CN102340985B - 冷却对流层的方法 - Google Patents
冷却对流层的方法 Download PDFInfo
- Publication number
- CN102340985B CN102340985B CN2010800097399A CN201080009739A CN102340985B CN 102340985 B CN102340985 B CN 102340985B CN 2010800097399 A CN2010800097399 A CN 2010800097399A CN 201080009739 A CN201080009739 A CN 201080009739A CN 102340985 B CN102340985 B CN 102340985B
- Authority
- CN
- China
- Prior art keywords
- iron
- halogen
- carrier gas
- troposphere
- aerosol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000005436 troposphere Substances 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims abstract description 71
- 238000001816 cooling Methods 0.000 title claims abstract description 15
- 239000000460 chlorine Substances 0.000 claims abstract description 35
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 28
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 22
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000126 substance Substances 0.000 claims abstract description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 115
- 239000000443 aerosol Substances 0.000 claims description 81
- 239000012159 carrier gas Substances 0.000 claims description 75
- 229910052736 halogen Inorganic materials 0.000 claims description 67
- 229910052742 iron Inorganic materials 0.000 claims description 64
- 150000002367 halogens Chemical class 0.000 claims description 63
- 235000002639 sodium chloride Nutrition 0.000 claims description 48
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 45
- 239000000463 material Substances 0.000 claims description 44
- -1 NH 4Br Substances 0.000 claims description 35
- 150000003839 salts Chemical class 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 23
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 18
- 229910052710 silicon Inorganic materials 0.000 claims description 18
- 239000010703 silicon Substances 0.000 claims description 18
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 17
- 238000005868 electrolysis reaction Methods 0.000 claims description 16
- 239000011780 sodium chloride Substances 0.000 claims description 16
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- CTSLXHKWHWQRSH-UHFFFAOYSA-N oxalyl chloride Chemical compound ClC(=O)C(Cl)=O CTSLXHKWHWQRSH-UHFFFAOYSA-N 0.000 claims description 14
- 235000006408 oxalic acid Nutrition 0.000 claims description 13
- 239000013535 sea water Substances 0.000 claims description 13
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical class [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 12
- 150000002506 iron compounds Chemical class 0.000 claims description 11
- 239000002912 waste gas Substances 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 238000010521 absorption reaction Methods 0.000 claims description 9
- CODNYICXDISAEA-UHFFFAOYSA-N bromine monochloride Chemical compound BrCl CODNYICXDISAEA-UHFFFAOYSA-N 0.000 claims description 9
- 229910052717 sulfur Inorganic materials 0.000 claims description 9
- 239000011593 sulfur Substances 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 8
- 229910003902 SiCl 4 Inorganic materials 0.000 claims description 7
- 239000005864 Sulphur Substances 0.000 claims description 7
- 229910003691 SiBr Inorganic materials 0.000 claims description 6
- 238000000889 atomisation Methods 0.000 claims description 6
- 150000002505 iron Chemical class 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- 229910014265 BrCl Inorganic materials 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 4
- 150000002366 halogen compounds Chemical class 0.000 claims description 4
- 238000009938 salting Methods 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- XLUTWTYXYAQFCL-UHFFFAOYSA-J C(C(=O)[O-])(=O)[O-].[C+4].C(C(=O)[O-])(=O)[O-] Chemical compound C(C(=O)[O-])(=O)[O-].[C+4].C(C(=O)[O-])(=O)[O-] XLUTWTYXYAQFCL-UHFFFAOYSA-J 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 230000026030 halogenation Effects 0.000 claims description 3
- 238000005658 halogenation reaction Methods 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- 206010010144 Completed suicide Diseases 0.000 claims description 2
- 238000010248 power generation Methods 0.000 claims description 2
- 229910001069 Ti alloy Inorganic materials 0.000 claims 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- IXQWNVPHFNLUGD-UHFFFAOYSA-N iron titanium Chemical compound [Ti].[Fe] IXQWNVPHFNLUGD-UHFFFAOYSA-N 0.000 claims 2
- 229910000676 Si alloy Inorganic materials 0.000 claims 1
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 claims 1
- 125000001246 bromo group Chemical group Br* 0.000 claims 1
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 abstract description 3
- 230000002269 spontaneous effect Effects 0.000 abstract description 3
- 239000012267 brine Substances 0.000 abstract 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 30
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 30
- 238000007599 discharging Methods 0.000 description 13
- 239000002245 particle Substances 0.000 description 13
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 12
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 11
- 239000005431 greenhouse gas Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 238000009472 formulation Methods 0.000 description 10
- 150000004820 halides Chemical class 0.000 description 10
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 10
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 9
- 230000000630 rising effect Effects 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 8
- 235000011089 carbon dioxide Nutrition 0.000 description 8
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 8
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 230000009467 reduction Effects 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 7
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000005049 silicon tetrachloride Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 230000002349 favourable effect Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 229910000358 iron sulfate Inorganic materials 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 5
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 235000019253 formic acid Nutrition 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 229910021653 sulphate ion Inorganic materials 0.000 description 5
- FEONEKOZSGPOFN-UHFFFAOYSA-K tribromoiron Chemical compound Br[Fe](Br)Br FEONEKOZSGPOFN-UHFFFAOYSA-K 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 235000019504 cigarettes Nutrition 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- VFNGKCDDZUSWLR-UHFFFAOYSA-L disulfate(2-) Chemical compound [O-]S(=O)(=O)OS([O-])(=O)=O VFNGKCDDZUSWLR-UHFFFAOYSA-L 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 230000001976 improved effect Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000006303 photolysis reaction Methods 0.000 description 4
- 238000002310 reflectometry Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000004291 sulphur dioxide Substances 0.000 description 4
- 235000010269 sulphur dioxide Nutrition 0.000 description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000010079 rubber tapping Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- AIFMYMZGQVTROK-UHFFFAOYSA-N silicon tetrabromide Chemical compound Br[Si](Br)(Br)Br AIFMYMZGQVTROK-UHFFFAOYSA-N 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical class [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 239000003738 black carbon Substances 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 150000007942 carboxylates Chemical group 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000009841 combustion method Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- GFAUNYMRSKVDJL-UHFFFAOYSA-N formyl chloride Chemical compound ClC=O GFAUNYMRSKVDJL-UHFFFAOYSA-N 0.000 description 2
- JYGXADMDTFJGBT-VWUMJDOOSA-N hydrocortisone Chemical compound O=C1CC[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 JYGXADMDTFJGBT-VWUMJDOOSA-N 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
- 238000007539 photo-oxidation reaction Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- NHYCGSASNAIGLD-UHFFFAOYSA-N Chlorine monoxide Chemical compound Cl[O] NHYCGSASNAIGLD-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- DHNCFAWJNPJGHS-UHFFFAOYSA-J [C+4].[O-]C([O-])=O.[O-]C([O-])=O Chemical compound [C+4].[O-]C([O-])=O.[O-]C([O-])=O DHNCFAWJNPJGHS-UHFFFAOYSA-J 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- VZTDIZULWFCMLS-UHFFFAOYSA-N ammonium formate Chemical compound [NH4+].[O-]C=O VZTDIZULWFCMLS-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- UMEAURNTRYCPNR-UHFFFAOYSA-N azane;iron(2+) Chemical compound N.[Fe+2] UMEAURNTRYCPNR-UHFFFAOYSA-N 0.000 description 1
- AJGPQPPJQDDCDA-UHFFFAOYSA-N azanium;hydron;oxalate Chemical compound N.OC(=O)C(O)=O AJGPQPPJQDDCDA-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 229910000435 bromine oxide Inorganic materials 0.000 description 1
- 150000007516 brønsted-lowry acids Chemical class 0.000 description 1
- 150000007528 brønsted-lowry bases Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000004770 chalcogenides Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 229940062993 ferrous oxalate Drugs 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 150000004675 formic acid derivatives Chemical group 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002816 fuel additive Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000003864 humus Substances 0.000 description 1
- 229960000890 hydrocortisone Drugs 0.000 description 1
- JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Inorganic materials Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910001504 inorganic chloride Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical class Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- OWZIYWAUNZMLRT-UHFFFAOYSA-L iron(2+);oxalate Chemical compound [Fe+2].[O-]C(=O)C([O-])=O OWZIYWAUNZMLRT-UHFFFAOYSA-L 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 208000018883 loss of balance Diseases 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- NMJORVOYSJLJGU-UHFFFAOYSA-N methane clathrate Chemical compound C.C.C.C.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O NMJORVOYSJLJGU-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000003891 oxalate salts Chemical group 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- FMSOWMGJJIHFTQ-UHFFFAOYSA-N oxidobromine(.) Chemical compound Br[O] FMSOWMGJJIHFTQ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910021341 titanium silicide Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G15/00—Devices or methods for influencing weather conditions
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Atmospheric Sciences (AREA)
- Environmental Sciences (AREA)
- Treating Waste Gases (AREA)
- Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Sorption Type Refrigeration Machines (AREA)
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009004081.1 | 2009-01-02 | ||
| DE102009004081 | 2009-01-02 | ||
| DE102009006603.9 | 2009-01-29 | ||
| DE102009006603 | 2009-01-29 | ||
| DE102009057369 | 2009-12-09 | ||
| DE102009057369.0 | 2009-12-09 | ||
| DE102009059005.6 | 2009-12-17 | ||
| DE102009059005A DE102009059005A1 (de) | 2009-01-02 | 2009-12-17 | Klimakühlung mit eisenhaltigen Salzgemisch-Aerosolen |
| PCT/DE2010/000002 WO2010075856A2 (de) | 2009-01-02 | 2010-01-04 | Verfahren zur abkühlung der troposphäre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102340985A CN102340985A (zh) | 2012-02-01 |
| CN102340985B true CN102340985B (zh) | 2013-06-12 |
Family
ID=42174612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010800097399A Active CN102340985B (zh) | 2009-01-02 | 2010-01-04 | 冷却对流层的方法 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9456557B2 (enExample) |
| EP (1) | EP2381759B1 (enExample) |
| JP (1) | JP5439502B2 (enExample) |
| CN (1) | CN102340985B (enExample) |
| AU (1) | AU2010203265B2 (enExample) |
| BR (1) | BRPI1007391B1 (enExample) |
| CA (1) | CA2748680C (enExample) |
| DE (2) | DE102009059005A1 (enExample) |
| ES (1) | ES2474420T3 (enExample) |
| PL (1) | PL2381759T3 (enExample) |
| RU (1) | RU2511252C2 (enExample) |
| WO (1) | WO2010075856A2 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0921879D0 (en) * | 2009-12-15 | 2010-01-27 | Davidson Technology Ltd | Atmospheric delivery system |
| DE102011108433A1 (de) | 2011-07-26 | 2013-01-31 | Franz Dietrich Meyer-Oeste | Klimakühlung mittels dampfförmiger hydrophober Eisenverbindungen |
| DE102013007409A1 (de) | 2012-08-31 | 2014-03-20 | Franz Dietrich Meyer-Oeste | Den aktivierten Abbau der Treibhausgase Methan und Ozon in der Troposphäre auslösende Oberflächen |
| DE102017010697A1 (de) | 2017-08-06 | 2019-02-07 | Franz Dietrich Oeste | Verfahren zur Klimakühlung |
| DE102021117392A1 (de) | 2021-07-06 | 2023-01-12 | Atmospheric Methane Removal AG | Verwendung einer schwimmenden oder über oder auf Wasser fixierbaren Plattform zum Sprühen von Eisensalz-Aerosolen |
| DE102022001961A1 (de) | 2022-06-07 | 2023-12-07 | Franz Dietrich Oeste | Atmosphärischer Methanabbau mit Aqua-regia-Aerosol |
| WO2023051858A1 (de) * | 2021-10-01 | 2023-04-06 | Meyer Oeste Franz Dietrich | Photokatalytisches aerosol |
| DE102022001608A1 (de) | 2022-04-21 | 2023-10-26 | Franz Dietrich Oeste | Verfahren zur Beschleunigung des Treibhausgasabbaus Methan und Ozon in der Troposphäre |
| EP4547382A4 (en) * | 2021-12-16 | 2025-10-22 | Scott Christopher Bell | ATMOSPHERIC OXIDANT DISPERSION SYSTEMS AND METHODS FOR NET CONVERSION OF ATMOSPHERIC METHANE TO CARBON DIOXIDE |
| WO2024028346A1 (en) * | 2022-08-01 | 2024-02-08 | Franz Dietrich Oeste | A photocatalytic aerosol, its production and usage thereof |
| WO2024062112A1 (en) * | 2022-09-23 | 2024-03-28 | University Of Copenhagen | Method for quantification of methane removal |
| CN115863040A (zh) * | 2022-12-16 | 2023-03-28 | 浙江英洛华磁业有限公司 | 一种提高烧结NdFeB磁体性能的扩散方法 |
| WO2025083039A1 (en) | 2023-10-16 | 2025-04-24 | Franz Dietrich Oeste | Water making and cloud whitening |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2634407Y (zh) * | 2003-07-07 | 2004-08-18 | 王大荣 | 喷射式循环水冷却塔 |
| CN1617757A (zh) * | 2001-07-31 | 2005-05-18 | 欧内斯特·赖尔斯 | 添加了生命元素和/或保护物质的对流层容积元素 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA973655A (en) * | 1971-12-13 | 1975-09-02 | Minnesota Mining And Manufacturing Company | Moldable imaging composition |
| US5376346A (en) * | 1992-08-11 | 1994-12-27 | Powers; Richard M. | Method of reducing the destruction of ozone in the earth's stratosphere by the removal of chlorine, chlorine monoxide radicals, and catalytic aerosols |
| US5678783A (en) * | 1994-05-05 | 1997-10-21 | Wong; Alfred Y. | System and method for remediation of selected atmospheric conditions and system for high altitude telecommunications |
| RU2112357C1 (ru) * | 1995-06-07 | 1998-06-10 | Товарищество с ограниченной ответственностью "Простор Плюс" | Способ воздействия на атмосферные образования |
| DE10217932A1 (de) * | 2001-07-31 | 2003-02-13 | Franz Dietrich Oeste | Brennstoffe und Brennstoffzusätze zur nachhaltigen Verbesserung der menschlichen Existenzgrundlagen |
| CN101010261B (zh) * | 2004-10-08 | 2010-04-07 | 日本科技股份有限公司 | 中性电解水、中性电解水的制造方法及中性电解水的制造装置 |
| CA2629356A1 (en) * | 2005-11-10 | 2007-05-24 | Great Lakes Chemical Corporation | Compositions ,combustion prevention compositions, methods for preventing and/or extinguishing combustion, combustion prevention systems, and production processes |
| DE102007022685A1 (de) | 2006-07-13 | 2008-01-17 | Franz Dietrich Oeste | Verbrennungsabgase zur Klimakühlung |
| US20080257977A1 (en) * | 2007-04-18 | 2008-10-23 | Searete Llc, A Limited Liability Corporation Of The State Of Delaware | High altitude atmospheric alteration system and method |
| DE102009004281A1 (de) | 2008-01-21 | 2009-07-23 | Franz Dietrich Oeste | Klimakühlende Feststoff- und Gasverbrennung |
| CN101621714B (zh) | 2008-06-30 | 2013-06-12 | 华为技术有限公司 | 节点、数据处理系统和数据处理方法 |
-
2009
- 2009-12-17 DE DE102009059005A patent/DE102009059005A1/de not_active Withdrawn
-
2010
- 2010-01-04 PL PL10708885T patent/PL2381759T3/pl unknown
- 2010-01-04 RU RU2011128125/13A patent/RU2511252C2/ru active
- 2010-01-04 BR BRPI1007391-4A patent/BRPI1007391B1/pt not_active IP Right Cessation
- 2010-01-04 EP EP10708885.8A patent/EP2381759B1/de active Active
- 2010-01-04 ES ES10708885.8T patent/ES2474420T3/es active Active
- 2010-01-04 AU AU2010203265A patent/AU2010203265B2/en not_active Ceased
- 2010-01-04 CA CA2748680A patent/CA2748680C/en active Active
- 2010-01-04 WO PCT/DE2010/000002 patent/WO2010075856A2/de not_active Ceased
- 2010-01-04 CN CN2010800097399A patent/CN102340985B/zh active Active
- 2010-01-04 US US13/143,112 patent/US9456557B2/en active Active
- 2010-01-04 JP JP2011543976A patent/JP5439502B2/ja not_active Expired - Fee Related
- 2010-01-04 DE DE112010000104T patent/DE112010000104A5/de not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1617757A (zh) * | 2001-07-31 | 2005-05-18 | 欧内斯特·赖尔斯 | 添加了生命元素和/或保护物质的对流层容积元素 |
| CN2634407Y (zh) * | 2003-07-07 | 2004-08-18 | 王大荣 | 喷射式循环水冷却塔 |
Also Published As
| Publication number | Publication date |
|---|---|
| US9456557B2 (en) | 2016-10-04 |
| DE112010000104A5 (de) | 2012-06-06 |
| AU2010203265B2 (en) | 2013-11-21 |
| DE112010000104A8 (de) | 2013-06-13 |
| RU2511252C2 (ru) | 2014-04-10 |
| ES2474420T3 (es) | 2014-07-09 |
| JP5439502B2 (ja) | 2014-03-12 |
| JP2012514450A (ja) | 2012-06-28 |
| US20110284650A1 (en) | 2011-11-24 |
| DE102009059005A1 (de) | 2010-08-19 |
| WO2010075856A3 (de) | 2010-09-16 |
| WO2010075856A2 (de) | 2010-07-08 |
| PL2381759T3 (pl) | 2014-09-30 |
| CN102340985A (zh) | 2012-02-01 |
| EP2381759A2 (de) | 2011-11-02 |
| EP2381759B1 (de) | 2014-03-26 |
| BRPI1007391A2 (pt) | 2017-06-06 |
| CA2748680A1 (en) | 2010-07-08 |
| AU2010203265A1 (en) | 2011-07-28 |
| BRPI1007391B1 (pt) | 2018-04-10 |
| RU2011128125A (ru) | 2013-02-10 |
| CA2748680C (en) | 2017-03-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102340985B (zh) | 冷却对流层的方法 | |
| AU2007100157A4 (en) | Improved method of sequestering carbon dioxide as calcium carbonate | |
| US20250041840A1 (en) | Photocatalytic aerosol | |
| CN102762277A (zh) | 通过形成ii族碳酸盐和二氧化硅的二氧化碳固定 | |
| CN101992015A (zh) | 一种截存气体中二氧化碳的方法 | |
| US20100196244A1 (en) | Method and device for binding gaseous co2 to sea water for the flue gas treatment with sodium carbonate compounds | |
| US5499587A (en) | Sulfur-sorbent promoter for use in a process for the in-situ production of a sorbent-oxide aerosol used for removing effluents from a gaseous combustion stream | |
| WO2014194570A1 (zh) | 从窑法磷酸工艺的出窑烟气中水化吸磷及回收氟的方法 | |
| KR102362064B1 (ko) | 굴 패각을 이용한 바테라이트형 탄산칼슘 제조 방법 | |
| JP2024537093A (ja) | 捕捉性能を改善するためのガス状ｃｏ２捕捉システム、及びその使用方法 | |
| KR20200118601A (ko) | 탄산마그네슘의 성상 제어방법 및 탄산마그네슘의 제조방법 | |
| CN109422284A (zh) | 烟气脱硫与燃气脱氨污染物资源化以废治废的联合方法 | |
| Fu et al. | Al-doped Li4SiO4 for cyclic solar energy storage and CO2 capture: An experimental and DFT study | |
| WO2024028346A1 (en) | A photocatalytic aerosol, its production and usage thereof | |
| WO2025083039A1 (en) | Water making and cloud whitening | |
| KR102476720B1 (ko) | 굴껍질로부터 칼슘아세테이트 제설제의 제조방법 | |
| DE102013007409A1 (de) | Den aktivierten Abbau der Treibhausgase Methan und Ozon in der Troposphäre auslösende Oberflächen | |
| US11465902B2 (en) | Method for producing hydrogen gas | |
| Harrison et al. | Chemistry and climate change in the troposphere | |
| CN101406792A (zh) | 二氧化碳双重螯合系统及方法 | |
| WO2006135340A1 (en) | Method and apparatus for treating coal | |
| CN101705135A (zh) | 一种高效燃煤固硫剂及制备方法 | |
| Crutzen | Developments in tropospheric chemistry | |
| JPS6262890A (ja) | 海水を用いた人工石油の製造方法 | |
| CN108671725A (zh) | 一种碳酸氢钾热分解析出co2与高炉渣矿化耦合的方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |