CN102433777A - Preparation method of cold migration printing gum and color paste thereof - Google Patents
Preparation method of cold migration printing gum and color paste thereof Download PDFInfo
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- CN102433777A CN102433777A CN2011103644628A CN201110364462A CN102433777A CN 102433777 A CN102433777 A CN 102433777A CN 2011103644628 A CN2011103644628 A CN 2011103644628A CN 201110364462 A CN201110364462 A CN 201110364462A CN 102433777 A CN102433777 A CN 102433777A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
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Abstract
The invention discloses a preparation method of cold migration printing gum and color paste thereof. The gum contains starch oxide, printing oil and etherified starch. The cold migration printing gum has high water dissolving speed, and can be used for rapidly carrying a dye and transferring onto the surface of a fabric by being contacted with the fabric treated with a pretreatment liquid in the cold migration printing process. A film formed by drying color paste prepared from the gum has high elasticity, printing patterns can be effectively prevented from cracking, and meshes and ink cells are prevented from being blocked.
Description
Technical field
The printing gum that the present invention relates to use in the textile industry specifically is meant the compound method of a kind of cold-transfer printing thickener and mill base thereof.This cold-transfer printing is with the carrier of thickener as dyestuff; The print paste that is modulated into REACTIVE DYES or ACID DYES can be printed on the cold-transfer printing medium, and in the TRANSFER PRINTING process, decalcomania is transferred on the textile fabrics such as cotton, nylon from medium.
Background technology
Printing gum is meant and is added in the macromolecular compound that can play thickening power in the print paste.Cold-transfer printing technology at first will be printed on by the print paste that thickener and dyestuff constitute on the paper substrate; Formation has the transfer printing paper of required pattern or literal; Then with one side that dyestuff is arranged on this transfer printing paper and the driving fit of quilt seal fabric; Make dyestuff break away from or peel off through the pressure effect from paper substrate, and with the pattern on the transfer printing paper or words transfer printing to fabric.Thickener is a kind of liquid phase dispersion medium, is the carrier of dyestuff and stuffing, must have certain viscosity.The printing effect of thickener stamp and the print paste that constitutes by seal fabric, printing method and by thickener and dyestuff etc. have confidential relation.And key properties such as the rheological characteristic of print paste, shearing force, viscosity, viscosity, rate of drying depend on that former paste is the performance of thickener, so thickener plays crucial effects in the stamp process.Thickener in the TRANSFER PRINTING should be given certain viscosity and stamp characteristic as a kind of thickener of print paste, and after stamp, transfer, fixation process were accomplished, thickener can more easily be removed from fabric.In addition, thickener also plays the decentralized medium of each component such as dyestuff in the print paste and the effect of diluent, and the each component of printing gum can be evenly dispersed in the former paste.The thickener of conventional use mainly contains: seaweeds, comprise sodium alginate and alginic acid ester, and starch and cellulose modified class, modification guar gum class comprises the oxidation guar gum, etherificate guar gum, and acrylic compounds synthetic thickening agent.In view of the characteristics of cold-transfer printing technology, it is water-soluble fast to require thickener to have, so that when transfer printing, facilitate dyestuff to transfer on the fabric from paper fast; Because cold-transfer printing technology is that the flower type is printed on the paper, therefore also require to have good printing characteristic in addition.In order further to improve cold-transfer printing technology; Improve dye transfer rate and stamp product quality; And the cold-transfer printing that uses now is with the mill base of thickener and preparation thereof, and what have has obtained patent right, the instructions for use that not too meets my company that has; Therefore need a kind of novel cold-transfer printing thickener of exploitation, and have better printing and transferring properties.
Summary of the invention
In order to overcome the mill base of existing cold-transfer printing with thickener and preparation thereof; Obtained patent right because of what have, and the cold-transfer printing that has does not meet my company's instructions for use with thickener, so; The invention provides the compound method of a kind of cold-transfer printing thickener and mill base thereof; Can realize the water-soluble fast of cold-transfer printing thickener, and be suitable for being deployed into mill base and can be printed on the paper, can shift printing to smoothly by on the seal fabric.
The invention provides the compound method of a kind of cold-transfer printing thickener and mill base.
First aspect provides a kind of cold-transfer printing thickener, and its prescription according to percentage by weight is:
Oxidized starch 5-8%;
Stamp oil 0.5-1.5%;
Etherification starch 20-45%;
Adjust to 100% with deionized water.
Wherein said oxidized starch is hypochlorite oxidation starch or hydrogen peroxide oxidation starch or potassium permanganate oxidation starch or periodate oxidation starch; In dried starch, carboxyl mass fraction >=0.40% of said oxidized starch.Described stamp oil is selected the nonionic stamp oil of Ke Kai company for use for being the nonionic stamp oil of main component with the prosparol, or stamp similar with it oil.Said etherification starch is the low viscosity etherification starch, selects low viscosity hydroxyalkyl etherificate starch or low-viscosity carboxymethyl etherification starch for use; Said low viscosity is that with Brookfield viscometer per minute 20 transfer to tests, its viscosity is 20,000-50,000mPas under 25 ℃ of conditions with the former paste of the etherification starch of 10% weight (promptly 10% etherification starch and 90% system after the dried up abundant dissolving of going is called former paste).
The compound method of said cold-transfer printing thickener is:
The oxidized starch of 5-8% weight is put into container; Add 0.5-1.5% weight stamp oil and the etherification starch of 20-45% weight; Add deionized water again and fully stir after 100% weight, treat to dissolve fully with the system color all for the moment, promptly become the cold-transfer printing thickener.
Second aspect of the present invention provides the method for using above-mentioned cold-transfer printing paste formulation print paste.
Said cold-transfer printing paste formula according to percentage by weight is:
Cold-transfer printing thickener 30-55%;
Dyestuff 0.2-15%;
Reservehao S 0.5-1%;
Dispersant 0.1-8%;
Levelling agent 0.05-0.5%;
Water adjusts to 100%.
Wherein dyestuff can be selected REACTIVE DYES or ACID DYES for use; Dispersant is selected from methanonaphthalene sulfonic acid dispersant, or phenolic condensation compound sulfonate dispersant, or AEO silane type dispersant; Levelling agent is selected from the non-ionic surface active agent of alkane ether type, or aryl polyethenoxy ether sodium sulfate anion surfactant, or the two mixture.
The compound method of said cold-transfer printing mill base is:
The dyestuff that adds a small amount of cold water and 0.2-15% weight is in container, and the furnishing pasty state; The mixed liquor of the levelling agent of the reservehao S of the 0.5-1% weight that the adding dissolving is good then, the dispersant of 0.1-8% weight, 0.05-0.5% weight; Adding 85 ℃ of left and right sides warm water more fully dissolves dyestuff; Join after filtering in the cold-transfer printing thickener of 30-55% weight; And water stirs after adjusting to 100% weight, promptly makes the cold-transfer printing mill base.
Beneficial effect of the present invention is that oxidized starch has low viscosity, high solid dispersion property, minimum gelling.Because oxidized starch has been introduced carbonyl and carboxyl, make the retrogradation trend of amylose reduce to bottom line, thereby keep the stability of viscosity.And use cold-transfer printing thickener of the present invention and can form tough, clear, continuous films, more even than the film of acidified starch or ative starch thickener, the possibility of contraction and explosion still less.Use cold-transfer printing thickener of the present invention, its water-soluble speed is fast, in cold-transfer printing technology, and contacts through the pretreatment liquid fabric treated, can carry dye transfer fast to fabric face.Use the film that forms after the mill base drying of its allotment in addition and have good elasticity, can avoid printing the crackle of design effectively, and be applicable to the mode of printing of garden net, intaglio plate, gentle version, can avoid the obstruction of mesh or ink cell.
The specific embodiment
Followingly further specify the present invention, it should be noted that it is limitation of the present invention that these embodiment should not be regarded as with non-limiting example.
Embodiment 1
Be applicable to the cold-transfer printing thickener of vinyl-sulfone reactive dyes.
The percentage by weight that is applicable to the cold-transfer printing thickener each component of vinyl-sulfone reactive dyes is:
Hypochlorite oxidation starch accounts for 5% weight;
The triumphant PRINTOL S of section stamp oil accounts for 1.5% weight;
Low viscosity hydroxyalkyl etherificate starch accounts for 45% weight;
Adjust to 100% weight with deionized water.
The synthetic method of above-mentioned cold-transfer printing thickener:
Take above-mentioned 5% weight hypochlorite oxidation starch and put into container; The stamp oil and the 45% weight low viscosity hydroxyalkyl etherificate starch that add 1.5% weight Ke Kai company again; Add and fully stir after deionized water is adjusted to 100% weight; Treat to dissolve fully with the system color all for the moment, promptly become the cold-transfer printing thickener that is applicable to vinyl-sulfone reactive dyes.
Use the above-mentioned method that is applicable to the cold-transfer printing paste formulation print paste of vinyl-sulfone reactive dyes.
The cold-transfer printing paste formula according to percentage by weight is:
Above-mentioned cold-transfer printing thickener accounts for 55% weight;
Vinyl-sulfone reactive dyes accounts for 15% weight;
Reservehao S accounts for 1% weight;
Dispersant accounts for 7.5% weight;
Levelling agent accounts for 0.5% weight;
Water is adjusted to 100% weight.
Wherein the REACTIVE DYES consumption should be according to the allotment of the flower type design colours depth; The vinyl-sulfone reactive dyes of at present selecting for use accounts for 15% weight, and reservehao S is 1% weight, and dispersant dosage is 1/2nd of a REACTIVE DYES consumption; Be 7.5% weight; Dispersant is selected methanonaphthalene sulfonic acid dispersant for use, and levelling agent is selected aryl polyethenoxy ether sodium sulfate anion surfactant for use, is 0.5% weight.
The compound method of above-mentioned cold-transfer printing mill base is:
The vinyl-sulfone reactive dyes furnishing pasty state that adds a small amount of cold water and 15% weight; The mixed liquor of the aryl polyethenoxy ether sodium sulfate anion surfactant of the 1% weight reservehao S that the adding dissolving is good then, the methanonaphthalene sulfonic acid dispersant of 7.5% weight, 0.5% weight; Adding 85 ℃ of left and right sides warm water more fully dissolves dyestuff; Join after filtering in the cold-transfer printing thickener of 55% weight; And water stirs after adjusting to 100% weight, and the cold-transfer printing that promptly makes vinyl-sulfone reactive dyes is used mill base.
Embodiment 2
Be applicable to the cold-transfer printing thickener of symmetrical three pyridine type REACTIVE DYES.
Be applicable to the percentage by weight of the cold-transfer printing thickener each component of symmetrical three pyridine type REACTIVE DYES:
Hydrogen peroxide oxidation starch accounts for 6% weight;
The triumphant PRINTOL S-C of section stamp oil accounts for 1.2 weight %;
The low-viscosity carboxymethyl etherification starch accounts for 40% weight;
Adjust to 100% weight with deionized water.
The synthetic method of above-mentioned cold-transfer printing thickener:
Take above-mentioned 6% weight hydrogen peroxide oxidation starch; The Ke Kai company that adds 1.2% weight again produces stamp oil and 40% weight low-viscosity carboxymethyl etherification starch; Add and fully stir after deionized water is adjusted to 100% weight; Treat to dissolve fully with the system color all for the moment, promptly become the cold-transfer printing thickener that is applicable to symmetrical three pyridine type REACTIVE DYES.
Use the above-mentioned method that is applicable to the cold-transfer printing paste formulation print paste of symmetrical three pyridine type REACTIVE DYES.The cold-transfer printing paste formula according to percentage by weight is:
Above-mentioned cold-transfer printing thickener accounts for 30% weight;
Symmetry three pyridine type REACTIVE DYES account for 5% weight;
Reservehao S accounts for 0.5% weight;
Dispersant accounts for 2.5% weight;
Levelling agent accounts for 0.3% weight;
Water is adjusted to 100% weight.
Wherein the REACTIVE DYES consumption should be according to the allotment of the flower type design colours depth; The symmetry three pyridine type REACTIVE DYES of at present selecting for use are 5% weight, and reservehao S is 0.5% weight, and dispersant dosage is 1/2nd of a REACTIVE DYES consumption; Be 2.5% weight; Dispersant is selected phenolic condensation compound sulfonate dispersant for use, and levelling agent is 0.3% weight, selects the non-ionic surface active agent of alkane ether type and the mixture that aryl polyethenoxy ether sodium sulfate anion surfactant was modulated by weight 2: 1 for use.
The compound method of above-mentioned cold-transfer printing mill base is:
The symmetry three pyridine type REACTIVE DYES furnishing pasty states that add a small amount of cold water and 5% weight; The non-ionic surface active agent of the alkane ether type of the reservehao S of 0.5% weight that the adding dissolving is good then, the phenolic condensation compound sulfonate dispersant of 2.5% weight, 0.3% weight and aryl polyethenoxy ether sodium sulfate anion surfactant are by weight the mixture of modulation in 2: 1; Adding 85 ℃ of left and right sides warm water more fully dissolves dyestuff; Join after filtering in the cold-transfer printing thickener of 30% weight; And water stirs after adjusting to 100% weight, and the cold-transfer printing that promptly makes symmetrical three pyridine type REACTIVE DYES is used mill base.
Embodiment 3
Be applicable to the cold-transfer printing thickener of ACID DYES.
Be applicable to the percentage by weight of the cold-transfer printing thickener each component of ACID DYES:
Potassium permanganate oxidation starch accounts for 8% weight;
In the worker's ZG-338 of chemical industry Co., Ltd stamp oil of printing and dyeing account for 0.5% weight;
The low-viscosity carboxymethyl etherification starch accounts for 20% weight;
Adjust to 100% weight with deionized water.
The above-mentioned synthetic method that is applicable to the cold-transfer printing thickener of ACID DYES:
Take above-mentioned 8% weight potassium permanganate oxidation starch and put into container; The middle worker who adds 0.5% weight again the print and dye ZG-338 of chemical industry Co., Ltd stamp oil and 20% weight low-viscosity carboxymethyl etherification starch; Add and fully stir after deionized water is adjusted to 100% weight; Treat to dissolve fully with the system color all for the moment, promptly become the cold-transfer printing thickener that is applicable to vinyl-sulfone reactive dyes.
Use the above-mentioned method that is applicable to the preparation print paste of ACID DYES.The cold-transfer printing paste formula according to percentage by weight is:
Above-mentioned cold-transfer printing thickener accounts for 45% weight;
ACID DYES accounts for 10% weight;
Reservehao S accounts for 0.8% weight;
Dispersant accounts for 5% weight;
Levelling agent accounts for 0.2% weight;
Water is adjusted to 100% weight.
Wherein the ACID DYES consumption is according to the allotment of the flower type design colours depth; The ACID DYES of at present selecting for use is 10% weight, and reservehao S is 0.5% weight, and dispersant dosage is 1/2nd of an ACID DYES consumption; Be 5% weight; Select AEO silane type dispersant for use, levelling agent accounts for 0.2% weight, selects the non-ionic surface active agent of alkane ether type for use.
The compound method of above-mentioned cold-transfer printing mill base is:
The ACID DYES furnishing pasty state that adds a small amount of cold water and 10% weight; The mixed liquor of the alkane ether type non-ionic surface active agent of the 0.8% weight reservehao S that the adding dissolving is good then, the AEO silane type dispersant of 5% weight, 0.2% weight; Adding 85 ℃ of left and right sides warm water more fully dissolves dyestuff; Join after filtering in the cold-transfer printing thickener of 45% weight; And water stirs after adjusting to 100% weight, and the cold-transfer printing that promptly makes vinyl-sulfone reactive dyes is used mill base.
Among the foregoing description 1, embodiment 2 and the embodiment 3, carboxyl mass fraction >=0.40% of the oxidized starch of being selected for use; The low viscosity etherification starch of being selected for use, its low viscosity are with the former paste of the etherification starch of 10% weight, under 25 ℃ of conditions, use Brookfield viscometer, and with per minute 20 transfer to tests, its viscosity is 20,000-50,000mPas.
Claims (8)
1. a cold-transfer printing thickener is made up of oxidized starch, stamp oil, etherification starch and deionized water, it is characterized in that:
Said cold-transfer printing thickener according to each constituent content of percentage by weight is:
Oxidized starch accounts for 5-8% weight, and stamp oil accounts for 0.5-1.5% weight, and etherification starch accounts for 20-45% weight, adjusts to 100% weight with deionized water;
The oxidized starch of 5-8% weight is put into container; Add the stamp oil of 0.5-1.5% weight and the etherification starch of 20-45% weight; Add deionized water again and fully stir after 100% weight, treat to dissolve fully with the system color all for the moment, promptly become the cold-transfer printing thickener.
2. cold-transfer printing thickener according to claim 1 is characterized in that:
Carboxyl mass fraction >=0.40% of said oxidized starch; Select hypochlorite oxidation starch or hydrogen peroxide oxidation starch or potassium permanganate oxidation starch or periodate oxidation starch for use.
3. cold-transfer printing thickener according to claim 1 is characterized in that:
Said etherification starch is the low viscosity etherification starch, selects low viscosity hydroxyalkyl etherificate starch or low-viscosity carboxymethyl etherification starch for use; Said low viscosity is with the former paste of the etherification starch of 10% weight, under 25 ℃ of conditions, uses Brookfield viscometer, and with per minute 20 transfer to tests, its viscosity is 20,000-50,000mPas.
4. cold-transfer printing thickener according to claim 1 is characterized in that:
Said stamp oil is for the prosparol being the nonionic stamp oil of main component.
5. an application rights requires the color paste formulation method of 1 said cold-transfer printing thickener, it is characterized in that:
The mill base of said cold-transfer printing paste formulation according to each components contents of percentage by weight is:
Cold-transfer printing thickener slurry accounts for 30-55% weight, and dyestuff accounts for 0.2-15% weight, and reservehao S accounts for 0.5-1% weight, and dispersant accounts for 0.1-8% weight, and levelling agent accounts for 0.05-0.5% weight, and water is adjusted to 100% weight;
The dyestuff that adds low amounts of water and 0.2-15% weight is in container, and the furnishing pasty state; The mixed liquor of the levelling agent of the reservehao S of the 0.5-1% weight that the adding dissolving is good then, the dispersant of 0.1-8% weight, 0.05-0.5% weight; Adding 85 ℃ of left and right sides warm water more fully dissolves dyestuff; Join after the filtration in the cold-transfer printing thickener of 30-55% weight; Water stirs after adjusting to 100% weight again, promptly makes the cold-transfer printing mill base.
6. according to the compound method of the said print paste of claim 5, it is characterized in that:
Said dyestuff is selected REACTIVE DYES or ACID DYES for use.
7. according to the compound method of the said print paste of claim 5, it is characterized in that:
Said dispersant is selected from methanonaphthalene sulfonic acid dispersant or phenolic condensation compound sulfonate dispersant or AEO silane type dispersant.
8. according to the compound method of the said print paste of claim 5, it is characterized in that:
Said levelling agent is selected from the non-ionic surface active agent of alkane ether type, or aryl polyethenoxy ether sodium sulfate anion surfactant, or the two mixture.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110364462.8A CN102433777B (en) | 2011-11-17 | 2011-11-17 | Preparation method of cold migration printing gum and color paste thereof |
| TW101142940A TWI481761B (en) | 2011-11-17 | 2012-11-16 | Cold-transfer printing thicker and producing method for color paste thereof |
| PCT/CN2012/084758 WO2013071881A1 (en) | 2011-11-17 | 2012-11-16 | Cold transferring printing thickener and preparation method of color paste thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110364462.8A CN102433777B (en) | 2011-11-17 | 2011-11-17 | Preparation method of cold migration printing gum and color paste thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102433777A true CN102433777A (en) | 2012-05-02 |
| CN102433777B CN102433777B (en) | 2014-07-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110364462.8A Active CN102433777B (en) | 2011-11-17 | 2011-11-17 | Preparation method of cold migration printing gum and color paste thereof |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN102433777B (en) |
| TW (1) | TWI481761B (en) |
| WO (1) | WO2013071881A1 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013071881A1 (en) * | 2011-11-17 | 2013-05-23 | 长胜纺织科技发展(上海)有限公司 | Cold transferring printing thickener and preparation method of color paste thereof |
| CN103243582A (en) * | 2013-04-16 | 2013-08-14 | 杜芳莉 | Acidic levelling agent and preparation method thereof |
| CN104278565A (en) * | 2014-09-24 | 2015-01-14 | 无锡市东北塘宏良染色厂 | Transfer printing paste |
| CN105442355A (en) * | 2015-12-25 | 2016-03-30 | 罗莱生活科技股份有限公司 | Novel eight-color-separation fabric printing method |
| CN106245378A (en) * | 2016-08-17 | 2016-12-21 | 朱维 | A kind of polyhexamethylene adipamide compositions thickening agent |
| CN107385978A (en) * | 2017-08-11 | 2017-11-24 | 李月仙 | A kind of two-sided overlay film method for transfer printing |
| CN107869075A (en) * | 2017-12-20 | 2018-04-03 | 苏州润弘贸易有限公司 | Textile printing paste |
| CN108239888A (en) * | 2016-12-27 | 2018-07-03 | 长胜纺织科技发展(上海)有限公司 | With no paper method for transfer printing |
| CN115947923A (en) * | 2023-02-17 | 2023-04-11 | 广州山木新材料科技有限公司 | Waterborne polyurethane resin and digital pyrograph ink containing same |
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| CN108239887B (en) * | 2016-12-27 | 2020-07-31 | 长胜纺织科技发展(上海)有限公司 | Pretreatment method for plate-alignment liquid feeding |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013071881A1 (en) * | 2011-11-17 | 2013-05-23 | 长胜纺织科技发展(上海)有限公司 | Cold transferring printing thickener and preparation method of color paste thereof |
| CN103243582A (en) * | 2013-04-16 | 2013-08-14 | 杜芳莉 | Acidic levelling agent and preparation method thereof |
| CN104278565A (en) * | 2014-09-24 | 2015-01-14 | 无锡市东北塘宏良染色厂 | Transfer printing paste |
| CN105442355A (en) * | 2015-12-25 | 2016-03-30 | 罗莱生活科技股份有限公司 | Novel eight-color-separation fabric printing method |
| CN106245378A (en) * | 2016-08-17 | 2016-12-21 | 朱维 | A kind of polyhexamethylene adipamide compositions thickening agent |
| CN108239888A (en) * | 2016-12-27 | 2018-07-03 | 长胜纺织科技发展(上海)有限公司 | With no paper method for transfer printing |
| CN108239888B (en) * | 2016-12-27 | 2020-07-14 | 长胜纺织科技发展(上海)有限公司 | Paperless transfer printing method |
| CN107385978A (en) * | 2017-08-11 | 2017-11-24 | 李月仙 | A kind of two-sided overlay film method for transfer printing |
| CN107869075A (en) * | 2017-12-20 | 2018-04-03 | 苏州润弘贸易有限公司 | Textile printing paste |
| CN115947923A (en) * | 2023-02-17 | 2023-04-11 | 广州山木新材料科技有限公司 | Waterborne polyurethane resin and digital pyrograph ink containing same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102433777B (en) | 2014-07-23 |
| TW201323683A (en) | 2013-06-16 |
| WO2013071881A1 (en) | 2013-05-23 |
| TWI481761B (en) | 2015-04-21 |
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