CN102324284A - A kind of method of manufactured copper alloy cable - Google Patents
A kind of method of manufactured copper alloy cable Download PDFInfo
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- CN102324284A CN102324284A CN201110270207A CN201110270207A CN102324284A CN 102324284 A CN102324284 A CN 102324284A CN 201110270207 A CN201110270207 A CN 201110270207A CN 201110270207 A CN201110270207 A CN 201110270207A CN 102324284 A CN102324284 A CN 102324284A
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- Prior art keywords
- copper alloy
- alloy cable
- manufactured copper
- insulation
- casting
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- 238000000034 method Methods 0.000 title claims abstract description 24
- 229910000881 Cu alloy Inorganic materials 0.000 title claims abstract description 20
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 10
- 238000005266 casting Methods 0.000 claims abstract description 10
- 238000009413 insulation Methods 0.000 claims abstract description 10
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 6
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000032683 aging Effects 0.000 claims abstract description 5
- 238000009749 continuous casting Methods 0.000 claims abstract description 5
- 235000013312 flour Nutrition 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 5
- 238000010791 quenching Methods 0.000 claims abstract description 5
- 230000000171 quenching effect Effects 0.000 claims abstract description 5
- 238000010079 rubber tapping Methods 0.000 claims abstract description 5
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 5
- 239000002893 slag Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 238000010792 warming Methods 0.000 claims abstract description 5
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 5
- 239000000428 dust Substances 0.000 claims abstract description 3
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000035939 shock Effects 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000005275 alloying Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910000678 Elektron (alloy) Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000001458 anti-acid effect Effects 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
The invention discloses a kind of method of manufactured copper alloy cable, (1) is melted cathode copper with Efco-Northrup furnace and is warming up to 1300～1350 ℃, adds metal Ni, Mo, Zn, covers 150-180 order silica flour and carbon dust simultaneously, is incubated 15-18 minute; (2) pull slag out after, add Ti, W, Mg, the back tapping casting that stirs, and the control furnace temperature is at 1320～1370 ℃, the semi continuous casting is adopted in (3), uses nitrogen protection during casting; (4) under 100-120 ℃, be drawn into wire rod, then wire rod be heated to 3-4 hour oil of quenching of 700-820 ℃ of insulation, Ageing Treatment was carried out in insulation in 1-1.5 hour under 500-520 ℃ of temperature again; Gained cable wire technical characteristic is: HRB >=75, IACS >=75%.Therefore the performance of this cable can have irreplaceable effect in national defence and other key areas, and the mutual allotment through mentioned component has improved conductivity, resistance to acids and bases and under the situation of temperature shock, keeping good toughness basically.
Description
Technical field
The present invention relates to the manufacturing approach of cable, especially relate to a kind of method of manufactured copper alloy cable.
Background technology
Copper and alloy thereof are because of having excellent conducting performance, heat conductivility, anti-fatigue performance, chemical stability and intensity and being easy to characteristics such as manufacturing; Had application widely in industries such as electric power, machinery, electronics, traffic and the energy, become the important electron metal material.Along with fast development economic and science and technology, to used copper alloy with high strength and high conductivity demands for higher performance in field such as contact Wire for High-Speed Electric Railway, extensive integrated circuit lead frame and electrode materials.Yet, owing to the physical characteristic of copper alloy self causes being difficult to take into account simultaneously its intensity and conductivity, final acquisition intensity and all good copper alloys of conductivity of being difficult to.
At present, mainly solve the contradiction of copper alloy high strength and high conductivity through alloying and composite material method.Though the composite material method can obtain the superhigh intensity copper alloy, its complicated process of preparation is difficult for large-scale production; Alloying preparation technology is simple than the former, is widely used at present, but still has some problems, costs an arm and a leg like other composition that is added, and antiacid alkali resistant ability is lower, non-refractory, and conductance still can not satisfy the demands in some field.
Summary of the invention
To the deficiency of prior art, one of the object of the invention is to provide a kind of copper alloy cable that overcomes above-mentioned prior art defective.
The method of the prepared a kind of manufactured copper alloy cable of the present invention is to comprise the element of following weight percentage:
Ni 0.98-1.14％
Mg 0.2-0.39％
Ti 0.034-0.097％
W 0-3.47％
Zn 1.2-2.6％
Mo 0.047-0.27％
Surplus is copper and unavoidable impurities,
Concrete grammar is:
(1) with Efco-Northrup furnace with cathode copper fusing and be warming up to 1300～1350 ℃, add metal Ni, Mo, Zn, cover 150-180 order silica flour and carbon dust simultaneously, be incubated 15-18 minute;
(2) pull slag out after, add Ti, W, Mg, the back tapping casting that stirs, and the control furnace temperature is at 1320～1370 ℃,
(3) adopt the semi continuous casting, use nitrogen protection during casting;
(4) under 100-120 ℃, be drawn into wire rod, then wire rod be heated to 3-4 hour oil of quenching of 700-820 ℃ of insulation, Ageing Treatment was carried out in insulation in 1-1.5 hour under 500-520 ℃ of temperature again; Gained cable wire technical characteristic is: HRB >=75, IACS >=75%.
The preferred W 1.28-3.02% of said alloy.
Preferred Mo 0.113-0.207%.
Preferred Ti 0.054-0.078%.
Preferably: Mg
2The Mo phase content is no more than 2%.
Outstanding advantage of the present invention is the design of this alloying component, makes it be applicable to the technical problem that is solved, and it is the proportioning of each content particularly; Outstanding more is that in order to improve above-mentioned advantage, that more superior is Mg
2The Mo phase content is no more than 2%, because find Mg after deliberation
2Mo has influenced conductance mutually significantly, intercepts effective transmission of electronics, and content surpasses 2% simultaneously, causes segregation easily, and local concentration is too high, is unfavorable for improving tensile strength.
Embodiment
Embodiment one
A kind of method of manufactured copper alloy cable is to comprise the element of following weight percentage:
Ni 0.98％
Mg 0.2％
Ti 0.034％
Zn 1.2％
Mo 0.047％
Surplus is copper and unavoidable impurities, and concrete grammar is:
(1) with Efco-Northrup furnace with cathode copper fusing and be warming up to 1350 ℃, add metal Ni, Mo, Zn, cover 180 order silica flour and carbon dusts simultaneously, be incubated 18 minutes;
(2) pull slag out after, add Ti, W, Mg, the back tapping casting that stirs, and the control furnace temperature is at 1370 ℃,
(3) adopt the semi continuous casting, use nitrogen protection during casting;
(4) under 120 ℃, be drawn into wire rod, then wire rod be heated to 4 hours oil of quenching of 820 ℃ of insulations, Ageing Treatment was carried out in insulation in 1.5 hours under 520 ℃ of temperature again; Gained cable wire technical characteristic is: HRB=75, IACS=75%.
Embodiment two
A kind of method of manufactured copper alloy cable is to comprise the element of following weight percentage:
Ni 1.14％
Mg 0.39％
Ti 0.097％
W 3.47％
Zn?2.6％
Mo?0.27％
Surplus is copper and unavoidable impurities, and concrete grammar is:
(1) with Efco-Northrup furnace with cathode copper fusing and be warming up to 1300 ℃, add metal Ni, Mo, Zn, cover 150 order silica flour and carbon dusts simultaneously, be incubated 15 minutes;
(2) pull slag out after, add Ti, W, Mg, the back tapping casting that stirs, and the control furnace temperature is at 1320 ℃,
(3) adopt the semi continuous casting, use nitrogen protection during casting;
(4) under 100 ℃, be drawn into wire rod, then wire rod be heated to 3-4 hour oil of quenching of 700 ℃ of insulations, Ageing Treatment was carried out in insulation in 1 hour under 500 ℃ of temperature again; Gained cable wire technical characteristic is: HRB=80, IACS=76.2%.
Embodiment three
Ni 1.04％
Mg 0.28％
Ti 0.063％
W 2.23％
Zn 1.92％
Mo 0.19％
Surplus is copper and unavoidable impurities, and method is with embodiment 1.
Embodiment four
Ni 1.09％
Mg 0.31％
Ti 0.057％
W 1.84％
Zn?2.03％
Mo?0.147％
Surplus is copper and unavoidable impurities, and method is with embodiment 2.
Through the copper alloy cable detection to above embodiment 1-4, Mg
2The Mo phase content is respectively 1.7%, 1.9%, 1.6%, 2.0%, and tensile strength is about 283Mpa, at 20%H
2SO
4Solution in the 35%NaOH solution, soaks 48h and does not have corrosion, oxidation, and-50 ℃ to 800 ℃, tensile strength does not have significant change.
Applicant's statement; The present invention explains detailed process equipment of the present invention and technological process through the foregoing description; But the present invention is not limited to above-mentioned detailed process equipment and technological process, does not mean that promptly the present invention must rely on above-mentioned detailed process equipment and technological process could be implemented.The person of ordinary skill in the field should understand, and to any improvement of the present invention, to the interpolation of the equivalence replacement of each raw material of product of the present invention and auxiliary element, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (6)
1. the method for a manufactured copper alloy cable: said alloy comprises the element of following weight percentage:
Ni 0.98-1.14%, Mg 0.2-0.39%, Ti 0.034-0.097%, W 0.01-3.47%, Zn1.2-2.6%, Mo 0.047-0.27%, surplus is copper and unavoidable impurities; It is characterized in that concrete grammar is:
(1) with Efco-Northrup furnace with cathode copper fusing and be warming up to 1300～1350 ℃, add metal Ni, Mo, Zn, cover 150-180 order silica flour and carbon dust simultaneously, be incubated 15-18 minute;
(2) pull slag out after, add Ti, W, Mg, the back tapping casting that stirs, and the control furnace temperature is at 1320～1370 ℃,
(3) adopt the semi continuous casting, use nitrogen protection during casting;
(4) under 100-120 ℃, be drawn into wire rod, then wire rod be heated to 3-4 hour oil of quenching of 700-820 ℃ of insulation, Ageing Treatment was carried out in insulation in 1-1.5 hour under 500-520 ℃ of temperature again; Gained cable wire technical characteristic is: HRB >=75, IACS >=75%.
2. the method for a kind of manufactured copper alloy cable according to claim 1 is characterized in that:
W?1.28-3.02％。
3. the method for a kind of manufactured copper alloy cable according to claim 1 is characterized in that:
Mo?0.113-0.207％。
4. the method for a kind of manufactured copper alloy cable according to claim 1 is characterized in that:
Ti?0.054-0.078％。
5. the method for a kind of manufactured copper alloy cable according to claim 1 is characterized in that:
Ni?1.02-1.11％。
6. according to the method for the arbitrary described a kind of manufactured copper alloy cable of claim 1-5, it is characterized in that: Mg
2The Mo phase content is no more than 2%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110270207A CN102324284A (en) | 2011-09-13 | 2011-09-13 | A kind of method of manufactured copper alloy cable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110270207A CN102324284A (en) | 2011-09-13 | 2011-09-13 | A kind of method of manufactured copper alloy cable |
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| Publication Number | Publication Date |
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| CN102324284A true CN102324284A (en) | 2012-01-18 |
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| CN201110270207A Pending CN102324284A (en) | 2011-09-13 | 2011-09-13 | A kind of method of manufactured copper alloy cable |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925724A (en) * | 2012-10-30 | 2013-02-13 | 海门市海菱碳业有限公司 | Preparation method of copper-zinc alloy |
| CN107217170A (en) * | 2017-05-27 | 2017-09-29 | 京仪股份有限公司 | A kind of high temperature resistant gold copper cable |
| CN109285617A (en) * | 2018-10-29 | 2019-01-29 | 宁波来和圣诞礼品有限公司 | A kind of conducting wire for LED light |
| CN110634588A (en) * | 2019-11-05 | 2019-12-31 | 郑家法 | Anti-heat-cracking copper alloy conductive material for cable and preparation method thereof |
-
2011
- 2011-09-13 CN CN201110270207A patent/CN102324284A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925724A (en) * | 2012-10-30 | 2013-02-13 | 海门市海菱碳业有限公司 | Preparation method of copper-zinc alloy |
| CN107217170A (en) * | 2017-05-27 | 2017-09-29 | 京仪股份有限公司 | A kind of high temperature resistant gold copper cable |
| CN107217170B (en) * | 2017-05-27 | 2019-08-13 | 京仪股份有限公司 | A kind of high temperature resistant gold copper cable |
| CN109285617A (en) * | 2018-10-29 | 2019-01-29 | 宁波来和圣诞礼品有限公司 | A kind of conducting wire for LED light |
| CN110634588A (en) * | 2019-11-05 | 2019-12-31 | 郑家法 | Anti-heat-cracking copper alloy conductive material for cable and preparation method thereof |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120118 |