CN102383334B - Dichloroethylene water-based paint - Google Patents
Dichloroethylene water-based paint Download PDFInfo
- Publication number
- CN102383334B CN102383334B CN 201110325210 CN201110325210A CN102383334B CN 102383334 B CN102383334 B CN 102383334B CN 201110325210 CN201110325210 CN 201110325210 CN 201110325210 A CN201110325210 A CN 201110325210A CN 102383334 B CN102383334 B CN 102383334B
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- dichloroethylene
- water
- methyl
- water paint
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Abstract
Dichloroethylene water-based paint contains the following components according to mass fraction: 800-1000 parts of 1, 1-dichloroethylene, 500-700 parts of methyl acrylate, 200-300 parts of acrylic acid-Beta-phema, 100-150 parts of methyl methacrylate, 100-150 parts of butyl acrylate, 15-30 parts of water-based epoxy resin and 100 parts of hexabromocyclododecane (HBCD). When the paint is coated on a piece of paper, in general storage conditions, the performance and luster of the paper out of a factory can be maintained; and in outdoor storage conditions, the effect of relieving ultraviolet oxidization can be achieved.
Description
Technical field
The invention belongs to the water based paint technical field, relate in particular to a kind of dichloroethylene water paint, the anti-oxidant and printing that is used for paper product improves.
Background technology
The antioxidant of paper product mainly contains following several: (1) BHA: butylated hydroxy anisole.Because it is good to add thermal after-effect fruit retentivity, to preserve on the food effectively, it is one of widely used antioxidant in the world at present, also is one of China's antioxidant commonly used.With other antioxidant synergy is arranged, and with uses such as synergist such as citric acid, its antioxidant effect is more remarkable.It is generally acknowledged that BHA toxicity is very little, safer.(2) BHT: dibutyl hydroxy toluene.Compare with other antioxidant, stability is higher, and good heat resistance influences under common cook temperature not quite, antioxidant effect, and the food and the bakery product that are used for long preservation are very effective.It is the present cheap antioxidant of extensive use aspect aquatic products processing particularly in the world.General and BHA and usefulness, and be synergist with citric acid or other organic acids.Relative BHA, toxicity is higher slightly.(3) PG: n-propyl gallate.More stable to ratio of specific heat.The antioxidation of the lard of PG than BHA and BHT more by force.Toxicity is lower.(4) TBHQ: ditert-butylhydro quinone.Be a newer class phenol antioxidant, its antioxidant effect is better.
But above-mentioned oxidant all is to make an addition in the paper pulp, in process of production easily loss.
Summary of the invention
The technical problem that solves:The present invention aims to provide a kind of dichloroethylene water paint, and the anti-oxidant and printing that is used for paper product improves.
Technical scheme:The dichloroethylene water paint, be grouped into by following one-tenth by mass fraction: 1,800～1000 parts of 1-dichloroethylene, 500～700 parts of methyl acrylates, 200～300 parts of senecioates-hydroxyl ethyl ester, 100～150 parts of methyl methacrylates, 100～150 parts of butyl acrylates, 15～30 parts of aqueous epoxy resins, 100 parts of hexabromo-Cyclododecane.
800 parts of described vinylidene chlorides.
600 parts of described methyl acrylates.
300 parts of described senecioates-hydroxyl ethyl ester.
Beneficial effect:Coating of the present invention is coated on the paper, and under general storage condition, paper product can be kept performance and the color and luster when dispatching from the factory, and under the storage condition, the effect of slowing down ultraviolet oxidation is arranged also in the open.
The specific embodiment
Embodiment 1
The dichloroethylene water paint is grouped into by following one-tenth by mass fraction: 1000 parts of vinylidene chlorides, 700 parts of methyl acrylates, 300 parts of senecioates-hydroxyl ethyl ester, 150 parts of methyl methacrylates, 150 parts of butyl acrylates, 30 parts of aqueous epoxy resins, 100 parts of hexabromo-Cyclododecane.
Dichloroethylene, methyl acrylate, hydroxyl ethyl ester and water are added in the reactor, carry out emulsion polymerisation, at last leftover materials are added to stir obtaining emulsion.
This coating is coated on the common printed paper, and direct projection 48h under ultraviolet light, the numerical value on the color board do not become substantially.
Do not relate in the literary composition part all the prior art that maybe can adopt same as the prior art realized.The above is the preferred embodiments of the present invention, but the present invention also is not limited to above only embodiment, does improvement slightly and also will be considered as protection scope of the present invention on embodiment.
Claims (2)
1. dichloroethylene water paint, it is characterized in that being grouped into by following one-tenth according to the mass fraction: 1,800 ~ 1000 parts of 1-dichloroethylene, 500 ~ 700 parts of methyl acrylates, 200 ~ 300 parts of senecioates-hydroxyl ethyl ester, 100 ~ 150 parts of methyl methacrylates, 100 ~ 150 parts of butyl acrylates, 15 ~ 30 parts of aqueous epoxy resins, 100 parts of hexabromo-Cyclododecane, dichloroethylene, methyl acrylate, hydroxyl ethyl ester and water are added in the reactor, carry out emulsion polymerisation, at last leftover materials are added to stir obtaining emulsion.
2. dichloroethylene water paint according to claim 1 is characterized in that 800 parts of described vinylidene chlorides.
3. dichloroethylene water paint according to claim 1 is characterized in that 600 parts of described methyl acrylates.
4. dichloroethylene water paint according to claim 1 is characterized in that 300 parts of described senecioates-hydroxyl ethyl ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110325210 CN102383334B (en) | 2011-10-24 | 2011-10-24 | Dichloroethylene water-based paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110325210 CN102383334B (en) | 2011-10-24 | 2011-10-24 | Dichloroethylene water-based paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102383334A CN102383334A (en) | 2012-03-21 |
| CN102383334B true CN102383334B (en) | 2013-07-03 |
Family
ID=45823136
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110325210 Expired - Fee Related CN102383334B (en) | 2011-10-24 | 2011-10-24 | Dichloroethylene water-based paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102383334B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152012A (en) * | 1995-12-15 | 1997-06-18 | 中国人民解放军海军后勤技术装备研究所 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
| CN1239494A (en) * | 1996-12-04 | 1999-12-22 | 格尔德·胡戈 | Coating material |
| CN1454944A (en) * | 2002-04-29 | 2003-11-12 | 北京化大天瑞纳米材料技术有限公司 | Antibacterial water-based coating composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU6014398A (en) * | 1997-12-19 | 1999-07-12 | Gerald Sugerman | Low environmental toxicity latex coatings |
-
2011
- 2011-10-24 CN CN 201110325210 patent/CN102383334B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152012A (en) * | 1995-12-15 | 1997-06-18 | 中国人民解放军海军后勤技术装备研究所 | Fire-retardant, electrostatic-conducting, heat-resisting and anticorrosive paint |
| CN1239494A (en) * | 1996-12-04 | 1999-12-22 | 格尔德·胡戈 | Coating material |
| CN1454944A (en) * | 2002-04-29 | 2003-11-12 | 北京化大天瑞纳米材料技术有限公司 | Antibacterial water-based coating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102383334A (en) | 2012-03-21 |
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| PB01 | Publication | ||
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: NANTONG PUTHON CHEMICAL CO., LTD. Free format text: FORMER OWNER: WUJIANG TIANYUAN PLASTICS CO., LTD. Effective date: 20150430 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 215212 SUZHOU, JIANGSU PROVINCE TO: 226000 NANTONG, JIANGSU PROVINCE |
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| TR01 | Transfer of patent right |
Effective date of registration: 20150430 Address after: 226000, Jiangsu County, Nantong City, Rudong province Rudong County mouth chemical gathering area Patentee after: Nantong Bai Sen Chemical Co., Ltd. Address before: Wujiang City, Suzhou City, Jiangsu province 215212 Lili Town Industrial Park of arch bridge Patentee before: Wujiang Tianyuan Plastic Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130703 Termination date: 20161024 |
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| CF01 | Termination of patent right due to non-payment of annual fee |