CN102339792A - Manufacture method of semiconductor device - Google Patents

Manufacture method of semiconductor device Download PDF

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Publication number
CN102339792A
CN102339792A CN2011103357229A CN201110335722A CN102339792A CN 102339792 A CN102339792 A CN 102339792A CN 2011103357229 A CN2011103357229 A CN 2011103357229A CN 201110335722 A CN201110335722 A CN 201110335722A CN 102339792 A CN102339792 A CN 102339792A
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China
Prior art keywords
metal
redundant
metallic channel
dielectric layer
etching
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CN2011103357229A
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Chinese (zh)
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毛智彪
胡友存
戴韫青
王剑
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Shanghai Huali Microelectronics Corp
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Shanghai Huali Microelectronics Corp
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Priority to CN2011103357229A priority Critical patent/CN102339792A/en
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Abstract

The invention discloses a manufacture method of a semiconductor device. The method comprises the following steps: providing a semiconductor substrate which comprises a redundant metal area and a nonredundant metal area; forming a medium layer on the semiconductor substrate; reducing the medium layer on the nonredundant metal area; etching the medium layer to form a redundant metal groove and a metal conductor groove, wherein the depth of the redundant metal groove is less than that of the metal conductor groove; depositing a metal layer in the redundant metal groove, in the metal conductor groove and on the medium layer; and performing chemical mechanical grinding process until partial or whole metal layer in the redundant metal groove is removed. On the premise that a uniform grinding effect is achieved, the coupling capacitance in the metal layers and among the metal layers introduced by redundant metal filling is reduced, even completely eliminated.

Description

Manufacturing method of semiconductor device
Technical field
The present invention relates to integrated circuit and make field, particularly a kind of manufacturing method of semiconductor device.
Background technology
Along with the integrated level of semiconductor chip improves constantly, transistorized characteristic size is constantly dwindled thereupon.After entering into 130 nm technology node, receive the restriction of the high-ohmic of aluminium, copper-connection substitution of Al interconnection gradually becomes metal interconnected main flow.Because the dry etch process of copper is difficult for realizing that the manufacture method of copper interconnecting line can not obtain through etching sheet metal that as aluminum interconnecting the manufacture method of the copper interconnecting line that extensively adopts now is the embedding technique that is called Damascus technics.This Damascus technics comprises single Damascus technics of only making plain conductor and makes the dual damascene process of through hole (also claiming contact hole) and plain conductor simultaneously.Specifically; Single damascene structure (also claiming single inlay structure) only is to change the production method of single-layer metal lead into mosaic mode (dielectric layer etching+metal filled) by traditional mode (metal etch+dielectric layer is filled); Dual-damascene structure then is that through hole and plain conductor are combined, and so only needs metal filled step together.The common method of making dual-damascene structure generally has following several kinds: all-pass hole precedence method (Full VIA First), half via-first method (Partial VIA First), plain conductor precedence method (Full Trench First) and self aligned approach (Self-alignment method).
As shown in Figure 1, existing a kind of plain conductor manufacture craft comprises the steps: at first, metallization medium layer 110 at first on Semiconductor substrate 100; In dielectric layer 110, form metallic channel through photoetching and etching technics then; Depositing metal layers subsequently, said metal level are filled in the metallic channel and on said dielectric layer 110 surfaces and have also deposited metal; Then, carry out cmp (CMP) technology and remove the metal on the said dielectric layer 110, thereby in said metallic channel, processed plain conductor 140.
As stated, in Damascus technics, need utilize chemical mechanical milling tech, be embedded in the plain conductor 140 in the dielectric layer 110 with final formation.Yet,, therefore can cause the depression of not expecting (dishing) and corrode (erosion) phenomenon the selectivity of grinding because the rate that removes of metal and dielectric layer material is generally inequality.Depression occurs in metal often and goes down to the plane of contiguous dielectric layer or exceed more than the plane of contiguous dielectric layer, and corroding then is that the part of dielectric layer is thin excessively.Depression and erosion are subject to the structure of figure and the density influence of figure.Therefore, in order to reach uniform grinding effect, require the metallic pattern density on the Semiconductor substrate even as far as possible, and the metallic pattern density of product design usually can not satisfy the requirement of the cmp uniformity.At present, the method for solution is to fill the pattern density homogenizing that redundant metal pattern makes domain at the white space of domain, thereby also forms redundant metal (dummy metal) 150 when in dielectric layer 110, forming plain conductor 140, and is as shown in Figure 2.But,, but introduced in the extra metal level inevitably and the coupling capacitance of metal interlevel though redundant metal has improved the uniformity of pattern density.
Summary of the invention
The present invention provides a kind of manufacturing method of semiconductor device, to reduce or to have eliminated in the metal level of redundant metal filled introducing the coupling capacitance with metal interlevel fully.
For solving the problems of the technologies described above, the present invention provides a kind of manufacture method of semiconductor device, comprising:
Semiconductor substrate is provided, and said Semiconductor substrate comprises redundant metal area and nonredundancy metal area;
On said Semiconductor substrate, form dielectric layer;
Dielectric layer on the said nonredundancy metal area of attenuate;
The said dielectric layer of etching is to form redundant metallic channel and metallic channel, and the degree of depth of said redundant metallic channel is less than the degree of depth of said metallic channel;
Depositing metal layers in said redundant metallic channel and metallic channel and on the dielectric layer; And
Carry out chemical mechanical milling tech, part or all of metal level in removing said redundant metallic channel.
Optional; In the manufacture method of described semiconductor device; The said dielectric layer of etching comprises with the step that forms redundant metallic channel and metallic channel: the dielectric layer on while said redundant metal area of etching and the nonredundancy metal area, and to form redundant metallic channel and metallic channel simultaneously.
Optional, in the manufacture method of described semiconductor device, the said dielectric layer of etching comprises with the step that forms redundant metallic channel and metallic channel: the dielectric layer on the said nonredundancy metal area of etching forms through hole; Dielectric layer on while said redundant metal area of etching and the nonredundancy metal area is to form redundant metallic channel and metallic channel simultaneously.
Optional, in the manufacture method of described semiconductor device, the said dielectric layer of etching comprises with the step that forms redundant metallic channel and metallic channel: on said dielectric layer, form hard mask layer; The said hard mask layer of etching forms the hard mask layer groove and removes the hard mask layer on the said redundant metal area; Dielectric layer on the said nonredundancy metal area of etching forms through hole with the position at said hard mask layer groove; Dielectric layer on while said redundant metal area of etching and the nonredundancy metal area is to form redundant metallic channel and metallic channel simultaneously.
The present invention is after metallization medium layer; Dielectric layer on elder generation's attenuate nonredundancy metal area; And then the said dielectric layer of etching is to form redundant metallic channel and metallic channel; Make the degree of depth of said redundant metallic channel less than the degree of depth of said metallic channel, and utilize chemical mechanical milling tech to remove all or part of metal level in the said redundant metallic channel, thereby in said metallic channel, form plain conductor; Reaching under the prerequisite of uniform grinding effect, reducing or eliminated in the metal level of redundant metal filled introducing the coupling capacitance with metal interlevel fully.
Description of drawings
Fig. 1 is the structural representation of existing a kind of semiconductor device;
Fig. 2 is the structural representation of existing another kind of semiconductor device;
Fig. 3 is the schematic flow sheet of the manufacture method of semiconductor device of the present invention;
Fig. 4 A~4E is the cross-sectional view of the corresponding device of each step in the manufacture method of semiconductor device of the embodiment of the invention one;
Fig. 5 A~5F is the cross-sectional view of the corresponding device of each step in the manufacture method of semiconductor device of the embodiment of the invention two;
Fig. 6 A~6H is the cross-sectional view of the corresponding device of each step in the manufacture method of semiconductor device of the embodiment of the invention three.
Embodiment
Mention that in background technology though redundant metal has improved the uniformity of pattern density, but introduced in the extra metal level and the coupling capacitance of metal interlevel, electric capacity can be calculated by formula:
C = ϵ 0 ϵ r S d
Wherein, ε 0Be permittivity of vacuum; ε rBe the medium dielectric constant; S is relative metallic area; The intermetallic distance that d is.This shows that the relative area that reduces metal can reduce electric capacity with increase intermetallic distance.That is to say that the volume that reduces redundant metal can reduce owing to adding the extra intermetallic coupling capacitance that redundant metal is introduced.For this reason; The present invention is after metallization medium layer; Dielectric layer on elder generation's attenuate nonredundancy metal area, and then the said dielectric layer of etching to be to form redundant metallic channel and metallic channel, the degree of depth of said redundant metallic channel is less than the degree of depth of said metallic channel; And utilize chemical mechanical milling tech to remove all or part of metal level in the said redundant metallic channel; Thereby in said metallic channel, form plain conductor, the present invention is reaching under the prerequisite of uniform grinding effect, reduces or has eliminated in the metal level of redundant metal filled introducing the coupling capacitance with metal interlevel fully.
Please refer to Fig. 3, it is the schematic flow sheet of the manufacture method of semiconductor device of the present invention.As shown in Figure 3, the manufacture method of said semiconductor device comprises the steps:
Step S310: Semiconductor substrate is provided, and said Semiconductor substrate comprises redundant metal area and nonredundancy metal area;
Step S320: on said Semiconductor substrate, form dielectric layer;
Step S330: the dielectric layer on the said nonredundancy metal area of attenuate;
Step S340: the said dielectric layer of etching is to form redundant metallic channel and metallic channel, and the degree of depth of said redundant metallic channel is less than the degree of depth of said metallic channel;
Step S350: depositing metal layers in said redundant metallic channel and metallic channel and on the dielectric layer;
Step S360: carry out chemical mechanical milling tech, part or all of metal level in removing said redundant metallic channel is to form plain conductor in said metallic channel.
Manufacturing method of semiconductor device below in conjunction with generalized section proposes the present invention is respectively done further to specify.
Embodiment one
Shown in Fig. 4 A, at first, Semiconductor substrate 400 is provided, this Semiconductor substrate 400 comprises redundant metal area 402 and nonredundancy metal area 401, the semiconductor substrate region outside the said redundant metal area 402 is nonredundancy metal area 401.Wherein, be formed with the metal line (not shown) in the said Semiconductor substrate 400.Because the present invention relates generally to the manufacture craft of metal damascene structure, thus will not introduce the process that in Semiconductor substrate 400, forms metal line, but those skilled in the art are still this and know.
Continue with reference to figure 4A, then, on Semiconductor substrate 400, form dielectric layer 410.Wherein, said dielectric layer 410 is preferably low-k (K) dielectric layer, postpones with the resistance capacitance that reduces its parasitic capacitance and metallic copper, satisfies the requirement of conduction fast.Preferable; It is black diamond (black diamond that said dielectric layer 410 adopts the trade mark of Material Used (Applied Materials) company; BD) silicon oxide carbide; Perhaps adopt the Coral material of Novellus company, perhaps adopt again and utilize spin coating process to make the Silk advanced low-k materials of Dow Corning Corporation etc.
In other embodiments of the invention; Before forming dielectric layer 410 on the said Semiconductor substrate 400; Also can form etching stop layer (not shown) earlier; Said etching stop layer can be used for preventing metal diffusing in the metal line in dielectric layer 410, and said in addition etching stop layer can prevent that also the metal line in the Semiconductor substrate 400 is etched in follow-up etching process of carrying out.The material of said etching stop layer for example is a silicon nitride, and the dielectric layer of itself and follow-up formation has good adhesive force property.
Shown in Fig. 4 B; Then, utilize photoetching process on said dielectric layer 410, to form first mask layer, said first mask layer exposes the dielectric layer on the nonredundancy metal area 401; Be mask with said first mask layer subsequently; The said dielectric layer 410 of etching is with the dielectric layer on the attenuate nonredundancy metal area 401, and then removes said first mask layer, and the mode of said first mask layer dry method capable of using or wet method is removed.After accomplishing this step, the thickness of dielectric layers H2 on the said redundant metal area 402 is greater than the thickness of dielectric layers H1 on the said nonredundancy metal area 401.
Shown in Fig. 4 C;, utilize photoetching process on dielectric layer 410 form second mask layer with metallic channel pattern and redundant metallic channel pattern, and be mask with said second mask layer thereafter; The said dielectric layer 410 of etching forms metallic channel 412 and redundant metallic channel 411; Because the dielectric layer on the said nonredundancy metal area 401 has been thinned, although therefore be etching simultaneously in this step, the degree of depth of the redundant metallic channel 411 of final formation will be less than the degree of depth of metallic channel 412; Said metallic channel 412 is the thickness that dielectric layer is thinned with the difference of redundant metallic channel 411 degree of depth (highly), removes said second mask layer then.Wherein, the height of said redundant metallic channel 412 can change according to concrete technology accordingly, and the thickness that the dielectric layer on the said nonredundancy metal area 401 is thinned can confirm that also the present invention also will not limit this according to concrete technology.
Shown in Fig. 4 D, subsequently, depositing metal layers 420 in said redundant metallic channel 411 and metallic channel 412, because the characteristic of depositing operation also can deposit metal on this process medium layer 410, the material of wherein said metal level 420 is a copper.
Shown in Fig. 4 E, last, carry out chemical mechanical milling tech, part or all of metal level in removing said redundant metallic channel 411 is to form plain conductor 422 in said metallic channel 412.Owing in redundant metallic channel 411, formed redundant metal in the abovementioned steps; Therefore this grinding steps still can reach uniform grinding effect; Therefore all or part of metal of having removed in the redundant metallic channel 411 of this step simultaneously reduces even has eliminated in the metal level of redundant metal filled introducing the coupling capacitance with metal interlevel fully.Preferable, shown in Fig. 4 E, the metal level of said redundant metallic channel 411 is all ground away, thereby has eliminated in the metal level of redundant metal filled introducing the coupling capacitance with metal interlevel fully.
Embodiment two
Shown in Fig. 5 A, at first, Semiconductor substrate 500 is provided, this Semiconductor substrate 500 comprises redundant metal area 502 and nonredundancy metal area 501, on Semiconductor substrate 500, forms dielectric layer 510 subsequently.
Shown in Fig. 5 B, then, utilize the thickness of dielectric layers on the said nonredundancy metal area 501 of photoetching and etching technics attenuate, accomplish this step after, the thickness of dielectric layers on the said redundant metal area 502 is greater than the thickness of dielectric layers on the said nonredundancy metal area 501.
Shown in Fig. 5 C; Utilize photoetching process on dielectric layer 510, to form first mask layer with through-hole pattern; And be mask with said first mask layer; Dielectric layer on the said nonredundancy metal area 501 of etching, thus through hole 513 on the nonredundancy metal area, formed, and then remove said first mask layer.
Shown in Fig. 5 D; Subsequently; On said dielectric layer 510, form second mask layer, and be mask, simultaneously the dielectric layer on said redundant metal area of etching and the nonredundancy metal area with said second mask layer with metallic channel pattern and redundant metallic channel pattern; Forming redundant metallic channel 511, and form metallic channel 512 at through hole 513 correspondence positions.
Shown in Fig. 5 E, subsequently, depositing metal layers 520 in said redundant metallic channel 511 and metallic channel 512 is because the characteristic of depositing operation also can deposit metal on this process medium layer 510.
Shown in Fig. 5 F; At last; Carry out chemical mechanical milling tech, all or part of metal level in removing said redundant metallic channel 512 is to form plain conductor 522 in said metallic channel 511 and through hole 513; Owing in redundant metallic channel 511, formed redundant metal in the abovementioned steps; Therefore still can reach uniform grinding effect, all or part of again metal of having removed in the redundant metallic channel 511 in this step simultaneously can reduce or eliminates in the metal level of redundant metal filled introducing the coupling capacitance with metal interlevel fully.
Embodiment three
Shown in Fig. 6 A, at first, Semiconductor substrate 600 is provided, this Semiconductor substrate 600 comprises redundant metal area 602 and nonredundancy metal area 601, on Semiconductor substrate 600, forms dielectric layer 610 subsequently.
Shown in Fig. 6 B, then, utilize the dielectric layer on the said nonredundancy metal area 601 of photoetching and etching technics attenuate, accomplish this step after, the thickness of dielectric layers on the said redundant metal area 602 is greater than the thickness of dielectric layers on the said nonredundancy metal area 601.
Shown in Fig. 6 C, then, on dielectric layer 610, form hard mask layer 630, preferably, have preferable etching selection ratio at hard mask layer described in the subsequent etching technology 630 and dielectric layer 610.
Shown in Fig. 6 D, subsequently, the said hard mask layer 630 of etching forms hard mask layer groove 631, and removes the hard mask layer on the said redundant metal area 602.
Shown in Fig. 6 E, thereafter, the said dielectric layer 610 of etching forms through hole 613 with the position at hard mask layer groove 631, and said hard mask layer groove 631 has played the effect of autoregistration (Self-alignment).
Shown in Fig. 6 F, then, etching dielectric layer 610 forms metallic channel 612 with the position at through hole 613, and on redundant metal area, forms redundant metallic channel 611, and the degree of depth of said redundant metallic channel 611 is less than the degree of depth of metallic channel 612.
Shown in Fig. 6 G, subsequently, depositing metal layers 620 in redundant metallic channel 611 and metallic channel 612 is because the characteristic of depositing operation also can deposit metal on this process medium layer 610.
Shown in Fig. 6 H; At last; Carry out chemical mechanical milling tech, all or part of metal level in removing said redundant metallic channel 612 is to form plain conductor 622 in said metallic channel 611 and through hole 613; Owing in redundant metallic channel 611, formed redundant metal in the abovementioned steps; Therefore still can obtain uniform grinding effect, therefore all or part of again metal of having removed in the redundant metallic channel in this step simultaneously reduces even has eliminated in the metal level of redundant metal filled introducing the coupling capacitance with metal interlevel fully.
Need to prove that each embodiment adopts the mode of going forward one by one to describe in this specification, each embodiment stresses all is the difference with other embodiment, the reference mutually of relevant part.And accompanying drawing all adopts the form of simplifying very much and all uses non-ratio accurately, only is used for the purpose of convenience, each embodiment of aid illustration the present invention lucidly.
In addition; Although be that example has specified the present invention with the dual damascene metal interconnect structure (referring to embodiment two) of single Damascus metal interconnect structure (referring to embodiment one), through hole elder generation etching and the dual damascene metal interconnect structure (referring to embodiment three) of the first etching of the hard mask groove of autoregistration formula respectively below, those skilled in the art can also carry out various changes and modification and not break away from the spirit and scope of the present invention the present invention.Like this, belong within the scope of claim of the present invention and equivalent technologies thereof if of the present invention these are revised with modification, then the present invention also is intended to comprise these changes and modification interior.

Claims (4)

1. the manufacture method of a semiconductor device comprises:
Semiconductor substrate is provided, and said Semiconductor substrate comprises redundant metal area and nonredundancy metal area;
On said Semiconductor substrate, form dielectric layer;
Dielectric layer on the said nonredundancy metal area of attenuate;
The said dielectric layer of etching is to form redundant metallic channel and metallic channel, and the degree of depth of said redundant metallic channel is less than the degree of depth of said metallic channel;
Depositing metal layers in said redundant metallic channel and metallic channel and on the dielectric layer; And
Carry out chemical mechanical milling tech, part or all of metal level in removing said redundant metallic channel.
2. the manufacture method of semiconductor device as claimed in claim 1 is characterized in that, the said dielectric layer of etching comprises with the step that forms redundant metallic channel and metallic channel:
Dielectric layer on while said redundant metal area of etching and the nonredundancy metal area is to form redundant metallic channel and metallic channel simultaneously.
3. the manufacture method of semiconductor device as claimed in claim 1 is characterized in that, the said dielectric layer of etching comprises with the step that forms redundant metallic channel and metallic channel:
Dielectric layer on the said nonredundancy metal area of etching forms through hole;
Dielectric layer on while said redundant metal area of etching and the nonredundancy metal area is to form redundant metallic channel and metallic channel simultaneously.
4. the manufacture method of semiconductor device as claimed in claim 1 is characterized in that, the said dielectric layer of etching comprises with the step that forms redundant metallic channel and metallic channel:
On said dielectric layer, form hard mask layer;
The said hard mask layer of etching forms the hard mask layer groove and removes the hard mask layer on the said redundant metal area;
Dielectric layer on the said nonredundancy metal area of etching forms through hole with the position at said hard mask layer groove;
Dielectric layer on while said redundant metal area of etching and the nonredundancy metal area is to form redundant metallic channel and metallic channel simultaneously.
CN2011103357229A 2011-10-29 2011-10-29 Manufacture method of semiconductor device Pending CN102339792A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105097774A (en) * 2014-05-14 2015-11-25 中芯国际集成电路制造(上海)有限公司 Chip wafer and manufacturing method thereof
CN113517310A (en) * 2021-04-02 2021-10-19 长江先进存储产业创新中心有限责任公司 Semiconductor device and manufacturing method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6849549B1 (en) * 2003-12-04 2005-02-01 Taiwan Semiconductor Manufacturing Co., Ltd Method for forming dummy structures for improved CMP and reduced capacitance
US7470630B1 (en) * 2005-04-14 2008-12-30 Altera Corporation Approach to reduce parasitic capacitance from dummy fill
CN101692437A (en) * 2009-10-15 2010-04-07 复旦大学 Method for selectively depositing diffusion barrier for copper interconnection

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6849549B1 (en) * 2003-12-04 2005-02-01 Taiwan Semiconductor Manufacturing Co., Ltd Method for forming dummy structures for improved CMP and reduced capacitance
US7470630B1 (en) * 2005-04-14 2008-12-30 Altera Corporation Approach to reduce parasitic capacitance from dummy fill
CN101692437A (en) * 2009-10-15 2010-04-07 复旦大学 Method for selectively depositing diffusion barrier for copper interconnection

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105097774A (en) * 2014-05-14 2015-11-25 中芯国际集成电路制造(上海)有限公司 Chip wafer and manufacturing method thereof
CN113517310A (en) * 2021-04-02 2021-10-19 长江先进存储产业创新中心有限责任公司 Semiconductor device and manufacturing method thereof
CN113517310B (en) * 2021-04-02 2024-06-04 长江先进存储产业创新中心有限责任公司 Semiconductor device and manufacturing method thereof

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Application publication date: 20120201