CN102389694A - Air purifying agent and preparation method and application thereof - Google Patents
Air purifying agent and preparation method and application thereof Download PDFInfo
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- CN102389694A CN102389694A CN2011102310494A CN201110231049A CN102389694A CN 102389694 A CN102389694 A CN 102389694A CN 2011102310494 A CN2011102310494 A CN 2011102310494A CN 201110231049 A CN201110231049 A CN 201110231049A CN 102389694 A CN102389694 A CN 102389694A
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Abstract
The invention discloses an air purifying agent and a preparation method and application thereof, belonging to the field of everyday use chemicals. The air purifying agent is prepared form the following raw material formulas according to the weight ratio, wherein the raw material formula 1 comprises the following components of 8-16 percent of sodium chlorate and 0.5-1.5 percent of cane sugar; the raw material formula 2 comprises the following components of 1-4 percent of potassium polyacrylate, 2-5 percent of sodium polyacrylate, 4-8 percent of particular water-absorption type resin, 1-3 percent of guar gum and the balance of water. The air purifying agent obtained in the method has the characteristics of long duration time and low cost, can effectively remove toxic and harmful gases, can carry out sterilization and deodorization, rotatably releases during using without construction of specialized personnel, and is convenient for carrying.
Description
Technical field
The present invention relates to the articles for daily use field, be specifically related to a kind of air purifying preparation and preparation method thereof and purposes.
Background technology
We can adopt air purifying preparation to remove airborne toxic and harmful usually after the house decoration or when environmental air smell and poor quality; Wherein the most frequently used is the formaldehyde remover, but the present formaldehyde remover duration falls short of, removal effect is only removed to a kind of pernicious gas of formaldehyde basically.
The applicant is in patent application (a kind of formaldehyde remover and preparation method thereof of application on March 26th, 2009; Application number 200910058707.7; Open day on September 23rd, 2009) disclose a kind of remover and preparation method thereof, this remover adopts sodium chlorite, potassium dihydrogen phosphate etc. to produce this remover longer duration; Can remove multiple toxic and harmful, and can deodorization and sterilization.Remover volatilizees naturally during use, need not spray and embrocate, and does not also need professional construction troop, and is very easy to use.
Because sodium chlorite is somewhat expensive, therefore adopt the raw material more cheap to replace sodium chlorite to become the technical staff to want a difficult problem that solves to reduce the air purifying preparation product cost than sodium chlorite.
People expect adopting sodium chlorate to replace sodium chlorite, but in the reaction of potassium dihydrogen phosphate and sodium chlorate except the chlorine dioxide that production purifies air, also generate toxic gas chlorine, therefore can not satisfy people's demand.
Summary of the invention
To the weak point of above-mentioned existing air purifying preparation, one of the object of the invention provides a kind of air purifying preparation, and this air purifying preparation can significantly reduce production costs; And longer duration can be removed multiple toxic and harmful, and the ability deodorization and sterilization; Remover volatilizees naturally during use; Need not spray and embrocate, also not need professional construction troop, very easy to use.
Technical scheme is: a kind of air purifying preparation, this air purifying preparation by following composition of raw materials by weight processing:
Composition of raw materials 1 is grouped into by following one-tenth:
Sodium chlorate 8-16%
Sucrose 0.5-1.5%;
Composition of raw materials 2 is grouped into by following one-tenth:
Potassium dihydrogen phosphate 1-4%
Citric acid 2-5%;
Composition of raw materials 3 comprises following composition:
Polyacrylic acid potassium 1-4%
Sodium Polyacrylate 2-5%
Granular water-absorbent type resin 4-8%
Guar gum 1-3%;
Surplus is a water.
As preferably, said composition of raw materials 3 also comprises polyacrylamide, and the polyacrylamide amine content is 1-3%.
As preferably, this air purifying preparation also comprises composition of raw materials 4, and this composition of raw materials 4 comprises following composition:
Lemon extract 0.5-1%
Apple fragrance type essence 0.5-1%
Emulsifying agent 0.1-0.5%.
Two of the object of the invention provides a kind of preparation method of air purifying preparation, and this preparation method is used to prepare above-mentioned air purifying preparation.
Technical scheme is: a kind of method for preparing above-mentioned air purifying preparation may further comprise the steps:
Step 1 is filled a prescription above-mentioned raw materials 1 water-soluble; Step 2 adds above-mentioned raw materials prescription 2 and above-mentioned raw materials prescription 3.
As preferably, said step 1 is at 62-66 ℃ of following constant temperature 10-15 minute; Add fashionable stirring in the said step 2 after 1-2 minute, placed 10 minutes.
Three of the object of the invention provides another preparation method of a kind of air purifying preparation, and this preparation method is used to prepare above-mentioned air purifying preparation.
Technical scheme is: a kind of method for preparing above-mentioned air purifying preparation may further comprise the steps: step 1 is water-soluble with above-mentioned described composition of raw materials 1 and above-mentioned described composition of raw materials 4; Step 2 adds above-mentioned raw materials prescription 2 and above-mentioned raw materials prescription 3.
As preferably, in the said step 1, solution is heated up, at 62-66 ℃ of following constant temperature 10-15 minute; Add fashionable stirring in the said step 2 after 1-2 minute, placed 10 minutes, the operation of said step 2 is accomplished at the place, field of employment.
Last purpose of the present invention provides the purposes of above-mentioned air purifying preparation.
Technical scheme is: above-mentioned air purifying preparation is applied in to be removed in airborne formaldehyde, benzene, ammonia, TVOC or its mixture.
As preferably, when using release, adopt above-mentioned air purifying preparation rotary-type mode to discharge.
Beneficial effect is: because the cost of sodium chlorate well below sodium chlorite, therefore, adopts sodium chlorate can reduce the production cost of air purifying preparation greatly; Add sucrose when producing in the raw material, then can not generate toxic gas chlorine in the reaction of potassium dihydrogen phosphate and sodium chlorate, and the activator, stabilizing agent, sustained release agent and the fumet that add can make the air purifying preparation longer duration of generation; Can remove multiple toxic and harmful; And can deodorization and sterilization, and remover volatilizees naturally when using, and need not spray and embrocate; Do not need professional construction troop yet, very easy to use.
The specific embodiment
To specifically illustrate the present invention with reference to embodiment below, but the present invention is not limited thereto.
Embodiment 1.
Get 8g sodium chlorate, 0.5g sucrose and mix and be dissolved in the 80.5g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.1g potassium dihydrogen phosphate, 2g citric acid, 1g polyacrylic acid potassium, 2g Sodium Polyacrylate, 4g granular water-absorbent type resin and 1g guar gum are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation A1.
Embodiment 2.
Get 12g sodium chlorate, 1g sucrose and mix and be dissolved in the 67g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.2.5g potassium dihydrogen phosphate, 3.5g citric acid, 2.5g polyacrylic acid potassium, 3.5g Sodium Polyacrylate, 6g granular water-absorbent type resin and 2g guar gum are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation A2.
Embodiment 3.
Get 16g sodium chlorate, 1.5g sucrose and mix and be dissolved in the 53.5g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.4g potassium dihydrogen phosphate, 5g citric acid, 4g polyacrylic acid potassium, 5g Sodium Polyacrylate, 8g granular water-absorbent type resin and 3g guar gum are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation A3.
Embodiment 4.
Get 8g sodium chlorate, 0.5g sucrose and mix and be dissolved in the 79.5g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.1g potassium dihydrogen phosphate, 2g citric acid, 1g polyacrylic acid potassium, 2g Sodium Polyacrylate, 4g granular water-absorbent type resin, 1g guar gum and 1g polyacrylamide are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation B1.
Embodiment 5.
Get 12g sodium chlorate, 1g sucrose and mix and be dissolved in the 65g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.2.5g potassium dihydrogen phosphate, 3.5g citric acid, 2.5g polyacrylic acid potassium, 3.5g Sodium Polyacrylate, 6g granular water-absorbent type resin, 2g guar gum and 2g polyacrylamide are added in the mixing material; Stir after 1-2 minute; Placed 10 minutes, and made air purifying preparation B2.
Embodiment 6.
Get 16g sodium chlorate, 1.5g sucrose and mix and be dissolved in the 50.5g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.4g potassium dihydrogen phosphate, 5g citric acid, 4g polyacrylic acid potassium, 5g Sodium Polyacrylate, 8g granular water-absorbent type resin, 3g guar gum and 3g polyacrylamide are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation B3.
Embodiment 7.
Get 8g sodium chlorate, 0.5g sucrose, 0.5g lemon extract, 0.5g apple fragrance type essence and 0.1g emulsifier and be dissolved in the 79.4g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.1g potassium dihydrogen phosphate, 2g citric acid, 1g polyacrylic acid potassium, 2g Sodium Polyacrylate, 4g granular water-absorbent type resin and 1g guar gum are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation C1.
Embodiment 8.
Get 12g sodium chlorate, 1g sucrose, 0.75g lemon extract, 0.75g apple fragrance type essence and 0.3g emulsifier and be dissolved in the 65.2g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.2.5g potassium dihydrogen phosphate, 3.5g citric acid, 2.5g polyacrylic acid potassium, 3.5g Sodium Polyacrylate, 6g granular water-absorbent type resin and 2g guar gum are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation C2.
Embodiment 9.
Get 16g sodium chlorate, 1.5g sucrose, 1g lemon extract, 1g apple fragrance type essence and 0.5g emulsifier and be dissolved in the 51g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.4g potassium dihydrogen phosphate, 5g citric acid, 4g polyacrylic acid potassium, 5g Sodium Polyacrylate, 8g granular water-absorbent type resin and 3g guar gum are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation C3.
Embodiment 10.
Get 8g sodium chlorate, 0.5g sucrose, 0.5g lemon extract, 0.5g apple fragrance type essence and 0.1g emulsifier and be dissolved in the 78.4g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.1g potassium dihydrogen phosphate, 2g citric acid, 1g polyacrylic acid potassium, 2g Sodium Polyacrylate, 4g granular water-absorbent type resin, 1g guar gum and 1g polyacrylamide are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation D1.
Embodiment 11.
Get 12g sodium chlorate, 1g sucrose, 0.75g lemon extract, 0.75g apple fragrance type essence and 0.3g emulsifier and be dissolved in the 63.2g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.2.5g potassium dihydrogen phosphate, 3.5g citric acid, 2.5g polyacrylic acid potassium, 3.5g Sodium Polyacrylate, 6g granular water-absorbent type resin, 2g guar gum and 2g polyacrylamide are added in the mixing material; Stir after 1-2 minute; Placed 10 minutes, and made air purifying preparation D2.
Embodiment 12.
Get 16g sodium chlorate, 1.5g sucrose, 1g lemon extract, 1g apple fragrance type essence and 0.5g emulsifier and be dissolved in the 48g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.4g potassium dihydrogen phosphate, 5g citric acid, 4g polyacrylic acid potassium, 5g Sodium Polyacrylate, 8g granular water-absorbent type resin, 3g guar gum 3g polyacrylamide are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation D3.
The contrast experiment 1
Get 8g sodium chlorate, 0.5g lemon extract, 0.5g apple fragrance type essence and 0.1g emulsifier and be dissolved in the 78.9g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.1g potassium dihydrogen phosphate, 2g citric acid, 1g polyacrylic acid potassium, 2g Sodium Polyacrylate, 4g granular water-absorbent type resin, 1g guar gum and 1g polyacrylamide are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation 1.
The contrast experiment 2
Get 12g sodium chlorate, 0.75g lemon extract, 0.75g apple fragrance type essence and 0.3g emulsifier and be dissolved in the 64.2g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.2.5g potassium dihydrogen phosphate, 3.5g citric acid, 2.5g polyacrylic acid potassium, 3.5g Sodium Polyacrylate, 6g granular water-absorbent type resin, 2g guar gum and 2g polyacrylamide are added in the mixing material; Stir after 1-2 minute; Placed 10 minutes, and made air purifying preparation 2.
The contrast experiment 3
Get 16g sodium chlorate, 1g lemon extract, 1g apple fragrance type essence and 0.5g emulsifier and be dissolved in the 49.5g water, stir, heating at 62-66 ℃ of following constant temperature 10-15 minute, is processed mixing material.4g potassium dihydrogen phosphate, 5g citric acid, 4g polyacrylic acid potassium, 5g Sodium Polyacrylate, 8g granular water-absorbent type resin, 3g guar gum 3g polyacrylamide are added in the mixing material, stir after 1-2 minute, placed 10 minutes, make air purifying preparation 3.
The contrast experiment 4
Get the 10g sodium chlorite, 2g urea is dissolved in the 57g water; And under 25-30 with solution stirring 12 hours, stir accomplish after, 2g spices, 2g borneol and 5g ethanol are added solution and dissolved 24 hours; Then 2g potassium dihydrogen phosphate, 5g polyacrylate, 5g granular water-absorbent type resin, 1g boric acid, 1g citric acid, 2g guar gum and 6g polyacrylamide are added in the mixing material; Stir after 1-2 minute, placed 10 minutes, make air purifying preparation 4.
With testing air purifying preparation A1-A3, B1-B3, C1-C3, the D1-D3 that 1-12 makes; Whether the air purifying preparation that contrast experiment 1-4 makes detects respectively 4 1-has chlorine to generate, and carries out formaldehyde after the detection respectively and removes test, benzene and remove that test is removed in test, ammonia, TVOC removes test, air sterillization experiment.
Whether detect chlorine produces: with the air purifying preparation that makes at 1m
3The indoor release of vacuum experiment, the indoor chlorine alarm that is equipped with of vacuum experiment.Test result is seen table one.
Table one
Cleanser Test event | Whether the chlorine alarm reports to the police |
A1 | Do not report to the police |
A2 | Do not report to the police |
A3 | Do not report to the police |
B1 | Do not report to the police |
B2 | Do not report to the police |
B3 | Do not report to the police |
C1 | Do not report to the police |
C2 | Do not report to the police |
C3 | Do not report to the police |
D1 | Do not report to the police |
D2 | Do not report to the police |
D3 | Do not report to the police |
To 1 | Report to the police |
To 2 | Report to the police |
To 3 | Report to the police |
To 4 | Do not report to the police |
Air purifying preparation validity (property removed, sterilization property) duration experiment:
1) the removal experimental test condition is following: at 1m
3In the airtight experiment storehouse, inject certain volume chemical pure formaldehyde (or benzene or ammonia or TOVC), open the storehouse internal fan, gas concentration is an initial concentration in the test storehouse of sampling immediately after 1 hour.At 1m
3In the airtight experiment storehouse; The air purifying preparation that has just made (after maybe the air purifying preparation that makes being placed 2880 hours) is put into this storehouse; Inject the chemical pure formaldehyde (or benzene or ammonia or TOVC) of equal volume, gas concentration in the storehouse of sampling test is immediately calculated clearance after 72 hours.Clearance=(initial concentration-sample solution concentration) * 100/ initial concentration.Test result is seen table two (, two).
2) air sterillization experiment: at about 50m
3In the laboratory, the air purifying preparation that makes (after maybe the air purifying preparation that makes being placed 2880 hours) is released in the air and natural bacteria effect 48 hours average bacterium number before sterilizing rate=(average bacterium number before the test-average bacterium number in test back) * 100/ test.Test result is seen table three.
The air purifying preparation test that table two () has just made
The air purifying preparation that table two (two) makes is placed the test of 2880 hours (promptly 120 days) back
Table three
The cleanser of the present invention's protection can be removed formaldehyde, benzene, ammonia, TVOC; The effectively sterilization of cleanser of the present invention's protection; The air purifying preparation that preparation method of the present invention produces has been strengthened the stability of chlorine dioxide; Thereby make the air purifying preparation of generation elongated effective time, after placing 120 days, also have sterilization and the effect of removing formaldehyde, benzene, ammonia, TVOC.
Claims (10)
1. air purifying preparation is characterized in that: this air purifying preparation by following composition of raw materials by weight processing:
Composition of raw materials 1 is grouped into by following one-tenth:
Sodium chlorate 8-16%
Sucrose 0.5-1.5%;
Composition of raw materials 2 is grouped into by following one-tenth:
Potassium dihydrogen phosphate 1-4%
Citric acid 2-5%;
Composition of raw materials 3 comprises following composition:
Polyacrylic acid potassium 1-4%
Sodium Polyacrylate 2-5%
Granular water-absorbent type resin 4-8%
Guar gum 1-3%;
Surplus is a water.
2. air purifying preparation according to claim 1 is characterized in that: said composition of raw materials 3 also comprises polyacrylamide, and the polyacrylamide amine content is 1-3%.
3. air purifying preparation according to claim 1 is characterized in that: this air purifying preparation also comprises composition of raw materials 4, and this composition of raw materials 4 comprises following composition:
Lemon extract 0.5-1%
Apple fragrance type essence 0.5-1%
Emulsifying agent 0.1-0.5%.
4. air purifying preparation according to claim 3 is characterized in that: said composition of raw materials 3 also comprises polyacrylamide, and the polyacrylamide amine content is 1-3%.
5. method for preparing claim 1 or 2 described air purifying preparations may further comprise the steps:
Step 1 is water-soluble with the described composition of raw materials of claim 11;
Step 2 adds the described composition of raw materials 2 of claim 1 and claim 1 or 2 described composition of raw materials 3.
6. the method for air purifying preparation according to claim 5, it is characterized in that: said step 1 is at 62-66 ℃ of following constant temperature 10-15 minute; Add fashionable stirring in the said step 2 after 1-2 minute, placed 10 minutes.
7. method for preparing claim 3 or 4 described air purifying preparations may further comprise the steps:
Step 1 is water-soluble with the described composition of raw materials of described composition of raw materials of claim 11 and claim 34;
Step 2 adds the described composition of raw materials 2 of claim 1 and claim 3 or 4 described composition of raw materials 3.
8. the method for air purifying preparation according to claim 7 is characterized in that: in the said step 1, solution is heated up, at 62-66 ℃ of following constant temperature 10-15 minute; Add fashionable stirring in the said step 2 after 1-2 minute, placed 10 minutes, the operation of said step 2 is accomplished at the place, field of employment.
9. one kind is applied in like the described air purifying preparation of the arbitrary claim of claim 1-4 and removes in airborne formaldehyde, benzene, ammonia, TVOC or its mixture.
10. the application of air purifying preparation according to claim 9 is characterized in that: use and adopt rotary-type mode to discharge when discharging.
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CN102698304A (en) * | 2012-05-25 | 2012-10-03 | 上海复振科技有限公司 | Plant source compound chemical odor removal agent, preparation method and application thereof |
CN102698580A (en) * | 2012-05-25 | 2012-10-03 | 上海复振科技有限公司 | Plant source compound formaldehyde clear spray, and preparation method and application thereof |
CN103800928A (en) * | 2014-03-06 | 2014-05-21 | 苏州爱德芬生物科技有限公司 | Antibiotic deodorant |
CN105435612A (en) * | 2015-12-16 | 2016-03-30 | 无锡吉进环保科技有限公司 | Preparation method of indoor air purifying agent |
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CN106731641A (en) * | 2016-11-21 | 2017-05-31 | 郑州诚合信息技术有限公司 | A kind of material with sterilizing function and its preparation method and application |
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CN107158877A (en) * | 2017-05-31 | 2017-09-15 | 安徽梅兰园林景观工程有限公司 | A kind of air purifying preparation of environment-friendly engineering and preparation method thereof |
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