CN102428934B - Novel germicide composition containing probenazole - Google Patents
Novel germicide composition containing probenazole Download PDFInfo
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- CN102428934B CN102428934B CN201110455452.5A CN201110455452A CN102428934B CN 102428934 B CN102428934 B CN 102428934B CN 201110455452 A CN201110455452 A CN 201110455452A CN 102428934 B CN102428934 B CN 102428934B
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- probenazole
- thifluzamide
- isoprothiolane
- kasugarnycin
- jinggangmeisu
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Abstract
The invention discloses a novel germicide composition containing probenazole. The composition is mainly characterized by containing an active ingredient A, an active ingredient B and the balance of auxiliaries, wherein the active ingredient A is probenazole; the active ingredient B is any one of kasugamycin, validamycin, thifluzamide and isoprothiolane; and the weight ratio of the active ingredient A to the active ingredient B is (80:1)-(1:80). The composition can be prepared into wettable powder, water dispersible granules, emulsifiable solution, suspensions, suspoemulsion, emulsion in water, microemulsion, microcapsule suspensions and microcapsule-microcapsule suspensions. The composition can be used for controlling various diseases, has obvious synergistic effect, expands the germicidal spectrum, has higher activity against the diseases of rice, cruciferous vegetables, fruit trees and cotton, has slow release effect, reduces the pesticide application quantity, is harmless to people and livestock, has no phytotoxicity and has good environmental compatibility. The preparations have the advantages of enhanced adhesive forces, rain wash resistance, long duration of efficacy and the like.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of bactericidal composition containing probenazole.
Background technology
Probenazole (probenazole), chemical name: PROBENAZOLE, chemical molecular formula: C
10h
9nO
3s.Can extensively protect and eradicate field crop, fruit tree, grassland, vegetables germ.Antimicrobial acivity slightly in isolated test; Process paddy rice, promote Root Absorption, cover crop is not subject to infecting of Pyricularia oryzae and rice bacterial leaf spot pathogenic bacteria.
The bactericide such as kasugarnycin, jinggangmeisu, thifluzamide, Isoprothiolane have excellent preventive effect and therapeutic action to rice blast, banded sclerotial blight, false smut.
Yet in the real process of agricultural production, preventing and treating the problem that disease the most easily produces is the generation of disease drug resistance.Different cultivars composition carries out composite, is to prevent and treat the very common method of resistance disease.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor's lot of experiments, find, after probenazole and kasugarnycin, jinggangmeisu, thifluzamide, Isoprothiolane are composite, synergistic effect is remarkable, and Environmental compatibility is fabulous, has greatly reduced agricultural chemicals dosage.
Summary of the invention
The Pesticidal combination that the present invention proposes contains in probenazole and kasugarnycin, jinggangmeisu, thifluzamide, Isoprothiolane any one two kinds of active components, and appropriate surfactant and carrier.
A bactericidal composition containing probenazole, comprises active components A, active component B, auxiliary agent surplus.It is characterized in that: active components A is probenazole, active component B is a kind of arbitrarily in kasugarnycin, jinggangmeisu, thifluzamide, Isoprothiolane, and the weight ratio of active components A and active component B is 80 ︰ 1～1 ︰ 80.
The described bactericidal composition containing probenazole, is characterized in that: the weight ratio of active components A and active component B is 60 ︰ 1～1 ︰ 40.
The described bactericidal composition containing probenazole, is characterized in that: the weight ratio of active components A and kasugarnycin is 45 ︰ 1～5 ︰ 1.
The described bactericidal composition containing probenazole, is characterized in that: the weight ratio of active components A and jinggangmeisu is 36 ︰ 1～1 ︰ 1.
The described bactericidal composition containing probenazole, is characterized in that: the weight ratio of active components A and thifluzamide is 35 ︰ 1～1 ︰ 1.
The described bactericidal composition containing probenazole, is characterized in that: the weight ratio of active components A and Isoprothiolane is 18 ︰ 1～1 ︰ 3.
The described bactericidal composition containing probenazole, is characterized in that: composition is made wetting powder, water dispersible granules, missible oil, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, micro-capsule-microcapsule suspending agent.
The described bactericidal composition containing probenazole is for preventing and treating the application of disease on paddy rice, brassicaceous vegetable, fruit tree, cotton.
Described application, prevents and treats disease and comprises: rice blast, banded sclerotial blight, false smut, damping off, bacterial leaf-blight, powdery mildew, gray mold, downy mildew, leaf spot, anthracnose, fusarium wilt, rust, early blight, late blight, bacillary angle spot, shot hole, shothole disease, culm rot.
In Pesticidal combination of the present invention, at least contain a kind of surfactant, the dispersion of active component in water while being beneficial to use.Surface-active contents is 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, emulsifier or defoamer.
The described bactericidal composition containing probenazole, is characterized in that: while making wetting powder, comprise following constituent content: active components A 0.1%～80%, active component B0.1%～80%, dispersant 5%～10%, wetting agent 2%～10%, filler 8%～92.8%.
Active components A, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, can be made into probenazole kasugarnycin wetting powder product.
The described bactericidal composition containing probenazole, is characterized in that: when composition is made water dispersible granules, comprise following constituent content: active components A 0.1%～80%, active component B0.1%～80%, dispersant 3%～12%, wetting agent 1%～8%, disintegrant 1%～10%, filler 10%～94.8%.
Active components A, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, make probenazole kasugamycin water-dispersion granule product.
The described bactericidal composition containing probenazole, it is characterized in that: when composition is made suspending agent, comprise following constituent content: active components A 0.1%～50%, active component B0.1%～50%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, thickener 0.1～2%, antifreeze 0.1～8%, emulsifier 0.5%～5%, water adds to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in above-mentioned formulation material are mixed through high speed shear, add probenazole, kasugarnycin ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make suspending agent product of the present invention.
The described bactericidal composition containing probenazole, it is characterized in that: when composition is made suspension emulsion, comprise following constituent content: active components A 0.1%～50%, active component B0.1%～50%, emulsifier 2%～12%, dispersant 2%～10%, defoamer 0.1%～2%, thickener 0.1%～2%, antifreeze 0.1%～8%, stabilizing agent 0.05%～3%, deionized water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in above-mentioned formulation material are mixed through high speed shear, add the former medicine of probenazole, in ball mill, ball milling is 2～3 hours, make diameter of particle all below 5 μ m, make probenazole suspending agent, then by the former medicine of active component B, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.
When making aqueous emulsion, composition comprises following constituent content: active components A 0.1%～50%, active component B0.1%～50%, solvent 0%～30%, emulsifier 1%～15%, co-emulsifier 0%～8%, antifreeze 0%～10%, thickener 0.1%～2%, defoamer 0.01%～2%, deionized water are supplied surplus.
Above-mentioned formula is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make to be dissolved into even oil phase; Water, antifreeze, thickener, defoamer are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, make aqueous emulsion product of the present invention.
When making microemulsion, composition comprises following constituent content: active components A 0.1%～50%, active component B0.1%～50%, solvent 0%～30%, emulsifier 3%～20%, co-emulsifier 0%～12%, antifreeze 0%～10%, thickener 0.1%～2%, defoamer 0.01%～2%, stabilizing agent 0%～4%, deionized water is supplied surplus.
Probenazole and the former medicine of active component B are dissolved in the homogenizer that solvent and cosolvent are housed; After emulsifier, stabilizing agent and antifreeze, water being joined in the homogenizer that above-mentioned solution is housed, give strong mixing and homogenize, finally obtain the as clear as crystal microemulsion product of the present invention of outward appearance.
The formulation technique that composition is made missible oil, microcapsule suspending agent, micro-capsule-microcapsule suspending agent is technical matters conventionally known to one of skill in the art.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during ester polyoxyethylene is phonetic.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, washing powder, agriculture breast 2000
#series, sldium lauryl sulfate, wetting and penetrating agent F, wetting agent T, spaonin powder, tea are withered, one or more in silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, glucose.
Described emulsifier is selected from: agriculture breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400
#(benzyl dimethyl phenol polyoxy ethyl ether), agriculture breast 600
#(phenyl phenol polyoxy ethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxy ethyl ether), agriculture breast 36
#(phenethyl fluosite polyoxy ethyl ether), agriculture breast 1600
#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), agriculture breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), agriculture breast 34
#one or more in (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), EO series (fat alcohol alcohol APEO).
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10aliphatic alcohols, C
10～20one or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate, vegetable oil.
Described macromolecule cyst material: PIC, polyfunctional group acyl halide polyamines, polyfunctional group acyl halide dihydroxylic alcohols.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Missible oil the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspending agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) probenazole and kasugarnycin, jinggangmeisu, thifluzamide, Isoprothiolane composite after, there is notable synergistic and lasting effect;
(2) expanded fungicidal spectrum, the rice blast of paddy rice, brassicaceous vegetable, fruit tree, cotton, banded sclerotial blight, false smut, damping off, bacterial leaf-blight, bacillary angle spot, shot hole, shothole disease, culm rot etc. have all been had to greater activity;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4) to person poultry safety, Environmental compatibility is good, and disease is difficult for developing immunity to drugs.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment is weight ratio, but the present invention is not limited thereto.
Application Example one
Embodiment 1 62% probenazole kasugarnycin wetting powder
Probenazole 60%, kasugarnycin 2%, polyoxyethylene carboxylate 5.8%, wetting and penetrating agent F6.5%, bentonite add to 100%, and mixture carries out air-flow crushing, make 62% probenazole kasugarnycin wetting powder.
Embodiment 2 81% probenazole kasugarnycin wetting powders
Probenazole 80%, kasugarnycin 1%, aliphatic amine polyoxyethylene are phonetic 5.5%, expoxy propane condensation product 5%, white carbon 6.5%, and kaolin adds to 100%, and mixture carries out air-flow crushing, makes 81% probenazole kasugarnycin wetting powder.
Embodiment 3 60% probenazole jinggangmeisu wetting powders
Probenazole 55%, jinggangmeisu 5%, the phonetic formaldehyde condensation products sulphate 5.5% of alkylphenol-polyethenoxy, soapberry powder 5.5%, bentonite add to 100%, and mixture carries out air-flow crushing, make 60% probenazole jinggangmeisu wetting powder.
Embodiment 4 75% probenazole jinggangmeisu wetting powders
Probenazole 72%, jinggangmeisu 3%, aryl phenol polyoxyethylene succinate sulfonate 4.5%, neopelex 5.5%, spaonin powder 2.5%, kaolin add to 100%, mixture carries out air-flow crushing, makes 75% probenazole jinggangmeisu wetting powder.
Embodiment 5 66% probenazole thifluzamide wetting powders
Probenazole 64%, thifluzamide 2%, aliphatic amine polyoxyethylene are phonetic 5.5%, soapberry powder 5.5%, white carbon 6.5%, and kaolin adds to 100%, and mixture carries out air-flow crushing, makes 66% probenazole thifluzamide wetting powder.
Embodiment 6 81% probenazole thifluzamide wetting powders
Probenazole 80%, thifluzamide 1%, ester polyoxyethylene are phonetic 6.5%, silkworm excrement 3.5%, bentonite add to 100%, and mixture carries out air-flow crushing, makes 81% probenazole thifluzamide wetting powder.
Embodiment 7 72% probenazole Isoprothiolane wetting powders
Probenazole 70%, Isoprothiolane 2%, aliphatic amine polyoxyethylene are phonetic 5%, expoxy propane condensation product 5%, white carbon 6.5%, and kaolin adds to 100%, and mixture carries out air-flow crushing, makes 72% probenazole Isoprothiolane wetting powder.
Embodiment 8 81% probenazole Isoprothiolane wetting powders
Probenazole 1%, Isoprothiolane 80%, polyoxyethylene carboxylate 5.5%, wetting and penetrating agent F5.5%, bentonite add to 100%, and mixture carries out air-flow crushing, make 81% probenazole Isoprothiolane wetting powder.
Embodiment 9 55% probenazole kasugamycin water-dispersion granules
Probenazole 50%, kasugarnycin 5%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5.5%, expoxy propane condensation product 5.5%, kaolin add to 100%, mix and make 55% probenazole kasugamycin water-dispersion granule.
Embodiment 10 82% probenazole kasugamycin water-dispersion granules
Probenazole 80%, kasugarnycin 2%, wetting agent T6.5%, naphthalene sulfonic acid-formaldehyde condensation product 4.5%, polyvinylpyrrolidone 3%, white carbon 5%, bentonite add to 100%, mix and make 82% probenazole kasugamycin water-dispersion granule.
Embodiment 11 64% probenazole jinggangmeisu water dispersible granules
Probenazole 60%, jinggangmeisu 4%, polyoxyethylene carboxylate 5.5%, soapberry powder 5%, aluminium chloride 3.5%, kaolin add to 100%, mix and make 64% probenazole jinggangmeisu water dispersible granules.
Embodiment 12 80% probenazole jinggangmeisu water dispersible granules
Probenazole 72%, jinggangmeisu 8%, polycarboxylate 5.5%, wetting and penetrating agent F4.5%, sodium bicarbonate 2%, gum Arabic 2.5%, bentonite add to 100%, mix and make 80% probenazole jinggangmeisu water dispersible granules.
Embodiment 13 68% probenazole thifluzamide water dispersible granules
Probenazole 64%, thifluzamide 4%, wetting agent T6%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5%, polyvinylpyrrolidone 3%, white carbon 5%, bentonite add to 100%, mix and make 68% probenazole thifluzamide water dispersible granules.
Embodiment 14 78% probenazole thifluzamide water dispersible granules
Probenazole 76%, thifluzamide 2%, octylphenol polyethylene oxyethylene group ether sulfate 5%, Nekal BX 4%, sodium bicarbonate 4%, white dextrin 2%, bentonite add to 100%, mix and make 78% probenazole thifluzamide water dispersible granules.
Embodiment 15 60% probenazole 'Daowenling ' water dispersible granules
Probenazole 50%, Isoprothiolane 10%, wetting agent T4.5%, naphthalene sulfonic acid-formaldehyde condensation product 6%, polyvinylpyrrolidone 4%, white carbon 5%, bentonite add to 100%, mix and make 60% probenazole 'Daowenling ' water dispersible granule.
Embodiment 16 85% probenazole 'Daowenling ' water dispersible granules
Probenazole 80%, Isoprothiolane 5%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, expoxy propane condensation product 4%, kaolin add to 100%, mix and make 85% probenazole 'Daowenling ' water dispersible granule.
Embodiment 17 36% probenazole kasugarnycin suspending agents
Probenazole 32%, kasugarnycin 4%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, amide-type defoamer 4%, aluminium-magnesium silicate 3%, OP series 6%, deionized water add to 100%, mix and make 36% probenazole kasugarnycin suspending agent.
Embodiment 18 48% probenazole kasugarnycin suspending agents
Probenazole 45%, kasugarnycin 3%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, wetting agent T5%, C
8～10aliphatic alcohols 3%, polyvinyl alcohol 3%, deionized water add to 100%, mix and make 48% probenazole kasugarnycin suspending agent.
Embodiment 19 35% probenazole jinggangmeisu suspending agents
Probenazole 30%, jinggangmeisu 5%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, spaonin powder 2%, PAA 5%, silicone oil 2%, deionized water add to 100%, mix and make 35% probenazole jinggangmeisu suspending agent.
Embodiment 20 44% probenazole jinggangmeisu suspending agents
Probenazole 40%, jinggangmeisu 4%, polycarboxylate 5%, the phonetic formaldehyde condensation products sulphate 4% of alkylphenol-polyethenoxy, silicone defoamer 2%, aluminium-magnesium silicate 2%, phenyl phenol polyoxy ethyl ether phosphate 5%, deionized water add to 100%, mix and make 44% probenazole jinggangmeisu suspending agent.
Embodiment 21 36% probenazole thifluzamide suspending agents
Probenazole 33%, thifluzamide 3%, polyoxyethylene carboxylate 6.5%, silicone defoamer 2%, aluminium-magnesium silicate 3%, OP series 6%, deionized water add to 100%, mix and make 36% probenazole thifluzamide suspending agent.
Embodiment 22 42% probenazole thifluzamide suspending agents
Probenazole 40%, thifluzamide 2%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, soapberry powder 3%, PAA 5%, silicone oil 2%, deionized water add to 100%, mix and make 42% probenazole thifluzamide suspending agent.
Embodiment 23 30% probenazole Isoprothiolane suspending agents
Probenazole 20%, Isoprothiolane 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, amide-type defoamer 4%, aluminium-magnesium silicate 3%, OP series 6%, deionized water add to 100%, mix and make 30% probenazole Isoprothiolane suspending agent.
Embodiment 24 50% probenazole Isoprothiolane suspending agents
Probenazole 25%, Isoprothiolane 25%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, wetting agent T5%, C
8～10aliphatic alcohols 3%, polyvinyl alcohol 3%, deionized water add to 100%, mix and make 50% probenazole Isoprothiolane suspending agent.
Embodiment 25 42% probenazole kasugarnycin suspension emulsions
Probenazole 40%, kasugarnycin 2%, lignosulfonates 6%, Nekal BX 6%, 600# phosphate 6%, crospolyvinylpyrrolidone 3%, glycerine 2%, deionized water add to 100%, mix and make 42% probenazole kasugarnycin suspension emulsion.
Embodiment 26 40.5% probenazole kasugarnycin suspension emulsions
Probenazole 0.5%, kasugarnycin 40%, ester polyoxyethylene are phonetic 6%, spaonin powder 5%, sodium alginate 3%, Nongru-700 #6%, triethylene glycol 3%, silicone oil 2%, deionized water add to 100%, through mixing, make 40.5% probenazole kasugarnycin suspension emulsion.
Embodiment 27 39% probenazole jinggangmeisu suspension emulsions
Probenazole 36%, jinggangmeisu 3%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, tea are withered 4%, polyvinylpyrrolidone 2%, agriculture breast 36#6%, glycerine 3%, silicone 2%, deionized water add to 100%, through mixing, make 39% probenazole jinggangmeisu suspension emulsion.
Embodiment 28 40.5% probenazole jinggangmeisu suspension emulsions
Probenazole 40%, jinggangmeisu 0.5%, triethanolamine salt 6%, agriculture breast 33#6%, silicone compound 3%, polyethylene glycol 2%, propane diols 2%, deionized water add to 100%, mix and make 40.5% probenazole jinggangmeisu suspension emulsion.
Embodiment 29 32% probenazole thifluzamide suspension emulsions
Probenazole 30%, thifluzamide 2%, lignosulfonates 6%, Nekal BX 5%, agriculture breast 1600#6%, carboxymethyl cellulose 3%, glycerine 2%, deionized water add to 100%, mix and make 32% probenazole thifluzamide suspension emulsion.
Embodiment 30 40.5% probenazole thifluzamide suspension emulsions
Probenazole 0.5%, thifluzamide 40%, ester polyoxyethylene are phonetic 7%, spaonin powder 3%, polyvinylpyrrolidone 4%, agriculture breast 1600#5%, glycerine 3%, C
8～10aliphatic alcohols 2%, deionized water add to 100%, through mixing, make 40.5% probenazole thifluzamide suspension emulsion.
Embodiment 31 40% probenazole Isoprothiolane suspension emulsions
Probenazole 10%, Isoprothiolane 30%, ester polyoxyethylene are phonetic 6.5%, spaonin powder 4%, sodium alginate 2%, Nongru-700 #5.5%, triethylene glycol 2%, silicone oil 2%, deionized water add to 100%, through mixing, make 40% probenazole Isoprothiolane suspension emulsion.
Embodiment 32 44% probenazole Isoprothiolane suspension emulsions
Probenazole 40%, Isoprothiolane 4%, lignosulfonates 6%, Nekal BX 3%, 600# phosphate 5%, crospolyvinylpyrrolidone 3%, glycerine 2%, deionized water add to 100%, mix and make 44% probenazole Isoprothiolane suspension emulsion.
Embodiment 33 65% probenazole kasugarnycin missible oil
Probenazole 62.5%, kasugarnycin 2.5%, ethanol 5%, OP series 6%, polyethylene glycol 5%, toluene add to 100%, through mixing, make 65% probenazole kasugarnycin missible oil.
Embodiment 34 63% probenazole jinggangmeisu missible oil
Probenazole 60%, jinggangmeisu 3%, triethanolamine salt 6%, agriculture breast 33#6%, polyethylene glycol 6%, propane diols 5%, dimethylbenzene add to 100%, mix and make 63% probenazole jinggangmeisu missible oil.
Embodiment 35 65% probenazole thifluzamide missible oil
Probenazole 60%, thifluzamide 5%, styrene polyoxyethylene ether ammonium sulfate salt 6%, agriculture breast 600#5%, diethylene glycol (DEG) 6%, propane diols 3%, acetone add to 100%, mix and make 65% probenazole thifluzamide missible oil.
Embodiment 36 80% probenazole Isoprothiolane missible oil
Probenazole 60%, Isoprothiolane 20%, triethanolamine salt 6%, agriculture breast 33#6%, polyethylene glycol 7%, propane diols 4%, dimethylbenzene add to 100%, mix and make 80% probenazole Isoprothiolane missible oil.
Embodiment 37 30% probenazole kasugarnycin microemulsions
Probenazole 24%, kasugarnycin 6%, ethylene oxide-propylene oxide block copolymer 5%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, propane diols 3%, butyl ether 3%, deionized water supplies 100%, mixes and makes 30% probenazole kasugarnycin microemulsion.
Embodiment 38 50% probenazole kasugarnycin microemulsions
Probenazole 48%, kasugarnycin 2%, sapn series 6%, methyl alcohol 5%, aliphatic alcohol polyoxyvinethene phosphate 6%, propane diols 2%, gelatin 2%, deionized water supplies 100%, mixes and makes 50% probenazole kasugarnycin microemulsion.
Embodiment 39 24.3% probenazole jinggangmeisu microemulsions
Probenazole 0.3%, jinggangmeisu 24%, AEO series 6%, methyl alcohol 4%, aliphatic alcohol polyoxyvinethene phosphate 5%, propane diols 2%, gelatin 2%, deionized water supplies 100%, mixes and makes 24.3% probenazole jinggangmeisu microemulsion.
Embodiment 40 32% probenazole jinggangmeisu microemulsions
Probenazole 28%, jinggangmeisu 4%, By series 6%, ethyl acetate 6%, polyethylene glycol 6%, C
10～20saturated fat acids 2%, deionized water adds to 100%, through mixing, makes 32% probenazole jinggangmeisu microemulsion.
Embodiment 41 27% probenazole thifluzamide microemulsions
Probenazole 24%, thifluzamide 3%, By series 6%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, propane diols 3%, butyl ether 2%, deionized water supplies 100%, mixes and makes 27% probenazole thifluzamide microemulsion.
Embodiment 42 41% probenazole thifluzamide microemulsions
Probenazole 1%, thifluzamide 40%, ethylene oxide-propylene oxide block copolymer 6%, methyl alcohol 4%, aliphatic alcohol polyoxyvinethene phosphate 6%, propane diols 2%, gelatin 2%, deionized water supplies 100%, mixes and makes 41% probenazole thifluzamide microemulsion.
Embodiment 43 40.5% probenazole Isoprothiolane microemulsions
Probenazole 40%, Isoprothiolane 0.5%, ethylene oxide-propylene oxide block copolymer 6%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, propane diols 3%, butyl ether 2%, deionized water supplies 100%, mixes and makes 40.5% probenazole Isoprothiolane microemulsion.
Embodiment 44 50% probenazole Isoprothiolane microemulsions
Probenazole 40%, Isoprothiolane 10%, sapn series 7%, methyl alcohol 5%, aliphatic alcohol polyoxyvinethene phosphate 5%, propane diols 2%, gelatin 2%, deionized water supplies 100%, mixes and makes 50% probenazole Isoprothiolane microemulsion.
Embodiment 45 20.5% probenazole kasugarnycin aqueous emulsions
Probenazole 0.5, kasugarnycin 20%, OP series phosphate 8%, butanols 5%, ethylene glycol 5%, silicone compound 2%, deionized water adds to 100%, makes 20.5% probenazole kasugarnycin aqueous emulsion.
Embodiment 46 34% probenazole kasugarnycin aqueous emulsions
Probenazole 32%, kasugarnycin 2%, aryl phenol polyoxyethylene succinate sulfonate 7%, agriculture breast 1600#7%, glycerine 3%, gum Arabic 2%, silicone oil 2%, deionized water supplies 100%, makes 34% probenazole kasugarnycin aqueous emulsion.
Embodiment 47 24% probenazole jinggangmeisu aqueous emulsions
Probenazole 20%, jinggangmeisu 4%, the phonetic formaldehyde condensation products sulphate 7% of alkylphenol-polyethenoxy, agriculture breast 33#6%, gelatin 3%, glycerine 3%, sodium chloride 2%, C
10～20saturated fat acids 2%, deionized water supplies 100%, makes 24% probenazole jinggangmeisu aqueous emulsion.
Embodiment 48 31% probenazole jinggangmeisu aqueous emulsions
Probenazole 1%, jinggangmeisu 30%, phenethyl phenol polyethenoxy ether 8%, alkylbenzenesulfonate 3%, agriculture breast 36#6%, glycerine 3%, gum Arabic 3%, silicone oil 2%, deionized water supplies 100%, makes 31% probenazole jinggangmeisu aqueous emulsion.
Embodiment 49 38% probenazole thifluzamide aqueous emulsions
Probenazole 36%, thifluzamide 2%, aryl phenol polyoxyethylene succinate sulfonate 6%, OP series 6%, glycerine 2%, gum Arabic 3%, silicone oil 2%, deionized water supplies 100%, makes 38% probenazole thifluzamide aqueous emulsion.
Embodiment 50 44% probenazole thifluzamide aqueous emulsions
Probenazole 40%, thifluzamide 4%, the phonetic formaldehyde condensation products sulphate 7% of alkylphenol-polyethenoxy, OP series 7%, gelatin 3%, glycerine 3%, sodium chloride 2%, C
10～20saturated fat acids 2%, deionized water supplies 100%, makes 44% probenazole thifluzamide aqueous emulsion.
Embodiment 51 36% probenazole isoprothiolane emulsion in waters
Probenazole 32%, Isoprothiolane 4%, aryl phenol polyoxyethylene succinate sulfonate 7%, agriculture breast 1600#7%, glycerine 2%, gum Arabic 2%, silicone oil 2%, deionized water supplies 100%, makes 36% probenazole isoprothiolane emulsion in water.
Embodiment 52 45% probenazole isoprothiolane emulsion in waters
Probenazole 30%, Isoprothiolane 15%, OP series phosphate 8%, butanols 5%, ethylene glycol 4%, silicone compound 2%, deionized water adds to 100%, makes 45% probenazole isoprothiolane emulsion in water.
Embodiment 53 40.5% probenazole active component B microcapsule suspending agents
Probenazole 0.5%, active component B40%, gamma cyhalothrin 7%, PIC 4.5%, octylphenol polyethylene oxyethylene group ether sulfate 4%, cyclohexanone 2.5%, ethylene oxide-propylene oxide block copolymer 3.5%, deionized water adds to 100% weight portion, makes 40.5% probenazole active component B microcapsule suspending agent.
Embodiment 54 40.5% probenazole active component B micro-capsule-microcapsule suspending agents
Probenazole 40%, active component B0.5%, polyfunctional group acyl halide dihydroxylic alcohols 3.5%, the phonetic formaldehyde condensation products sulphate 5.5% of alkylphenol-polyethenoxy, cyclohexanone 3.5%; By series 6.5%; deionized water adds to 100% weight portion, makes 40.5% probenazole active component B micro-capsule-microcapsule suspending agent.
Active component B described in above-described embodiment 53, embodiment 54 is a kind of arbitrarily in kasugarnycin, jinggangmeisu, thifluzamide, Isoprothiolane, and the weight ratio of probenazole and active component B is any one ratio between 1～80:80～1.
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR < 0.5 is antagonism, 0.5≤SR≤1.5 are summation action, SR > 1.5 is synergistic effect, on this basis, then carries out field trial.
Probenazole and active component B(B are selected from kasugarnycin, jinggangmeisu, thifluzamide, Isoprothiolane a kind of arbitrarily) composite to crop pest Toxicity Determination.
After the effective inhibition concentration scope of each medicament is determined in prerun, each medicament is established respectively 5 dosage by active constituent content and is processed, and establishes clear water contrast.With reference to < < farm-chemical indoor determination test rule bactericide > >, carry out, adopt mycelial growth rate method to measure the virulence of medicament to crop germ.After 72h, by right-angled intersection method, measure colony diameter, calculate and respectively process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value to (x), with method of least squares, tries to achieve virulence regression equation (y=a+bx), and calculates thus the EC50 value of every kind of medicament.According to Wadley method, calculate the different proportioning synergy ratio (SR) of two medicaments, SR < 0.5 is antagonism simultaneously, and 0.5≤SR≤1.5 are summation action, and SR > 1.5 is synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active component probenazole and active component B(kasugarnycin, jinggangmeisu, thifluzamide, Isoprothiolane) shared ratio in combination;
A is probenazole;
B is a kind of arbitrarily in kasugarnycin, jinggangmeisu, thifluzamide, Isoprothiolane.
Application Example two:
For trying disease: rice blast.
Experimental scheme: effective lethal concentration scope of determining probenazole, the former medicine of kasugarnycin and the two different proportioning mixture through preliminary experiment.
Toxicity test result one
The toxicity test of table 1 probenazole proportionings different from kasugarnycin to rice blast
As shown in Table 1, probenazole and the kasugarnycin EC to rice blast
50be respectively 12.45mg/L and 0.59mg/L.Probenazole and kasugarnycin proportioning are when 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that probenazole and kasugarnycin are mixed and all show synergistic effect in 80:1 to 1:80 scope, especially when the two proportioning is during at 35:1 to 1:1, synergistic effect is more obviously outstanding, through test people, find, probenazole and kasugarnycin are composite better to the spot synergistic effect of bacillary angle, wherein when probenazole and kasugarnycin percentage by weight are 15:1, synergy ratio SR is maximum, and synergistic effect is the most obvious.
Application Example three:
For trying disease: banded sclerotial blight.
Experimental scheme: effective lethal concentration scope of determining probenazole, the former medicine of jinggangmeisu and the two different proportioning mixture through preliminary experiment.
Toxicity test result two
The toxicity test of table 2 probenazole proportioning banded sclerotial blights different from jinggangmeisu
As shown in Table 2, probenazole and the jinggangmeisu EC to banded sclerotial blight
50be respectively 11.68mg/L and 1.35mg/L.Probenazole and jinggangmeisu proportioning are when 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that probenazole and jinggangmeisu are mixed and all show synergistic effect in 80:1 to 1:80 scope, especially when the two proportioning is during at 36:1 to 1:1, synergistic effect is more obviously outstanding, through test people, find, probenazole and composite jinggangmycin are better to damping off synergistic effect, wherein when probenazole and jinggangmeisu percentage by weight are 9:1, synergy ratio SR is maximum, and synergistic effect is the most obvious.
Application Example four:
For trying disease: banded sclerotial blight.
Experimental scheme: effective lethal concentration scope of determining probenazole, the former medicine of thifluzamide and the two different proportioning mixture through preliminary experiment.
Toxicity test result three
The toxicity test of table 3 probenazole proportionings different from thifluzamide to banded sclerotial blight
As shown in Table 3, probenazole and the thifluzamide EC to banded sclerotial blight
50be respectively 11.69mg/L and 0.82mg/L.Probenazole and thifluzamide proportioning are when 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that probenazole and thifluzamide are mixed and all show synergistic effect in 80:1 to 1:80 scope, especially when the two proportioning is during at 35:1 to 1:1, synergistic effect is more obviously outstanding, through test people, find, probenazole and thifluzamide are composite better to bacterial leaf-blight synergistic effect, wherein when probenazole and thifluzamide percentage by weight are 15:1, synergy ratio SR is maximum, and synergistic effect is the most obvious.
Application Example five:
For trying disease: rice blast.
Experimental scheme: effective lethal concentration scope of determining probenazole, isoprothiolane and the two different proportioning mixture through preliminary experiment.
Toxicity test result four
The toxicity test of table 4 probenazole proportionings different from Isoprothiolane to rice blast
As shown in Table 4, probenazole and the Isoprothiolane EC to rice blast
50be respectively 12.05mg/L and 3.95mg/L.Probenazole and Isoprothiolane proportioning are when 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that probenazole and Isoprothiolane are mixed and all show synergistic effect in 80:1 to 1:80 scope, especially when the two proportioning is during at 18:1 to 1:3, synergistic effect is more obviously outstanding, through test people, find, probenazole and Isoprothiolane are composite better to culm rot synergistic effect, wherein when probenazole and Isoprothiolane percentage by weight are 3:1, synergy ratio SR is maximum, and synergistic effect is the most obvious.
Application Example six probenazoles and kasugarnycin and the composite control rice blast test of pesticide effectiveness thereof
This test medicine is provided by individual, contrast medicament 8% probenazole granule (commercial), 6% kasugarnycin wetting powder (commercial).
The investigation rice blast state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after dispenser 3 days, 14 days, 30 days for the second time, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 5 probenazole, kasugarnycin and the composite control rice blast test of pesticide effectiveness thereof
As can be seen from Table 5, after probenazole and kasugarnycin are composite, can effectively prevent and treat rice blast, through test people, find, probenazole and kasugarnycin are composite all has favorable effect to control shot hole, shothole disease, culm rot etc., after medicine, 30 days preventive effects are up to more than 95%, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example seven probenazoles and jinggangmeisu and the composite false smut test of pesticide effectiveness of preventing and treating thereof
This test medicine is provided by individual, contrast medicament 8% probenazole granule (commercial), the solvable pulvis of 20% jinggangmeisu (commercial).
The investigation false smut state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after dispenser 3 days, 14 days, 30 days for the second time, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 6 probenazole, jinggangmeisu and the composite false smut test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 6, after probenazole and composite jinggangmycin, can effectively prevent and treat false smut, through applicant, find, also better to preventive effects such as damping off, bacterial leaf-blight, bacillary angle spots after probenazole and composite jinggangmycin, after medicine, 30 days preventive effects reach more than 95%, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example eight probenazoles and thifluzamide and the composite banded sclerotial blight test of pesticide effectiveness of preventing and treating thereof
This test medicine is provided by individual, contrast medicament 8% probenazole granule (commercial), 240 grams per liter thifluzamide suspending agents (commercial).
The investigation banded sclerotial blight state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after dispenser 3 days, 14 days, 30 days for the second time, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 7 probenazole, thifluzamide and the composite banded sclerotial blight test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 7, after probenazole and thifluzamide are composite, can effectively prevent and treat banded sclerotial blight, through applicant, find, probenazole and thifluzamide are composite rear also better to preventive effects such as false smut, damping off, bacterial leaf-blights, after medicine, 30 days preventive effects reach more than 95%, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example nine probenazoles and Isoprothiolane and the composite control rice blast test of pesticide effectiveness thereof
This test medicine is provided by individual, contrast medicament 8% probenazole granule (commercial), 40% Isoprothiolane missible oil (commercial).
The investigation rice blast state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after dispenser 3 days, 14 days, 30 days for the second time, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 8 probenazole, Isoprothiolane and the composite control rice blast test of pesticide effectiveness thereof
As can be seen from Table 8, after probenazole and Isoprothiolane are composite, can effectively prevent and treat rice blast, through applicant, find, probenazole and Isoprothiolane are composite rear also better to preventive effects such as rice blast, banded sclerotial blight, false smut, after medicine, 30 days preventive effects reach more than 95%, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Claims (5)
1. the bactericidal composition containing probenazole, by active components A, active component B, auxiliary agent forms, and it is characterized in that: active components A is probenazole, active component B is thifluzamide, and the weight ratio of active components A and active component B is 80 ︰ 1 ~ 1 ︰ 80.
2. the bactericidal composition containing probenazole according to claim 1, is characterized in that: the weight ratio of active components A and active component B is 60 ︰ 1 ~ 1 ︰ 40.
3. the bactericidal composition containing probenazole according to claim 2, is characterized in that: the weight ratio of active components A and active component B is 35 ︰ 1 ~ 1 ︰ 1.
4. the bactericidal composition containing probenazole according to claim 1, is characterized in that: composition is made wetting powder, water dispersible granules, missible oil, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent.
5. the bactericidal composition containing probenazole according to claim 4 is for preventing and treating the application of disease on paddy rice, brassicaceous vegetable, fruit tree, cotton.
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| CN103918668B (en) * | 2014-04-24 | 2015-05-13 | 深圳诺普信农化股份有限公司 | Bactericidal composition |
| CN106538585A (en) * | 2016-09-30 | 2017-03-29 | 江苏新农化工有限公司 | Composition containing MTI-446, thifluzamide and probenazole and its preparation and application |
| CN107711831A (en) * | 2017-03-01 | 2018-02-23 | 南京高正农用化工有限公司 | A kind of bactericidal composition and its application process comprising probenazole |
| CN107242239A (en) * | 2017-06-30 | 2017-10-13 | 江苏省绿盾植保农药实验有限公司 | A kind of composite bactericide containing probenazole and Isoprothiolane and its application |
| CN114304168A (en) * | 2020-10-09 | 2022-04-12 | 陕西西大华特科技实业有限公司 | Bactericidal composition containing benziothiazolinone and isoprothiolane and application thereof |
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| CN101049103A (en) * | 2006-04-04 | 2007-10-10 | 江苏丘陵地区镇江农业科学研究所 | Insecticide for preventing and curing false smut of rice |
| CN101069505A (en) * | 2007-06-21 | 2007-11-14 | 王建军 | Sterilizing composition containing kasugamycin and isoprothiolane |
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| CN101049103A (en) * | 2006-04-04 | 2007-10-10 | 江苏丘陵地区镇江农业科学研究所 | Insecticide for preventing and curing false smut of rice |
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