CN106245378A - A kind of polyhexamethylene adipamide compositions thickening agent - Google Patents
A kind of polyhexamethylene adipamide compositions thickening agent Download PDFInfo
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- CN106245378A CN106245378A CN201610682148.7A CN201610682148A CN106245378A CN 106245378 A CN106245378 A CN 106245378A CN 201610682148 A CN201610682148 A CN 201610682148A CN 106245378 A CN106245378 A CN 106245378A
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- polyhexamethylene adipamide
- thickening agent
- bentonite
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5278—Polyamides; Polyimides; Polylactames; Polyalkyleneimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of polyhexamethylene adipamide compositions thickening agent, it is made up of following parts by weight component: polyhexamethylene adipamide 20 parts 30 parts, stannic hydroxide 2 parts 4 parts, sodium sulfite 1 part 1.5 parts, Oxytarch 10 parts 14 parts, bentonite 15 parts 25 parts, cross-linking agent 2 parts 10 parts, deionized water 100 parts 150 parts.Its preparation method is according to parts by weight mixing and stirring by the raw material in addition to polyhexamethylene adipamide and bentonite, adds the polyhexamethylene adipamide of bentonite and high temperature fused state after ebuillition of heated, and mixing stands.The thickening agent that the inventive method prepares paste producing rate compared with tradition thickening agent is high, when textile printing, mill base transitivity is good, high to color and there is preferable plasticity and adhesion strength, fabric feeling and color fastness are affected little, electrolyte res is tance is good simultaneously, preparation method is easy, environment-friendly high-efficiency.
Description
Technical field:
The present invention relates to printing assistant technical field, be specifically related to a kind of polyhexamethylene adipamide compositions thickening agent.
Background technology:
In technical field, printing thickening agent is broadly divided into natural thickener according to the difference of chemical constitution and synthesis increases at present
Thick dose, the former is mainly natural polysaecharides material, and such as starch, cellulosic plant glue and alginate jelly and derivant thereof, the latter is main
Including polyacrylic and emulsion thickening class thickening agent.
Natural polysaecharides thickening agent is all to be made up of natural polysaccharide and derivant thereof, and with a long history, category is numerous, Ji Hushi
For all of printing technology, but its stamp paste has not endurance of cutting viscosity simultaneously and is prone to the shortcoming declined, and when using
When pigment printing, there is also consumption big and in the high problem of fabric face residual quantity, affect PRINTED FABRIC feel and color is firm
Degree；Owing to there is substantial amounts of carboxyl in polypropylene type thickening agent, after alkali crowd closes, thickening agent viscosity can show in water on strand
Writing and increase, coloured light and feel to PRINTED FABRIC have little to no effect, but there is the shortcoming sensitive to electrolyte.Emulsion thickening
Class printing thickening agent is also called nation slurry A and is usually white thick concentrated emulsions, not only makes PRINTED FABRIC have good color bright and fresh
Gorgeous degree, stamp is dried send out mixed with kerosene in baking process and water simultaneously, and residual is few, to fabric feeling and color fastness almost without shadow
Ring, but being volatized in air due to oily substances such as kerosene, not only cause the waste of resource, and cause environment dirty
Dye, so having received strict restriction.
Summary of the invention:
It is an object of the invention to provide a kind of New stablization, use polyhexamethylene adipamide compositions to constitute, at fabric
During stamp application, mill base transitivity is good, high to color and have preferable plasticity and adhesion strength, to fabric feeling and color jail
Degree impact is little, and electrolyte res is tance is good simultaneously, and preparation method is easy, environment-friendly high-efficiency.
For achieving the above object, the present invention is by the following technical solutions:
A kind of polyhexamethylene adipamide compositions thickening agent, is made up of following parts by weight component:
Polyhexamethylene adipamide 20 parts-30 parts, stannic hydroxide 2 parts-4 parts, sodium sulfite 1 part-1.5 parts, Oxytarch
10 parts-14 parts, bentonite 15 parts-25 parts, cross-linking agent 2 parts-10 parts, deionized water 100 parts-150 parts.
Preferably, it is made up of following parts by weight component:
Polyhexamethylene adipamide 20 parts-28 parts, stannic hydroxide 2 parts-3 parts, sodium sulfite 1.5 parts, Oxytarch 11 parts-
14 parts, bentonite 17 parts-20 parts, cross-linking agent 5 parts-10 parts, deionized water 100 parts-150 parts.
Preferably, described Oxytarch is the starch using hypochlorite oxidation.
Preferably, described bentonite is hydrogen-based bentonite.
The preparation method of above-mentioned polyhexamethylene adipamide compositions thickening agent is will be except polyhexamethylene adipamide and bentonite
Outer raw material according to parts by weight mixing and stirring, add after ebuillition of heated bentonite and high temperature fused state poly-oneself two
The mixing of acyl hexamethylene diamine stands.
By above-mentioned polyhexamethylene adipamide compositions thickening agent, apply in dye printing.
Described polyhexamethylene adipamide compositions thickening agent interpolation percentage ratio in concentrator is 0.1-2%.
Polyhexamethylene adipamide is also known as polyamide, and for toughness cutin shape, translucent or creamy white crystals resin, often makes
Cylindrical pellets, the polyamide molecular weight being used as plastics is generally 1.5 ten thousand-2 ten thousand, and resistance to combustion, tensile strength is high, wear-resisting, electric insulation
Property good, heat-resisting, the mobility of molten resin is high, relative density 1.05-1.15, the most nontoxic.Maranyl goods are extensive
As various mechanically and electrically device parts, including bearing, gear, pulley impeller of pump, blade, high-pressure seal ring, pad, valve seat,
Lining, petroleum pipeline, oil container, rope, transmission band, emery wheel adhesive, battery case, electric apparatus coil, cable connector etc..Also has packaging
Yield with band, food grade film is the biggest.The application by under polyhexamethylene adipamide molten condition with other seethe with excitement component
Mixing standing prepares a kind of novel polyhexamethylene adipamide compositions thickening agent, this thickener molecule chain extension and being formed
Network structure, strengthens thickening power, and under electrostatic repulsion effect, macromolecular chain extends simultaneously, has thickening power, is formed
Clear viscous solution, absorbs a large amount of free moisture, promotes to contaminate on dyestuff, and tinctorial yield is high, good penetrability, and printing and dyeing are clear-cut,
Dry Sack is uniform, it is possible to overcomes tradition thickening agent in prior art to be had the disadvantage in that, is with a wide range of applications.
The method have the advantages that
1. the thickening agent that the inventive method prepares paste producing rate compared with tradition thickening agent is high, the mill base when textile printing
Transitivity is good, high to color and have preferable plasticity and adhesion strength.
After thickening agent application post-drying the most of the present invention, print paste can form certain elastic and resistance to ripple at fabric face
Property thin film, fabric feeling and color fastness are affected little, electrolyte res is tance is good simultaneously, and preparation method is easy, environment-friendly high-efficiency.
3. the present invention prepares one by mixing standing with other boiling components under polyhexamethylene adipamide molten condition
Novel polyhexamethylene adipamide compositions thickening agent, this thickening agent macromolecular chain extends and is formed network structure, strengthens thickening
Effect, under electrostatic repulsion effect, macromolecular chain extends simultaneously, has thickening power, forms clear viscous solution, absorbs
A large amount of free moistures, promote to contaminate on dyestuff, and tinctorial yield is high, and good penetrability, printing and dyeing are clear-cut, and Dry Sack is uniform, it is possible to overcome
In prior art, tradition thickening agent is had the disadvantage in that, is with a wide range of applications.
Detailed description of the invention:
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solving
Release the present invention, the present invention will not be constituted any restriction.
Embodiment one
A kind of polyhexamethylene adipamide compositions thickening agent, is made up of following parts by weight component:
Polyhexamethylene adipamide 20 parts, stannic hydroxide 2 parts, sodium sulfite 1 part, Oxytarch 10 parts, bentonite 15 parts,
Cross-linking agent 2 parts, deionized water 100 parts.
Embodiment two
A kind of polyhexamethylene adipamide compositions thickening agent, is made up of following parts by weight component:
Polyhexamethylene adipamide 30 parts, stannic hydroxide 4 parts, sodium sulfite 1.5 parts, Oxytarch 14 parts, bentonite 25
Part, cross-linking agent 10 parts, deionized water 150 parts.
Embodiment three
A kind of polyhexamethylene adipamide compositions thickening agent, is made up of following parts by weight component:
Polyhexamethylene adipamide 20 parts, stannic hydroxide 4 parts, sodium sulfite 1 part, Oxytarch 14 parts, bentonite 15 parts,
Cross-linking agent 10 parts, deionized water 100 parts.
A kind of polyhexamethylene adipamide compositions thickening agent, is made up of following parts by weight component:
Embodiment four
A kind of polyhexamethylene adipamide compositions thickening agent, is made up of following parts by weight component:
Polyhexamethylene adipamide 30 parts, stannic hydroxide 2 parts, sodium sulfite 1.5 parts, Oxytarch 10 parts, bentonite 25
Part, cross-linking agent 2 parts, deionized water 150 parts.
Embodiment five
A kind of polyhexamethylene adipamide compositions thickening agent, is made up of following parts by weight component:
Polyhexamethylene adipamide 20 parts, stannic hydroxide 2 parts, sodium sulfite 1.5 parts, Oxytarch 11 parts, bentonite 17
Part, cross-linking agent 5 parts, deionized water 100 parts.
Embodiment six
A kind of polyhexamethylene adipamide compositions thickening agent, is made up of following parts by weight component:
Polyhexamethylene adipamide 28 parts, stannic hydroxide 3 parts, sodium sulfite 1.5 parts, Oxytarch 14 parts, bentonite 20
Part, cross-linking agent 10 parts, deionized water 150 parts.
Embodiment seven
A kind of polyhexamethylene adipamide compositions thickening agent, is made up of following parts by weight component:
Polyhexamethylene adipamide 20 parts, stannic hydroxide 3 parts, sodium sulfite 1.5 parts, Oxytarch 14 parts, bentonite 17
Part, cross-linking agent 10 parts, deionized water 100 parts.
Embodiment eight
A kind of polyhexamethylene adipamide compositions thickening agent, is made up of following parts by weight component:
Polyhexamethylene adipamide 28 parts, stannic hydroxide 2 parts, sodium sulfite 1.5 parts, Oxytarch 11 parts, bentonite 20
Part, cross-linking agent 5 parts, deionized water 150 parts.
In above-described embodiment, Oxytarch is the starch using hypochlorite oxidation, and described bentonite is hydrogen-based bentonite.
The preparation method of above-mentioned polyhexamethylene adipamide compositions thickening agent is will be except polyhexamethylene adipamide and bentonite
Outer raw material according to parts by weight mixing and stirring, add after ebuillition of heated bentonite and high temperature fused state poly-oneself two
Acyl hexamethylene diamine, mixing stands.
Application:
Printing technology flow process
Preparation print paste → stamp → drying (80 DEG C, 5min) → decatize → cold water washes → hot water wash → soap → (45
DEG C, 5min) → reduction cleaning → hot water wash → cold water washes → dries
Thickening agent (g/200g)
Thickening agent 0.2-4 described in embodiment, coating indigo plant 15g, binding agent SS-871 2, water 182.8
The dyestuff that addition warm water has dissolved in thickening agent system, is subsequently adding binding agent.
Dyed fabric is measured with reference to GB/T 3,920 2008 " textile color stability test colour fastness to rubbing " method
Dry, fastness to wet rubbing
Table one: PRINTED FABRIC the performance test results
According to table one it will be seen that after thickening agent application described in embodiment mill base color and luster normal, soft, decorative pattern
Profile cleans, and does not occur the phenomenon of imbibition and network blocking, crock fastness and soaping fastness all to reach required requirement, thickening agent
Can anchor at completely and above fiber, form firm thin film, it is not easy to be swelling by whom, give the soaping fastness that fabric is good
And crock fastness.
Thickening agent is made into the white slurry of 2%, then with sodium hydroxide and the pH value of the white slurry of acetic acid regulation, then measures white slurry
The resistance to acids and bases of the viscosity measurement thickening agent when different pH value.
In thickening agent starched in vain, drip the NaCl solution (concentration is 0.1%) prepared in advance, often add 1g and survey a viscosity,
The salt resistance ability of test product.
Table two: thickening agent acid and alkali-resistance ability
Table three: thickening agent resistance to alkali salt ability
The thickening agent that embodiment prepares is applied in dye printing have good resistance to acids and bases and salt tolerance, mill base
Color and luster is normal, soft, and decorative pattern profile cleans, and does not occur the phenomenon of imbibition and network blocking, crock fastness and soaping fastness equal
Reaching required requirement, thickening agent can anchor at completely and form firm thin film above fiber, it is not easy to swelling by whom,
Give the good soaping fastness of fabric and crock fastness.
Claims (7)
1. a polyhexamethylene adipamide compositions thickening agent, it is characterised in that be made up of following parts by weight component:
Polyhexamethylene adipamide 20 parts-30 parts, stannic hydroxide 2 parts-4 parts, sodium sulfite 1 part-1.5 parts, Oxytarch 10 parts-
14 parts, bentonite 15 parts-25 parts, cross-linking agent 2 parts-10 parts, deionized water 100 parts-150 parts.
A kind of polyhexamethylene adipamide compositions thickening agent the most according to claim 1, it is characterised in that by following weight
Number component forms:
Polyhexamethylene adipamide 20 parts-28 parts, stannic hydroxide 2 parts-3 parts, sodium sulfite 1.5 parts, Oxytarch 11 part-14
Part, bentonite 17 parts-20 parts, cross-linking agent 5 parts-10 parts, deionized water 100 parts-150 parts.
A kind of polyhexamethylene adipamide compositions thickening agent the most according to claim 1, it is characterised in that: described oxidation is formed sediment
Powder is the starch using hypochlorite oxidation.
A kind of polyhexamethylene adipamide compositions thickening agent the most according to claim 1, it is characterised in that: described bentonite
For hydrogen-based bentonite.
5. the preparation method of one of Claims 1-4 described polyhexamethylene adipamide compositions thickening agent, it is characterised in that: will
Raw material in addition to polyhexamethylene adipamide and bentonite, according to parts by weight mixing and stirring, adds swelling after ebuillition of heated
Soil and the polyhexamethylene adipamide of high temperature fused state, mixing stands.
6. one of Claims 1-4 described polyhexamethylene adipamide compositions thickening agent, the application in dye printing.
The polyhexamethylene adipamide compositions thickening agent the most according to claim 6 application in dye printing, its feature
It is: described polyhexamethylene adipamide compositions thickening agent interpolation percentage ratio in concentrator is 0.1-2%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610682148.7A CN106245378A (en) | 2016-08-17 | 2016-08-17 | A kind of polyhexamethylene adipamide compositions thickening agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610682148.7A CN106245378A (en) | 2016-08-17 | 2016-08-17 | A kind of polyhexamethylene adipamide compositions thickening agent |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1155643A1 (en) * | 1982-05-19 | 1985-05-15 | Таджикский государственный университет им.В.И.Ленина | Method of producing thickener for printing ink for polyamide fibre materials |
| CN102433777A (en) * | 2011-11-17 | 2012-05-02 | 上海长胜纺织制品有限公司 | Preparation method of cold migration printing gum and color paste thereof |
| CN104695249A (en) * | 2015-03-06 | 2015-06-10 | 徐饶春 | Printing thickening agent |
| CN104928951A (en) * | 2015-07-06 | 2015-09-23 | 常州大学 | Preparation method for organic-inorganic composite printing thickener |
-
2016
- 2016-08-17 CN CN201610682148.7A patent/CN106245378A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1155643A1 (en) * | 1982-05-19 | 1985-05-15 | Таджикский государственный университет им.В.И.Ленина | Method of producing thickener for printing ink for polyamide fibre materials |
| CN102433777A (en) * | 2011-11-17 | 2012-05-02 | 上海长胜纺织制品有限公司 | Preparation method of cold migration printing gum and color paste thereof |
| CN104695249A (en) * | 2015-03-06 | 2015-06-10 | 徐饶春 | Printing thickening agent |
| CN104928951A (en) * | 2015-07-06 | 2015-09-23 | 常州大学 | Preparation method for organic-inorganic composite printing thickener |
Non-Patent Citations (1)
| Title |
|---|
| 汪多仁: "《纺织用化工新产品与新技术》", 31 October 2001, 江苏科学技术出版社 * |
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Application publication date: 20161221 |