CN104674543A - Water-proof finishing process of cotton knitted fabric through dyeing and finishing at low temperature - Google Patents
Water-proof finishing process of cotton knitted fabric through dyeing and finishing at low temperature Download PDFInfo
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- CN104674543A CN104674543A CN201310637325.6A CN201310637325A CN104674543A CN 104674543 A CN104674543 A CN 104674543A CN 201310637325 A CN201310637325 A CN 201310637325A CN 104674543 A CN104674543 A CN 104674543A
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- 239000004744 fabric Substances 0.000 title claims abstract description 60
- 229920000742 Cotton Polymers 0.000 title claims abstract description 46
- 238000004043 dyeing Methods 0.000 title claims abstract description 42
- 238000007730 finishing process Methods 0.000 title claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 49
- 238000004078 waterproofing Methods 0.000 claims abstract description 23
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 15
- 238000001035 drying Methods 0.000 claims abstract description 4
- 230000000149 penetrating effect Effects 0.000 claims abstract 5
- 238000005096 rolling process Methods 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 238000004061 bleaching Methods 0.000 claims description 11
- 238000009991 scouring Methods 0.000 claims description 7
- 239000000344 soap Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 4
- 239000000985 reactive dye Substances 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims 2
- -1 neutralize Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 22
- 239000001814 pectin Substances 0.000 abstract description 7
- 229920001277 pectin Polymers 0.000 abstract description 7
- 235000010987 pectin Nutrition 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 7
- 230000002209 hydrophobic effect Effects 0.000 abstract description 2
- 238000007493 shaping process Methods 0.000 abstract description 2
- 238000012545 processing Methods 0.000 description 16
- 230000002940 repellent Effects 0.000 description 11
- 239000005871 repellent Substances 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 10
- 230000000740 bleeding effect Effects 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000002386 leaching Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 238000009940 knitting Methods 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000006392 deoxygenation reaction Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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Abstract
The invention provides a water-proof finishing process of a cotton knitted fabric through dyeing and finishing at low temperature. According to the technical formula of the water-proof finishing process, a 20-150g/L water-proofing agent, a 0-50g/L cross-linking agent, and a 0-5g/L penetrating agent are adopted; the water-proof finishing process comprises the steps of impregnating twice, rolling twice, drying and shaping at high temperature. The water-proof finishing process is specially used for the cotton knitted fabric after dyeing and finishing treatment at the low temperature, as the cotton knitted fabric after the dyeing and finishing treatment at the low temperature has natural hydrophobic substances such as cotton wax and pectin, the cotton knitted fabric has the natural waterproof effect; and besides, the later waterproof treatment is combined, and therefore, the cotton knitted fabric with the high water-proof finishing efficiency and the excellent waterproof effect can be acquired.
Description
Technical field
The present invention relates to a kind of water-proof finish technique of cotton fabrics, be specifically related to a kind of water-proof finish technique for the cotton fabrics after the process of whole process low-temperature dyeing and finishing processes.
Background technology
Traditional dyeing and finishing machining based conception is thought, cotton fiber, except cellulose, also contains wax, nitrogen substance, pectin, ash content, the natural commensal such as pigment, these natural commensals must all be removed in the stage of scouringing and bleaching, such requirement that could meet follow-up dyeing, Scouring and bleaching process generally adopts the chemical method of high temperature highly basic that fabric is processed 30-60 minute in the high temperature of 95-100 DEG C, passes through caustic soda, surfactant, the hydrolysis of the chemicals such as hydrogen peroxide, saponification, emulsification, washing, solubilising, oxidation and the physics chemical action such as dissolving are by above-mentioned natural commensal and other Impurity removals of attaching, under so strong chemical action, natural commensal (comprising useful cotton wax etc.) on cotton fiber is removed totally, so traditional handicraft power consumption is high, fabric loss is large, blowdown is serious, feel is coarse, cloth cover folding line and scratch are clearly, along with the continuous appearance of the policy of country in the energy and blowdown, the application limitation of traditional handicraft is more and more obvious, uses the pressure of dye-works in energy consumption and environmental protection of traditional handicraft also increasing, thus facilitates dyeing and finishing technology gradually to low energy consumption, low blowdown, high-quality, the future development of the low temperature process of high yield, in recent years, along with the knitting processing aid of cotton, the fast development of equipment, low temperature process and the processing of open width continous mode become topmost two development trends gradually.
Therefore, applicant proposed a kind of whole process low-temperature dyeing and finishing processing technology knitting for cotton, comprise low temperature and scouring and bleaching, (Chinese patent application: 201310113041.7) achieves and traditional handicraft quite even better processing effect low temperature soaping etc.The knitting whole process low-temperature dyeing and finishing processing technology of described cotton applies suitable low temperature process process, blowdown is also reduced while reduction energy consumption, natural materials on cotton fiber can be made to be fully used simultaneously, and then obtaining excellent feel, less weightlessness and desirable cloth cover effect, this is that conventional high temperature processing procedure cannot obtain; Only use low temperature pre-treatment, subsequent process high temperature process is also difficult to obtain.
Applicant finds in further research, and the knitting whole process low-temperature dyeing and finishing processing technology of described cotton remains the lyophobic dusts such as a large amount of cotton waxs and pectin in the process of process, thus makes fabric be provided with certain natural waterproof effect.
In order to reach better waterproof effect, applicant is a kind of special in this water-proof finish technique after low-temperature dyeing and finishing process with the cotton fabrics of the lyophobic dusts such as a large amount of cotton wax and pectin for exploitation further, makes the cotton fabrics through WATER REPELLENT TREATMENT have traditional processing mode and the unexistent high waterproof effect of fabric that obtains.
Therefore, have and need to provide a kind of newly, special water-proof finish technique for the cotton fabrics after low-temperature dyeing and finishing process, thus obtain the splendid cloth of a kind of waterproof effect.
Summary of the invention
The present invention aims to provide a kind of specially for the water-proof finish technique of the cotton fabrics after low-temperature dyeing and finishing process, thus obtains a kind of cloth with the waterproof effect that current common process cannot obtain.
In order to achieve the above object, the invention provides the water-proof finish technique of the cotton fabrics of the full low-temperature dyeing and finishing processing of a kind of warp,
The technical recipe of described water-proof finish technique is:
Waterproofing agent 20 ~ 150g/L
Crosslinking agent 0 ~ 50g/L
Bleeding agent 0 ~ 5g/L,
Two leachings two are rolled, 80 ~ 110 DEG C, high-temperature shaping after drying for 0.5 ~ 3 minute.
In an embodiment of the present invention, described waterproofing agent is fluorine-containing water repellent, and described bleeding agent is nonionic penetrant.
In an embodiment of the present invention, described waterproofing agent is waterproofing agent DM-3668, and described crosslinking agent is crosslinking agent DM-3523, and described bleeding agent is bleeding agent DM-1230.
In an embodiment of the present invention, the consumption of described waterproofing agent is preferably 20 ~ 150g/L; Be particularly preferably 60 ~ 120g/L.
In an embodiment of the present invention, described dosage of crosslinking agent is preferably 10 ~ 50g/L; Be particularly preferably 20 ~ 40g/L.
In an embodiment of the present invention, described bleeding agent consumption is preferably 1 ~ 3g/L; Be particularly preferably 2g/L.
In an embodiment of the present invention, the pressure condition that process is rolled in described two leachings two is 1 ~ 2kgf/cm
2.
In an embodiment of the present invention, the process conditions of described type-approval process are 150 ~ 180 DEG C, 60 ~ 180 seconds.
In a preferred embodiment of the present invention, the technical recipe of described water-proof finish technique is:
Waterproofing agent DM-3668 20 ~ 150g/L
Crosslinking agent DM-3523 0 ~ 50g/L
Bleeding agent DM-1230 0 ~ 5g/L,
Two leachings two are rolled, and pressure condition is 1 ~ 2kgf/cm
2; Then 80 ~ 110 DEG C, within 0.5 ~ 3 minute, dry; Final high temperature is shaped, and setting process condition is 150 ~ 180 DEG C, 60 ~ 180 seconds.
In a preferred embodiment of the present invention, provide the water-proof finish technique of the cotton fabrics of the full low-temperature dyeing and finishing processing of a kind of warp,
First described cotton fabrics is processed through full low-temperature dyeing and finishing, and described full low-temperature dyeing and finishing process comprises: low temperature is scouringed and bleaching, low temperature wash water, low temperature dyeing, low temperature soaping, wherein,
The technical recipe that described low temperature is scouringed and bleaching is:
Bath raio 1:5 ~ 20,10 ~ 30 DEG C enter cloth, and 2 DEG C/min are warmed up to 40 ~ 70 DEG C, are incubated 30 ~ 120 minutes, discharge opeing, 40 ~ 70 DEG C of wash waters 10 minutes, cold wash;
The technical recipe of described low temperature dyeing is:
REACTIVE DYES≤5.0%(O.W.F)
Na
2SO
410-50.0g/L
Na
2CO
35-20.0g/L
Bath raio 1:5 ~ 20,10 ~ 30 DEG C enter cloth, and 1 ~ 3 DEG C/min is warmed up to 40 ~ 70 DEG C, are incubated 30 ~ 80 minutes, discharge opeing, cold wash, and neutralization, soaps;
The technique of described low temperature soaping is:
Low temperature soaping agent DM-1542 0.2 ~ 2.0g/L
Bath raio 1:5 ~ 20,10 ~ 30 DEG C enter cloth, and 2 DEG C/min are warmed up to 40 ~ 70 DEG C, are incubated 10 ~ 30 minutes, discharge opeing, cold wash, obtain the cotton fabrics through dyeing and finishing processing;
Then, carry out WATER REPELLENT TREATMENT to the described cotton fabrics through dyeing and finishing processing, the technical recipe of described water-proof finish technique is:
Waterproofing agent DM-3668 20 ~ 150g/L
Crosslinking agent DM-3523 0 ~ 50g/L
Bleeding agent DM-1230 0 ~ 5g/L,
Two leachings two are rolled, and pressure condition is 1 ~ 2kgf/cm
2; Then 80 ~ 110 DEG C, within 0.5 ~ 3 minute, dry; Final high temperature is shaped, and setting process condition is 150 ~ 180 DEG C, 60 ~ 180 seconds.
It should be noted that, reagent described in the present invention is all have commercially available product, and wherein said waterproofing agent DM-3668, crosslinking agent DM-3523, bleeding agent DM-1230, high dense scouring agent DM-1361, Activation of Hydrogen Peroxide Solution agent DM-1430, low temperature soaping agent DM-1542 are the externally commercially available product of Guangdong Demei Fine Chemical Co., Ltd..
Water-proof finish technique of the present invention is specially for the cotton fabrics after low-temperature dyeing and finishing process, cotton fabrics after full low-temperature dyeing and finishing process is utilized to have the characteristic of natural waterproof effect because having the hydrophobicity natural materials such as cotton cured, pectin, again in conjunction with later stage WATER REPELLENT TREATMENT of the present invention, thus obtain the cotton fabrics that a kind of water-proof finish efficiency is high, waterproof effect is remarkable.
Detailed description of the invention
Be described in detail the present invention below in conjunction with embodiment, embodiment is intended to explain and non-limiting technical scheme of the present invention.
In the present embodiment, water-proof treatment technology of the present invention and traditional handicraft compare by applicant, so that remarkable beneficial effect of the present invention to be described.
In the present embodiment, following experiment material, medicine and instrument has mainly been used.
Experiment material
18.3tex combed cotton double knit grey cloth (grammes per square metre 180g/m
2, GuangZhou, China good name Textile Co., Ltd. weaves).
Medicine
High dense scouring agent DM-1361, Activation of Hydrogen Peroxide Solution agent DM-1430, hydrogen peroxide stabilizer DM-1404, low temperature soaping agent DM-1542, anti-staining soaping agent DM-1572, nonionic penetrant DM-1230, C8 waterproofing agent DM-3668, crosslinking agent DM-3523, above-mentioned auxiliary agent is Guangdong Demei Fine Chemical Co., Ltd. and produces and sell.
H
2o
2(AR, content 30%), NaOH(technical grade), Na
2sO
4(AR), Na
2cO
3(AR), above chemicals is produced by Guangdong Xilong Chemical Co., Ltd.
Instrument
Omnipotent type device for testing color (Xiamen Rapid Precision Machinery Co., Ltd.); Capillary effect tester (Shandong Textile Research Institute), HunterLab ultrascan VIS(1307) spectrophotometric color measurement instrument (U.S., HunterLab); YG026PC type imported electronic fabric strength tester (Instrument Ltd. is had an area of in Wenzhou); 5B-6(C) type three parameter determinator (connecting China Tech skill).
The water-proof finish technique of the cotton fabrics that 1.1 the present invention process through full low-temperature dyeing and finishing
Applicant first according to full low-temperature dyeing and finishing processing technology and water-proof finish technique of the present invention to experiment material 18.3tex combed cotton double knit grey cloth.Concrete technology flow process is: low temperature is scouringed and bleaching → low temperature wash water → low temperature dyeing → low temperature soaping → WATER REPELLENT TREATMENT, wherein,
The technical recipe that described low temperature is scouringed and bleaching is:
Bath raio 1:5 ~ 20,10 ~ 30 DEG C enter cloth, and 2 DEG C/min are warmed up to 40 ~ 70 DEG C, are incubated 30 ~ 120 minutes, discharge opeing, 40 ~ 70 DEG C of wash waters 10 minutes, cold wash;
The technical recipe of described low temperature dyeing is:
REACTIVE DYES≤5.0%(O.W.F)
Na
2SO
410-50.0g/L
Na
2CO
35-20.0g/L
Bath raio 1:5 ~ 20,10 ~ 30 DEG C enter cloth, and 1 ~ 3 DEG C/min is warmed up to 40 ~ 70 DEG C, are incubated 30 ~ 80 minutes, discharge opeing, cold wash, and neutralization, soaps;
The technique of described low temperature soaping is:
Low temperature soaping agent DM-1542 0.2 ~ 2.0g/L
Bath raio 1:5 ~ 20,10 ~ 30 DEG C enter cloth, and 2 DEG C/min are warmed up to 40 ~ 70 DEG C, are incubated 10 ~ 30 minutes, discharge opeing, cold wash, obtain the cotton fabrics through dyeing and finishing processing;
Then, carry out WATER REPELLENT TREATMENT to the described cotton fabrics through dyeing and finishing processing, the technical recipe of described water-proof finish technique is:
Waterproofing agent DM-3668 20 ~ 150g/L
Crosslinking agent DM-3523 0 ~ 50g/L
Bleeding agent DM-1230 0 ~ 5g/L,
Two leachings two are rolled, and pressure condition is 2kgf/cm
2; Then 80 ~ 100 DEG C, within 0.5 ~ 3 minute, dry; Final high temperature is shaped, and setting process condition is 150 ~ 180 DEG C, 60 ~ 180 seconds.
The technical recipe of described water-proof finish technique specifically asks for an interview table 1.
The different process formula of water-proof finish technique in table 1 the present embodiment
The dyeing and finishing of 1.2 traditional handicrafts and waterproof technology
Secondly, applicant has also carried out dyeing and finishing and the waterproof technology of traditional handicraft.Technological process is: 98 DEG C of → 90 DEG C of wash water → 60 DEG C dyeing → 95 DEG C of → WATER REPELLENT TREATMENT of soaping of scouringing and bleaching, wherein,
1) scouring and bleaching for 98 DEG C
Bath raio 1:10,30 DEG C enter cloth, and 2 DEG C/min are warmed up to 98 DEG C, are incubated 45 minutes, cool to 80 DEG C, discharge opeing, 90 DEG C of wash waters 10 minutes, cold wash, neutralization, deoxygenation.
2) 60 DEG C of dyeing
Active red 3BS 2.0%(O.W.F)
Na
2SO
450.0g/L
Na
2CO
320.0g/L
Bath raio 1:10,30 DEG C enter cloth, and 2 DEG C/min are warmed up to 60 DEG C, are incubated 60 minutes, discharge opeing, cold wash, and neutralization, soaps.
3) soap for 95 DEG C
Anti-staining soaping agent DM-1572 1.0g/L
Bath raio 1:10,30 DEG C enter cloth, and 2 DEG C/min are warmed up to 95 DEG C, are incubated 20 minutes, discharge opeing, cold wash;
4) WATER REPELLENT TREATMENT
Carry out WATER REPELLENT TREATMENT to the described cotton fabrics through dyeing and finishing processing, the technical recipe of described water-proof finish technique is:
Waterproofing agent DM-3668 20 ~ 150g/L
Crosslinking agent DM-3523 0 ~ 50g/L
Two leachings two are rolled, and pressure condition is 1 ~ 2kgf/cm
2; Then 80 ~ 100 DEG C, within 0.5 ~ 3 minute, dry; Final high temperature is shaped, and setting process condition is 150 ~ 180 DEG C, 60 ~ 180 seconds.
The contrast of 1.3 techniques of the present invention and common process
Main test event and method
1. test event: 1.1 and 1.2 clothes obtained are not washed respectively, wash 1 time, wash 5 times, the water resistance of washing 10 times measures;
2. water resistance reference: GB/T5553-2007 surfactant waterproofing agent waterproof amylograph is tested;
3. washing methods:
Standard synthetic detergent 1g/L, bath raio 1:30,45 DEG C wash 12 minutes for wash water once, wash 60 minutes continuously for wash water 5 times, after discharge opeing, then wash 60 minutes continuously for wash water 10 times.
According to above-mentioned test event and method, applicant obtains following contrast form
The waterproof effect test result of table 2, present invention process and common process
Shown by the data of above table, without water-proof finish (blank), cloth specimen through full low temperature process process has certain waterproof effect, and can be washable 5 times, main cause is because the fabric of full low temperature process process remains a certain amount of hydrophobic cotton wax and pectin, there is natural waterproof effect, and the cloth specimen of traditional handicraft process do not possess waterproof effect completely.
Meanwhile, under the condition of the waterproofing agent of water-proof finish technique of the present invention containing identical amount on fabric, the waterproof effect of cloth is obviously better than technique of passing on Gong.Meanwhile, applicant finds in an experiment, in traditional handicraft, when waterproofing agent consumption reaches 3.8%(O.W.F) time, the waterproof effect of cloth has reached maximum water resistance 85 points, and the consumption continuing to increase waterproofing agent also cannot improve water resistance.
And utilize technique of the present invention, first be the efficiency that improve WATER REPELLENT TREATMENT, as can be seen from the table, technique of the present invention is when waterproofing agent consumption is less than traditional handicraft, the waterproof effect of cloth is significantly more than the maximum of traditional handicraft, and this just can reduce the use amount of waterproofing agent greatly, not only can reduce production cost, more can reduce the discharge of waste water, greatly to alleviate environmental pollution; Secondly, technique of the present invention also substantially increases the maximum water resistance of cotton fabrics, breaches the limiting value of traditional handicraft, has the effect of highly significant.
Water-proof finish technique of the present invention is specially for the cotton fabrics after low-temperature dyeing and finishing process, cotton fabrics after full low-temperature dyeing and finishing process is utilized to have the characteristic of natural waterproof effect because having the hydrophobicity natural materials such as cotton cured, pectin, again in conjunction with later stage WATER REPELLENT TREATMENT of the present invention, thus obtain the cotton fabrics that a kind of water-proof finish efficiency is high, waterproof effect is remarkable.
The present invention is described by above-mentioned related embodiment, but above-described embodiment is only enforcement example of the present invention.Must it is noted that published embodiment limit the scope of the invention.On the contrary, be contained in the spirit of claims and the amendment of scope and impartial setting to be included in scope of the present invention.
Claims (6)
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| CN201310637325.6A CN104674543A (en) | 2013-12-02 | 2013-12-02 | Water-proof finishing process of cotton knitted fabric through dyeing and finishing at low temperature |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310637325.6A CN104674543A (en) | 2013-12-02 | 2013-12-02 | Water-proof finishing process of cotton knitted fabric through dyeing and finishing at low temperature |
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| Publication Number | Publication Date |
|---|---|
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Family
ID=53310093
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105088800A (en) * | 2015-09-11 | 2015-11-25 | 无锡市长安曙光手套厂 | Low-temperature water-based water-proofing agent and production process thereof |
| CN106758232A (en) * | 2016-11-29 | 2017-05-31 | 广东德美高新材料有限公司 | Bafta special-purpose water-proof oil-proofing agent, preparation method and its bafta processed through full low-temperature dyeing and finishing |
| CN107829291A (en) * | 2017-10-10 | 2018-03-23 | 江苏拓福服装有限公司 | Waterproof shirt fabric |
| CN108998968A (en) * | 2018-06-28 | 2018-12-14 | 东莞市喜宝体育用品科技有限公司 | A kind of mould proof deodorizing antibiotic of gushet waterproof flies to knit vamp and its manufacture craft |
| CN110409183A (en) * | 2019-08-31 | 2019-11-05 | 三赢家居用品(河源)有限公司 | A kind of free-floride water-proof aagent and its methods for making and using same |
| CN110678601A (en) * | 2017-05-24 | 2020-01-10 | 仓敷纺绩株式会社 | Fiber assembly containing cellulose water-proof fiber, method for producing same, and fiber product |
| CN111118718A (en) * | 2019-12-31 | 2020-05-08 | 江苏东源纺织科技实业有限公司 | Production process of ice oxygen bar cool feeling bacteriostatic water-repellent fabric |
-
2013
- 2013-12-02 CN CN201310637325.6A patent/CN104674543A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105088800A (en) * | 2015-09-11 | 2015-11-25 | 无锡市长安曙光手套厂 | Low-temperature water-based water-proofing agent and production process thereof |
| CN106758232A (en) * | 2016-11-29 | 2017-05-31 | 广东德美高新材料有限公司 | Bafta special-purpose water-proof oil-proofing agent, preparation method and its bafta processed through full low-temperature dyeing and finishing |
| CN106758232B (en) * | 2016-11-29 | 2019-08-30 | 绍兴德美新材料有限公司 | Cotton fabric special-purpose water-proof oil-proofing agent, preparation method and its cotton fabric processed through full low-temperature dyeing and finishing |
| CN110678601A (en) * | 2017-05-24 | 2020-01-10 | 仓敷纺绩株式会社 | Fiber assembly containing cellulose water-proof fiber, method for producing same, and fiber product |
| CN107829291A (en) * | 2017-10-10 | 2018-03-23 | 江苏拓福服装有限公司 | Waterproof shirt fabric |
| CN108998968A (en) * | 2018-06-28 | 2018-12-14 | 东莞市喜宝体育用品科技有限公司 | A kind of mould proof deodorizing antibiotic of gushet waterproof flies to knit vamp and its manufacture craft |
| CN110409183A (en) * | 2019-08-31 | 2019-11-05 | 三赢家居用品(河源)有限公司 | A kind of free-floride water-proof aagent and its methods for making and using same |
| CN111118718A (en) * | 2019-12-31 | 2020-05-08 | 江苏东源纺织科技实业有限公司 | Production process of ice oxygen bar cool feeling bacteriostatic water-repellent fabric |
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Application publication date: 20150603 |