma processor is that model is the textile fabric plasma processor of SZW-1800, moving back the model of boiling rinsing combination machine is LMH022-200, refining agent SA-23 wins chemical Co., Ltd available from the Suzhou connection, efficient destarch enzyme JN-160 is available from the outstanding promise biology enzyme in Zaozhuang City Co., Ltd, and bleeding agent CG is available from the chemical industry Co., Ltd of expounding one's ideas in writing.
Embodiment 1
Be 8S * 8S 48 * 3263 with specification " the general comb of cotton turn over cloth and margin to seam, then the general comb of the cotton that obtains is placed the processor of the singing processing of singing, the described parameter of processing of singing is: the speed of a motor vehicle is 120 ± 2m/min; 1 #The burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2 #The burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; The mode of singing is for thoroughly burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The process that the present invention will the obtain general comb of cotton of processing of singing places plasma processor to carry out Cement Composite Treated by Plasma, the parameter of plasma processor is set to: input voltage is 350V ~ 400V, electric current is 75A ~ 85A, power is 25KW ~ 30KW, frequency is 20000 hertz ~ 25000 hertz, and the speed of a motor vehicle is 30 ± 2/min;
It is that moving back of LMH022-200 boiled rinsing combination machine and carried out the alkali destarch and process that the general comb of cotton of the process Cement Composite Treated by Plasma that the present invention will obtain places model, and the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, wash with 93 ± 3 ℃ hot water, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the caustic soda of the component of following mass concentration: 10g/L and the refining agent SA-23 of 1g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of the general comb of cotton is processed.
The general comb of cotton that the above-mentioned destarch of the process that the present invention will obtain is processed carries out index test, and the result is as shown in table 2, and table 2 is the test result that the embodiment of the invention 1 and comparative example 1 obtain.
Comparative example 1
Be 8S * 8S 48 * 3263 with specification " the general comb of cotton turn over cloth and margin to seam, then the general comb of the cotton that obtains is placed the processor of the singing processing of singing, the described parameter of processing of singing is: the speed of a motor vehicle is 120 ± 2m/min; 1 #The burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2 #The burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; The mode of singing is for thoroughly burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The process that the present invention will obtain is singed, and to place model be that moving back of LMH022-200 boiled rinsing combination machine and carried out the alkali destarch and process for the general comb of cotton processed, and the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, wash with 93 ± 3 ℃ hot water, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the caustic soda of the component of following mass concentration: 40g/L and the refining agent SA-23 of 2g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of the general comb of cotton is processed.
The general comb of cotton that the above-mentioned destarch of the process that the present invention will obtain is processed carries out index test, and the result is as shown in table 2, and table 2 is the test result that the embodiment of the invention 1 and comparative example 1 obtain.
The test result that table 2 embodiment of the invention 1 and comparative example 1 obtain.
Figure BDA00002308995500101
As can be seen from Table 2, desizing method provided by the invention has preferably destarch rate, compare traditional handicraft and improved approximately 20%, and the capillary effect of the fabric that obtains and fracture strength also is improved; In addition, the alkali consumption of method provided by the invention has reduced approximately 70%, is conducive to realize clean destarch.
Embodiment 2
Be 8S * 8S 48 * 3263 with specification " the general comb of cotton turn over cloth and margin to seam, then the general comb of the cotton that obtains is placed the processor of the singing processing of singing, the described parameter of processing of singing is: the speed of a motor vehicle is 120 ± 2m/min; 1 #The burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2 #The burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; The mode of singing is for thoroughly burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The process that the present invention will the obtain general comb of cotton of processing of singing places plasma processor to carry out Cement Composite Treated by Plasma, the parameter of plasma processor is set to: input voltage is 350V ~ 400V, electric current is 75A ~ 85A, power is 25KW ~ 30KW, frequency is 20000 hertz ~ 25000 hertz, and the speed of a motor vehicle is 30 ± 2/min;
It is that moving back of LMH022-200 boiled rinsing combination machine and carried out the alkali destarch and process that the general comb of cotton of the process Cement Composite Treated by Plasma that the present invention will obtain places model, and the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, wash with 93 ± 3 ℃ hot water, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the caustic soda of the component of following mass concentration: 12g/L and the refining agent SA-23 of 2g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of the general comb of cotton is processed.
The result shows, method provided by the invention is so that fabric has higher destarch rate, and the capillary effect of the fabric that obtains and intensity also is improved, and is beneficial to the carrying out of its subsequent technique.
Comparative example 2
Be 8S * 8S 48 * 3263 with specification " the general comb of cotton turn over cloth and margin to seam, then the general comb of the cotton that obtains is placed the processor of the singing processing of singing, the described parameter of processing of singing is: the speed of a motor vehicle is 120 ± 2m/min; 1 #The burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2 #The burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; The mode of singing is for thoroughly burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The process that the present invention will obtain is singed, and to place model be that moving back of LMH022-200 boiled rinsing combination machine and carried out the alkali destarch and process for the general comb of cotton processed, and the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, wash with 93 ± 3 ℃ hot water, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the caustic soda of the component of following mass concentration: 42g/L and the refining agent SA-23 of 3g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of the general comb of cotton is processed.
Compare by the result with embodiment 2, the result shows, the destarch rate of the fabric that method provided by the invention obtains has improved approximately 20%; And method alkali consumption provided by the invention reduced approximately 70%, realized the cleaning destarch.
Embodiment 3
Be 21S * 21S 108 * 5863 with specification " the general comb of cotton turn over cloth and margin to seam, then the general comb of the cotton that obtains is placed the processor of the singing processing of singing, the described parameter of processing of singing is set to: the speed of a motor vehicle is 125 ± 2m/min; 1# burner air pressure 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2# burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar.The mode of singing is for thoroughly burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The process that the present invention will the obtain general comb of cotton of processing of singing places plasma processor to carry out Cement Composite Treated by Plasma, and the parameter of plasma processor is set to: input voltage is 350V ~ 400V, and electric current is 75A ~ 85A; Power is 25KW ~ 30KW; Frequency is 20000 hertz ~ 25000 hertz; The speed of a motor vehicle is 35 ± 2m/min;
The general comb of cotton of the process Cement Composite Treated by Plasma that the present invention will obtain places to move back and boils rinsing combination machine and carry out destarch and process, and the condition setting that destarch is processed is as follows: the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, with 93 ± 3 ℃ hot water wash, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the efficient destarch enzyme JN-160 of the component of following mass concentration: 2g/L and the bleeding agent CG of 0.5g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of the general comb of cotton is processed.
The general comb of cotton that the above-mentioned destarch of the process that the present invention will obtain is processed carries out index test, and the result is as shown in table 3, and table 3 is the test result that the embodiment of the invention 3 and comparative example 3 obtain.
Comparative example 3
Be 21S * 21S 108 * 5863 with specification " the general comb of cotton turn over cloth and margin to seam, then the general comb of the cotton that obtains is placed the processor of the singing processing of singing, the described parameter of processing of singing is set to: the speed of a motor vehicle is 125 ± 2m/min; 1# burner air pressure 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2# burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar.The mode of singing is for thoroughly burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The general comb of cotton that the present invention will obtain processing through singing places to move back and boils rinsing combination machine and carry out destarch and process, and the condition setting that destarch is processed is as follows: the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, with 93 ± 3 ℃ hot water wash, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the efficient destarch enzyme JN-160 of the component of following mass concentration: 2g/L and the bleeding agent CG of 2g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of the general comb of cotton is processed.
The general comb of cotton that the above-mentioned destarch of the process that the present invention will obtain is processed carries out index test, and the result is as shown in table 3, and table 3 is the test result that the embodiment of the invention 3 and comparative example 3 obtain.
The test result that table 3 embodiment of the invention 3 and comparative example 3 obtain
Figure BDA00002308995500131
As can be seen from Table 3, the destarch rate that method provided by the invention obtains is 85.55%, compares traditional handicraft and has improved approximately 27%, and this illustrates that method provided by the invention can improve the destarch rate effectively.
Embodiment 4
Be 21S * 21S 108 * 5863 with specification " the general comb of cotton turn over cloth and margin to seam, then the general comb of the cotton that obtains is placed the processor of the singing processing of singing, the described parameter of processing of singing is set to: the speed of a motor vehicle is 125 ± 2m/min; 1# burner air pressure 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2# burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar.The mode of singing is for thoroughly burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The process that the present invention will the obtain general comb of cotton of processing of singing places plasma processor to carry out Cement Composite Treated by Plasma, and the parameter of plasma processor is set to: input voltage is 350V ~ 400V, and electric current is 75A ~ 85A; Power is 25KW ~ 30KW; Frequency is 20000 hertz ~ 25000 hertz; The speed of a motor vehicle is 35 ± 2m/min;
The general comb of cotton of the process Cement Composite Treated by Plasma that the present invention will obtain places to move back and boils rinsing combination machine and carry out destarch and process, and the condition setting that destarch is processed is as follows: the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, with 93 ± 3 ℃ hot water wash, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the efficient destarch enzyme JN-160 of the component of following mass concentration: 3g/L and the bleeding agent CG of 1g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of the general comb of cotton is processed.
The general comb of cotton that the above-mentioned destarch of the process that the present invention will obtain is processed carries out performance test, and the result shows that the general comb of cotton that method provided by the invention obtains has higher destarch rate.
Comparative example 4
Be 21S * 21S 108 * 5863 with specification " the general comb of cotton turn over cloth and margin to seam, then the general comb of the cotton that obtains is placed the processor of the singing processing of singing, the described parameter of processing of singing is set to: the speed of a motor vehicle is 125 ± 2m/min; 1# burner air pressure 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2# burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar.The mode of singing is for thoroughly burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The general comb of cotton that the present invention will obtain processing through singing places to move back and boils rinsing combination machine and carry out destarch and process, and the condition setting that destarch is processed is as follows: the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, with 93 ± 3 ℃ hot water wash, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the efficient destarch enzyme JN-160 of the component of following mass concentration: 3g/L and the bleeding agent CG of 3g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of the general comb of cotton is processed.
Compare by the result with embodiment 4, the result shows, the destarch rate of the fabric that method provided by the invention obtains has improved approximately 30%, and its mechanical property also is improved, this illustrates that method provided by the invention carries out destarch to fabric, destarch rate and the mechanical strength of fabric be can improve, the carrying out of follow-up dyeing and finishing technology and the dyeing and finishing level of raising fabric are conducive to.
Embodiment 5
" turn over cloth and margin to seam, then the fabric that obtains is placed the gassing frame processing of singing, the parameter of described gassing frame arranges as follows: the speed of a motor vehicle is 135 ± 2m/min with the general comb of polyester cotton blending T65/C35 21S * 21S 108 * 5863; 1# burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2# burner air pressure is 29 ± 1mbar, gas pressure: 25 ± 1mbar.The mode of singing is to burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The process that the present invention will the obtain fabric of processing of singing places plasma processor to carry out Cement Composite Treated by Plasma, and the parameter of plasma machine arranges as follows: input voltage is 350V ~ 400V, and electric current is 75A ~ 85A; Power is 25KW ~ 30KW; Frequency is 20000 hertz ~ 25000 hertz; The speed of a motor vehicle is 35 ± 2m/min;
The fabric of the process Cement Composite Treated by Plasma that the present invention will obtain places to move back and boils rinsing combination machine and carry out destarch and process, and move back the running parameter that boils rinsing combination machine and arrange as follows: the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, with 93 ± 3 ℃ hot water wash, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the efficient destarch enzyme JN-160 of the component of following mass concentration: 2g/L and the bleeding agent CG of 0.5g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of fabric is processed.
The fabric that the above-mentioned destarch of the process that the present invention will obtain is processed carries out performance test, and the result is as shown in table 4, and table 4 is the test result that the embodiment of the invention 5 and comparative example 5 obtain.
Comparative example 5
" turn over cloth and margin to seam, then the fabric that obtains is placed the gassing frame processing of singing, the parameter of described gassing frame arranges as follows: the speed of a motor vehicle is 135 ± 2m/min with the general comb of polyester cotton blending T65/C35 21S * 21S 108 * 5863; 1# burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2# burner air pressure is 29 ± 1mbar, gas pressure: 25 ± 1mbar.The mode of singing is to burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The singe fabric processed of the process that the present invention will obtain places to move back and boils rinsing combination machine and carry out destarch and process, and move back the running parameter that boils rinsing combination machine and arrange as follows: the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, with 93 ± 3 ℃ hot water wash, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the efficient destarch enzyme JN-160 of the component of following mass concentration: 2g/L and the bleeding agent CG of 2g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of fabric is processed.
The fabric that the above-mentioned destarch of the process that the present invention will obtain is processed carries out performance test, and the result is as shown in table 4, and table 4 is the test result that the embodiment of the invention 5 and comparative example 5 obtain.
The test result that table 4 embodiment of the invention 5 and comparative example 5 obtain
Figure BDA00002308995500161
As can be seen from Table 4, the destarch rate of the fabric that method provided by the invention obtains is increased to 92.35%, compares traditional handicraft and has approximately improved 23.6%, this explanation, the fabric that method provided by the invention obtains has higher destarch rate, and has improved the mechanical property of fabric.
Embodiment 6
" turn over cloth and margin to seam, then the fabric that obtains is placed the gassing frame processing of singing, the parameter of described gassing frame arranges as follows: the speed of a motor vehicle is 135 ± 2m/min with the general comb of polyester cotton blending T65/C35 21S * 21S 108 * 5863; 1# burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2# burner air pressure is 29 ± 1mbar, gas pressure: 25 ± 1mbar.The mode of singing is to burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The process that the present invention will the obtain fabric of processing of singing places plasma processor to carry out Cement Composite Treated by Plasma, and the parameter of plasma machine arranges as follows: input voltage is 350V ~ 400V, and electric current is 75A ~ 85A; Power is 25KW ~ 30KW; Frequency is 20000 hertz ~ 25000 hertz; The speed of a motor vehicle is 35 ± 2m/min;
The fabric of the process Cement Composite Treated by Plasma that the present invention will obtain places to move back and boils rinsing combination machine and carry out destarch and process, and move back the running parameter that boils rinsing combination machine and arrange as follows: the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, with 93 ± 3 ℃ hot water wash, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the efficient destarch enzyme JN-160 of the component of following mass concentration: 3g/L and the bleeding agent CG of 1g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of fabric is processed.
The fabric that the above-mentioned destarch of the process that the present invention will obtain is processed carries out performance test, and the result shows that the fabric that method provided by the invention obtains has higher destarch rate.
Comparative example 6
" turn over cloth and margin to seam, then the fabric that obtains is placed the gassing frame processing of singing, the parameter of described gassing frame arranges as follows: the speed of a motor vehicle is 135 ± 2m/min with the general comb of polyester cotton blending T65/C35 21S * 21S 108 * 5863; 1# burner air pressure is that 29 ± 1mbar, gas pressure are 25 ± 1mbar; 2# burner air pressure is 29 ± 1mbar, gas pressure: 25 ± 1mbar.The mode of singing is to burning (two positive two is anti-); Natural pressure is 0.11 ± 0.01Mpa; The dryer steam pressure is 0.10 ± 0.05Mpa; The fire extinguishing box steam pressure is 0.02 ± 0.01Mpa; Padding machine pressure is 0.3 ± 0.05Mpa; Tension rack pressure is 0.25 ± 0.05Mpa so that the rank of singing of fabric be 4 grades and more than;
The singe fabric processed of the process that the present invention will obtain places to move back and boils rinsing combination machine and carry out destarch and process, and move back the running parameter that boils rinsing combination machine and arrange as follows: the speed of a motor vehicle is 60 ± 2m/min, and the time of banking up is 40min, and the crawler belt temperature is 99 ± 1 ℃.Hot water circuit with 93 ± 3 ℃ in the 1st ~ 2 lattice rinsing bowl is washed, in the 3rd lattice rinsing bowl, be that 80 ± 5 ℃ of hot water carry out circulating water wash with water temperature, in the 4th ~ 7 lattice rinsing bowl, with 93 ± 3 ℃ hot water wash, in the 8th lattice rinsing bowl, wash with 80 ± 5 ℃ hot water circuit.Destarch working solution temperature is 80 ± 5 ℃ in the hopper, the destarch working solution comprises the efficient destarch enzyme JN-160 of the component of following mass concentration: 3g/L and the bleeding agent CG of 3g/L, 1# ~ 2#, 4# ~ 7# roll applied pressure is 0.24 ± 0.02Mpa, the 3# nip pressure is 0.2 ± 0.02Mpa, high-capacity squeezer pressure is 3.5bar, water drain valve pressure 0.4 ± 0.1MPa, each rinsing bowl and drying cylinder tension rack pressure are 0.2 ± 0.1Mpa, cropping clot pressure is 0.5 ± 0.1Mpa; No. 2 groove adds the flow-control of water spinner flowmeter at 0.6 ± 0.1m 3/ h; No. 8 groove adds the flow-control of water spinner flowmeter at 0.9 ± 0.1m 3/ h, steam box scale window liquid level and pipe bent position keep level, finish the destarch of fabric is processed.
Compare by the result with embodiment 6, the result shows, the destarch rate of the fabric that method provided by the invention obtains has improved approximately 25%, and its mechanical property also is improved, this illustrates that method provided by the invention carries out destarch to fabric, destarch rate and the mechanical strength of fabric be can improve, the carrying out of follow-up dyeing and finishing technology and the dyeing and finishing level of raising fabric are conducive to.
As seen from the above embodiment, the invention provides a kind of desizing method of fabric, may further comprise the steps: a) pending fabric is carried out Cement Composite Treated by Plasma; B) fabric that described step a) is obtained carries out destarch to be processed.Before the present invention carries out destarch with pending fabric, it is carried out Cement Composite Treated by Plasma, high energy particle produces corrasion to the textile fabric surface in the plasma, make the continuous covering state of fiber spreading mass and wax oxidized and destroy, the strand of slurry is cut off, serosa surface forms hole and crack, is conducive to caustic soda and infiltrates; Plasma is introduced the hydrophilic radicals such as hydroxyl, carboxyl simultaneously, and the caustic soda Fast-swelling decomposes slurry, and the slurry solubility is improved, and contains the more wax of c h bond also oxidized, and the C=O linkage content is increased, and impurity is easy to be removed; Cement Composite Treated by Plasma can also be carried out chemical modification to fiber surface: can generate ion and free group at fiber surface, the crystal region of the large molecular surface of fiber and the ratio of amorphous region are changed, thereby change water imbibition and the permeability of fiber surface.Because of above-mentioned reason, when containing caustic soda in the destarch working solution that adopts, lower NaOH consumption just can make the water imbibition of COTTON FABRIC obtain larger raising, is conducive to fabric and realizes cleaning destarch.Experimental result shows, desizing method provided by the invention can reach more than 85% the destarch rate of fabric, has guaranteed the quality of fabric in follow-up printing and dyeing, and has improved the feel of fabric, has improved level in kind.
The above only is preferred embodiment of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (10)

1. the desizing method of a fabric may further comprise the steps:
A) pending fabric is carried out Cement Composite Treated by Plasma;
B) fabric that described step a) is obtained carries out destarch to be processed.
2. method according to claim 1 is characterized in that, the frequency of described step a) Cement Composite Treated by Plasma applying plasma is 18000 hertz ~ 25000 hertz.
3. method according to claim 1 is characterized in that, the electrode in the described step a) Cement Composite Treated by Plasma and the distance between fabric are 1mm ~ 5mm.
4. method according to claim 1 is characterized in that, the number of times that described step a) applying plasma is processed is 5 times ~ 10 times.
5. method according to claim 4 is characterized in that, the number of times that described step a) applying plasma is processed is that the fabric positive and negative respectively carries out 5 times ~ 10 times.
6. method according to claim 1 is characterized in that, the sparking electrode that described step a) applying plasma is processed is 15 ~ 20.
7. method according to claim 1 is characterized in that, the speed of fabric is 25m/min ~ 50m/min in the described step a) Cement Composite Treated by Plasma.
8. method according to claim 1 is characterized in that, described step b) is specially:
B1) fabric that described step a) is obtained carries out the processing of the first hot water wash successively, the room temperature washing is processed and the first squezzing is processed;
B2) with described step b1) fabric that obtains immerses and carries out destarch in the destarch working solution and process;
B3) with described step b2) fabric that obtains rolls successively that material, decatize are processed, the second hot water wash is processed and the second squezzing is processed.
9. method according to claim 8 is characterized in that, the temperature that described the first hot water wash is processed is 90 ℃ ~ 96 ℃;
The temperature that described the second hot water wash is processed is 93 ℃ ~ 95 ℃.
10. method according to claim 9 is characterized in that, the temperature of described decatize is 98 ℃ ~ 100 ℃;
The time of described decatize is 25min ~ 45min.
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