CN102367293A - 一种高耐热老化橡胶及其制备方法 - Google Patents
一种高耐热老化橡胶及其制备方法 Download PDFInfo
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- CN102367293A CN102367293A CN2011102591178A CN201110259117A CN102367293A CN 102367293 A CN102367293 A CN 102367293A CN 2011102591178 A CN2011102591178 A CN 2011102591178A CN 201110259117 A CN201110259117 A CN 201110259117A CN 102367293 A CN102367293 A CN 102367293A
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 230000032683 aging Effects 0.000 title abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 239000006229 carbon black Substances 0.000 claims abstract description 24
- 238000002156 mixing Methods 0.000 claims abstract description 20
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 12
- 235000019484 Rapeseed oil Nutrition 0.000 claims abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 10
- 239000000292 calcium oxide Substances 0.000 claims abstract description 9
- -1 dioctyl ester Chemical class 0.000 claims abstract description 8
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims abstract description 7
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 claims abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000005864 Sulphur Substances 0.000 claims abstract description 7
- 230000003712 anti-aging effect Effects 0.000 claims description 21
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 18
- 230000006866 deterioration Effects 0.000 claims description 14
- 239000000806 elastomer Substances 0.000 claims description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 239000004816 latex Substances 0.000 claims description 9
- 229920000126 latex Polymers 0.000 claims description 9
- 239000011701 zinc Substances 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- 235000012255 calcium oxide Nutrition 0.000 claims description 8
- 238000004073 vulcanization Methods 0.000 claims description 7
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 6
- REQPQFUJGGOFQL-UHFFFAOYSA-N dimethylcarbamothioyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)SC(=S)N(C)C REQPQFUJGGOFQL-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims description 3
- 238000005987 sulfurization reaction Methods 0.000 abstract description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000003963 antioxidant agent Substances 0.000 abstract 2
- 230000003078 antioxidant effect Effects 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000013016 damping Methods 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 2
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 abstract 1
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 abstract 1
- 244000043261 Hevea brasiliensis Species 0.000 abstract 1
- 235000021355 Stearic acid Nutrition 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 229920003052 natural elastomer Polymers 0.000 abstract 1
- 229920001194 natural rubber Polymers 0.000 abstract 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 1
- 239000008117 stearic acid Substances 0.000 abstract 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 235000019241 carbon black Nutrition 0.000 description 16
- 238000002955 isolation Methods 0.000 description 4
- 238000004513 sizing Methods 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000010058 rubber compounding Methods 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 238000010077 mastication Methods 0.000 description 1
- 238000004643 material aging Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Abstract
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Priority Applications (1)
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CN 201110259117 CN102367293B (zh) | 2011-09-02 | 2011-09-02 | 一种高耐热老化橡胶及其制备方法 |
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CN 201110259117 CN102367293B (zh) | 2011-09-02 | 2011-09-02 | 一种高耐热老化橡胶及其制备方法 |
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CN102367293A true CN102367293A (zh) | 2012-03-07 |
CN102367293B CN102367293B (zh) | 2013-02-13 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103146037A (zh) * | 2013-03-20 | 2013-06-12 | 柯宇旋 | 一种环保型高耐热汽车发动机减震器橡胶配方 |
CN105199179A (zh) * | 2015-10-08 | 2015-12-30 | 安徽冠宜箱包有限公司 | 一种箱包防污橡胶面料 |
CN105419030A (zh) * | 2015-12-15 | 2016-03-23 | 宁国天运橡塑制品有限公司 | 一种抗震耐高温汽车用橡胶减震件 |
CN108503903A (zh) * | 2018-04-27 | 2018-09-07 | 江苏骆氏减震件有限公司 | 天然橡胶-氯丁橡胶组合物材料、其制备方法和应用 |
CN110511450A (zh) * | 2019-10-11 | 2019-11-29 | 内蒙古一机集团力克橡塑制品有限公司 | 一种汽车减震制品用橡胶 |
CN113896962A (zh) * | 2021-11-04 | 2022-01-07 | 内蒙古一机集团力克橡塑制品有限公司 | 一种装甲车减震制品用橡胶材料 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090048390A1 (en) * | 2001-10-04 | 2009-02-19 | Xiaorong Wang | Nano-Particle Preparation And Applications |
CN101585938A (zh) * | 2009-02-20 | 2009-11-25 | 山东美晨科技股份有限公司 | 一种汽车用空气弹簧配方 |
CN101891905A (zh) * | 2009-11-18 | 2010-11-24 | 九江学院 | 一种无骨雨刷胶条及其制备方法 |
-
2011
- 2011-09-02 CN CN 201110259117 patent/CN102367293B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090048390A1 (en) * | 2001-10-04 | 2009-02-19 | Xiaorong Wang | Nano-Particle Preparation And Applications |
CN101585938A (zh) * | 2009-02-20 | 2009-11-25 | 山东美晨科技股份有限公司 | 一种汽车用空气弹簧配方 |
CN101891905A (zh) * | 2009-11-18 | 2010-11-24 | 九江学院 | 一种无骨雨刷胶条及其制备方法 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103146037A (zh) * | 2013-03-20 | 2013-06-12 | 柯宇旋 | 一种环保型高耐热汽车发动机减震器橡胶配方 |
CN103146037B (zh) * | 2013-03-20 | 2015-02-11 | 柯宇旋 | 一种环保型高耐热汽车发动机减震器橡胶配方 |
CN105199179A (zh) * | 2015-10-08 | 2015-12-30 | 安徽冠宜箱包有限公司 | 一种箱包防污橡胶面料 |
CN105419030A (zh) * | 2015-12-15 | 2016-03-23 | 宁国天运橡塑制品有限公司 | 一种抗震耐高温汽车用橡胶减震件 |
CN108503903A (zh) * | 2018-04-27 | 2018-09-07 | 江苏骆氏减震件有限公司 | 天然橡胶-氯丁橡胶组合物材料、其制备方法和应用 |
CN110511450A (zh) * | 2019-10-11 | 2019-11-29 | 内蒙古一机集团力克橡塑制品有限公司 | 一种汽车减震制品用橡胶 |
CN113896962A (zh) * | 2021-11-04 | 2022-01-07 | 内蒙古一机集团力克橡塑制品有限公司 | 一种装甲车减震制品用橡胶材料 |
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Denomination of invention: High heat resistance and aging resistance rubber, and its preparation method Effective date of registration: 20160512 Granted publication date: 20130213 Pledgee: Wuhu SME financing Company limited by guarantee Pledgor: Wuhu Hetian Automotive Industry Co.,Ltd. Registration number: 2016990000382 |
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Denomination of invention: High heat resistance and aging resistance rubber, and its preparation method Effective date of registration: 20170606 Granted publication date: 20130213 Pledgee: Wuhu SME financing Company limited by guarantee Pledgor: Wuhu Hetian Automotive Industry Co.,Ltd. Registration number: 2017990000462 |
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Denomination of invention: High heat resistance and aging resistance rubber, and its preparation method Effective date of registration: 20180706 Granted publication date: 20130213 Pledgee: Wuhu SME financing Company limited by guarantee Pledgor: Wuhu Hetian Automotive Industry Co.,Ltd. Registration number: 2018340000290 |
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Denomination of invention: High heat resistance and aging resistance rubber, and its preparation method Effective date of registration: 20190702 Granted publication date: 20130213 Pledgee: Wuhu SME financing Company limited by guarantee Pledgor: Wuhu Hetian Automotive Industry Co.,Ltd. Registration number: 2019340000349 |
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Denomination of invention: A high heat aging rubber and its preparation method Effective date of registration: 20200909 Granted publication date: 20130213 Pledgee: Wuhu SME financing Company limited by guarantee Pledgor: WUHU HETIAN AUTOMOTIVE INDUSTRY Co.,Ltd. Registration number: Y2020320000189 |
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