CN102369253A - Oil gelling agent, composition containing oil gelling agent, and external preparation or cosmetic for skin - Google Patents
Oil gelling agent, composition containing oil gelling agent, and external preparation or cosmetic for skin Download PDFInfo
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- CN102369253A CN102369253A CN2010800100832A CN201080010083A CN102369253A CN 102369253 A CN102369253 A CN 102369253A CN 2010800100832 A CN2010800100832 A CN 2010800100832A CN 201080010083 A CN201080010083 A CN 201080010083A CN 102369253 A CN102369253 A CN 102369253A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
- A61K47/16—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing nitrogen, e.g. nitro-, nitroso-, azo-compounds, nitriles, cyanates
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Abstract
Provided is an oil gelling agent capable of forming a gel that is highly stable and highly transparent by the addition thereof in a small amount to a nonpolar or low-polarity oil-based preparation. The oil gelling agent is produced by mixing a 1,2-bis(acylamino)cyclohexane derivative wherein the acyl segment is a linear alkyl group having 15 to 21 carbons, and a bis(acylamino)cyclohexane derivative wherein the acyl segment is a linear alkyl group having a total number of carbons of 15 to 21 and a linear alkyl group as a substituent group at position 1.
Description
Technical field
The present invention relates to contain the oleogel agent of two (acyl amino) cyclohexane derivants with straight chained alkyl and two (acyl amino) cyclohexane derivants with branched-chain alkyl; The oily gel composition that contains this oleogel agent; And the makeup that are added with this oily gel composition, external composition for skin.
Background technology
In the field of makeup; In makeup, add when being the butyrous makeup base (finish) of liquid or solid under the normal temperature,, in finish, add the oleogel agent sometimes in order to make as various informativeization of makeup and further to improve usability; Be prepared into gelation oily gel composition after add again; Gelating agent contains stability, the usability of the makeup of finish through viscosity, the structural usability that improves of control finish for raising, has important effect.
In the past; As the oleogel agent of adding in the finishes such as hydrocarbon, ester, triglyceride level, silicone oil; With solid-like finishes such as waxes is representative; Use dextrin fatty acid ester, 12-oxystearic acid etc., through kind, the mixture ratio of finish and oleogel agent being studied the raising of the usability of the oily gel composition that uses in the realization makeup.But, if use wax, then under the concentration that forms stable oily gel composition as the oleogel agent; Gonorrhoea can appear in oily gel composition; Might there be unfavorable condition when being used for being coupled to the high makeup of transparent feel, gloss, when using dextrin fatty acid ester in addition, then forms transparent oily gel composition as the oleogel agent; Cooperate but be necessary to carry out high density, the usability aspect that this is external when being coupled in the makeup of the softness that at high temperature becomes etc. is not preferred sometimes.Further, when using the 12-oxystearic acid as the oleogel agent, the kind of finish that can gelation is few, even under can the situation of gelation, the gelatinous compsn that obtains also be thick gel, usability is not so good.
On the other hand; For the DACH verivate; The compsns (with reference to patent documentation 1) such as medicine, makeup, food of two (acyl amino) cyclohexane derivants have been proposed to contain; In addition, also having proposed with carbonatoms is that 6～22 saturated straight chain and/or the monoamide derivatives more than a kind or 2 kinds in the branched chain fatty acid and/or diamide derivatives are the gelation or the solidifying agent (with reference to patent documentation 2) of the organic liquid of effective constituent.
The prior art document
Patent documentation
Patent documentation 1: japanese kokai publication hei 10-237034 communique
Patent documentation 2: No. 3620878 communique of Japanese Patent
Summary of the invention
The objective of the invention is to, provide, can form the oleogel agent of the high transparent high gel of stability through being coupled on a small quantity in the nonpolar or low polar finish.
Contriver of the present invention furthers investigate the back and finds in order to solve above-mentioned problem; It is 1 of 15～21 straight chained alkyl that acyl moiety is had carbonatoms; Two (acyl amino) cyclohexane derivants of 2-and acyl moiety have total carbon atom number be 15～21,1 have straight chained alkyl as 1 of substituent straight chained alkyl; Each a kind ofly is mixed with the oleogel agent that forms two (acyl amino) cyclohexane derivants of 2-, when adding in the finish, even addition is compared with oleogel agent in the past; Concentration is low, also can form transparency height, have good stability, is applicable to the gel that is coupled in the makeup.In addition, also confirm: it is 1 of 15～21 straight chained alkyl that acyl moiety is had carbonatoms, and two (acyl amino) cyclohexane derivants of 2-are a kind of separately during as the oleogel agent; Then gonorrhoea can appear in oily gel composition, and containing acyl moiety in the oleogel agent, to have carbonatoms be 1 of 8 branched-chain alkyl, during two (acyl amino) cyclohexane derivant of 2-; It is very high that solvent temperature becomes sometimes; Further, 1, in two (acyl amino) cyclohexane derivants of 2-; 1 of cyclohexane ring and 2 substituent acyl moiety one side are that straight chain, the opposing party are under the situation of side chain; Gelatinous compsn gonorrhoea occurs or solvent temperature raises, and when being used for being coupled to makeup, has unfavorable condition.The present invention is based on above-mentioned discovery and accomplishes.
That is, the present invention relates to:
[1] a kind of oleogel agent, this oleogel agent contains:
(A): two (acyl amino) cyclohexane derivants shown in the formula (I),
[Chemical formula 1]
Chemical formula 1
(in the formula, R
1The expression carbonatoms is 15～21 straight chained alkyl); With
(B): two (acyl amino) cyclohexane derivants shown in the formula (II),
[Chemical formula 2]
(in the formula, R
2The expression total carbon atom number be 15～21,1 have straight chained alkyl as substituent straight chained alkyl);
[2] the oleogel agent of record in above-mentioned [1] is characterized in that (A): mass ratio (B) is 80: 20～20: 80;
[3] a kind of oily gel composition is characterized in that, this oily gel composition contains the oleogel agent and the finish of record in above-mentioned [1] or [2];
[4] oily gel composition of record in above-mentioned [3] is characterized in that finish contains the polyolefine with side chain;
[5] oily gel composition of record in above-mentioned [4] is characterized in that the polyolefine with side chain is a Parleam;
[6] a kind of makeup is characterized in that, these makeup contain the oily gel composition of any record in above-mentioned [1] or [2] the middle oleogel agent put down in writing or above-mentioned [3]～[5];
[7] a kind of external composition for skin is characterized in that, this external composition for skin contains the oily gel composition of any record in above-mentioned [1] or [2] the middle oleogel agent put down in writing or above-mentioned [3]～[5].
Description of drawings
The gel outward appearance of [Fig. 1] expression comparative sample #9 (a) and embodiment sample #14 (b).
Embodiment
(oleogel agent)
As oleogel agent of the present invention, as long as contain (A): one or more of two (acyl amino) cyclohexane derivants shown in the following formula (I) (wherein, in the formula (I), R
1The expression carbonatoms is 15～21 straight chained alkyl) and (B): one or more of two (acyl amino) cyclohexane derivants shown in the following formula (II) (wherein, in the formula (II), R
2The expression total carbon atom number be 15～21,1 have straight chained alkyl as substituent straight chained alkyl) just not special the qualification, preferably use above-mentioned (A) and (B) each is a kind of.And, among the present invention, the R of formula (I)
1Between and the R of formula (II)
2Between respectively identical.In addition, oleogel agent of the present invention is not only by above-mentioned (A) and the oleogel agent (B) formed, as other composition, only otherwise hinder (A) and (B) action effect, can also contain by product when preparing, impurity etc.
R as following formula (I)
1In " carbonatoms is 15～21 straight chained alkyl ", specifically, can enumerate pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, eicosyl, heneicosyl.
The R of following formula (II)
2In " total carbon atom number be 15～21,1 have straight chained alkyl as substituent straight chained alkyl " be meant as 1 of the main chain of straight chain, promptly be substituted with straight chained alkyl and form with the carbon atom of carbonyl bonding, total carbonatoms is 15～21 alkyl.As total carbon atom number be 15～21,1 have straight chained alkyl as substituent straight chained alkyl; Specifically, can enumerate 1-methyl tetradecyl, 1-methyl pentadecyl, 1-methyl hexadecyl, 1-methyl heptadecyl, 1-methyl octadecyl, 1-methyl nonadecyl, 1-methyl eicosyl, 1-ethyl tridecyl, 1-ethyl tetradecyl, 1-ethyl pentadecyl, 1-ethylhexadecyl, 1-ethyl heptadecyl, 1-ethyl octadecyl, 1-ethyl nonadecyl, 1-propyl group dodecyl, 1-propyl group tridecyl, 1-propyl group tetradecyl, 1-propyl group pentadecyl, 1-propyl group hexadecyl, 1-propyl group heptadecyl, 1-propyl group octadecyl, 1-butyl undecyl, 1-butyl dodecyl, 1-butyl tridecyl, 1-butyl tetradecyl, 1-butyl pentadecyl, 1-butyl hexadecyl, 1-butyl heptadecyl, 1-amyl group decyl, 1-amyl group undecyl, 1-amyl group dodecyl, 1-amyl group tridecyl, 1-amyl group tetradecyl, 1-amyl group pentadecyl, 1-amyl group hexadecyl, 1-hexyl nonyl, 1-hexyl decyl, 1-hexyl undecyl, 1-hexyl dodecyl, 1-hexyl tridecyl, 1-hexyl tetradecyl, 1-hexyl pentadecyl, 1-heptyl octyl group, 1-heptyl nonyl, 1-heptyl decyl, 1-heptyl undecyl, 1-heptyl dodecyl, 1-heptyl tridecyl, 1-heptyl tetradecyl, 1-octyl group octyl group, 1-octyl group nonyl, 1-octyl-decyl, 1-octyl group undecyl, 1-octyl group dodecyl, 1-octyl group tridecyl, 1-nonyl nonyl, 1-nonyl decyl, 1-nonyl undecyl, 1-nonyl dodecyl, 1-decyl decyl, 1-decyl undecyl etc.
Can infer: oleogel agent of the present invention is through adding in the finish; Utilize molecular association in finish, to form mesh-shape or three dimensional network ocular structure such as fibrous; Through in mesh, keeping finish molecule etc., can make liquid oil solidify the compsn of (gelation).In addition, only otherwise damage effect of the present invention, then can also contain other any composition.
Compound method as two (acyl amino) cyclohexane derivants shown in the following formula (I); Can enumerate the compound method that comprises following known method: make 1; The method of 2-DACH and carboxylic acid halides condensation in the presence of alkali, said carboxylic acid halides are that 16～22 linear saturated fatty acids is handled with halogenating agents such as THIONYL CHLORIDE 97s and obtained through a kind of carbonatoms that will suitably select; Make 1; 2-DACH and a kind of carbonatoms of suitably selecting are that 16～22 linear saturated fatty acids is as required in the presence of the catalyzer such as MOX of tin, nickel etc., in chemical processes such as the amidate action of 100～250 ℃ of following dehydration reactions about 5～20 hours etc.Further, the product of these reactions can come purifying through the purification process that comprises known method such as recrystallization, column chromatography.As above-mentioned 1, the 2-DACH can be anti-form-1,2-DACH or cis-1, and the 2-DACH, but be preferably anti-form-1,2-DACH.As above-mentioned linear saturated fatty acids, can enumerate hexadecanoic acid (palmitinic acid), margaric acid (pearly-lustre resin acid), octadecanoic acid (Triple Pressed Stearic Acid), nondecylic acid, arachic acid (eicosanoic acid), heneicosanoic acid, docosane acid docosoic).
Compound method as two (acyl amino) cyclohexane derivants shown in the following formula (II); Can enumerate and use 1, the 2-DACH, with a kind of carbonatoms of suitably selecting be 16～22,2 have straight chained alkyl comprises known method such as above-mentioned chemical process as substituent sfas compound method.
As above-mentioned 1, the 2-DACH can be anti-form-1,2-DACH or cis-1, and the 2-DACH, but be preferably anti-form-1,2-DACH.
Has straight chained alkyl as substituent sfas as 2; Specifically, can enumerate that 2-methyl pentadecylic acid, 2-methyl hexadecanoic acid, 2-methylheptadecanoic acid, 2-methyl octadecanoic acid, 2-methyl nondecylic acid, 2-methyl arachic acid, 2-methyl heneicosanoic acid, 2-ethyl tetradecanoic acid, 2-ethyl pentadecylic acid, 2-ethyl hexadecanoic acid, 2-ethyl margaric acid, 2-ethyl octadecanoic acid, 2-ethyl nondecylic acid, 2-ethyl arachic acid, 2-propyl group tridecanoic acid, 2-propyl group tetradecanoic acid, 2-propyl group pentadecylic acid, 2-propyl group hexadecanoic acid, 2-propyl group margaric acid, 2-propyl group octadecanoic acid, 2-propyl group nondecylic acid, 2-butyl dodecylic acid, 2-butyl tridecanoic acid, 2-butyl tetradecanoic acid, 2-butyl pentadecylic acid, 2-butyl hexadecanoic acid, 2-butyl margaric acid, 2-butyl octadecanoic acid, 2-amyl group undecanoic acid, 2-amyl group dodecylic acid, 2-amyl group tridecanoic acid, 2-amyl group tetradecanoic acid, 2-amyl group pentadecylic acid, 2-amyl group hexadecanoic acid, 2-amyl group margaric acid, 2-hexyldecanoic acid, 2-hexyl undecanoic acid, 2-hexyl dodecylic acid, 2-hexyl tridecanoic acid, 2-hexyl tetradecanoic acid, 2-hexyl pentadecylic acid, 2-hexyl hexadecanoic acid, 2-heptyl n-nonanoic acid, 2-heptyl capric acid, 2-heptyl undecanoic acid, 2-heptyl dodecylic acid, 2-heptyl tridecanoic acid, 2-heptyl tetradecanoic acid, 2-heptyl pentadecylic acid, 2-octyl group are sad, 2-octyl group n-nonanoic acid, 2-octyl group capric acid, 2-octyl group undecanoic acid, 2-octyl group dodecylic acid, 2-octyl group tridecanoic acid, 2-octyl group tetradecanoic acid, 2-nonyl n-nonanoic acid, 2-nonyl capric acid, 2-nonyl undecanoic acid, 2-nonyl dodecylic acid, 2-nonyl tridecanoic acid, 2-decyl capric acid, 2-decyl undecanoic acid, 2-decyl dodecylic acid, 2-undecyl undecanoic acid etc.
(A) in the oleogel agent of the present invention: two (acyl amino) cyclohexane derivants shown in the following formula (I) with (B): the mass ratio of two (acyl amino) cyclohexane derivants shown in the following formula (II) is not special to be limited; Be preferably 80: 20～20: 80, more preferably 60: 40～20: 80.When the ratio of two (acyl amino) cyclohexane derivants shown in the formula (I) surpasses 80 quality %; Oleogel agent of the present invention might crystallinity raise, perhaps become really up to the mark; And making the transparency significantly reduce, during less than 20 quality %, gel hardness might significantly reduce.
(oil-base gel compsn)
Oil-base gel compsn of the present invention contains above-mentioned oleogel agent and finish.
As finish, can enumerate for example following finish.
Can enumerate hydro carbons such as whiteruss, Vitabiosol, Supraene, polybutylenes, Parleam,
Fatty acids such as palmitinic acid, oleic acid, Triple Pressed Stearic Acid,
Lipoval A, Semen Lini oil, Prunus amygdalus oil, perilla oil, Chinese torreyanut oil (カ ヤ oil), Uni Ace R, sweet oil, Semen Maydis oil, Viscotrol C, Thistle oil, sunflower oil, Oleum Gossypii semen, Jojoba oil, Macadamia nut oil, wheatgerm oil, VT 18, peanut oil, Oleum Cocois, plam oil, palm-kernel oil, Camellia oil, root of Redsepal Eveningprimrose wet goods plant oil
Animal oils such as mink oil, fish oil, lard, butter,
Diisobutyl adipate; Hexanodioic acid 2-hexyl ester in the last of the ten Heavenly stems; Hexanodioic acid two-2-heptyl undecyl ester; Single Unimac 5680 N-alkyl glycol ester; The different cetyl of Unimac 5680; Three Unimac 5680 TriMethylolPropane(TMP)s; The 2 ethyl hexanoic acid cetyl; Two-2 ethyl hexanoic acid glycol ester; Two-2 ethyl hexanoic acid DOPCP; Three 2 ethyl hexanoic acid glyceryl ester; Three-2 ethyl hexanoic acid TriMethylolPropane(TMP); Four-2 ethyl hexanoic acid pentaerythritol ester; Octanoic acid, hexadecyl ester; Octyl group dodecyl glue ester (オ Network チ Le De デ シ Le ガ system エ ス テ Le); Oleyl oleate; Oleic acid octyl group dodecyl ester; Decyl oleate; Two capric acid DOPCPs; Triethyl citrate; Succsinic acid 2-ethylhexyl; Pentyl acetate; ETHYLE ACETATE; Butylacetate; Standamul 7061; Butyl stearate; Wickenol 117; Diisooctyl Sebacate; The lactic acid cetyl; Tetradecyl lactate; Wickenol 111; Palmitinic acid 2-ethylhexyl; Palmitinic acid 2-hexyl ester in the last of the ten Heavenly stems; Palmitinic acid 2-heptyl undecyl ester; 12-oxystearic acid cholesterol ester; The Dipentaerythritol fatty ester; Isopropyl myristate; Tetradecanoic acid 2-octyl group dodecyl ester; Tetradecanoic acid 2-hexyl ester in the last of the ten Heavenly stems; Tetradecyl tetradecanoate; The sad hexyl of dimethyl-ester in the last of the ten Heavenly stems; Laurate ethyl; Lauric acid hexyl ester; N-lauroyl-L-L-glutamic acid-2-octyl group dodecyl ester; Ester classes such as oxysuccinic acid two different stearyl esters
Type siloxanes such as dimethyl polysiloxane, methyl phenyl silicone, hydrogenated methyl ZGK 5, octamethylcyclotetrasiloxane, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes, tetramethyl-tetrahydro-cyclotetrasiloxane, fluorine modified polyorganosiloxane,
Fluorine class finish classes such as perfluoro decane, PFO, PFPE etc.
For hardness, the transparency that improves gel, the preferred polyolefine with side chain that cooperates specifically, can be enumerated (C7; 8) isoparaffin, (C8,9) isoparaffin, (C9-11) isoparaffin, (C10-13) isoparaffin, (C11,12) isoparaffin, (C11-13) isoparaffin, (C13; 14) isoparaffin classes such as isoparaffin, (C13-16) isoparaffin, (C18-70) isoparaffin, olefin oligomer, hydrogenation C6-14 olefin polymer; Polybutylenes, Parleam, hydrogenation poly decene etc.; Wherein, consider from usability aspects such as the transparency of gel, tacks, more preferably polybutylenes, Parleam, hydrogenation C6-14 olefin polymer.These finishes can use or use two or more separately.
As oil-base gel preparation of compositions method of the present invention, can enumerate: after above-mentioned (A), (B) and above-mentioned finish are mixed, the method for heating for dissolving to homogeneous state; Or the preparation be mixed with above-mentioned (A) and oleogel agent (B) after, it is added in the warmed-up finish to blending dispersion to homogeneous state, standing methods at normal temperatures.
Can also be with above-mentioned (A) and (B), cooperate any composition as required, prepare oil-base gel compsn of the present invention.
When preparing oil-base gel compsn of the present invention, do not limit,, be preferably 0.01～20 quality %, 0.1～15 quality % more preferably with respect to the oil-base gel total composition to the use level of adding the above-mentioned oleogel agent in the finish to is special.As the machine that is used for above-mentioned blending dispersion, can enumerate dispersing and mixing machine, roller mill, HV mixing machine, omnipotent stirrer, Henschel mixer etc.
Purposes as oil-base gel compsn of the present invention; Can enumerate makeup, external composition for skin, coating, printing ink, lubricated wet goods; Be preferably makeup (comprising similar drug),, can preferably enumerate lipstick, lip protector (lip gloss), lipstick lip makeup such as (lip cream) as the makeup that cooperate oil-base gel compsn of the present invention; Foundation creams such as oiliness foundation cream, water-in-oil-type and oil-in-water type emulsion foundation emulsion; Color make-up makeup such as eye shadow (eye color), eyeliner, Mascara, nail varnish, armor wet goods agent for beautifying nail, hair care goods such as hair dye, hair conditioner, a film; The material of haircuting such as pomade, hair liquid, hair oil, hair-cream; Skin protection cosmeticss such as emulsion, emulsifiable paste, beauty liquid, beautification oil, facial mask etc. in addition as external composition for skin, can preferably be enumerated water-in-oil type skin external preparation, lipid formulations, Liposomal formulation of suppository, water-in-oil-type and oil-in-water-type etc.
The use level of the above-mentioned oleogel shape compsn in makeup of the present invention, the external composition for skin is not special to be limited, and with respect to the total amount of makeup, external composition for skin etc., is preferably 0.01～100 quality %, 0.1～99.5 quality % more preferably.
In makeup of the present invention, the external composition for skin etc.; Except above-mentioned (A), (B) or finish; The composition that can proper fit in the scope of not damaging effect of the present invention in makeup, external composition for skin etc., uses usually, for example alcohols, wetting Agent for Printing Inks, gelating agent, powder, UV light absorber, sanitas, antiseptic-germicide, inhibitor, pH regulator agent, U.S. flesh with composition, external medicine etc. as any composition.These compositions can cooperate when the above-mentioned oleogel shape compsn of preparation or be coupled in the oleogel agent.
As above-mentioned alcohols; Can enumerate for example lower alcohol such as ethanol, Virahol; Glycerine, two glycerine, poly-glycerol, Diethylene Glycol, polyoxyethylene glycol, Ucar 35, dipropylene glycol, W 166,1; Polyvalent alcohols such as 3-butyleneglycol, tetrahydroxybutane, sugar alcohols such as Sorbitol Powder, SANMALT-S, Xylitol, maltose alcohol, or sterols such as cholesterol, Sitosterol, plant sterol, lanosterol etc.
As above-mentioned wetting Agent for Printing Inks, can enumerate for example urea, mucinase, CHS, pyrrolidone carboxylic acid salt etc.
As the gelling agent, as long as the gelling agent is water or oily gelling agent is not particularly limited, for example, as an aqueous gelling agent include gum arabic, tragacanth gum, arabinogalactan, angle bean gum, guar gum, karaya gum, carrageenan, pectin, agar, quince seed (from quinces, etc.), starch (from rice, corn, potatoes, wheat, etc.), sodium alginate, Suites ra nn Suites gum (trant ? gum), locust bean gum, and other plant-based polymers, xanthan gum, dextran, succinylated dextran, amylopectin and other microbial-based polymers, collagen, casein, albumin, gelatin and other animal high molecule, carboxymethyl starch, methyl starch-based polymers such as hydroxypropyl starch, methyl cellulose, hydroxypropylmethyl cellulose, carboxymethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl propyl cellulose, cellulose sulfate, sodium carboxymethyl cellulose and other cellulose-based polymers, sodium alginate, alginic acid propylene glycol ester seaweed polymers, sodium polyacrylate, carboxy vinyl polymer, an alkyl group modified carboxyvinyl polymer, polyacrylamide, polyvinyl alcohol, polyvinyl pyrrolidone, ethylene-based polymers, or polyethylene glycol, ethylene oxide-propylene oxide copolymers, bentonite, aluminum magnesium silicate, lithium algae earth, hectorite, silica and other inorganic.
As above-mentioned powder; Can enumerate for example inorganic powder, organic powder, metallic soap powder, colored pigment, pearly pigment, metal-powder, tar colorant, natural pigment etc., irrelevant with its particle shape (spherical, needle-like, tabular etc.), particle diameter (smoke-like, particulate, pigment-level etc.) or particle structure (porous matter, atresia matter etc.).These powder can directly use, and the powder that also can use two or more compoundization of powder to form can also use finish, silicone compounds, fluorine cpd etc. to implement surface treatment.
As UV light absorber; Can enumerate for example benzoic acids UV light absorber such as para-amino benzoic acid, anthranilic acid UV light absorbers such as methyl o-aminobenzoate, salicylic acid UV light absorbers such as wintergreen oil; Cinnamic acid UV light absorbers such as p-methoxycinnamic acid monooctyl ester; Benzophenone UV light absorbers such as 2,4 dihydroxyl benzophenone, or urocanic acid class UV light absorber such as urocanic acid ethyl ester etc.
As sanitas, antiseptic-germicide; Can enumerate for example p-Hydroxybenzoate, phenylformic acid, Sodium Benzoate, Sorbic Acid, POTASSIUM SORBATE GRANULAR WHITE, phenoxyethyl alcohol, Whitfield's ointment, phenol, Sorbic Acid, parachlorometacresol, Hexachlorophene, benzalkonium chloride, chlorhexidine hydrochloride, trichlorocarbanilide, plain, the isopropyl methyl phenol, 1 of sensitization, 2-pentanediol etc.
As inhibitor, can enumerate for example Viteolin, butylated hydroxy anisole, butylated hydroxytoluene etc.
As the pH regulator agent, can enumerate for example lactic acid, lactic acid salt, Hydrocerol A, Citrate trianion, oxyacetic acid, succsinic acid, tartrate, oxysuccinic acid, salt of wormwood, sodium hydrogencarbonate, bicarbonate of ammonia etc.
Use composition as U.S. flesh; Can enumerate for example whitening agents such as arbutin, gsh, saxifrage extract; Cell-activating agent pachylosis activators such as royal jelly, sensitization element, cholesterin derivative, tire bovine blood extract; The capable promotor of blood such as Vanillyl pelargonic amide (n-nonanoic acid ワ レ ニ Le ア ミ De), nicotinic acid benzene methyl, nicotinic acid Beta-Butoxy ethyl ester, capsaicine, gingerol, cantharides tincture, isarol, theine, tannic acid, α-borneol, nicotinic acid Viteolin, Vasonicit, Cyclelate, Stutgin, phenylmethylimidazoline, vagusstoff, Verapamilum, cepharanthine, γ-orizanol; The agent of skin contraction such as zinc oxide, tannic acid, or lipotropisms such as sulphur, thianthol leak agent etc.
Form as makeup of the present invention, external composition for skin; Can enumerate emulsifiable paste shape, gel, liquid state, solid-like, multilayer shape etc.; As the formulation of makeup of the present invention, external composition for skin, can enumerate oiliness system, oil-in-water emulsify system, oil-in-water type emulsion system, solvent system etc.
Below, through embodiment the present invention is explained more specifically, but technical scope of the present invention is not limited by these examples.
Embodiment
(reference example: 1, two (acyl amino) cyclohexane derivants of 2-synthetic)
[synthesizing of compound (1)]
With 1,2-DACH 3.43g and triethylamine 7.29g are dissolved in the THF (below be called THF) of 130mL, ice-cooled down, add palmityl chloride 19.24g.Stirred reflux number minute under the room temperature 1 hour.Add the acetone leaching insolubles of 100mL, use washing with acetone.The compound that obtains is dissolved in immediately in the ethanol of 100mL, put cold after, add the water of 300mL, leaching insolubles.Further with after washing with acetone and the drying, after the crude product heating for dissolving that obtains is in the ethanol of 150mL, add the acetone of 400mL, the precipitate of leaching white obtains the compound (1) shown in the following formula (III).The receipts amount is 12.91g.
[chemical formula 3]
Compound (1)
[synthesizing of compound (2)]
With 1,2-DACH 3.43g and triethylamine 7.29g are dissolved among the THF of 130mL, and be ice-cooled following, adds stearyl chloride 21.1g.Stirred reflux number minute under the room temperature 1 hour.Add the acetone leaching insolubles of 100mL, use washing with acetone.The compound that obtains is dissolved in immediately in the ethanol of 100mL, put cold after, add the water of 300mL, leaching insolubles.Further with after washing with acetone and the drying, after the crude product heating for dissolving that obtains is in the ethanol of 150mL, add the acetone of 150mL, the precipitate of leaching white obtains the compound (2) shown in the following formula (IV).The receipts amount is 11.5g.
[chemical formula 4]
Compound (2)
[synthesizing of compound (3)]
With 1,2-DACH 11.42g and triethylamine 24.29g are dissolved among the THF of 250mL, and be ice-cooled following, adds 2-hexyl decanoyl chloride 54.98g.Stirred reflux number minute under the room temperature 1 hour.Remove THF with the vaporizer distillation, add the acetone leaching insolubles of 100mL, use washing with acetone.The compound that obtains is dissolved in immediately in the ethanol of 100mL, put cold after, add the water of 300mL, leaching insolubles.Further with after washing with acetone and the drying, with the acetone recrystallization of the crude product that obtains by 400mL, the precipitate of leaching white obtains the compound shown in the following formula V (3).The receipts amount is 43.14g.
[chemical formula 5]
Compound (3)
[synthesizing of compound (4)]
With 1,2-DACH 3.43g and triethylamine 7.29g are dissolved among the THF of 130mL, and be ice-cooled following, adds 2-heptyl undecane acyl chlorides 18.18g.Stirred reflux number minute under the room temperature 1 hour.Remove THF with the vaporizer distillation, add the acetone leaching insolubles of 100mL, use washing with acetone.The compound that obtains is dissolved in immediately in the ethanol of 100mL, put cold after, add the water of 300mL, leaching insolubles.Further with after washing with acetone and the drying, with the acetone recrystallization of the crude product that obtains by 400mL, the precipitate of leaching white obtains the compound (4) shown in the following formula (VI).The receipts amount is 10.81g.
[chemical formula 6]
Compound (4)
[synthesizing of compound (5)]
With 1,2-DACH 3.43g and triethylamine 7.29g are dissolved among the THF of 130mL, and be ice-cooled following, adds 2-(2-methyl-4,4-dimethyl-amyl group)-4-methyl-6,6-dimethyl-g acyl chlorides 18.18g.Stirred reflux number minute under the room temperature 1 hour.After adding the acetone leaching insolubles of 100mL and removing, remove filtrating with the vaporizer distillation after, by the 50mL acetone recrystallization, the precipitate of leaching white obtains the compound (5) shown in the following formula (VII).The receipts amount is 6.42g.
[chemical formula 7]
Compound (5)
[synthesizing of compound (6)]
With 1,2-DACH 8.57g and triethylamine 16.70g are dissolved among the THF of 400mL, and be ice-cooled following, adds isostearoyl chlorine (Buddha's warrior attendant sand mold) 42.44g.Stir after 1 hour reflux number minute under the room temperature.The acetone that adds 300mL, the leaching insolubles and remove after, remove filtrating with the vaporizer distillation, by the 300mL acetone recrystallization, obtain the crude product of 40g.Further be dissolved in the hot ethanol of 50mL, the acetone that adds 200mL carries out recrystallization, and the precipitate of leaching white obtains the compound (6) shown in the following formula (VIII).The receipts amount is 34.5g.
[chemical formula 8]
Compound (6)
Wherein, the Unimac 5680 of diamond-type is meant that the carbonatoms that the by product unsaturated fatty acids hydrogenation that produces with by the synthetic dipolymer acid of oleic acid the time obtains is 18, and side chain has methyl, the uncertain Unimac 5680 of structure.Isostearoyl chlorine (Buddha's warrior attendant sand mold) is meant the muriate of above-mentioned Unimac 5680.
[synthesizing of compound (7)]
With 1,2-DACH 11.42g and triethylamine 24.28g are dissolved among the THF of 150mL, and be ice-cooled following, adds 2-ethyl hexanoyl chloro 32.53g.Stir after 3 hours reflux number minute under the room temperature.Be cooled to room temperature, the gel that suction filtration generated.The compound dissolution that obtains in the ethanol of 200mL, is added the water of 300mL, the suction filtration insolubles.The crude product heating for dissolving that obtains in the methyl alcohol of 100mL, is added the acetone of 600mL, recrystallization, leaching white separate out composition, obtain the compound (7) shown in the following formula (IX).The receipts amount is 15.15g.
[chemical formula 9]
Compound (7)
[preparation of mixture (1) (mixtures of compound (2), (7) and (8))]
With 1,2-DACH 8.57g and triethylamine 16.70g are dissolved among the THF of 400mL, and be ice-cooled following, adds 2-ethyl hexanoyl chloro 12.20g and stearyl chloride 21.10g.Stir after 1 hour reflux number minute under the room temperature.Add the acetone of 300mL, the leaching insolubles is used washing with acetone.Then, be dissolved in the ethanol of 100mL, put cold after, the water that adds 300mL carries out leaching, with washing with acetone and dry.With the acetone recrystallization of the crude product that obtains by 400mL, the solids component of leaching white obtains compound.This compound is the mixture that the compound (8) shown in the following formula (X) and above-claimed cpd (2) and (7) mix.The receipts amount is 10.81g.
[Chemical formula 1 0]
Compound (8)
[embodiment 1]
[used for cosmetic oiliness gelatinous compsn: 1]
Use above-mentioned compound (1)～(7) and the mixture (1) that synthesizes, prepares, the sample of embodiment sample #1～#2 that constitutes shown in the preparation table 1 and the oily gel composition of comparative sample #1～#8.For each sample, after the metering total amount, heating for dissolving in the time of stirring, after the transparent dissolving, the cooling preparation is estimated for solvent temperature, gel outward appearance, gel formation, gel hardness.Solvent temperature after the formation thing mixing with each sample, is slowly heated up by room temperature, the transparent dissolved of each oily gel composition sample of visual judgement temperature constantly.For the gel outward appearance; Above-mentioned each oily gel composition sample is filled into the square pond of plexiglass system 1cm (cell); Judge in the time of can not recognizing the literal of Century thing 12 fonts through the pond and be evaluated as " gonorrhoea "; Judge when existing muddiness still can recognize to be evaluated as " translucent ", judge when muddiness can be known identification hardly to be evaluated as " transparent ".For gel hardness; With above-mentioned each oily gel composition sample heat be dissolved to transparent after; After in 25 ℃ thermostatic bath, leaving standstill 3 hours,, use the plunger of φ 2mm with FUDOH corporate system rheometer (NRM-2002DD); Load peak (g) when mensuration got into 3mm with admission velocity 6cm/ minute is confirmed gel hardness thus.The result is as shown in table 1.
[table 1]
*1: パ one Le リ one system 18 (Japanese grease society system)
(determinating reference)
Gel outward appearance: ◎: transparent
Zero: translucent
△: gonorrhoea
*: crystallization
Gel formation: zero: do not flow backwards
△: a part flows backwards
*: all flow backwards
[result]
The compound (2) of the compound (1) of embodiment sample #1 and the combination of compound (3) and embodiment sample #2 and the combination of compound (4); The result of solvent temperature, gel outward appearance, gel formation, gel hardness is good; And for combination and the compound (2) of comparative sample #2 and the combination of compound (6) of compound (2) and the compound (5) of comparative sample #1; The value of gel hardness is very low, aspect usability such as the homogeneity of gel, slipperiness, is inappropriate as gelating agent; When improving use level in order to improve gel hardness, then the transparency of gel significantly reduces.Confirm that in addition 1 shown in the formula (II) when the acyl moiety of two (acyl amino) cyclohexane derivants of 2-has the many alkyl of the side chain of so-called aldol condensation type, when having so-called Buddha's warrior attendant sand mold alkyl, is inappropriate as oleogel agent of the present invention.Confirm in addition; Combination and the compound (2) of comparative sample #6 and the combination of compound (7) for compound (1) and the compound (7) of comparative sample #5; Solvent temperature is 180 ℃, very high; Consider improperly from the preparation of makeup, the viewpoint of filling formability, acyl moiety is that the carbonatoms of side chain is two (acyl amino) cyclohexane derivants of 8, and it is inappropriate being used for oleogel agent of the present invention.In addition, among the comparative sample #3, compound (2) is during separately as the oleogel agent; And among the comparative sample #4, compound (4) is during separately as the oleogel agent, and gonorrhoea appears in prepared oily gel composition; Even be two (acyl amino) cyclohexane derivants that use among the present invention; When using separately, aspect prepared oily gel composition transparent, also be inappropriate.Can know in addition; The carbonatoms of the above-mentioned acyl moiety of the compound of comparative sample #7 (7) is that two (acyl amino) cyclohexane derivants of 8 are during separately as the oleogel agent; Solvent temperature is too high, and gel crystalsization is as the mixture (1) of comparative sample #8; Under the situation of the combination of compound (2), (7) and (8), solvent temperature is too high or gel hardness is low excessively.
[embodiment 2]
(used for cosmetic oiliness gelatinous compsn: 2)
For above-claimed cpd (2) and (4), change the ratio that cooperates and append preparation embodiment sample #3～#8, with above-mentioned solvent temperature, gel outward appearance, gel formation and the gel hardness likewise measured.The result is as shown in table 2.
[table 2]
[result]
Compound (2) or compound (4) are during respectively separately as the oleogel agent, and gonorrhoea appears in oily gel composition, and compound (2) during with compound (4) and as the oleogel agent, is had nothing to do with cooperating ratio, and the degree of gonorrhoea is little.Can know that by the transparency of gel and the evaluation of gel hardness the mass ratio of compound (2) and (4) is at 60: 40～20: 80 o'clock, and is good as the oleogel agent, particularly 40: 60～20: 80 good especially aspect gel transparent.
[embodiment 3]
(used for cosmetic oiliness gelatinous compsn: 3)
Each 2.5% adds in the finish of the formation shown in the following table 3 with above-claimed cpd (2) and (4), with above-mentioned solvent temperature, gel outward appearance, gel formation, the gel hardness likewise measured.The result is as shown in table 3.
[table 3]
[result]
For each finish shown in the table 3; Show good result for solvent temperature, gel outward appearance, gel formation and gel hardness; Represent gelating agent of the present invention and finish kind, cooperate ratio irrelevant, be effectively, and the polyolefinic Parleam with side chain is during separately as finish (embodiment sample #9); Confirm that transparency is very high, be particularly suitable for being coupled to the situation in the high makeup of transparent feel or gloss.
[embodiment 4]
(used for cosmetic oiliness gelatinous compsn: 4)
For above-claimed cpd (2) and (4), append preparation embodiment sample #14, with above-mentioned solvent temperature, gel outward appearance and the gel hardness likewise measured.The result is as shown in table 4.
[table 4]
| Embodiment sample #14 | Comparative sample #9 | |
| Compound (2) | 0.5 | |
| Compound (4) | 1.5 | |
| Rheopearl TL *2 | 12.0 | |
| Parleam *1 | 50.0 | 50.0 |
| Three isocaprylic acid glyceryl ester | 47.85 | 37.85 |
| Sanitas | 0.1 | 0.1 |
| Spices | 0.05 | 0.05 |
| Solvent temperature (℃) | 110 | 90 |
| The gel outward appearance | ◎ is transparent | Zero is translucent |
| Gel hardness | 11.6 | 6.8 |
*2: レ オ パ one Le KL2 (Chiba powder process society system)
[result]
The gel outward appearance of embodiment sample #14 and comparative sample #9 is as shown in Figure 1.(embodiment sample #14) forms clear gel when using the gelating agent of combination of compound (2) and (4), the use Rheopearl TL during as gelating agent (comparative sample #9) form translucent gel.Oleogel agent of the present invention can use the amount of the sixth of the gelating agent that in the past used to form the high good gel of transparency.
[embodiment 5]
(lip stick (ス テ イ Star Network shape lipstick))
[prescription] (quality %)
1. ethylene-propylene copolymer
*3 5.0
2. compound 1 0.2
3. compound 3 0.1
4. three Unimac 5680s, two glyceryl ester 20.0
5. ten Unimac 5680s, ten glyceryl ester 10.0
6. polybutylenes
*4 5.0
7. siloxane branches type polyether modified siloxane
*5 2.0
8. the didecyl acid propylene glycol ester 10.0
9. three isocaprylic acid glyceryl ester surpluses
10. siloxane treated red iron oxide lining mica
*6 2.0
11. siloxane treated mica titanium
*6 2.0
12. red No. 202 0.15
13. yellow No. 4 0.7
14. titanium oxide 1.5
15. iron oxide black 0.1
16. sanitas is an amount of
17. inhibitor is an amount of
18. spices is an amount of
*3:EP-700 (ニ ユ one Off エ one ズ テ Network ノ ロ ジ one society's system)
*4: polybutylenes 100R (the emerging product of bright dipping society system)
*5:KF-6028P (chemical industry society of SHIN-ETSU HANTOTAI system)
*6:3% (dimethyl polysiloxane/methyl polysiloxane) multipolymer is handled
[preparation method]
A: composition 1～9 is heated after the dissolving, add composition 10～15 and also mix homogeneous.
B: in A, add 16～17 and mix homogeneous.
C: in B, add composition 18, heating after the deaeration, is filled in the container, and cooling obtains lip stick.
[result]
Lip stick of the present invention can reduce solid oil masses such as wax, simultaneously can moulding, have slick smoothening property and gloss, and appearance color is excellent with colour developing.
[embodiment 6]
(oiliness foundation cream)
[prescription] (quality %)
1. compound 2 2.0
2. compound 4 3.0
3. siloxane branches type dodecyl triglycerin base modified siloxane
*7 2.0
4. three Unimac 5680s, two glyceryl ester 10.0
5. three (capric acid is sad) glyceryl ester surplus
6. dimethyl polysiloxane
*8 5.0
7. olefin polymer
*9 5.0
8. aerosil 0.1
9. particulate titanium dioxide 1.0
10. titanium oxide 8.0
11. permanent white 2.0
12. sericite 15.0
13. red iron oxide 1.0
14. yellow oxide of iron 2.0
15. iron oxide black 0.5
16. Carbopol ETD2050
*11 0.1
17.1,3-butyleneglycol 0.5
18. spices is an amount of
*7:KF-6105 (chemical industry society of SHIN-ETSU HANTOTAI system)
*8:KF-96A-6cs (chemical industry society of SHIN-ETSU HANTOTAI system)
*9: alpha-olefin low polymers (little Sakai pharmacy society system)
*10:AEROSIL R972 (Japanese ア エ ロ ジ Le society system)
*11: カ one ボ Port one Le 940 (グ Star De リ Star チ society system)
[preparation method]
A: composition 1～7 is heated after the dissolving, add composition 8～17 and also mix homogeneous.
B: in A, add 18, heating after the deaeration, is filled in the metal ware, and cooling obtains the oiliness foundation cream.
[result]
Oiliness foundation cream of the present invention can be with few gelation dosage moulding, and is smooth and have light smoothening property and gloss, and appearance color, colour developing are excellent.
[embodiment 7]
(oiliness eye shadow)
[prescription] (quality %)
1. compound 1 1.0
2. compound 3 3.0
3. three isocaprylic acid glyceryl ester 10.0
4. olefin oligomer
*12 10.0
5. alkyl, polyether modified siloxane
*13 7.0
6. pentaerythritol fatty ester
*14 5.0
7. Vitabiosol surplus
8. the didecyl acid propylene glycol ester 15.0
9. stearyl modification acrylate siloxanes
*15 10.0
10. sesquialter oleic acid sorbitan 0.5
11. single oleic acid T 46155 (20) sorbitan 0.8
12. nylon powder
*16 2.0
13. siloxane treated talcum
*6 10.0
14. red No. 202 0.5
15. blue No. 404 1.0
16. siloxane treated titanium oxide 2.0
17. mica titanium 10.0
18. aerosil
*8 1.0
19. spices is an amount of
*12: ノ system コ one ト HPD-C (day clear オ イ リ オ society system)
*13:ABIL EM90 (go one Le De シ ユ ミ Star ト society system)
*14: コ ス モ one Le 168ARN (day clear オ イ リ オ society back of the body system)
*15:KP-561P (chemical industry society of SHIN-ETSU HANTOTAI system)
*16: nylon powder SP-500 (DongレShe system)
[preparation method]
A: after composition 1～11 heating for dissolving, add composition 12～18 and mix homogeneous.
B: in A, add composition 19, heating after the deaeration, is filled in the metal ware, and cooling obtains the oiliness eye shadow.
[result]
Oiliness eye shadow of the present invention can be with few gelation dosage moulding, and is smooth and have light smoothening property and gloss, and appearance color, colour developing are excellent.
[embodiment 8]
(water-in-oil type sunscreen emulsifiable paste)
[prescription] (quality %)
1. methyl trimethoxy based polysiloxane
*17 5.0
2. vinylformic acid-siloxane treated particulate titanium dioxide
*18 5.0
3. siloxane branches type dodecyl polyether modified siloxane
*19 0.5
4. dimethyl polysiloxane
*20 2.0
5. trimethylsiloxy silicic acid/decamethylcyclopentaandoxane solution
*21 5.0
6. compound 1 0.1
7. compound 3 0.1
8. the p-methoxycinnamic acid monooctyl ester 3.0
9. the isocaprylic acid cetyl 5.0
10. siloxane branches type polyether modified siloxane
*5 2.0
11. ethanol 7.0
12. glycerine 2.0
13. sodium-chlor 1.0
14. sanitas is an amount of
15. silicone powder
*22 2.0
16. spices is an amount of
17. purified water surplus
*(17:TMF-1.5 chemical industry society of SHIN-ETSU HANTOTAI system)
*18:KP-549 (chemical industry society of SHIN-ETSU HANTOTAI system) handles particulate titanium dioxide
*19:KF-6038 (chemical industry society of SHIN-ETSU HANTOTAI system)
*20:KF-96-2cs (chemical industry society of SHIN-ETSU HANTOTAI system)
*21:KF-7312J (chemical industry society of SHIN-ETSU HANTOTAI system)
*22:KSP-100 (chemical industry society of SHIN-ETSU HANTOTAI system)
[preparation method]
A: composition 1～3 usefulness ball mill is handled homogeneous disperse.
B:, A and composition 15 are mixed homogeneous with composition 4～10 dissolving of heating.
C: with composition 11～14 and composition 17 mixed dissolutions.
D: after the emulsification, cool off when in B, adding C.
E: added ingredients 16 mixes homogeneous in D, obtains the water-in-oil type sunscreen emulsifiable paste.
[result]
Water-in-oil type sunscreen emulsifiable paste of the present invention in the time of on being coated on skin, smoothens glossily, and is good to the compactness of skin, for can not oily finished product, the transparency and excellent in stability.
[embodiment 9]
(hair-cream)
[prescription] (quality %)
1. the stearyl trimethyl ammonium chloride 0.5
2. Tego Alkanol 16 1.0
3. V-1326 1.5
4. different n-nonanoic acid isotridecyl ester 2.0
5. compound 2 0.1
6. compound 4 0.2
7. dimethyl polysiloxane
*8 2.0
8. decamethylcyclopentaandoxane 5.0
9. Ucar 35 5.0
10. ethanol 5.0
11. Poise C-80M
*23 0.1
12. XG 550
*24 0.1
13. sanitas is an amount of
14. purified water surplus
15. spices is an amount of
*23: polymkeric substance JR400 (ユ ニ オ Application カ one バ イ De society system)
*24: ケ Le ト ロ one Le (ケ Le コ カ Application パ ニ one society's system)
[preparation method]
A: composition 2～8 is heated and mixed homogeneous.
B: composition 1 and composition 9～14 are heated and mixed homogeneous.
Carry out emulsification when in B, adding A under C:80 ℃.
D: after the cooling, in C, add composition 15 and mix homogeneous, obtain hair-cream.
[result]
Hair-cream of the present invention smoothens when being applied to hair glossily, and is good to the consistency of hair, for can not the oily finished product, and gloss and excellent with the consistence of hair.
[embodiment 10]
(pasty state lip protector (lip gloss))
[prescription] (quality %)
1. compound 2 0.1
2. compound 4 0.2
3. oxysuccinic acid two different stearyl esters 20.0
4. polybutylenes
*2 60.0
5. the didecyl acid propylene glycol ester 10.0
6. three isocaprylic acid glyceryl ester surpluses
7. siloxane treated mica titanium
*6 1.0
8. red No. 202 0.02
9. yellow No. 4 0.04
10. titanium oxide 0.15
Industrial applicibility
Oleogel agent of the present invention; Be coupled in the nonpolar or low polar finish through lower concentration; Can stably form the high oily gel composition of the transparency, the makeup, the external composition for skin that are combined with above-mentioned oleogel agent, oleogel compsn are excellent at the aspects such as the transparency of stability, usability, outward appearance.
Claims (7)
1. oleogel agent, this oleogel agent contains:
(A): two (acyl amino) cyclohexane derivants shown in the formula (I),
Chemical formula 1
In the formula, R
1The expression carbonatoms is 15～21 straight chained alkyl; With
(B): two (acyl amino) cyclohexane derivants shown in the formula (II),
Chemical formula 2
In the formula, R
2The expression total carbon atom number be 15～21,1 have straight chained alkyl as substituent straight chained alkyl.
2. oleogel agent as claimed in claim 1 is characterized in that, (A): mass ratio (B) is 80: 20～20: 80.
3. an oily gel composition is characterized in that, this oily gel composition contains claim 1 or 2 described oleogel agent and finishes.
4. oily gel composition as claimed in claim 3 is characterized in that finish contains the polyolefine with side chain.
5. oily gel composition as claimed in claim 4 is characterized in that, the polyolefine with side chain is a Parleam.
6. makeup is characterized in that, these makeup contain any described oily gel composition in claim 1 or 2 described oleogel agent or the claim 3～5.
7. an external composition for skin is characterized in that, this external composition for skin contains any described oily gel composition in claim 1 or 2 described oleogel agent or the claim 3～5.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009053920 | 2009-03-06 | ||
| JP2009-053920 | 2009-03-06 | ||
| PCT/JP2010/001538 WO2010100939A1 (en) | 2009-03-06 | 2010-03-05 | Oil gelling agent, composition containing oil gelling agent, and external preparation or cosmetic for skin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102369253A true CN102369253A (en) | 2012-03-07 |
| CN102369253B CN102369253B (en) | 2014-01-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080010083.2A Expired - Fee Related CN102369253B (en) | 2009-03-06 | 2010-03-05 | Oil gelling agent, composition containing oil gelling agent, and external preparation or cosmetic for skin |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP5526121B2 (en) |
| KR (1) | KR20110125645A (en) |
| CN (1) | CN102369253B (en) |
| HK (1) | HK1167157A1 (en) |
| TW (1) | TWI444204B (en) |
| WO (1) | WO2010100939A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105408305A (en) * | 2013-07-25 | 2016-03-16 | 阿科玛法国公司 | Cycloaliphatic and aliphatic diamine-based fatty acid diamides used as organogelators |
| CN107625660A (en) * | 2017-09-27 | 2018-01-26 | 广州环亚化妆品科技有限公司 | A kind of transparent sun-proof oleogel and preparation method thereof |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011225557A (en) * | 2010-03-31 | 2011-11-10 | Kose Corp | Solid cleansing agent |
| JP5792443B2 (en) * | 2010-09-03 | 2015-10-14 | 株式会社コーセー | Oily fragrance composition |
| JP5607468B2 (en) * | 2010-09-03 | 2014-10-15 | 株式会社コーセー | Oily makeup cosmetics |
| FR2996553B1 (en) * | 2012-10-05 | 2015-09-04 | Arkema France | FATTY ACID AMIDE BASED ON 14-HYDROXY EICOSANOIC ACID, AS ORGANOGELER |
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- 2010-03-05 CN CN201080010083.2A patent/CN102369253B/en not_active Expired - Fee Related
- 2010-03-05 JP JP2011502663A patent/JP5526121B2/en not_active Expired - Fee Related
- 2010-03-05 KR KR1020117020491A patent/KR20110125645A/en not_active Application Discontinuation
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| CN105408305A (en) * | 2013-07-25 | 2016-03-16 | 阿科玛法国公司 | Cycloaliphatic and aliphatic diamine-based fatty acid diamides used as organogelators |
| CN107625660A (en) * | 2017-09-27 | 2018-01-26 | 广州环亚化妆品科技有限公司 | A kind of transparent sun-proof oleogel and preparation method thereof |
| CN107625660B (en) * | 2017-09-27 | 2021-04-02 | 广州环亚化妆品科技有限公司 | Transparent sunscreen oil gel and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| HK1167157A1 (en) | 2012-11-23 |
| JPWO2010100939A1 (en) | 2012-09-06 |
| TWI444204B (en) | 2014-07-11 |
| WO2010100939A1 (en) | 2010-09-10 |
| CN102369253B (en) | 2014-01-15 |
| KR20110125645A (en) | 2011-11-21 |
| TW201041602A (en) | 2010-12-01 |
| JP5526121B2 (en) | 2014-06-18 |
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