CN104231668A - Preparation method and application of yellow reactive dye combination and fibers or fiber fabrics dyed with yellow reactive dye combination - Google Patents
Preparation method and application of yellow reactive dye combination and fibers or fiber fabrics dyed with yellow reactive dye combination Download PDFInfo
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- CN104231668A CN104231668A CN201410532528.3A CN201410532528A CN104231668A CN 104231668 A CN104231668 A CN 104231668A CN 201410532528 A CN201410532528 A CN 201410532528A CN 104231668 A CN104231668 A CN 104231668A
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Abstract
The invention provides a preparation method and application of a yellow reactive dye combination, and fiber or fiber fabrics dyed with the yellow reactive dye combination, and belongs to the field of reactive dye. The dye combination is composed of, by weight parts, 30-60 parts of a component A shown in a formula (I), 30-60 parts of a component B shown in a formula (II), 1-10 parts of a component C shown in a formula (III), and 0-60 parts of auxiliaries. The yellow reactive dye combination is applicable to dyeing various fibers and fiber fabrics and can obtain excellent color fastness performance.
Description
Technical field
The present invention relates to a kind of printing and dyeing being applicable to cotton, wool, regenerated fibre or their yarn fabric, or the printing and dyeing of tynex, cellulosic fibre, protein fibre or their yarn fabric, be specially adapted to the Yellow active dye composition of cellulosic fibre and yarn fabric printing and dyeing thereof, belong to reactive dyestuff field.The invention still further relates to preparation method and the purposes of described Yellow active dye composition, and the yarn fabric of the fiber obtained by its printing and dyeing or fiber.
Background technology
Along with the development with staining technique of being on the increase of fiber species, the requirement of people to textiles is also more and more higher, and this creates great challenge power to the raising of the application performance of reactive dyestuffs.Reactive yellow, as the larger look kind of market share amount, not only requires to have good light fastness, washing fastness, level-dyeing property and reproducibility, and when requiring to dye, dye uptake, lifting force and degree of fixation are high.Many conventional Yellow reactive dyes kinds still do not possess above-mentioned every all round properties, as publication CN1253150 and CN101899228 in the market.
Patent publication No. be CN1253150 patent document discloses a kind of cellulolytic activity azoic dyestuff, its to be upper dye be yellow azoic dyestuff.Although this Yellow reactive dyes has good dyefastness, degree of fixation is not high.
Patent publication No. is the Yellow reactive dyes that patent document discloses a kind of cellulose dyeing of CN101899228, and the dye uptake of this dyestuff and fastness to rubbing are very high, but washing fastness not yet reaches requirement.
Above-mentioned Yellow reactive dyes kind does not still possess above-mentioned every all round properties, particularly washing fastness and degree of fixation is not all very high, is difficult to the demand meeting various occasion.
Summary of the invention
the problem that invention will solve
The invention provides a kind of Yellow active dye composition, it is applicable to the printing and dyeing of cellulosic fibre material, as the printing and dyeing of cotton, wool, regenerated fibre and yarn fabric thereof, be also applicable to the printing and dyeing of tynex, cellulosic fibre, protein fibre and yarn fabric thereof in addition.Every fastness ability such as dye uptake, degree of fixation, lifting force of this reactive dye compositions is all good, and particularly water-fastness colour fastness significantly improves.
for the scheme of dealing with problems
The invention provides a kind of Yellow active dye composition, it comprises the component A shown in formula (I), the B component shown in formula (II), the component C shown in formula (III), and optional auxiliary agent; Component A is 30 ~ 60 weight parts, and B component is 30 ~ 60 weight parts, and component C is 1 ~ 10 weight part, and auxiliary agent is 0 ~ 60 weight part:
Wherein, M
1, M
2, M
3be hydrogen, potassium or sodium independently of one another; R
2for-CH=CH
2or-C
2h
4oSO
3m
1, R
4for-CH=CH
2or-C
2h
4oSO
3m
2, R
6for-CH=CH
2or-C
2h
4oSO
3m
3; R
1, R
3, R
5be (C independently of one another
1~ C
3)-alkyl or-NH
2; X
1, X
2be selected from chlorine or fluorine independently of one another.
The content of component A is preferably 35 ~ 60 weight parts, then is preferably 40 ~ 60 weight parts, is more preferably 45 ~ 60 weight parts.
The content of B component is preferably 35 ~ 60 weight parts, then is preferably 40 ~ 60 weight parts, is more preferably 45 ~ 60 weight parts.
The content of component C is preferably 1 ~ 9 weight part, then is preferably 1 ~ 8 weight part, is more preferably 2 ~ 8 weight parts.
Auxiliary agent is preferably 0 ~ 50 weight part, is more preferably 0 ~ 40 weight part, then is preferably 0 ~ 35 weight part.
Described Yellow active dye composition, is characterized in that, described component A be selected from formula (I-1) ~ (I-7) compound one or more
Described Yellow active dye composition, is characterized in that, described B component be selected from formula (II-1) ~ (II-8) compound one or more
Described Yellow active dye composition, is characterized in that, described component C be selected from formula (III-1) ~ (III-7) compound one or more
Described Yellow active dye composition, is characterized in that, described auxiliary agent is dispersion agent, diffusant and/or weighting agent, can be used alone one, also can use their mixture.Above auxiliary agent is commercially available conventional variety and dyestuff production routine adds kind.
The present invention also provides the preparation method of described Yellow active dye composition, one of comprises the steps:
(1) by the dry powder of the dry powder of component A, B component, the dry powder of component C and optional auxiliary agent, carry out being mixed to get product;
(2) by the slurry of the slurry of component A, B component, the slurry of component C and optional auxiliary agent, add in container, stir subsequently, then drying obtains product;
(3) join in the slurry of remaining components by the dry powder of one or two component in component A, B component, component C, together with optional auxiliary agent, add in container, stir subsequently, then drying obtains product.
Preferably, carry out drying through spray tower, drying room or flash distillation and obtain granular or powder-like product.
Preferably, the preparation method of above-mentioned composition comprises component A, B component, component C and auxiliary agent (if needing to add auxiliary agent), as sodium sulfate (as Sodium sulfate anhydrous.min(99)) and dispersion agent after crushed first, then mix with mixing tank, mixing tank can be taper, drum-type or pears blade, mixes that rear test analysis is qualified to be packed again.
Preferably, the preparation method of above-mentioned composition comprises the component A that will have produced, the slurry of B component, component C and auxiliary agent (if needing to add auxiliary agent), as Sodium sulfate anhydrous.min(99) (anhydrous sodium sulphate), dispersion agent and diffusant, add the toning storage tank that band stirs in proportion, start stirrer to stir, test passes is directly packed and is made liquiform product; Or carry out drying through spray tower, drying room, flash distillation etc. and obtain granular or powder-like product.
The present invention also provides described composition to be used as the purposes of Yellow active dye.Described Yellow active dye is used for the printing and dyeing of fiber or its yarn fabric, described printing and dyeing are the printing and dyeing to cotton fibre, wool fiber, regenerated fibre or their yarn fabric, or the printing and dyeing to tynex, cellulosic fibre, protein fibre or their yarn fabric.
The present invention also provides a kind of fiber, and it adopts described Yellow active dye composition print and dye to fiber and obtain.
The present invention also provides a kind of yarn fabric of fiber, and it adopts the yarn fabric of described Yellow active dye composition to fiber print and dye and obtain.
the effect of invention
Composition of the present invention, when using as Yellow reactive dyes, has the following advantages: bright in color light, light fastness and washing fastness are good, degree of fixation is high, reproducibility is good.Product of the present invention is applicable to the printing and dyeing of cotton, wool, regenerated fibre or their yarn fabrics, or the printing and dyeing of tynex, cellulosic fibre, protein fibre or their yarn fabric, is specially adapted to the printing and dyeing of cellulosic fibre.
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited to this.
Active yellow dye composition of the present invention, the component A used, B component and component C, can synthesize by mode well known to those skilled in the art easily, as diazotization conveniently, couling process preparation, also can adopt commercially available prod.
Embodiment 1
The B component of the component A of 49 weight part formulas (I-1), 49 weight part formulas (II-1) and the component C of 2 weight part formulas (III-1) are carried out dry powder blend by Mixed Pinyin machine, obtain composition 1, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.
Embodiment 2
By give money as a gift containing 45 weight part formulas (I-1) component A dyestuff magma, give money as a gift and stir containing the B component dyestuff magma of 50 weight part formulas (II-1) and the component C dyestuff magma of giving money as a gift containing 5 weight part formulas (III-1) after, dry in drying room, obtain composition 2, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.
Embodiment 3
The B component of the component A of 46 weight part formulas (I-4), 46 weight part formulas (II-1) and the component C of 8 weight part formulas (III-1) are carried out dry powder blend by Mixed Pinyin machine, obtain composition 3, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.
Embodiment 4
The B component of the component A of 45 weight part formulas (I-4), 45 weight part formulas (II-4), the component C of 5 weight part formulas (III-1) and the Sodium sulfate anhydrous.min(99) of 5 weight parts are carried out dry powder blend by Mixed Pinyin machine, obtain composition 4, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.
Embodiment 5
The B component of the component A of 48 weight part formulas (I-1), 47 weight part formulas (II-4) and the component C of 5 weight part formulas (III-1) are carried out dry powder blend by Mixed Pinyin machine, obtain composition 5, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.
Embodiment 6
The B component of the component A of 48 weight part formulas (I-4), 47 weight part formulas (II-1) and the component C of 5 weight part formulas (III-1) are carried out dry powder blend by Mixed Pinyin machine, obtain composition 6, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.
Comparative example 1
The component A of 60 weight part formulas (I-1) and the Sodium sulfate anhydrous.min(99) of 40 weight parts are carried out dry powder blend by Mixed Pinyin machine, obtains composition 7, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.
Comparative example 2
The B component of the component A of 50 weight part formulas (I-1) and 50 weight part formulas (II-1) is carried out dry powder blend by Mixed Pinyin machine, obtains composition 8, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.
Comparative example 3
The B component of 60 weight part formulas (II-1), the component C of 5 weight part formulas (III-1) and the Sodium sulfate anhydrous.min(99) of 35 weight parts are carried out dry powder blend by Mixed Pinyin machine, obtain composition 9, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.
Comparative example 4
The component A of 57 weight part formulas (I-1), the component C of 8 weight part formulas (III-1) and the Sodium sulfate anhydrous.min(99) of 35 weight parts are carried out dry powder blend by Mixed Pinyin machine, obtain composition 10, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.
Comparative example 5
With reference to patent No. CN1253150A embodiment 10, component shown in component shown in 50 weight part formulas (A-2), 50 weight part formulas (B-1) is carried out dry powder blend by Mixed Pinyin machine, obtain composition 11, using described composition as Yellow reactive dyes, can by cotton dyeing yellowly.M in formula (A-2) and (B-1) represents sodium ion.
Comparative example 6
With reference to patent No. CN101899228A embodiment 3, component shown in component shown in 60 weight part formulas (I-2), 8 weight part formulas (II-2) and the component shown in 32 weight part formulas (III-2) are carried out dry powder blend by Mixed Pinyin machine, be prepared into composition 12, using described composition as Yellow reactive dyes, cotton dyeing can be become golden yellow.
Dyeing Example
100g cotton fabric is put into the dye bath of the composition that 1000g 45g/L sodium-chlor and 2g obtain according to embodiment 1 ~ 6 and comparative example 1 ~ 6, after being warmed up to 60 DEG C with 1 DEG C/minute, add the sodium carbonate solution of 100g 20g/L, and dye 45 minutes at this temperature, then rinsed by dyeing and weaving thing, post rinse after soaping 15 minutes with nonionic detergent is also dry.Carry out testing its degree of fixation, fast light, water-fastness and colour fastness to perspiration according to GB/T 2391-2006, GB/T8427-2008, GB/T 3921-2008 and GB/T 3922-1995, result is as table 1:
Table 1
As shown in Table 1, composition of the present invention, when being applied to printing and dyeing as Yellow reactive dyes, degree of fixation and washing fastness high, every fastness properties is excellent, thus has comparatively excellent over-all properties.
Claims (11)
1. a Yellow active dye composition, it comprises the component A shown in formula (I), the B component shown in formula (II), the component C shown in formula (III) and optional auxiliary agent; Component A is 30 ~ 60 weight parts, and B component is 30 ~ 60 weight parts, and component C is 1 ~ 10 weight part, and auxiliary agent is 0 ~ 60 weight part:
Wherein, M
1, M
2, M
3be hydrogen, potassium or sodium independently of one another; R
2for-CH=CH
2or-C
2h
4oSO
3m
1, R
4for-CH=CH
2or-C
2h
4oSO
3m
2, R
6for-CH=CH
2or-C
2h
4oSO
3m
3; R
1, R
3, R
5be (C independently of one another
1~ C
3)-alkyl or-NH
2; X
1, X
2be selected from chlorine or fluorine independently of one another.
2. Yellow active dye composition according to claim 1, is characterized in that, described component A be selected from formula (I-1) ~ (I-7) compound one or more
3. the Yellow active dye composition according to any one of claim 1 ~ 2, is characterized in that, described B component be selected from formula (II-1) ~ (II-8) compound one or more
4. the Yellow active dye composition according to any one of claims 1 to 3, is characterized in that, described component C be selected from formula (III-1) ~ (III-7) compound one or more
5. the Yellow active dye composition according to any one of Claims 1 to 4, is characterized in that, described auxiliary agent is dispersion agent, diffusant and/or weighting agent, can be used alone one, also can use their mixture.
6. the preparation method of Yellow active dye composition according to any one of Claims 1 to 5, one of comprises the steps:
(1) by the dry powder of the dry powder of component A, B component, the dry powder of component C and optional auxiliary agent, carry out being mixed to get product;
(2) by the slurry of the slurry of component A, B component, the slurry of component C and optional auxiliary agent, add in container, stir subsequently, then drying obtains product;
(3) join in the slurry of remaining components by the dry powder of one or two component in component A, B component, component C, together with optional auxiliary agent, add in container, stir subsequently, then drying obtains product.
7. according to any one of Claims 1 to 5, composition is used as the purposes of Yellow active dye.
8. purposes according to claim 7, is characterized in that, described Yellow active dye is used for the printing and dyeing of fiber or its yarn fabric.
9. purposes according to claim 8, it is characterized in that, described printing and dyeing are the printing and dyeing to cotton fibre, wool fiber, regenerated fibre or their yarn fabric, or the printing and dyeing to tynex, cellulosic fibre, protein fibre or their yarn fabric.
10. a fiber, is characterized in that, adopts Yellow active dye composition described in any one of Claims 1 to 5 print and dye to fiber and obtain.
The yarn fabric of 11. 1 kinds of fibers, is characterized in that, adopts the yarn fabric of Yellow active dye composition to fiber described in any one of Claims 1 to 5 print and dye and obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410532528.3A CN104231668B (en) | 2014-10-11 | 2014-10-11 | A kind of Yellow active dye composition and its production and use, and the yarn fabric of the fiber obtained by its printing and dyeing or fiber |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410532528.3A CN104231668B (en) | 2014-10-11 | 2014-10-11 | A kind of Yellow active dye composition and its production and use, and the yarn fabric of the fiber obtained by its printing and dyeing or fiber |
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| Publication Number | Publication Date |
|---|---|
| CN104231668A true CN104231668A (en) | 2014-12-24 |
| CN104231668B CN104231668B (en) | 2016-03-09 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317956A (en) * | 2016-07-26 | 2017-01-11 | 萧县凯奇化工科技有限公司 | Green and environment-friendly yellow G dye and preparation method thereof |
| CN106433216A (en) * | 2016-10-12 | 2017-02-22 | 上海雅运纺织化工股份有限公司 | Yellow reactive dye composition and dyeing application and method thereof on fibers |
| CN110387143A (en) * | 2019-07-22 | 2019-10-29 | 浙江瑞华化工有限公司 | A kind of Yellow active dye composition and its preparation method and application |
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| JPH07238232A (en) * | 1994-02-28 | 1995-09-12 | Mitsubishi Kasei Hoechst Kk | Reactive dye composition |
| CN101597435A (en) * | 2008-06-03 | 2009-12-09 | 上海雅运纺织化工有限公司 | Yellow active dye composition and application thereof |
| CN101899228A (en) * | 2010-06-29 | 2010-12-01 | 浙江科永化工有限公司 | Active yellow dye composition |
| CN102433030A (en) * | 2011-10-28 | 2012-05-02 | 浙江瑞华化工有限公司 | Active yellow dye composition |
| CN103965653A (en) * | 2014-05-12 | 2014-08-06 | 浙江亿得化工有限公司 | Post-mercerized composite activated dye as well as dyeing method and use thereof |
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2014
- 2014-10-11 CN CN201410532528.3A patent/CN104231668B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07238232A (en) * | 1994-02-28 | 1995-09-12 | Mitsubishi Kasei Hoechst Kk | Reactive dye composition |
| CN101597435A (en) * | 2008-06-03 | 2009-12-09 | 上海雅运纺织化工有限公司 | Yellow active dye composition and application thereof |
| CN101899228A (en) * | 2010-06-29 | 2010-12-01 | 浙江科永化工有限公司 | Active yellow dye composition |
| CN102433030A (en) * | 2011-10-28 | 2012-05-02 | 浙江瑞华化工有限公司 | Active yellow dye composition |
| CN103965653A (en) * | 2014-05-12 | 2014-08-06 | 浙江亿得化工有限公司 | Post-mercerized composite activated dye as well as dyeing method and use thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317956A (en) * | 2016-07-26 | 2017-01-11 | 萧县凯奇化工科技有限公司 | Green and environment-friendly yellow G dye and preparation method thereof |
| CN106433216A (en) * | 2016-10-12 | 2017-02-22 | 上海雅运纺织化工股份有限公司 | Yellow reactive dye composition and dyeing application and method thereof on fibers |
| CN106433216B (en) * | 2016-10-12 | 2018-04-20 | 上海雅运纺织化工股份有限公司 | Yellow active dye composition and its tint applications and method on fiber |
| CN110387143A (en) * | 2019-07-22 | 2019-10-29 | 浙江瑞华化工有限公司 | A kind of Yellow active dye composition and its preparation method and application |
| CN110387143B (en) * | 2019-07-22 | 2020-12-15 | 浙江瑞华化工有限公司 | Yellow reactive dye composition and preparation method and application thereof |
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|---|---|
| CN104231668B (en) | 2016-03-09 |
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