CN103233371A - Printing paste and applications thereof - Google Patents
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- CN103233371A CN103233371A CN2013101747239A CN201310174723A CN103233371A CN 103233371 A CN103233371 A CN 103233371A CN 2013101747239 A CN2013101747239 A CN 2013101747239A CN 201310174723 A CN201310174723 A CN 201310174723A CN 103233371 A CN103233371 A CN 103233371A
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Abstract
The invention discloses a printing paste and applications thereof, belonging to the technical field of printing. The printing paste comprises the following ingredients by weight: 0.01-4 of active dye, 30-50 of polyacrylic acid thickening agent raw paste, 1-3 of sodium carbonate, and the balance of water. By mixing proper active dye and the printing paste materials, the technical difficulties of salt tolerance, rheological property, fixation rate and the like widely existing in the printing paste can be effectively solved, the printing colour yield and fixation rate of the active dye can be greatly improved, so that the printing paste replaces the use of a great deal of urea, thus completely realizing the non-urea printing technique, and having a remarkable effect in the industry.
Description
Technical field:
The present invention relates to a kind of printing paste, specifically refer to a kind of printing paste, and the application that is applicable to the cellulose base fiber fabric printing technology.
Background technology:
The REACTIVE DYES chromatogram is complete, and wet fastness height is soft, is the main dyestuff that the cellulose fibre stamp is used.Not only extensive use on cotton, viscose glue, day silk, bast fiber fabrics, and on the silk like fabric, also use in a large number.At present, REACTIVE DYES mainly adopts a phase method (alkali and REACTIVE DYES with slurry) direct printing technology, and printing gum mainly adopts sodium alginate, but that weak point is loose colour is too heavy, and the after washing task is heavy, causes whitely easily and is infected with, and influences product quality.Produce a large amount of dyeing and printing sewages simultaneously, environment is caused have a strong impact on, and increased the cost of wastewater treatment.Cause The above results, mainly because of reactive dye color fixing rate high causing not, in the actual production degree of fixation surpass 80% few, most between 60-70%.
The factor that influences the printing with reactive dye degree of fixation is a lot, and wherein reactive dyestuff molecule structure, reaction activity are one of principal element.Low form REACTIVE DYES reactivity is too high, hydrolysis takes place easily, and the High Temperature Type Reactive Dyes reactivity is low, easily causes the incomplete phenomenon of reaction.
Selecting activity moderate in developing focus, make every effort to improve degree of fixation both at home and abroad, to improve tinctorial yield, but still undesirable, what mainly adopt at present is a chloro-s-triazine dyestuff and Vinyl-Sulfone Type dyestuff.
1, a chloro-s-triazine dyestuff:
One chloro-s-triazine dyestuff alkali resistance height, mill base is facile hydrolysis not, and the covalent bond after the fixation also is difficult for scission of link under alkaline environment, and therefore, a chloro-s-triazine REACTIVE DYES is the REACTIVE DYES of the most suitable all-in method stamp in the market.Its stability of pigment paste height, period of storage is long, even under 40 ℃ of hot environments, its changes of shade are also very little after two weeks of placement, even untimely the evaporating of stamp semi-products also is not easy to occur wind seal defect.But its active group reactivity is low, and steam moisture is had relatively high expectations, and particularly prints the regenerated celulose fibre fabric.When draw a design in the laboratory, the steam moisture abundance, Dry Sack is rich and gaudy, but when producing greatly, because steam moisture is lower, causes Dry Sack shallow through regular meeting, and coloured light withers secretly, and it is serious that aberration is criticized in front and back, even problems such as left, center, right aberration, cloth complexion flower occur.In addition, its degree of fixation is lower, most of dye fixing rates are 50%～60%, and therefore production even lower greatly when doing dark color or special dark color, the easy imbibition of flower type, can cause a large amount of loose colours during washing, and easily cause white background staining, the rope form washing also the problem of cutting marks can occur, and the wet fastness of stamp product is poor, a series of problems such as waste water COD height.If any wax seal enterprise particularly of factory, the dye dosage of 12% (o.w.f) even higher concentration often appears.For pure cotton knitted fabric, most of printing and dyeing enterprises do not carry out mercerising to be handled, so Dry Sack is more shallow.In order to improve above problem, stamp enterprise uses urea in a large number, becomes ammonia nitrogen discharging rich and influential family.
2, Vinyl-Sulfone Type dyestuff:
Though Vinyl-Sulfone Type dyestuff degree of fixation height, it is applicable to two phase printing, is not suitable for more general all-in method stamp now.The vinyl sulfone(Remzaol active group is reactive high, so easy and fiber-reactive, but also easy and water reaction forms not alkaline-resisting covalent bond, facile hydrolysis.Particularly under the condition that a large amount of urea exist, hydrolysis is more serious.Its print paste is placed and should not be surpassed 2 days, particularly when summer temperature is high, and facile hydrolysis more, color shoals, and black even become coffee color causes dyestuff to waste in a large number.Because the existence of urea, the fabric behind the stamp easily absorbs airborne moisture in the process of banking up, cause local dyestuff hydrolysis, thereby wind seal defect occurs.
In addition, adopt double-active radical dye in addition, the solubility of double-active radical dye is generally relatively poor, as bright blue MGB, dark blue M2GE, red M2B etc., occur look flower, aberration when dying dark color easily, even color dot occurs, therefore must strengthen the consumption of urea, but consumption can accelerate the hydrolysis of dyestuff too greatly again.In addition, the double-active radical dye great majority are a chloro-s-triazine and two active groups of vinyl sulfone(Remzaol, therefore have wind seal problem equally, occur shade bar when piecing together green as dark blue M2GE easily.
Technique scheme, all urea is used in indispensable meeting, adds the tinting strength, tinting power that urea can obviously improve dyestuff during printing with reactive dye, realizes higher degree of fixation in limited steaming time, thereby improves tinctorial yield.Reduce discharging 10% target and clearly propose ammonia nitrogen according to China's " the 12 five-year plan outline of national economy and social development ".Therefore new dye and the fixation system of no urea or low urea needed in market badly, can meet the requirement of national environmental protection index, guarantees to obtain higher degree of fixation and tinctorial yield again.
The factor that influences degree of fixation in addition on the one hand is printing gum.At present, REACTIVE DYES cellulose fibre print paste preparation sodium alginate thickener commonly used has to take off to stick with paste and cleans advantage easily, has charge repulsion with REACTIVE DYES, is conducive to REACTIVE DYES and transfers on the cellulose fibre from mill base.But also exist rheological characteristic undesirable, circle (put down) wire mark flower particularly high order is counted defectives such as wire mark, meticulous colored type and large tracts of land stamp printing effect be undesirable, and its tinctorial yield is more too late other synthetic slurries also.The sodium alginate price improves in recent years in addition, causes the stamp production cost to rise.
Summary of the invention:
At the problems referred to above, the first aspect present invention purpose provides and a kind ofly is applicable to the cellulose fibre stamp, and has higher tinctorial yield, the printing paste of look flower and aberration can not occur.
The technical scheme that the present invention takes is as follows, and a kind of printing paste is characterized in that, described printing paste comprises following composition by weight:
REACTIVE DYES 0.01-4;
The former paste of polyacrylic thickener 30-50;
Sodium bicarbonate 1-3;
Water surplus.
Preferably:
Described REACTIVE DYES is any one of reactive yellow P-2RN, reactive brilliant bule P-3R, reactive red P-6B, active emerald green blue P-GR, reactive orange P-2R, reactive red P-4B, reactive black P-Q, reactive black P-GR-2.
The former paste compound method of described polyacrylic thickener is as follows: take by weighing polyacrylic thickener 16 gram, add water to total amount be 100 grams, stir into even stock white pasty state.
Described polyacrylic thickener is preferably thickener 401 especially, and as the thickener 401 that the biochemical Co., Ltd of the smart industry in Zhejiang produces, its solid content is 50%.
The compound method of described printing paste is as follows: take by weighing the former paste of polyacrylic thickener according to technical recipe, take by weighing required REACTIVE DYES and sodium bicarbonate more respectively, after REACTIVE DYES and the dissolving of sodium bicarbonate difference water, pour in the former paste of polyacrylic thickener, stirring gets final product.
The second aspect present invention purpose provides the application of a kind of aforementioned printing paste in the cellulose fibre printing technology.
Cellulose fibre printing technology flow process is as follows:
---stamp---oven dry---decatize---cold wash---hot water wash------hot water wash---Warm Wash---cold wash of soaping of fabric after pre-treatment.
Wherein:
Decatize condition: temperature 100-102 ℃, time 8-10min.
The condition of soaping: soaping agent 1-2g/L, 95 ℃ of temperature, time 10-15min.
Operation principle of the present invention and beneficial effect are as follows:
1, the selection of dyestuff: the present invention is by experimentizing to a large amount of REACTIVE DYES and screening, several REACTIVE DYES kinds such as final definite reactive yellow P-2RN, reactive brilliant bule P-3R, reactive red P-6B, active emerald green blue P-GR, reactive orange P-2R, reactive red P-4B, reactive black P-Q, reactive black P-GR-2, above-mentioned REACTIVE DYES not only salt content is low, and cooperate with printing paste thickener of the present invention to have good colour fixation, thereby solved this thickener salt tolerance difference and the low technical barrier of degree of fixation.
2, the preparation of thickener: printing paste thickener of the present invention, adopt the polyacrylic thickener, have tinctorial yield height, good, the lower-price characteristic of rheological characteristic.
3, the cooperation of dyestuff and thickener: because the salt tolerance of polyacrylic thickener is relatively poor, meets the viscosity that makes the mill base thickener after the salt and reduce thinningly, so that flower type flushing phenomenon takes place during stamp, thereby limit its application.Therefore, in order to improve the rheological characteristic of mill base, and the colored type that overcomes due to the REACTIVE DYES salt content height spreads flushing, the unsharp problem of profile, the present invention is by the selection of REACTIVE DYES, and the content of thickener in the raising mill base, further increase the viscosity of mill base, thereby solve rheological characteristic and the salt tolerance problem of printing paste of the present invention.
4, the printing paste of preparation of the present invention, in suitable cellulose fibre printing technology, by the control to decatize condition and the condition of soaping, proper extension steaming time, increase the reaction set chance of mill base humidity and dyestuff and fiber, the fixation rate of REACTIVE DYES is had further bigger lifting.
5, the present invention is by the cooperation of REACTIVE DYES and printing paste thickener, efficiently solve the technical barriers such as salt tolerance, rheological characteristic and degree of fixation that extensively exist in the printing paste, make the tinctorial yield of printing with reactive dye and fixation rate that by a relatively large margin raising be arranged, thereby substituted the use of a large amount of urea, realize the printing technology of no urea fully, have outstanding effect in the industry.
The present invention is further illustrated below in conjunction with the drawings and specific embodiments.
Description of drawings:
Fig. 1 is the apparent color depth value contrast that traditional printing paste and printing paste of the present invention adopt reactive yellow P-2RN printing with reactive dye;
Fig. 2 is the apparent color depth value contrast that traditional printing paste and printing paste of the present invention adopt reactive red P-6B printing with reactive dye;
Fig. 3 is the apparent color depth value contrast that traditional printing paste and printing paste of the present invention adopt reactive brilliant bule P-3B printing with reactive dye;
Fig. 4 is the apparent color depth value contrast that traditional printing paste and printing paste of the present invention adopt reactive black P-GR-2 printing with reactive dye;
Among the figure:
The apparent color depth value positive, that reverse side refers to the PRINTED FABRIC positive and negative;
Tradition refers to adopt traditional printing paste prescription (adding urea, sodium alginate thickener);
New 6 min refer to adopt the printing technology of printing paste of the present invention under steaming time 6 min;
New 8min refers to adopt the printing technology of printing paste of the present invention under steaming time 8 min;
New 10 min refer to adopt the printing technology of printing paste of the present invention under steaming time 10 min;
New 12 min refer to adopt the printing technology of printing paste of the present invention under steaming time 12 min.
The specific embodiment:
Embodiment 1: the printing paste technology preparation:
REACTIVE DYES 0.01-4g
Thickener 401 former paste 30-50g
Sodium bicarbonate 1-3g
Water surplus
100g。
The compound method of printing paste: take by weighing thickener 401 former paste 30-50 grams according to technology preparation, take by weighing the required REACTIVE DYES of technology preparation and sodium bicarbonate in addition respectively, REACTIVE DYES and sodium bicarbonate are used an amount of water-soluble solution respectively, to going in the thickener 401 former pastes, and the water of adding surplus, stirring gets final product.
REACTIVE DYES is chosen as reactive yellow P-2RN, reactive brilliant bule P-3R, reactive red P-6B, active emerald green blue P-GR, reactive orange P-2R, reactive red P-4B, reactive black P-Q or reactive black P-GR-2.
Thickener 401 former paste prescriptions:
Thickener 401 16 grams
Water surplus
100 grams.
Thickener 401 former paste compound methods: take by weighing 16 gram thickeners 401, adding suitable quantity of water to total amount is 100 grams, stirs into even stock white pasty state.
Embodiment 2: the printing paste Performance Detection of different formulations.
According to the printing paste of embodiment 1 method preparation, select different REACTIVE DYES respectively, detect saliferous rate, the viscosity of its REACTIVE DYES, the rheological characteristic of thickener, carry out stamp at cotton knitted fabric, carry out the contrast of printing technology effect with traditional printing paste.
1, method of testing:
1.1: viscosity test: with NDJ-1 type viscometer determining.
1.2:PVI mensuration: namely η 60/ η 6 is than the PVI value of the former paste of value representation, and η 60, η 6 are 60, the viscosity number of former paste during 6r/min.This value is more little, illustrates that slurry increases its viscosity with shear stress and descends more soon, and mill base sees through the screen cloth of high order number, decorative pattern fineness height easily when scraping.
1.3: the mensuration of surperficial color depth value: adopt Datacolor SF600 to survey color matching system, to measure the reflectivity of fabric under D65 light source, the 10 ° of visual angles, calculate apparent color depth value K/S from albedometer, the K/S value is more big, and color is more dense, the tinctorial yield height; Otherwise then more light, tinctorial yield is low.
2, the printing paste of different activities dyestuff preparation:
In the commercialization preparation process of REACTIVE DYES, add with a large amount of neutral electrolytes, the existence of these salt is with the use of impact polypropylene acids thickener.Therefore, this test is by adopting identical mill base preparation prescription and method, the mill base that 26 commercially available REACTIVE DYES that are applicable to stamp are prepared carries out viscosity test, can judge the salt content of REACTIVE DYES from the data of surveying: viscosity is more low, the REACTIVE DYES salt content is more high, otherwise then salt content is low.Concrete outcome sees Table 1.
Table 1: the printing paste viscosity number of different activities dyestuff preparation.
Annotate: the printing paste prescription in the form 1 is for by weight percentage: REACTIVE DYES 2%, and thickener 401 former pastes 30%, sodium bicarbonate 2% adds water to 100%.
From table 1 data as can be seen:
In the K type REACTIVE DYES: reactive orange K-GN, reactive red K-3B, active purple k-3r have higher viscosity, and these several dyestuff salt content are lower as can be known.In the P type REACTIVE DYES, reactive orange P-2R, reactive yellow P-2RN, reactive red P-4B, reactive red P-6B, reactive brilliant bule P-3R, active emerald green blue P-GR, reactive black P-Q, these several viscosity numbers of reactive black P-GR-2 are higher, and salt content is less.
And in actual production, dyestuff needs mutual colorant match to use, and obtaining various color and lusters, and dyestuff preferably belongs to same type during colorant match, just has compatibility preferably, produces stable coloured light.From above-mentioned data as can be seen, that the kind that salt content is low in the P type REACTIVE DYES has possessed is red, yellow, primary colors and black kind, can satisfy the colorant match needs of actual production.Therefore the preferred P type REACTIVE DYES that adopts can have stable coloured light.
3, adopt the printing paste Performance Detection of the former paste of polyacrylic thickener (be example with thickener 401):
Below be Comparative Examples with traditional printing paste (adopt sodium alginate thickener), carry out rheological characteristic with printing paste of the present invention (adopting thickener 401 former pastes) and apparent color depth value detects analysis.
3.1 rheological characteristic:
Printing paste with the former paste of employing sodium alginate is Comparative Examples, adopts the printing paste of thickener 401 former pastes to compare with the present invention, and measures its PVI value respectively, to reflect their rheological characteristic, the results are shown in Table 2:
The rheological characteristic of table 2, thickener 401 former pastes and the former paste of sodium alginate relatively
The former paste prescription of sodium alginate:
Calgon 0.8 gram
Water surplus
100 grams
The former Preparation Method that pastes of sodium alginate: take by weighing 16 gram sodium alginate thickeners, slowly adding has been dissolved with in the ormal weight hydrothermal solution of calgon while stirring, until being transparent pasty state.
The mill base preparation method of sodium alginate thickener: the former paste of sodium alginate that takes by weighing ormal weight in the mill base prescription, take by weighing REACTIVE DYES and the sodium bicarbonate of ormal weight in addition respectively, after the suitable quantity of water dissolving, inject the former paste of alginic acid, add the water of surplus, stirring is mill base.
From 2 table data as can be seen:
The PVI value of the printing paste of thickener 401 former pastes and preparation is all lower than the sodium alginate, the mill base that thickener 401 is prepared as thickener is described, can print more meticulous decorative pattern, be fit to print the hydrophilic cellulose fabric, be beneficial to mill base, infiltration wetting to textiles.
3.2 stamp tinctorial yield:
Adopt printing paste (the no urea of embodiment 1 preparation, thickener 401 former pastes), (add urea with traditional printing paste, the sodium alginate thickener) is applied to the cellulose fibre printing technology, respectively with reactive yellow P-2RN, reactive red P-6B, reactive brilliant bule P-3B, the REACTIVE DYES that these four salt content of reactive black P-GR-2 are lower is carried out printing tests, and measure the apparent color depth value of PRINTED FABRIC positive and negative respectively, simultaneously, detect printing paste of the present invention respectively and under different steaming time conditions, (adopt 6 min respectively, 8 min, 10 min, the variation of printing with reactive dye tinctorial yield 12min) the results are shown in Figure 1, Fig. 2, Fig. 3 and Fig. 4.
The printing technology flow process:
---stamp---oven dry---decatize---cold wash---hot water wash------hot water wash---Warm Wash---cold wash of soaping of fabric after pre-treatment.
Decatize condition: 100-102 ℃, 8-10min.
The condition of soaping: soaping agent 1-2g/L, 95 ℃, 10-15min.
Tradition printing paste prescription:
REACTIVE DYES 2 grams
Former paste 50 grams of sodium alginate
Sodium bicarbonate 3 grams
Water is an amount of
100 grams.
Steam temperature: 100-102 ℃; Steaming time: 6 min.
Printing paste prescription of the present invention:
REACTIVE DYES 2 grams
Thickener 401 former paste 50 grams
Sodium bicarbonate 3 grams
Water is an amount of
100 grams.
Steam temperature: 100-102 ℃; Steaming time is selected respectively: 6 min, 8 min, 10 min, 12min.
Statistical analysis:
From Fig. 1～Fig. 4 as can be seen:
Adopting new technology does not namely have the urea printing technology, under the enough situation of steaming time, all can obtain close with traditional printing technology even better apparent color depth value.Wherein the steaming time of reactive yellow P-2RN, reactive red P-6B, these three REACTIVE DYES of reactive brilliant bule P-3B is the apparent color depth value that 8min just can reach traditional printing technology substantially, and the steaming time of length is 10min and reactive black P-GR-2 needs.In addition, from the K/S value of fabric backing and positive K/S value ratio, new technology has than the better printthrough of traditional handicraft, and its ratio is higher.
In sum, screen the printing paste of back preparation as printing gum, to REACTIVE DYES with thickener 401 former pastes, be applied to the cellulose base fiber fabric printing technology, cooperate the proper extension steaming time, under the situation that does not have urea to add, can obtain the tinctorial yield close with traditional printing technology, and the rheological characteristic of printing paste, printthrough are better than traditional printing technology, thereby have really realized no urea printing technique.
Claims (8)
1. a printing paste is characterized in that, described printing paste comprises following composition by weight percentage:
REACTIVE DYES 0.01-4;
The former paste of polyacrylic thickener 30-50;
Sodium bicarbonate 1-3;
Water surplus.
2. a kind of printing paste according to claim 1 is characterized in that: described REACTIVE DYES is any one of reactive yellow P-2RN, reactive brilliant bule P-3R, reactive red P-6B, active emerald green blue P-GR, reactive orange P-2R, reactive red P-4B, reactive black P-Q or reactive black P-GR-2.
3. a kind of printing paste according to claim 1 is characterized in that: the former paste of described polyacrylic thickener refers to polyacrylic thickener and water are formed by weight the 16:84 configuration.
4. according to claim 1 or 3 described a kind of printing pastes, it is characterized in that: the former paste compound method of described polyacrylic thickener is as follows: take by weighing polyacrylic thickener 16 gram, add water to total amount be 100 grams, stir into even stock white pasty state.
5. a kind of printing paste according to claim 1, it is characterized in that: the compound method of described printing paste is as follows: take by weighing the former paste of polyacrylic thickener according to technical recipe, take by weighing required REACTIVE DYES and sodium bicarbonate more respectively, after REACTIVE DYES and the dissolving of sodium bicarbonate difference water, pour in the former paste of polyacrylic thickener, stirring gets final product.
6. a kind of printing paste according to claim 3, it is characterized in that: described polyacrylic thickener is thickener 401.
7. the application of the printing paste of one of claim 1-6 in the cellulose fibre printing technology.
8.---stamp---oven dry---decatize---cold wash---hot water wash------hot water wash---Warm Wash---cold wash of soaping that the application of a kind of printing paste according to claim 7 in the cellulose fibre printing technology may further comprise the steps: the fabric after pre-treatment; Wherein: decatize condition: temperature 100-102 ℃, time 8-10min; The condition of soaping: soaping agent 1-2g/L, 95 ℃ of temperature, time 10-15min.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103469618A (en) * | 2013-09-06 | 2013-12-25 | 浙江华东纺织印染有限公司 | Non-urea reactive dye printing paste, manufacturing method and printing and dyeing method |
| CN103556500A (en) * | 2013-11-04 | 2014-02-05 | 绍兴文理学院 | Printing paste, and preparation method and application thereof |
| CN106012605A (en) * | 2016-05-31 | 2016-10-12 | 山东洁晶集团股份有限公司 | Thickener used for all-cotton and artificial cotton printing, and preparation method thereof |
| CN107415449A (en) * | 2017-07-10 | 2017-12-01 | 安徽万方织染有限公司 | The efficient printing system and method for a kind of warp knit textile cloth |
| CN107476042A (en) * | 2016-06-08 | 2017-12-15 | 福建福田纺织印染科技有限公司 | A kind of reactive printing new technology based on EST soaping agents |
| CN109594364A (en) * | 2018-11-29 | 2019-04-09 | 上海雅运新材料有限公司 | A kind of reactive printing urea substituting agent and preparation method thereof |
| CN112281520A (en) * | 2020-09-27 | 2021-01-29 | 绍兴市华绅纺织品整理有限公司 | Reactive dye printing method with high color fixing rate |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805542A (en) * | 2010-05-13 | 2010-08-18 | 鲁继烈 | Water-based dye ink and application thereof |
| CN102433776A (en) * | 2011-09-09 | 2012-05-02 | 浙江理工大学 | Method for preparing environment-friendly natural fiber printing paste |
-
2013
- 2013-05-13 CN CN201310174723.9A patent/CN103233371B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805542A (en) * | 2010-05-13 | 2010-08-18 | 鲁继烈 | Water-based dye ink and application thereof |
| CN102433776A (en) * | 2011-09-09 | 2012-05-02 | 浙江理工大学 | Method for preparing environment-friendly natural fiber printing paste |
Non-Patent Citations (1)
| Title |
|---|
| 姚晓平等: ""人造棉长巾印花工艺"", 《印染》 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103469618A (en) * | 2013-09-06 | 2013-12-25 | 浙江华东纺织印染有限公司 | Non-urea reactive dye printing paste, manufacturing method and printing and dyeing method |
| CN103469618B (en) * | 2013-09-06 | 2016-04-13 | 浙江华东纺织印染有限公司 | A kind of without urea printing with reactive dye mill base, manufacture method and dyeing method |
| CN103556500A (en) * | 2013-11-04 | 2014-02-05 | 绍兴文理学院 | Printing paste, and preparation method and application thereof |
| CN103556500B (en) * | 2013-11-04 | 2016-02-17 | 绍兴文理学院 | A kind of print paste and preparation method thereof and application |
| CN106012605A (en) * | 2016-05-31 | 2016-10-12 | 山东洁晶集团股份有限公司 | Thickener used for all-cotton and artificial cotton printing, and preparation method thereof |
| CN107476042A (en) * | 2016-06-08 | 2017-12-15 | 福建福田纺织印染科技有限公司 | A kind of reactive printing new technology based on EST soaping agents |
| CN107415449A (en) * | 2017-07-10 | 2017-12-01 | 安徽万方织染有限公司 | The efficient printing system and method for a kind of warp knit textile cloth |
| CN109594364A (en) * | 2018-11-29 | 2019-04-09 | 上海雅运新材料有限公司 | A kind of reactive printing urea substituting agent and preparation method thereof |
| CN109594364B (en) * | 2018-11-29 | 2021-03-23 | 太仓宝霓实业有限公司 | Reactive printing urea substitute and preparation method thereof |
| CN112281520A (en) * | 2020-09-27 | 2021-01-29 | 绍兴市华绅纺织品整理有限公司 | Reactive dye printing method with high color fixing rate |
| CN112281520B (en) * | 2020-09-27 | 2023-03-31 | 浙江七色彩虹科技有限公司 | Reactive dye printing method with high color fixing rate |
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