CN102378643A - 用于生产纯化的合成气的方法 - Google Patents

用于生产纯化的合成气的方法 Download PDF

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Publication number
CN102378643A
CN102378643A CN2010800152288A CN201080015228A CN102378643A CN 102378643 A CN102378643 A CN 102378643A CN 2010800152288 A CN2010800152288 A CN 2010800152288A CN 201080015228 A CN201080015228 A CN 201080015228A CN 102378643 A CN102378643 A CN 102378643A
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China
Prior art keywords
synthesis gas
gas
rich
absorption liquid
gas stream
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CN2010800152288A
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Chinese (zh)
Inventor
I·C·梵登鲍恩
G·J·范赫林根
C·J·史密特
A·F·沃尔德惠斯
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Shell Internationale Research Maatschappij BV
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Shell Internationale Research Maatschappij BV
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0408—Pretreatment of the hydrogen sulfide containing gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/05—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/52—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/20—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/406—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/408—Cyanides, e.g. hydrogen cyanide (HCH)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Industrial Gases (AREA)
  • Gas Separation By Absorption (AREA)
CN2010800152288A 2009-03-30 2010-03-30 用于生产纯化的合成气的方法 Pending CN102378643A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09156572 2009-03-30
EP09156572.1 2009-03-30
PCT/EP2010/054186 WO2010112501A1 (en) 2009-03-30 2010-03-30 Process for producing purified synthesis gas

Publications (1)

Publication Number Publication Date
CN102378643A true CN102378643A (zh) 2012-03-14

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CN2010800152288A Pending CN102378643A (zh) 2009-03-30 2010-03-30 用于生产纯化的合成气的方法

Country Status (8)

Country Link
US (1) US20120095119A1 (enExample)
EP (1) EP2414074A1 (enExample)
JP (1) JP2012521956A (enExample)
KR (1) KR20120007020A (enExample)
CN (1) CN102378643A (enExample)
AU (1) AU2010230279B2 (enExample)
CA (1) CA2756138A1 (enExample)
WO (1) WO2010112501A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106029557A (zh) * 2013-12-17 2016-10-12 阿克森斯公司 通过用胺的水溶液洗涤来纯化合成气的方法
CN108249493A (zh) * 2016-12-28 2018-07-06 宝钢工程技术集团有限公司 节能型减压蒸氨装置及其使用方法
CN110049944A (zh) * 2016-10-25 2019-07-23 内斯特化学有限公司 从源自于废物气化的合成气中制备纯氢气的方法和相关装置
CN110615404A (zh) * 2018-06-18 2019-12-27 乔治洛德方法研究和开发液化空气有限公司 用于从经变换和未变换的粗合成气生产多种气体产物的方法和设施

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FR2966054B1 (fr) * 2010-10-18 2015-02-27 Arkema France Capture d'oxydes de carbone
US8663949B2 (en) * 2010-12-20 2014-03-04 Lanzatech New Zealand Limited Fermentation method
JP2012224484A (ja) * 2011-04-15 2012-11-15 Babcock Hitachi Kk シフト反応装置及びガスタービンプラント
JP6025603B2 (ja) * 2013-02-21 2016-11-16 三菱重工業株式会社 Ｃｏシフト反応装置及びｃｏシフト変換方法
JP6173817B2 (ja) * 2013-07-30 2017-08-02 株式会社東芝 酸性ガス吸収剤、酸性ガス除去方法及び酸性ガス除去装置
WO2015173234A1 (en) * 2014-05-12 2015-11-19 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Method and apparatus for purification of biogas
WO2015173253A2 (en) * 2014-05-12 2015-11-19 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Method and apparatus for purification of natural gas
WO2016073209A1 (en) 2014-11-03 2016-05-12 Anellotech, Inc. Improved process for recovering carbon monoxide from catalytic fast pyrolysis product
CA2995649C (en) * 2015-09-07 2023-12-19 Vikrant Nanasaheb URADE Conversion of biomass into a liquid hydrocarbon material
RU2612481C1 (ru) * 2016-01-28 2017-03-09 Общество С Ограниченной Ответственностью "Ноко" Способ получения серы из отходящих металлургических газов
US10399852B2 (en) * 2017-05-11 2019-09-03 Uop Llc Process and apparatus for treating a sour synthesis gas
KR102142300B1 (ko) * 2018-09-21 2020-08-10 주식회사 포스코 황을 포함하는 연료로부터 합성가스를 생성하는 방법 및 장치
GB202204766D0 (en) * 2022-04-01 2022-05-18 Johnson Matthey Davy Technologies Ltd Method of producing liquid hydrocarbons from a syngas
US20230416088A1 (en) * 2022-06-28 2023-12-28 Merichem Company Catalyst for carbonyl sulfide removal from hydrocarbons

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CN101031350A (zh) * 2004-07-22 2007-09-05 国际壳牌研究有限公司 从含有h2s和cos的合成气流中脱除cos的方法
EP1918352A1 (en) * 2006-11-01 2008-05-07 Shell Internationale Researchmaatschappij B.V. Solid carbonaceous feed to liquid process
EP1961697A1 (de) * 2007-01-30 2008-08-27 Linde Aktiengesellschaft Erzeugung von Produkten aus Raffinerieabgasen
WO2009016139A1 (en) * 2007-07-31 2009-02-05 Shell Internationale Research Maatschappij B.V. Process for producing purified gas from gas comprising h2s, co2 and hcn and/or cos

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EP1918352A1 (en) * 2006-11-01 2008-05-07 Shell Internationale Researchmaatschappij B.V. Solid carbonaceous feed to liquid process
EP1961697A1 (de) * 2007-01-30 2008-08-27 Linde Aktiengesellschaft Erzeugung von Produkten aus Raffinerieabgasen
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106029557A (zh) * 2013-12-17 2016-10-12 阿克森斯公司 通过用胺的水溶液洗涤来纯化合成气的方法
CN110049944A (zh) * 2016-10-25 2019-07-23 内斯特化学有限公司 从源自于废物气化的合成气中制备纯氢气的方法和相关装置
CN110049944B (zh) * 2016-10-25 2022-09-27 内斯特化学股份公司 从源自于废物气化的合成气中制备纯氢气的方法和相关装置
CN108249493A (zh) * 2016-12-28 2018-07-06 宝钢工程技术集团有限公司 节能型减压蒸氨装置及其使用方法
CN110615404A (zh) * 2018-06-18 2019-12-27 乔治洛德方法研究和开发液化空气有限公司 用于从经变换和未变换的粗合成气生产多种气体产物的方法和设施

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CA2756138A1 (en) 2010-10-07
AU2010230279B2 (en) 2013-10-10
AU2010230279A8 (en) 2012-03-08
KR20120007020A (ko) 2012-01-19
JP2012521956A (ja) 2012-09-20
US20120095119A1 (en) 2012-04-19
EP2414074A1 (en) 2012-02-08
WO2010112501A1 (en) 2010-10-07
AU2010230279A1 (en) 2011-10-13

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Application publication date: 20120314