Disclosure of Invention
The invention aims to provide a preparation method of a long-acting anti-fouling fabric based on nanogel treatment, so as to solve the problems in the prior art.
In order to achieve the purpose, the invention provides the following technical scheme:
the long-acting anti-fouling fabric is mainly prepared by the following steps:
(1) self-making modified ground yarns; taking silk, placing the silk in a sodium carbonate solution for degumming treatment, standing and cooling to room temperature, collecting the degummed silk, then taking deionized water, calcium chloride, absolute ethyl alcohol and the degummed silk, stirring, mixing and dialyzing, centrifugally separating, collecting supernatant, carrying out rotary concentration to obtain regenerated silk fibroin particles, stirring and mixing the regenerated silk fibroin particles, collagen particles and hexafluoroisopropanol, placing the mixture in a room temperature, stirring and mixing to obtain spinning solution, carrying out electrostatic spinning, collecting spinning fibers, and obtaining modified filling fibers;
(2) weaving ground yarns and surface yarns into a base fabric: the surface yarn is combed cotton spun yarn, and the modified filling fiber and the combed cotton spun yarn are woven to obtain a base fabric;
(3) preparing the long-acting anti-fouling fabric by treating the nano gel solution: taking deionized water, hydrochloric acid and ethyl orthosilicate, carrying out ultrasonic oscillation, stirring and mixing to obtain sol base fluid, stirring and mixing collagen fibers and hexafluoroisopropanol, collecting mixed liquor, carrying out electrostatic spinning, collecting spinning fibers, adding the collagen fibers into the sol base fluid according to the mass ratio of 1:15, grinding and dispersing through a screen, collecting nano gel fluid, soaking the prepared base fabric into the nano gel fluid, carrying out two-time soaking and two-time rolling, placing in a drying device, carrying out steam treatment by using a glutaraldehyde solution, carrying out hot press molding, standing and cooling to room temperature to complete nano gel fluid treatment, wherein collagen fibers are loaded in the nano gel fluid.
The further preferred scheme is as follows: the self-made modified ground yarn is prepared by the following steps:
(1) taking silk, placing the silk in a sodium carbonate solution with the mass fraction of 0.5% according to the mass ratio of 1:10, soaking, heating, boiling, degumming for 1-2 hours, standing, cooling to room temperature, filtering, collecting a filter cake, washing with deionized water for 3-5 times, performing vacuum drying, collecting the degummed silk, respectively weighing 45-50 parts by weight of deionized water, 3-6 parts by weight of calcium chloride, 5-10 parts by weight of absolute ethyl alcohol and 10-15 parts by weight of degummed silk, placing the degummed silk in a beaker, stirring, mixing, stirring and dissolving at 75-80 ℃, collecting a dissolving solution, performing dialysis treatment, after dialysis is completed, performing centrifugal separation, collecting a supernatant, and performing rotary concentration at 35-40 ℃ to 1/5 of the original volume to obtain regenerated silk fibroin particles; stirring and mixing regenerated silk fibroin particles, collagen particles and hexafluoroisopropanol, stirring and mixing at room temperature to obtain a spinning solution, adding the spinning solution into a glass injector, controlling the spinning voltage to be 15-17 kV, the spinning temperature to be 20-25 ℃, the humidity to be 55-65%, controlling the flow rate of the spinning solution to be 2-3 mL/h, the receiving distance to be 8-10 cm, carrying out electrostatic spinning, collecting spinning fibers, and carrying out vacuum drying for 3-5 h to obtain modified filling fibers;
(2) weaving the modified filling fiber and the combed cotton yarn with a plating weft plain stitch structure according to the mass ratio of 1:4, controlling the length of the surface yarn to be 120mm/50 coils, controlling the length of the ground yarn coil to be 40mm/50 coils, and weaving to obtain the base fabric.
The further preferred scheme is as follows: the nano gel liquid treatment steps are as follows:
(1) respectively weighing 45-50 parts by weight of deionized water, 10-15 parts by weight of 0.05mol/L hydrochloric acid and 25-30 parts by weight of ethyl orthosilicate, placing the deionized water, the hydrochloric acid and the ethyl orthosilicate into a three-neck flask, stirring and mixing the deionized water, the hydrochloric acid and the ethyl orthosilicate, carrying out ultrasonic oscillation treatment, and carrying out heat preservation and stirring mixing at the temperature of 45-55 ℃ for 25-30 min to obtain sol base fluid;
(2) adding collagen fibers into the sol matrix solution according to the mass ratio of 1:15, stirring and mixing, placing in a mortar, grinding and dispersing for 10-15 min, screening, and collecting to obtain a nano gel solution;
(3) soaking the prepared matrix fabric into a nano gel liquid, soaking for two times and rolling for two times, controlling the rolling residual rate to be 70%, after rolling is finished, performing steam treatment on the fabric by using a glutaraldehyde solution for 6-8 hours in a drying device, collecting the steam-treated fabric, drying the fabric at 65-70 ℃ for 10-15 min, collecting the dried fabric, placing the dried fabric in an XLB-400 flat vulcanizing machine, controlling the hot pressing temperature to be 50-55 ℃ and the pressure to be 3-5 MPa, pressing for 3-5 s, standing and cooling to room temperature, and finishing the nano gel liquid treatment.
The further preferred scheme is as follows: the glutaraldehyde solution is a glutaraldehyde solution with the mass fraction of 20%.
The further preferred scheme is as follows: the spinning solution is prepared from the following components in percentage by mass 1: 2: 10, stirring and mixing the regenerated silk fibroin particles and the collagen particles with hexafluoroisopropanol.
The further preferred scheme is as follows: the screening treatment adopts a screen with the size of 0.28-0.30 mu m.
Compared with the prior art, the invention has the beneficial effects that:
(1) the technical scheme of the invention preferably adopts the silica gel material as the matrix gel processing material, because the silica sol is a colloidal solution with low viscosity, has good dispersibility, can be fully impregnated and filled in the interior of the fiber material, in particular to the fabric which is a porous substance with smooth and good cohesiveness on the surface, and can form a firm film by drying or sintering, the film forming temperature is low, and the firm film can not be dissolved in water or deteriorated once the film is formed, the sol is adsorbed on the surface of the material after being hydrolyzed, and then is adsorbed on the cotton fabric through the hydrogen bond action between the sol and the cotton fabric, so that the anti-fouling fabric is effectively coated and modified;
(2) the technical scheme of the invention aims at the preparation of the anti-fouling fabric and simultaneously improves the long-acting performance of the anti-fouling fabric, the technical scheme of the invention adds the mixed spinning of the fibroin and the collagen fiber in the matrix fabric, then adds the coating modification of the collagen fiber in the material gel treatment fluid, the collagen fiber and the composite fiber can be entangled, in the main entanglement phenomenon, the cotton fiber and the collagen fiber are mutually crossed and entangled and firstly play a skeleton role, the collagen fiber and the fibroin composite fiber form an entanglement network under the pressure action in the hot pressing process, simultaneously the formed fiber web is heated, the fiber in the fiber web deforms under the action of temperature and pressure, simultaneously along with the flowing and diffusion of fiber components, the deformed parts of the fiber are mutually contacted and diffused, the diffusion action is favorable for forming good adhesion, and the adhesion is formed on the surface of the fiber, the technical scheme of the invention adopts gel to coat, collagen fibers loaded in the gel are entangled with composite fibers in the fabric, and the composite fibers are subjected to crosslinking modification by glutaraldehyde solution, so that crosslinking reaction is realized and the degree of fibrosis is improved after the composite fibers are modified by glutaraldehyde steam, fibers with more fibroin content are converted from a spiral structure to a folded structure under the crosslinking action, the crystallinity is increased, the mechanical property of the crosslinked fiber composite material is more excellent, three-dimensional entanglement and effective adhesion are formed in the modification of the fibers and the gel coated in the fabric, the long-acting performance of the gel film material on the surface of the anti-fouling fabric is further improved, and the long-acting anti-fouling performance of the gel film material is further improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Respectively weighing 45-50 parts by weight of deionized water, 10-15 parts by weight of 0.05mol/L hydrochloric acid and 25-30 parts by weight of ethyl orthosilicate, placing the deionized water, the hydrochloric acid and the ethyl orthosilicate into a three-neck flask, stirring and mixing the deionized water, the hydrochloric acid and the ethyl orthosilicate, carrying out ultrasonic oscillation treatment, and carrying out heat preservation and stirring mixing at the temperature of 45-55 ℃ for 25-30 min to obtain sol base fluid; taking silk, placing the silk in a sodium carbonate solution with the mass fraction of 0.5% according to the mass ratio of 1:10, soaking, heating, boiling, degumming for 1-2 hours, standing, cooling to room temperature, filtering, collecting a filter cake, washing with deionized water for 3-5 times, performing vacuum drying, collecting the degummed silk, respectively weighing 45-50 parts by weight of deionized water, 3-6 parts by weight of calcium chloride, 5-10 parts by weight of absolute ethyl alcohol and 10-15 parts by weight of degummed silk, placing the degummed silk in a beaker, stirring, mixing, stirring and dissolving at 75-80 ℃, collecting a dissolving solution, performing dialysis treatment, after dialysis is completed, performing centrifugal separation, collecting a supernatant, and performing rotary concentration at 35-40 ℃ to 1/5 of the original volume to obtain regenerated silk fibroin particles; according to the mass ratio of 1: 2: 10, stirring and mixing regenerated silk fibroin particles, collagen particles and hexafluoroisopropanol, placing the mixture in a room temperature, stirring and mixing to obtain a spinning solution, adding the spinning solution into a glass injector, controlling the spinning voltage to be 15-17 kV, the spinning temperature to be 20-25 ℃, the humidity to be 55-65%, simultaneously controlling the flow rate of the spinning solution to be 2-3 mL/h and the receiving distance to be 8-10 cm, carrying out electrostatic spinning, collecting spinning fibers, and carrying out vacuum drying for 3-5 h to obtain modified filling fibers; stirring and mixing the collagen fibers and hexafluoroisopropanol according to the mass ratio of 1:5, collecting a mixed solution, adding the mixed solution into a glass injector, controlling the spinning voltage to be 12-15 kV, the flow rate of a spinning solution to be 2-3 mL/h and the receiving distance to be 9-10 cm, carrying out electrostatic spinning, collecting the spinning fibers, and carrying out vacuum drying for 2-3 h to obtain the collagen fibers; adding collagen fibers into the sol matrix solution according to the mass ratio of 1:15, stirring and mixing, placing in a mortar, grinding and dispersing for 10-15 min, sieving with a 0.28-0.30 mu m sieve, and collecting to obtain a nano gel solution; taking combed cotton spun yarn and weaving by using a yarn adding weft plain stitch structure, feeding the yarn in a plating mode, weaving, controlling self-made modified ground yarn to be 1:4 in a mass ratio, weaving the modified filling fiber and the combed cotton spun yarn, controlling the length of the face yarn to be 120mm/50 coils, controlling the length of the ground yarn coil to be 40mm/50 coils, and weaving to obtain a base fabric; soaking the prepared substrate fabric into a nano gel solution, soaking and rolling for two times, controlling the rolling residual rate to be 70%, after rolling is finished, performing steam treatment on the fabric by adopting a glutaraldehyde solution with the mass fraction of 20% in a drying device for 6-8 hours, collecting the steam-treated fabric, drying the fabric at 65-70 ℃ for 10-15 min, collecting the dried fabric, placing the dried fabric in an XLB-400 flat vulcanizing machine, controlling the hot pressing temperature to be 50-55 ℃ and the pressure to be 3-5 MPa, pressing for 3-5 s, standing and cooling to room temperature to obtain the long-acting anti-fouling fabric based on nano gel treatment.
Example 1
Respectively weighing 45 parts of deionized water, 10 parts of 0.05mol/L hydrochloric acid and 25 parts of ethyl orthosilicate in parts by weight, placing the deionized water, the 10 parts of 0.05mol/L hydrochloric acid and the 25 parts of ethyl orthosilicate into a three-neck flask, stirring and mixing the mixture, carrying out ultrasonic oscillation treatment, and carrying out heat preservation and stirring mixing at 45 ℃ for 25min to obtain sol base fluid; taking silk, placing the silk in a sodium carbonate solution with the mass fraction of 0.5% according to the mass ratio of 1:10, soaking, heating, boiling, degumming for 1h, standing, cooling to room temperature, filtering, collecting a filter cake, washing with deionized water for 3 times, performing vacuum drying, collecting the degummed silk, respectively weighing 45 parts of deionized water, 3 parts of calcium chloride, 5 parts of absolute ethyl alcohol and 10 parts of degummed silk by weight, placing the materials in a beaker, stirring, mixing, stirring and dissolving at 75 ℃, collecting a dissolved solution, performing dialysis treatment, after the dialysis is finished, performing centrifugal separation, collecting supernatant, and performing rotary concentration at 35 ℃ to 1/5 of the original volume to obtain regenerated silk fibroin particles; according to the mass ratio of 1: 2: 10, stirring and mixing regenerated silk fibroin particles, collagen particles and hexafluoroisopropanol, placing the mixture in a room temperature, stirring and mixing to obtain a spinning solution, adding the spinning solution into a glass injector, controlling the spinning voltage to be 15kV, the spinning temperature to be 20 ℃, the humidity to be 55%, simultaneously controlling the flow rate of the spinning solution to be 2mL/h and the receiving distance to be 8cm, carrying out electrostatic spinning, collecting spinning fibers, and carrying out vacuum drying for 3h to obtain modified filling fibers; stirring and mixing the collagen fibers and hexafluoroisopropanol according to the mass ratio of 1:5, collecting a mixed solution, adding the mixed solution into a glass syringe, controlling the spinning voltage to be 12kV, the flow rate of a spinning solution to be 2mL/h, the receiving distance to be 9cm, carrying out electrostatic spinning, collecting spinning fibers, and carrying out vacuum drying for 2h to obtain the collagen fibers; adding collagen fibers into the sol matrix solution according to the mass ratio of 1:15, stirring and mixing, placing in a mortar, grinding and dispersing for 10min, sieving by a 0.28-micron sieve, and collecting to obtain a nano gel solution; taking combed cotton spun yarn and weaving by using a yarn adding weft plain stitch structure, feeding the yarn in a plating mode, weaving, controlling self-made modified ground yarn to be 1:4 in a mass ratio, weaving the modified filling fiber and the combed cotton spun yarn, controlling the length of the face yarn to be 120mm/50 coils, controlling the length of the ground yarn coil to be 40mm/50 coils, and weaving to obtain a base fabric; soaking the prepared substrate fabric into a nano gel solution, soaking and rolling for two times, controlling the rolling residual rate to be 70%, after rolling is finished, performing steam treatment on the fabric by adopting a glutaraldehyde solution with the mass fraction of 20% in a drying device for 6-8 hours, collecting the steam-treated fabric, drying the fabric at 65 ℃ for 10min, collecting the dried fabric, placing the dried fabric in an XLB-400 flat vulcanizing machine, controlling the hot pressing temperature to be 50 ℃ and the pressure to be 3MPa, pressing for 3s, standing and cooling to room temperature, and thus obtaining the long-acting anti-fouling fabric based on nano gel treatment.
Example 2
Respectively weighing 47 parts by weight of deionized water, 12 parts by weight of 0.05mol/L hydrochloric acid and 27 parts by weight of ethyl orthosilicate, placing the deionized water, the 12 parts by weight of 0.05mol/L hydrochloric acid and the 27 parts by weight of ethyl orthosilicate into a three-neck flask, stirring and mixing the mixture, carrying out ultrasonic oscillation treatment, and carrying out heat preservation, stirring and mixing at 47 ℃ for 27min to obtain sol base fluid; taking silk, placing the silk in a sodium carbonate solution with the mass fraction of 0.5% according to the mass ratio of 1:10, soaking, heating, boiling, degumming for 1h, standing, cooling to room temperature, filtering, collecting a filter cake, washing with deionized water for 4 times, performing vacuum drying, collecting the degummed silk, respectively weighing 47 parts of deionized water, 4 parts of calcium chloride, 7 parts of absolute ethyl alcohol and 12 parts of degummed silk by weight, placing the materials in a beaker, stirring, mixing, stirring and dissolving at 77 ℃, collecting a dissolved solution, performing dialysis treatment, after the dialysis is finished, performing centrifugal separation, collecting supernatant, and performing rotary concentration at 37 ℃ to 1/5 of the original volume to obtain regenerated silk fibroin particles; according to the mass ratio of 1: 2: 10, stirring and mixing regenerated silk fibroin particles, collagen particles and hexafluoroisopropanol, placing the mixture in a room temperature, stirring and mixing to obtain a spinning solution, adding the spinning solution into a glass injector, controlling the spinning voltage to be 16kV, the spinning temperature to be 22 ℃, the humidity to be 60%, simultaneously controlling the flow rate of the spinning solution to be 2mL/h and the receiving distance to be 9cm, carrying out electrostatic spinning, collecting spinning fibers, and carrying out vacuum drying for 4h to obtain modified filling fibers; stirring and mixing the collagen fibers and hexafluoroisopropanol according to the mass ratio of 1:5, collecting a mixed solution, adding the mixed solution into a glass syringe, controlling the spinning voltage to be 13kV, the flow rate of a spinning solution to be 2mL/h, the receiving distance to be 10cm, carrying out electrostatic spinning, collecting spinning fibers, and carrying out vacuum drying for 2h to obtain the collagen fibers; adding collagen fibers into the sol matrix solution according to the mass ratio of 1:15, stirring and mixing, placing in a mortar, grinding and dispersing for 12min, sieving by a 0.29 mu m sieve, and collecting to obtain a nano gel solution; taking combed cotton spun yarn and weaving by using a yarn adding weft plain stitch structure, feeding the yarn in a plating mode, weaving, controlling self-made modified ground yarn to be 1:4 in a mass ratio, weaving the modified filling fiber and the combed cotton spun yarn, controlling the length of the face yarn to be 120mm/50 coils, controlling the length of the ground yarn coil to be 40mm/50 coils, and weaving to obtain a base fabric; soaking the prepared substrate fabric into a nano gel solution, soaking and rolling for two times, controlling the rolling residual rate to be 70%, after rolling is finished, performing steam treatment on the fabric by adopting a glutaraldehyde solution with the mass fraction of 20% for 7 hours in a drying device, collecting the steam-treated fabric, drying the fabric at 67 ℃ for 12min, collecting the dried fabric, placing the dried fabric in an XLB-400 flat vulcanizing machine, controlling the hot pressing temperature to be 52 ℃ and the pressure to be 4MPa, pressing for 4s, standing and cooling to room temperature, and thus obtaining the long-acting anti-fouling fabric based on nano gel treatment.
Example 3
Respectively weighing 50 parts by weight of deionized water, 15 parts by weight of 0.05mol/L hydrochloric acid and 30 parts by weight of ethyl orthosilicate, placing the deionized water, the 15 parts by weight of 0.05mol/L hydrochloric acid and the 30 parts by weight of ethyl orthosilicate into a three-neck flask, stirring and mixing the mixture, carrying out ultrasonic oscillation treatment, and carrying out heat preservation and stirring mixing at 55 ℃ for 30min to obtain sol base fluid; taking silk, placing the silk in a sodium carbonate solution with the mass fraction of 0.5% according to the mass ratio of 1:10, soaking, heating, boiling, degumming for 2 hours, standing, cooling to room temperature, filtering, collecting a filter cake, washing with deionized water for 5 times, performing vacuum drying, collecting the degummed silk, respectively weighing 50 parts by weight of deionized water, 6 parts by weight of calcium chloride, 10 parts by weight of absolute ethyl alcohol and 15 parts by weight of the degummed silk, placing the materials in a beaker, stirring, mixing, stirring and dissolving at 80 ℃, collecting a dissolved solution, performing dialysis treatment, after the dialysis is completed, performing centrifugal separation, collecting supernatant, and performing rotary concentration at 40 ℃ to 1/5 of the original volume to obtain regenerated silk fibroin particles; according to the mass ratio of 1: 2: 10, stirring and mixing the regenerated silk fibroin particles, the collagen particles and hexafluoroisopropanol, stirring and mixing at room temperature to obtain a spinning solution, adding the spinning solution into a glass injector, controlling the spinning voltage to be 17kV, the spinning temperature to be 25 ℃, the humidity to be 65%, simultaneously controlling the flow rate of the spinning solution to be 3mL/h and the receiving distance to be 10cm, carrying out electrostatic spinning, collecting spinning fibers, and carrying out vacuum drying for 5h to obtain modified filling fibers; stirring and mixing the collagen fibers and hexafluoroisopropanol according to the mass ratio of 1:5, collecting a mixed solution, adding the mixed solution into a glass syringe, controlling the spinning voltage to be 15kV, the flow rate of a spinning solution to be 3mL/h, the receiving distance to be 10cm, carrying out electrostatic spinning, collecting spinning fibers, and carrying out vacuum drying for 3h to obtain the collagen fibers; adding collagen fibers into the sol matrix solution according to the mass ratio of 1:15, stirring and mixing, placing in a mortar, grinding and dispersing for 15min, sieving by a 0.30 mu m sieve, and collecting to obtain a nano gel solution; taking combed cotton spun yarn and weaving by using a yarn adding weft plain stitch structure, feeding the yarn in a plating mode, weaving, controlling self-made modified ground yarn to be 1:4 in a mass ratio, weaving the modified filling fiber and the combed cotton spun yarn, controlling the length of the face yarn to be 120mm/50 coils, controlling the length of the ground yarn coil to be 40mm/50 coils, and weaving to obtain a base fabric; soaking the prepared substrate fabric into a nano gel solution, soaking and rolling for two times, controlling the rolling residual rate to be 70%, after rolling is finished, performing steam treatment on the fabric by adopting a glutaraldehyde solution with the mass fraction of 20% in a drying device for 8 hours, collecting the steam-treated fabric, drying the fabric at 70 ℃ for 15min, collecting the dried fabric, placing the dried fabric in an XLB-400 flat vulcanizing machine, controlling the hot pressing temperature to be 55 ℃ and the pressure to be 5MPa, pressing for 5s, standing and cooling to room temperature, and thus obtaining the long-acting anti-fouling fabric based on nano gel treatment.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
The technical scheme of the invention, namely the embodiment 1, the embodiment 2 and the embodiment 3, is compared with a control group for test.
The technical scheme adopted by the control group 1 is that the ground yarns without the modified filling fibers and the matrix sol solution are made into composite fabrics without collagen fibers;
the technical scheme adopted by the control group 2 is that the composite fabric prepared by collagen fibers is not added into the matrix sol solution;
the experimental steps are as follows:
(1) the materials of the above-mentioned examples and the control group were respectively subjected to washing treatment under the condition of AATCC61A-2003, followed by drying treatment, and after the drying, the weight was measured, and the gel retention rate after the modification of the fabric was measured.
(2) The contact angle was measured at room temperature using an optical contact angle measuring instrument, and the contact angle was measured after 5. mu.L of distilled water was dropped onto the surface of the sample for 15 seconds.
(1) As can be seen from the above table, after the fabric material prepared by the invention is soaped for 5 times, the retention rate of the fabric material prepared by the invention is obviously improved compared with that of a composite fabric prepared by ground yarns and matrix sol solution without adding modified filling fibers, and simultaneously, the retention rate of the fabric material prepared by the invention is better than that of a composite fabric prepared by collagen fibers without adding, so that the technical scheme of the invention adopts the technical scheme that the collagen fibers and the fibroin composite fibers firstly form an entangled network under the action of pressure in the hot pressing process, and the formed fiber web is heated, so that the fibers in the fiber web deform under the action of temperature and pressure, and simultaneously along with the flowing and diffusion of fiber components, the deformed parts of the fibers are mutually contacted and diffused, and the diffusion is favorable for forming good adhesion, and the long-acting performance of the material is effectively improved through the adhesion formed on the surfaces of the fibers;
(2) the above table shows that the fabric material prepared by the invention has good water repellency and anti-fouling performance before and after washing, and meanwhile, the control group material also shows excellent anti-fouling performance, because the silica gel material is adopted as the matrix gel processing material in the technical scheme of the invention, the silica sol is a colloidal solution with low viscosity and good dispersibility, can be fully impregnated and filled in the fiber material, can be adsorbed to the surface of the material after hydrolysis, can be adsorbed on a cotton fabric through the hydrogen bond action between the silica sol and the cotton fabric, and can be effectively coated and modified to form the anti-fouling fabric, so that the material has excellent and durable anti-fouling performance.