CN102417196B - 一种阻燃剂型氢氧化镁的生产方法 - Google Patents
一种阻燃剂型氢氧化镁的生产方法 Download PDFInfo
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- CN102417196B CN102417196B CN201110275320.4A CN201110275320A CN102417196B CN 102417196 B CN102417196 B CN 102417196B CN 201110275320 A CN201110275320 A CN 201110275320A CN 102417196 B CN102417196 B CN 102417196B
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- magnesium
- ammonia
- magnesium hydroxide
- fire retardant
- retardant type
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 title claims abstract description 56
- 239000000347 magnesium hydroxide Substances 0.000 title claims abstract description 55
- 229910001862 magnesium hydroxide Inorganic materials 0.000 title claims abstract description 55
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 32
- 239000003063 flame retardant Substances 0.000 title claims abstract description 31
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 125
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 61
- 238000000034 method Methods 0.000 claims abstract description 59
- 159000000003 magnesium salts Chemical class 0.000 claims abstract description 39
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 28
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 18
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims abstract description 18
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 14
- 239000013078 crystal Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims description 42
- 239000012266 salt solution Substances 0.000 claims description 25
- 239000000243 solution Substances 0.000 claims description 19
- 239000002245 particle Substances 0.000 claims description 16
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 12
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 9
- 239000011777 magnesium Substances 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 238000002425 crystallisation Methods 0.000 claims description 4
- 230000008025 crystallization Effects 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 3
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- 238000010924 continuous production Methods 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 45
- 239000007789 gas Substances 0.000 description 20
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 239000000395 magnesium oxide Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010335 hydrothermal treatment Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 210000002966 serum Anatomy 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- -1 ammonium radical ion Chemical class 0.000 description 2
- 230000004087 circulation Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- WQVVYEYAFFYPIX-UHFFFAOYSA-N azane;magnesium Chemical class N.[Mg] WQVVYEYAFFYPIX-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000001839 systemic circulation Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
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CN102417196B true CN102417196B (zh) | 2014-02-12 |
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Families Citing this family (10)
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CN103101936B (zh) * | 2013-01-31 | 2015-10-21 | 辽宁红豆杉技术发展有限公司 | 一种氨气喷射法制备氢氧化镁的方法 |
CN106564918B (zh) * | 2015-10-13 | 2018-04-17 | 黄冈师范学院 | 一种制备氢氧化镁的方法 |
CN105480991B (zh) * | 2016-01-21 | 2020-09-15 | 青海盐湖工业股份有限公司 | 一种氢氧化镁制备方法及装置 |
CN107758706A (zh) * | 2017-09-25 | 2018-03-06 | 沈阳化工大学 | 一步法制备四方块状氢氧化镁阻燃剂工艺方法 |
CN108439441A (zh) * | 2018-03-13 | 2018-08-24 | 中南大学 | 一种常压短流程生产氢氧化镁的方法 |
EP3980140A4 (en) | 2019-06-07 | 2023-06-14 | FRS Group, LLC | LONG TERM RETARDANT WITH CORROSION INHIBITORS AND METHODS OF MAKING AND USING THEREOF |
WO2020247780A1 (en) | 2019-06-07 | 2020-12-10 | Frs Group, Llc | Long-term fire retardant with an organophosphate and methods for making and using same |
EP4263689A1 (en) | 2020-12-15 | 2023-10-25 | FRS Group, LLC | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
CN115491477B (zh) * | 2021-06-18 | 2024-01-12 | 协和化学工业株式会社 | 退火隔离剂的制备方法以及退火隔离剂和方向性电磁钢板 |
CN113816404B (zh) * | 2021-09-30 | 2023-08-22 | 沈阳工业大学 | 一种基于资源化利用的氢氧化镁生产装置及方法 |
Citations (3)
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CN1446751A (zh) * | 2002-03-22 | 2003-10-08 | 丹东松元化学有限公司 | 氨全循环法生产氢氧化镁和氧化镁的工艺 |
CN101224902A (zh) * | 2008-01-30 | 2008-07-23 | 大连海事大学 | 液氨-氨水双联沉淀高纯氢氧化镁的方法 |
CN101525144A (zh) * | 2009-04-08 | 2009-09-09 | 辽宁红豆杉技术发展有限公司 | 氨气鼓泡法一步反应制备颗粒形状统一的氢氧化镁方法 |
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CN101119931B (zh) * | 2005-02-23 | 2011-12-14 | 株式会社野泽 | 氢氧化镁的制造方法 |
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CN1446751A (zh) * | 2002-03-22 | 2003-10-08 | 丹东松元化学有限公司 | 氨全循环法生产氢氧化镁和氧化镁的工艺 |
CN101224902A (zh) * | 2008-01-30 | 2008-07-23 | 大连海事大学 | 液氨-氨水双联沉淀高纯氢氧化镁的方法 |
CN101525144A (zh) * | 2009-04-08 | 2009-09-09 | 辽宁红豆杉技术发展有限公司 | 氨气鼓泡法一步反应制备颗粒形状统一的氢氧化镁方法 |
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Effective date of registration: 20170726 Address after: 201100 1AV02 room, No. 89 Xin Bang Road, Shanghai, Minhang District Patentee after: Shanghai Hebei Ningxin Material Co.,Ltd. Address before: 110142 Shenyang economic and Technological Development Zone, Liaoning, No. 11 Patentee before: Shenyang University of Chemical Technology |
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Effective date of registration: 20170810 Address after: 110016, No. 8-1, Choi Tower Street, Shenhe District, Liaoning, Shenyang (1-20-3) Patentee after: SHENYANG KAIMEIKE TECHNOLOGY CO.,LTD. Address before: 201100 1AV02 room, No. 89 Xin Bang Road, Shanghai, Minhang District Patentee before: Shanghai Hebei Ningxin Material Co.,Ltd. |
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Effective date of registration: 20200814 Address after: Room 904, 9th floor, Tengao headquarters economic building, No.1 Tengfei Road, Tengao Town, Haicheng City, Anshan City, Liaoning Province 114225 Patentee after: Liaoning Magna Technology Co.,Ltd. Address before: 110016 8-1 Cai TA street, Shenhe District, Shenyang, Liaoning (1-20-3) Patentee before: SHENYANG KAIMEIKE TECHNOLOGY Co.,Ltd. |
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Denomination of invention: A production method of flame retardant formulation magnesium hydroxide Effective date of registration: 20231214 Granted publication date: 20140212 Pledgee: Industrial Bank Co.,Ltd. Shenyang Branch Pledgor: Liaoning Magna Technology Co.,Ltd. Registration number: Y2023210000348 |