CN107217170B - A kind of high temperature resistant gold copper cable - Google Patents

A kind of high temperature resistant gold copper cable Download PDF

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Publication number
CN107217170B
CN107217170B CN201710391048.3A CN201710391048A CN107217170B CN 107217170 B CN107217170 B CN 107217170B CN 201710391048 A CN201710391048 A CN 201710391048A CN 107217170 B CN107217170 B CN 107217170B
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alloy
gold copper
high temperature
copper cable
temperature resistant
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CN107217170A (en
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张银久
张铜俊
张铜吉
徐国富
於文武
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Jingyi Ltd By Share Ltd
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Jingyi Ltd By Share Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H01B1/026Alloys based on copper
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Conductive Materials (AREA)
  • Insulated Conductors (AREA)

Abstract

The present invention provides a kind of high temperature resistant gold copper cables, are related to field of cables;Cable core is made of the element of following weight percent: Au 0.16-0.29%, Cr 0.22-0.35%, Co 0.18-0.26%, W 0.25-0.32%, Mo 0.12-0.16%, Zn 0.06-0.11%, Pt 0.13-0.15%, Rh 0.16-0.21%, remaining is Cu and inevitable impurity;In preparation method, raw material is mixed first, is suppressed, is made alloy preform, the binding force between alloy can be enhanced, while advantageously reducing subsequent melt temperature, melting speed is accelerated, keeps alloying component distribution more uniform.

Description

A kind of high temperature resistant gold copper cable
Technical field
The present invention relates to field of cables, and in particular to a kind of high temperature resistant gold copper cable.
Background technique
Copper and its alloy because having good conductive property, heating conduction, anti-fatigue performance, chemical stability and intensity and The features such as easily fabricated, has had a wide range of applications in industries such as electric power, machinery, electronics, traffic and the energy, has become important electricity Sub- metal material.With the economic fast development with science and technology, to contact Wire for High-Speed Electric Railway, large-scale integrated More stringent requirements are proposed for copper alloy with high strength and high conductivity performance used in the fields such as wire feed throughs frame and electrode material.However, by In copper alloy itself physical characteristic and cause to be difficult to combine its heat-resisting quantity and electric conductivity, be finally difficult obtain high temperature resistant The all good copper alloy with electric conductivity.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of high temperature resistant gold copper cables, so that alloy cable exists While with high conductivity, there is preferable heat-resisting quantity.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs:
A kind of high temperature resistant gold copper cable, cable core are made of the element of following weight percent: Au 0.16- 0.29%, Cr 0.22-0.35%, Co 0.18-0.26%, W 0.25-0.32%, Mo 0.12-0.16%, Zn 0.06- 0.11%, Pt 0.13-0.15%, Rh 0.16-0.21%, remaining is Cu and inevitable impurity.
Preferably, cable core is made of the element of following weight percent: Au 0.21%, Cr 0.25%, Co 0.22%, W 0.28%, Mo 0.14%, Zn 0.08%, Pt 0.13%, Rh 0.21%, remaining is for copper and inevitably Impurity.
A kind of preparation method of high temperature resistant gold copper cable, comprising the following steps: (1) weigh other originals in addition to Cu Material is put into high speed ball mill and is uniformly mixed, mixture is pressed into bulk with molding machine;(2) by bulk made from step (1) Prealloy puts into heating melting in vacuum drying oven, and heat preservation obtains prealloy liquid;(3) Cu is added in prealloy liquid, heating is molten Melt, alloy mixed liquor is made;(4) alloy mixed liquor is poured into mold, alloy pig is made;(5) by alloy pig in 680-720 8-10h is kept the temperature under the conditions of DEG C, carries out cold rolling after natural cooling;(6) alloy after cold rolling is kept the temperature into 4-5h at 500-550 DEG C, Gold copper cable core is made;(7) gold copper cable is made in cable core winding, package insulation sleeve.
Preferably, vacuum drying oven heating temperature is 1450-1500 DEG C in the step (2), soaking time 55-60min.
(3) beneficial effect
The present invention provides a kind of high temperature resistant gold copper cables, by the way that Au, W, Pt, Rh element are added in the alloy, both It ensure that the electric conductivity of alloy, and make alloy that there is high temperature resistance, the addition of Cr and Co guarantee that alloy still has at high temperature There is certain intensity, avoids leading to strength reduction because of high temperature;In preparation method, raw material is mixed first, suppresses, makes alloy It is preforming, the binding force between alloy can be enhanced, while advantageously reducing subsequent melt temperature, accelerates melting speed, make alloy Component distributing is more uniform.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention, Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is the present invention one Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making Every other embodiment obtained, shall fall within the protection scope of the present invention under the premise of creative work.
Embodiment 1:
A kind of high temperature resistant gold copper cable, cable core are made of the element of following weight percent: Au 0.21%, Cr 0.25%, Co 0.22%, W 0.28%, Mo 0.14%, Zn 0.08%, Pt 0.13%, Rh 0.21%, remaining for Cu and Inevitable impurity.
The preparation method of the high temperature resistant gold copper cable, comprising the following steps: (1) weigh other originals in addition to Cu Material is put into high speed ball mill and is uniformly mixed, mixture is pressed into bulk with molding machine;(2) by bulk made from step (1) Prealloy puts into heating melting in 1450 DEG C of vacuum drying ovens, keeps the temperature 60min, obtains prealloy liquid;(3) Cu is added to prealloy liquid In, alloy mixed liquor is made in heating melting;(4) alloy mixed liquor is poured into mold, alloy pig is made;(5) by alloy pig 9h is kept the temperature under the conditions of 700 DEG C, carries out cold rolling after natural cooling;(6) alloy after cold rolling is kept the temperature into 4h at 500 DEG C, be made Gold copper cable core;(7) gold copper cable is made in cable core winding, package insulation sleeve.
Embodiment 2:
A kind of high temperature resistant gold copper cable, cable core are made of the element of following weight percent: Au 0.29%, Cr 0.28%, Co 0.18%, W 0.25%, Mo 0.16%, Zn 0.09%, Pt 0.15%, Rh 0.18%, remaining for Cu and Inevitable impurity.
The preparation method of the high temperature resistant gold copper cable, comprising the following steps: (1) weigh other originals in addition to Cu Material is put into high speed ball mill and is uniformly mixed, mixture is pressed into bulk with molding machine;(2) by bulk made from step (1) Prealloy puts into heating melting in 1470 DEG C of vacuum drying ovens, keeps the temperature 55min, obtains prealloy liquid;(3) Cu is added to prealloy liquid In, alloy mixed liquor is made in heating melting;(4) alloy mixed liquor is poured into mold, alloy pig is made;(5) by alloy pig 10h is kept the temperature under the conditions of 720 DEG C, carries out cold rolling after natural cooling;(6) alloy after cold rolling is kept the temperature into 5h at 520 DEG C, be made Gold copper cable core;(7) gold copper cable is made in cable core winding, package insulation sleeve.
Embodiment 3:
A kind of high temperature resistant gold copper cable, cable core are made of the element of following weight percent: Au 0.16%, Cr 0.22%, Co 0.20%, W 0.32%, Mo 0.12%, Zn 0.11%, Pt 0.14%, Rh 0.20%, remaining for Cu and Inevitable impurity.
The preparation method of the high temperature resistant gold copper cable, comprising the following steps: (1) weigh other originals in addition to Cu Material is put into high speed ball mill and is uniformly mixed, mixture is pressed into bulk with molding machine;(2) by bulk made from step (1) Prealloy puts into heating melting in 1480 DEG C of vacuum drying ovens, keeps the temperature 60min, obtains prealloy liquid;(3) Cu is added to prealloy liquid In, alloy mixed liquor is made in heating melting;(4) alloy mixed liquor is poured into mold, alloy pig is made;(5) by alloy pig 9h is kept the temperature under the conditions of 700 DEG C, carries out cold rolling after natural cooling;(6) alloy after cold rolling is kept the temperature into 4h at 530 DEG C, be made Gold copper cable core;(7) gold copper cable is made in cable core winding, package insulation sleeve.
Embodiment 4:
A kind of high temperature resistant gold copper cable, cable core are made of the element of following weight percent: Au 0.25%, Cr 0.35%, Co 0.26%, W 0.30%, Mo 0.15%, Zn 0.06%, Pt 0.13%, Rh 0.16%, remaining for Cu and Inevitable impurity.
The preparation method of the high temperature resistant gold copper cable, comprising the following steps: (1) weigh other originals in addition to Cu Material is put into high speed ball mill and is uniformly mixed, mixture is pressed into bulk with molding machine;(2) by bulk made from step (1) Prealloy puts into heating melting in 1500 DEG C of vacuum drying ovens, keeps the temperature 55min, obtains prealloy liquid;(3) Cu is added to prealloy liquid In, alloy mixed liquor is made in heating melting;(4) alloy mixed liquor is poured into mold, alloy pig is made;(5) by alloy pig 8h is kept the temperature under the conditions of 680 DEG C, carries out cold rolling after natural cooling;(6) alloy after cold rolling is kept the temperature into 5h at 550 DEG C, be made Gold copper cable core;(7) gold copper cable is made in cable core winding, package insulation sleeve.
In order to embody gold copper cable heat-resisting quantity prepared by the present invention, by the Jin Tonghe of various embodiments of the present invention preparation Golden cable and existing copper alloy cable have done data comparison, as a result as follows:
As seen from the above table, compared with existing copper alloy cable, gold copper cable prepared by the present invention is other each in guarantee Under the premise of item index is similar, high temperature resistance has obtained larger raising.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that There is also other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments Invention is explained in detail, those skilled in the art should understand that: it still can be to aforementioned each implementation Technical solution documented by example is modified or equivalent replacement of some of the technical features;And these modification or Replacement, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.

Claims (2)

1. a kind of high temperature resistant gold copper cable, which is characterized in that cable core is made of the element of following weight percent: Au0.16-0.29%, Cr0.22-0.35%, Co0.18-0.26%, W0.25-0.32%, Mo0.12-0.16%, Zn0.06- 0.11%, Pt0.13-0.15%, Rh0.16-0.21%, remaining is Cu and inevitable impurity;
The high temperature resistant gold copper cable, preparation method the following steps are included: (1) weighs other raw materials in addition to Cu, It is put into high speed ball mill and is uniformly mixed, mixture is pressed into bulk with molding machine;(2) bulk made from step (1) is pre- Heating melting in ladle refining vacuum drying oven, heat preservation obtain prealloy liquid;(3) Cu is added in prealloy liquid, heating melting, Alloy mixed liquor is made;(4) alloy mixed liquor is poured into mold, alloy pig is made;(5) by alloy pig at 680-720 DEG C Under the conditions of keep the temperature 8-10h, carry out cold rolling after natural cooling;(6) alloy after cold rolling is kept the temperature into 4-5h at 500-550 DEG C, made Obtain gold copper cable core;(7) gold copper cable is made in cable core winding, package insulation sleeve;
Vacuum drying oven heating temperature is 1450-1500 DEG C in the step (2), soaking time 55-60min.
2. high temperature resistant gold copper cable as described in claim 1, which is characterized in that cable core is by following weight percent Element composition: Au0.21%, Cr0.25%, Co0.22%, W0.28%, Mo0.14%, Zn0.08%, Pt0.13%, Rh0.21%, remaining is copper and inevitable impurity.
CN201710391048.3A 2017-05-27 2017-05-27 A kind of high temperature resistant gold copper cable Active CN107217170B (en)

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Publication number Priority date Publication date Assignee Title
CN109754942A (en) * 2019-01-16 2019-05-14 京仪股份有限公司 A kind of high temperature resistant gold copper cable and its manufacturing method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102324284A (en) * 2011-09-13 2012-01-18 无锡市嘉邦电力管道厂 A kind of method of manufactured copper alloy cable
CN102324261A (en) * 2011-09-13 2012-01-18 无锡市嘉邦电力管道厂 Copper alloy cable
CN104060120A (en) * 2014-07-03 2014-09-24 兰宝琴 Method for preparing high-strength copper alloy wire rods
CN104361921A (en) * 2014-11-28 2015-02-18 彭伟成 Copper alloy single-core cable and manufacturing method thereof
CN106282645A (en) * 2016-08-10 2017-01-04 安徽晋源铜业有限公司 A kind of high strength and high conductivity copper alloy and processing method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102324284A (en) * 2011-09-13 2012-01-18 无锡市嘉邦电力管道厂 A kind of method of manufactured copper alloy cable
CN102324261A (en) * 2011-09-13 2012-01-18 无锡市嘉邦电力管道厂 Copper alloy cable
CN104060120A (en) * 2014-07-03 2014-09-24 兰宝琴 Method for preparing high-strength copper alloy wire rods
CN104361921A (en) * 2014-11-28 2015-02-18 彭伟成 Copper alloy single-core cable and manufacturing method thereof
CN106282645A (en) * 2016-08-10 2017-01-04 安徽晋源铜业有限公司 A kind of high strength and high conductivity copper alloy and processing method thereof

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