CN102296405A - Compound-type fabric containing liquid metal - Google Patents
Compound-type fabric containing liquid metal Download PDFInfo
- Publication number
- CN102296405A CN102296405A CN2010102197552A CN201010219755A CN102296405A CN 102296405 A CN102296405 A CN 102296405A CN 2010102197552 A CN2010102197552 A CN 2010102197552A CN 201010219755 A CN201010219755 A CN 201010219755A CN 102296405 A CN102296405 A CN 102296405A
- Authority
- CN
- China
- Prior art keywords
- liquid metals
- metal
- lining
- fabric
- gallium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910001338 liquidmetal Inorganic materials 0.000 title claims abstract description 209
- 239000004744 fabric Substances 0.000 title claims abstract description 99
- 239000000835 fiber Substances 0.000 claims abstract description 105
- 239000004753 textile Substances 0.000 claims abstract description 56
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 44
- 239000000956 alloy Substances 0.000 claims abstract description 44
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 35
- 229910052738 indium Inorganic materials 0.000 claims abstract description 30
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910000634 wood's metal Inorganic materials 0.000 claims abstract description 29
- 239000002356 single layer Substances 0.000 claims abstract description 28
- 239000010410 layer Substances 0.000 claims abstract description 19
- 239000002070 nanowire Substances 0.000 claims abstract description 19
- 229910003251 Na K Inorganic materials 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims description 47
- 239000000203 mixture Substances 0.000 claims description 41
- 238000009941 weaving Methods 0.000 claims description 34
- 238000009954 braiding Methods 0.000 claims description 19
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 15
- 229910052797 bismuth Inorganic materials 0.000 claims description 15
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 15
- 229910052793 cadmium Inorganic materials 0.000 claims description 15
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 15
- 229910052718 tin Inorganic materials 0.000 claims description 15
- 239000002105 nanoparticle Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 abstract description 13
- 239000002184 metal Substances 0.000 abstract description 13
- 230000005855 radiation Effects 0.000 abstract description 9
- 230000001954 sterilising effect Effects 0.000 abstract description 9
- 230000000845 anti-microbial effect Effects 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002082 metal nanoparticle Substances 0.000 abstract 1
- 230000003115 biocidal effect Effects 0.000 description 11
- 230000008859 change Effects 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 230000000844 anti-bacterial effect Effects 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 8
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000002344 surface layer Substances 0.000 description 6
- 230000003068 static effect Effects 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 208000037581 Persistent Infection Diseases 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 230000012010 growth Effects 0.000 description 4
- 238000009940 knitting Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 230000005670 electromagnetic radiation Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000012782 phase change material Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 208000035143 Bacterial infection Diseases 0.000 description 1
- 208000031872 Body Remains Diseases 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000000274 aluminium melt Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 208000022362 bacterial infectious disease Diseases 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 230000008260 defense mechanism Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000026683 transduction Effects 0.000 description 1
- 238000010361 transduction Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Abstract
The invention relates to a compound-type fabric containing liquid metal. The fabric can be completely woven by blended fiber yarn of a liquid-metal-containing fiber, and can also be woven by mixing a natural fiber yarn and blended fiber yarn of the liquid-metal-containing fiber, wherein the liquid-metal-containing fiber is a textile fiber the surface of which is adhered with liquid metal nanoparticles, a tubular textile fiber the pipe of which is filled with liquid metal, or a reticular casing-pipe-type textile fiber which is woven by nanowires and the reticular casing pipe of which is filled with liquid metal; and the liquid metal is gallium metal, gallium-based alloy, Na-K alloy or wood metal containing indium. The compound-type fabric can be made into a single layer, two layers or three layers according to requirements, can be used as a basic fabric for manufacturing articles such as clothes, trousers, shoes and hats, gloves, stockings, bedclothes and pillowcases and the like, can endow clothing and household articles with temperature adjusting, radiation proofing, electrostatic resisting and sterilizing and antimicrobial functions, has stable performance and high reliability, needs not to be added with other organic components, and can be used for making up the defect of the property singleness of the traditional fabric.
Description
Technical field
The present invention relates to a kind of compound lining, be particularly related to a kind of compound lining that contains liquid metals, the lining that promptly contains the metal fluid that is liquid condition under the room temperature, this lining has all obtained significant change with respect to traditional lining on its calorifics, phase transformation, electricity and biological characteristics.
Background technology
Clothes; initial stage as far back as human social development just occurs; it shields to human body, is a kind ofly to have technological daily necessities, and is the important symbol of reflection country, nationality and the political economy in epoch, science and culture, level of education and social morals looks to a certain extent.Along with the progress of the development of technology, culture and to the raising of health demand, people not only are satisfied with warming comfortable and attractive in appearance well-pressed for clothes, but have proposed more requirement.Thus, clothes and spin-off thereof have experienced from conservative to opening, from open into practicality, experiencing and incorporate from the practicality to the science and technology and evolution that function constantly promotes again comprehensively.In order to expand the function of clothes,, its functional pursuit had been become common practise already and obtained vigorous growth at home and abroad as basic comprising element---the lining of clothes.It is reported that the shared proportion of functional product in the textiles up to 39%, is respectively 21% and 28% in Europe with the U.S. in Japan.And functional fiber is grown up the fastest in the application of medical field, 1992 to 1997, world's sales volume annual growth is 6-10%, reached 1,370 hundred million dollars in 1997, reached 2,000 hundred million dollars in 2000, the U.S.'s this series products income from sales in 2000 has reached 76,000,000,000 dollars, than 2.4 times of nineteen ninety growths.
After a large amount of new technologies and new technology were used on the garment material, various functional fibers and lining had just arisen at the historic moment.The mode classification of functional fabric has a variety of, typical lining with market development is an example, angle from design of lining function and technical development is broadly divided into: warming profile material, high elasticity lining, dry and comfortable gas permeability lining, antibacterial and protective lining, fire-retardant lining, antistatic radiation-proof fabric or the like.Wherein warming profile material rises at first, and the realization of its function mainly relies on the absorbing environmental heat radiation, reduces the heat conduction, weakens the thermal balance that heat convection is kept human body.Further scientific achievement has added phase-change material (PCM) in fabric fibre, and when temperature Change, it is overheated to cushion cold-peace with absorption or release latent heat of phase change, makes human body remain on comfortable temperature range.Subsequently, the appearance of elastic fabric is performed meritorious deeds never to be obliterated to the upgrading of the popular and sportswear of easy suit, is subjected to market so far and pursues strongly.Along with the lifting of global climate environmental complexity, people's self-protection consciousness is strong further.The fiber of dry and comfortable gas permeability lining by selecting unique hygroscopicity for use, leading moist and wet putting, thus the textile structural that changes fabric is realized not sticking, not wet and comfortable sense of touch, and it is that people pursue the product that the comfortableness acclimatization changes; The antibacterial and protective lining comprises the function of antibacterial, antibiotic and isolating and protecting, and after having experienced the SARS epidemic situation, it has obtained further developing, and the widely-used of anti-bacterial fibre makes the development of antibacterial fabric enter a new stage.Fire-retardant lining, antistatic radiation-proof fabric can provide reliable and effective protection and guarantee for people equally in the productive life process.
Liquid metals is the general name that fusing point is no more than 17 kinds of metals of aluminium melt temperature (660.37 ℃).These 17 kinds of metals are respectively mercury, caesium, gallium, rubidium, potassium, sodium, indium, lithium, tin, bismuth, thallium, cadmium, lead, zinc, antimony, magnesium, aluminium.In addition, the alloy that also has many alloys and above-mentioned metal also for liquid, has only-12.5 ℃ as the fusing point of Na-K alloy during in room temperature even in lower temperature.In the liquid metals, fusing point is relatively low mercury, gallium, sodium, potassium etc., wherein the removal of mercury have toxicity and thermal conductivity low outside, other are as gallium, sodium, potassium and alloy thereof etc., general all have higher thermal conductivity coefficient, lower viscosity and good specific heat and stability, can be used as hot transduction agent and heat treatment agent.Liu of Physical Chemistry Technology Inst., Chinese Academy of Sciences waits quietly proposing first in 2002 a kind of with low-melting-point metal or its alloy computer chip cooling means as flow working medium.This method utilizes the alloy of silvery white and soft gallium or gallium as flow working medium, and the heat that under the effect of Power Drive Unit electromagnetic pump the computer chip surface is discharged is transported to the far-end radiator, and finally is dissipated in the environment.The crucial part of this technology has been to introduce the cooling working medium of the brand-new and superior performance of notion, and this type of working medium has remarkable thermal conductivity, good electrical conductivity, higher boiling point, extremely low vapour pressure and good specific heat and stability.Subsequently, this technology is successfully applied to the occasion of a series of release high heat density, and this is that conventional art is difficult to realize with heat radiation working medium.
In addition, the scientist from Washington university finds that by disturbing the nutriment of bacterium, gallium can kill the bacterium in the mouse body.The researcher represents: iron is very important for the growth of bacterium, and makes them possess the biomembranous ability of formation.When utilizing this and the very similar metal of iron---during gallium, can stop the formation of bacterial biof iotalm, thereby effectively reach bactericidal effect.And under the lower environment of concentration of iron, its effect is more obvious.Gallium is also effective for the very strong bacterial chronic infection of some resistance to the action of a drug.Thus, more and more stronger in the directed toward bacteria resistance to the action of a drug, and existing antibiotic is for the present situation of chronic infection poor effect, relies on the inherent defense mechanism of human body self, the method for utilizing gallium to carry out sterilization is a kind of effective ways of brand-new treatment bacterial infection.
Thus, according to the attribute of people to increasing demand of lining and low-melting-point liquid metal uniqueness, the present invention has proposed a kind of compound lining from brand-new angle, and promotes lining in calorifics, phase transformation, electricity and characteristic biologically by means of the metal fluid that at room temperature is liquid condition.This kind lining complete function, unique properties, the application scenario of expanding function lining to a certain extent.
Summary of the invention
The object of the present invention is to provide a kind of at calorifics, phase transformation, electricity and the compound lining that contains liquid metals that biologically has remarkable characteristic, it can be formed by the blend fibre yarn braiding that contains the liquid metals fiber fully, also can adopt general fibre and the blend fibre yarn mixed weaving that contains the liquid metals fiber.This compound lining, can become the basic lining of clothes such as making clothes, trousers, shoes and hats, gloves, socks according to demand, also can become basic lining, and can give simultaneously clothes and household articles with adjustment, radiation proof is antistatic and sterilization is antibiotic function as household articless such as bed clothes, pillowcases.This kind of lining stable performance, the reliability height need not to add other organic principles, has remedied the single defective of traditional function lining performance.
Technical scheme of the present invention is as follows:
The compound lining that contains liquid metals provided by the invention, the single-layer fabric that its blend fibre yarn of containing liquid metals of serving as reasons is formed by weaving;
The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
The compound lining that contains liquid metals provided by the invention, the single-layer fabric that its blend fibre yarn of containing liquid metals of serving as reasons is formed by weaving and be attached to the nexine lining that is formed by weaving by common natural fiber mixed yarn on this single-layer fabric one surface and the double-layer fabric that constitutes;
The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
The compound lining that contains liquid metals provided by the invention, nexine lining that is formed by weaving by common natural fiber mixed yarn on single-layer fabric that its blend fibre yarn of containing liquid metals of serving as reasons is formed by weaving and the about surface that is attached to this single-layer fabric respectively and top layer lining and the three aspect material that constitute; The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
The compound lining that contains liquid metals provided by the invention, the single-layer fabric that its serve as reasons the blend fibre yarn that contains liquid metals and common natural fiber mixed yarn are formed by weaving;
The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
The compound lining that contains liquid metals provided by the invention, the single-layer fabric that its serve as reasons the blend fibre yarn that contains liquid metals and common natural fiber mixed yarn are formed by weaving and be attached to the nexine lining that is formed by weaving by common natural fiber mixed yarn on this single-layer fabric one surface and the double-layer fabric that constitutes; The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
The compound lining that contains liquid metals provided by the invention, nexine lining that is formed by weaving by common natural fiber mixed yarn on single-layer fabric that its serve as reasons the blend fibre yarn that contains liquid metals and common natural fiber mixed yarn are formed by weaving and the about surface that is attached to this single-layer fabric respectively and top layer lining and the three aspect material that constitute;
The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
The compound lining that contains liquid metals of the present invention, can be respectively or finish following function simultaneously:
1) good heat conductivility, the heat that human body can be discharged exports to environment fast;
2) phase-changing and temperature-regulating can absorb or discharge latent heat of phase change to keep the comfortableness of human body when temperature Change;
3) heating of can switching on, liquid metals is the same with other metals, can produce the spontaneous heating phenomenon under certain external voltage, thereby realize the effect of heat-preservation cold-resistance.Because the thermal property that liquid metals is superior and the quality of metal thereof, so the thermal property of the compound lining that the present invention realized is also very remarkable, can become the basic comprising lining of the function clothes that satisfies human body comfort.
4) electromagnetic shielding and prevent static, the braided structure of liquid metals fiber 3 can be realized electromagnetic radiation shielding and the function that effectively prevents static thus at the wire netting that constitutes a connection; Because the flowability of liquid metals, so the reliability of the electromagnetic shielding realized of this lining and anti-static function is extremely strong, can output not cause the phenomenon of afunction because of the metal fibre fracture.
5) antibiotic and sterilizing because the liquid metals gallium can disturb the nutriment of bacterium, stops its biomembranous formation, thereby effectively reaches bactericidal effect.Gallium is also effective for the very strong bacterial chronic infection of some resistance to the action of a drug; When choosing gallium and a series of low melting point gallium-base alloy as liquid metals 2, this lining just can have the effect of antibiotic and sterilizing.
The compound lining that contains liquid metals of the present invention also possesses other traditional performances, as gas permeability, washability etc.
Description of drawings
Fig. 1 is the structural representation that contains the compound lining of liquid metals of the present invention.
Fig. 2-1 is a kind of structural representation that contains the fiber of liquid metals: be about to discrete for being attached to the fiber that contains liquid metals that the textile fabric surface makes behind the nanoscale drop.
Fig. 2-2 is the another kind of structural representation that contains the fiber of liquid metals: be about to liquid metals and be filled in the fiber that contains liquid metals that makes in the tubular fiber.
Fig. 2-3 contains the structural representation of the fiber of liquid metals for another: soon liquid metals is filled in the netted sleeve pipe of the mesh jacket tubular type textile fabric that is formed by the nano wire braiding, and the fiber that contains liquid metals that makes.
Fig. 3 is the double-deck structural representation that contains the compound lining of liquid metals of the present invention.
Fig. 4-1 and Fig. 4-2 is respectively the structural representation of the compound lining that contains liquid metals of three-decker.
The specific embodiment
Further describe the present invention below in conjunction with the drawings and specific embodiments:
Fig. 1 is the structural representation that contains the compound lining of liquid metals of the present invention, also is one embodiment of the present of invention.When need not directly to contact with human body skin for a long time, the present invention can be the compound lining that contains liquid metals that is formed by textile yarn 4 braidings that contain liquid metals fully; The fiber 3 that is about to contain liquid metals is woven into the blend fibre yarn 4 that contains liquid metals, is formed by weaving first kind of compound functional single-layer fabric that contains liquid metals of the present invention with this blend fibre yarn 4 that contains liquid metals again;
Also can be formed by weaving second kind of compound single-layer fabric that contains liquid metals of the present invention with common natural fabric textile yarn 6 by the textile yarn 4 that contains liquid metals.
The compound lining that contains liquid metals of the present invention, when needs directly contact with human body skin, can adopt following weaving mode: be the lining skin promptly with above-mentioned first kind compound single-layer fabric that contains liquid metals, go up the lining internal layer 72 that is formed by weaving by common natural fiber mixed yarn 6 by knitting method combination one deck on this first a kind surface of containing the compound single-layer fabric (shown in the label 71 among Fig. 3) of liquid metals, thereby constituted the compound lining that bilayer of the present invention contains liquid metals.
The compound lining that contains liquid metals of the present invention, when needs directly contact with human body skin, also can adopt following weaving mode: be the lining skin promptly with above-mentioned second kind compound single-layer fabric that contains liquid metals, go up the lining internal layer 72 that is formed by weaving by common natural fiber mixed yarn 6 by knitting method combination one deck on this second a kind surface of containing the compound single-layer fabric (shown in the label 71 among Fig. 3) of liquid metals, thereby constituted the compound lining that another kind of bilayer of the present invention contains liquid metals.
This lining internal layer 72 is formed by weaving for common natural fabric, can wear next to the skin and can not cause the discomfort of health and skin; Lining outer 71 forms for containing the liquid metals fibrous woven, because of being full of liquid metals, and have adjustment, function such as radiation proof is antistatic and sterilization is antibiotic.
In addition, the present invention also can adopt three-decker (shown in Fig. 4-1), promptly be formed by weaving first kind of central core 8 that contains the compound single-layer fabric of liquid metals as lining by the blended yarn 4 that contains liquid metals, be woven into the surface layer 91 of this lining and the bottom 92 of lining by common natural fiber mixed yarn 6 again, finally synthesize the compound lining of this three-decker by the method for stitching or the means of adhering and pressing.
Shown in Fig. 4-2, three-decker of the present invention can also adopt and weave closely lining as the surface layer 101 of lining and the bottom 102 of lining, on surface layer 101 and bottom 102 facing surfaces, directly apply the liquid metals layer 11 of micron order thickness, by the mode of sewing up liquid metals layer 11 and surface layer 101 and bottom 102 are connected and fixed again, finally form the compound lining that contains liquid metals of a kind of three-decker of the present invention.
The fiber that contains liquid metals 23 described in the present invention can be made by following mode:
Shown in Fig. 2-1, liquid metals is discrete for behind the nanoscale drop, it is attached on the textile fabric surface and makes the fiber 3 that contains liquid metals of the present invention;
Shown in Fig. 2-2, also liquid metals can be filled in the tubular fiber and make the fiber 3 that contains liquid metals of the present invention;
Shown in Fig. 2-3, also nano wire can be woven into mesh jacket tubular type textile fabric, help under the micro-nano-scale unique physical effect and liquid metals is riddled in the netted sleeve pipe of mesh jacket tubular type textile fabric form the fiber 3 that contains liquid metals of the present invention thereby relend.
If lining only for improving the heat conduction and the temperature adjusting performance of lining, then can be chosen Fig. 2-1 mode, after being about to liquid metals 2 and being separated into the nanoscale drop, attached on the textile fabric surface and make the fiber 3 that contains liquid metals of the present invention;
If be desirably in when improving the lining thermal conductivity, but when making it have the anlistatig function of electrical heating and radiation proof, just can choose mode Fig. 2-2 or Fig. 2-3 modes, promptly liquid metals is filled in the tubular fiber or is filled in the netted sleeve pipe of the mesh jacket tubular type textile fabric that is formed by the nano wire braiding.Fill method can be taked following measure: one, be soaked in the liquid metals pond with the tubulose textile fabric or by the mesh jacket tubular type textile fabric that nano wire braiding forms, treat liquid metals 2 rely on factor such as himself surface tension to be filled in tubular fiber gradually or the netted sleeve pipe of the mesh jacket tubular type textile fabric that forms by the nano wire braiding in; Two, adopt the micro-feed liquor device that has connected microneedle array, liquid metals is filled in the fiber; Wherein, during operation, liquid metals is filled in the fluid reservoir of storaging liquid metal of micro-feed liquor device, again micro-feed liquor device is connected with the micropin of microneedle array, micropin tip with microneedle array links to each other with tubular fiber (or mesh jacket tubular type textile fabric) fibre pipe at last, after starting micro-feed liquor device, liquid metals is slow being filled in and describedly being filled in the tubular fiber or being filled in the netted sleeve pipe of the mesh jacket tubular type textile fabric that is formed by the nano wire braiding at the uniform velocity of section just.
Fig. 3 is the double-decker schematic diagram of the compound lining that contains liquid metals that can directly contact with body surface provided by the invention: the blended yarn 4 and the common natural fiber mixed yarn 6 that are about to contain liquid metals combine by knitting method, synthetic a kind of double-deck lining, wherein will contain lining that the blended yarn 4 of liquid metals is formed by weaving as lining skin 71, the lining that common natural fiber mixed yarn 6 is formed by weaving is as lining internal layer 72; The lining internal layer 72 of the double-layer fabric that obtains is thus made for common natural fabric, can wear next to the skin and can not cause the discomfort of health and skin; Lining outer 71 is made for the fiber that contains liquid metals, because of being full of liquid metals in the fiber, so function such as outer 71 surfaces of this lining have adjustment, electrical heating, radiation proof is antistatic and sterilization is antibiotic; Therefore, this double-deck compound lining can extensively be adopted by the fabric relevant with human body, as can be applicable to improve the household articles such as clothes, shoes and hats, gloves, socks and bed clothes, pillowcase, sheet, pillow cover of human thermal comfort; Also can be applicable to the making of the physical protection device under particular job environment, as the protective clothes of resisting electromagnetic radiation, static and bacterium, shoes and hats, gloves, socks etc. are provided for human body.
Fig. 4 is the three-decker schematic diagram that contains the compound lining of liquid metals provided by the invention; As seen from the figure, the lining that is formed by weaving by the blended yarn 4 that contains liquid metals is as the central core 8 of lining; The lining that is formed by weaving by common natural fiber mixed yarn 6 is as the surface layer 91 of lining and the bottom 92 of lining; Finally synthesize the compound lining of this three-decker by the method for stitching or the means of adhering and pressing.
Fig. 4-2 is for directly applying the three-decker that micron order thickness liquid metals layer 11 forms closely in the quality that is formed by weaving by common natural fiber mixed yarn 6 between surface layer 101 and bottom 10-2; The compound lining of this three-decker is not only applicable to above-described application scenario, is more suitable for large-area fabric simultaneously and makes, as sheet, carpet, wallpaper etc.
In the above embodiment of the present invention, described liquid metals 2 can be chosen different liquid metals, as low melting point gallium-base alloy, Na-K alloy under gallium, the different proportioning and the Wood's metal (bismuth 50%, plumbous 25%, tin 12.5%, cadmium 12.5%) etc. that contains indium.
In the above embodiment of the present invention, described liquid metals 2 can be chosen according to the applied occasion of lining: only for simple when promoting heat conductivility or possessing antistatic radiation proof, low melting point gallium-base alloy, Na-K alloy under gallium, the different proportioning and the Wood's metal etc. that contains indium all can use as lining; When needs are given the lining temperature adjustment function, just can choose or prepare the liquid metals material that fusing point and latent heat of phase change are fit to; If when the expectation lining possessed adjustment and antibiotic function simultaneously, the low melting point gallium-base alloy under liquid metals gallium and the different proportioning thereof was the most suitable.
In addition, the compound functional fabric that contains liquid metals that the present invention realized, can be respectively or finish following function simultaneously: one, good heat conductivility, the heat that human body can be discharged exports to environment fast; Two, phase-changing and temperature-regulating can absorb or discharge latent heat of phase change to keep the comfortableness of human body when temperature Change; Three, the heating of can switching on even liquid metals is the same with other metals, produces the spontaneous heating phenomenon, thereby realizes the effect of heat-preservation cold-resistance under certain external voltage.Four, electromagnetic shielding and prevent static, the braided structure of liquid metals fiber 3 can be realized electromagnetic radiation shielding and the function that effectively prevents static thus at the wire netting that constitutes a connection; Because the flowability of liquid metals, so the reliability of the electromagnetic shielding realized of this lining and anti-static function is extremely strong, can output not cause the phenomenon of afunction because of the metal fibre fracture.Five, antibiotic and sterilizing because the liquid metals gallium can disturb the nutriment of bacterium, stops its biomembranous formation, thereby effectively reaches bactericidal effect.Gallium is also effective for the very strong bacterial chronic infection of some resistance to the action of a drug.Therefore, when the present invention chose gallium and a series of low melting point gallium-base alloy as liquid metals 2, this lining just can have the effect of antibiotic and sterilizing.And other traditional performances that this compound lining should possess can be solved according to the knitting type and the fiber type selecting of conventional lining as gas permeability, washability etc.
It should be noted last that the embodiment of compound moulding mixture that more than contains liquid metals is only unrestricted in order to technical scheme of the present invention to be described.Although the present invention is had been described in detail with reference to embodiment, those of ordinary skill in the art is to be understood that, technical scheme of the present invention is made amendment or is equal to replacement, do not break away from the spirit and scope of technical solution of the present invention, it all should be encompassed in the middle of the claim scope of the present invention.
Claims (6)
1. a compound lining that contains liquid metals is characterized in that, the single-layer fabric that its blend fibre yarn of containing liquid metals of serving as reasons is formed by weaving;
The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
2. compound lining that contains liquid metals, it is characterized in that the single-layer fabric that its blend fibre yarn of containing liquid metals of serving as reasons is formed by weaving and be attached to the nexine lining that is formed by weaving by common natural fiber mixed yarn on this single-layer fabric one surface and the double-layer fabric that constitutes;
The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
3. compound lining that contains liquid metals, it is characterized in that nexine lining that is formed by weaving by common natural fiber mixed yarn on single-layer fabric that its blend fibre yarn of containing liquid metals of serving as reasons is formed by weaving and the about surface that is attached to this single-layer fabric respectively and top layer lining and the three aspect material that constitute; The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
4. a compound lining that contains liquid metals is characterized in that, the single-layer fabric that its serve as reasons the blend fibre yarn that contains liquid metals and common natural fiber mixed yarn are formed by weaving;
The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
5. compound lining that contains liquid metals, it is characterized in that the single-layer fabric that its serve as reasons the blend fibre yarn that contains liquid metals and common natural fiber mixed yarn are formed by weaving and be attached to the nexine lining that is formed by weaving by common natural fiber mixed yarn on this single-layer fabric one surface and the double-layer fabric that constitutes;
The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The mesh jacket tubular type textile fabric that the described fiber that contains liquid metals 3 forms for the tubulose textile fabric that is filled with liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 12.5wt%.
6. compound lining that contains liquid metals, it is characterized in that nexine lining that is formed by weaving by common natural fiber mixed yarn on single-layer fabric that its serve as reasons the blend fibre yarn that contains liquid metals and common natural fiber mixed yarn are formed by weaving and the about surface that is attached to this single-layer fabric respectively and top layer lining and the three aspect material that constitute;
The described blend fibre yarn that contains liquid metals is formed by the fibrage that contains liquid metals;
The described fiber that contains liquid metals is the mesh jacket tubular type textile fabric that is filled with the tubulose textile fabric of liquid metals in the textile fabric that is attached with the liquid metals nano particle on the surface, the pipe or forms for the nano wire braiding that is filled with liquid metals in the netted sleeve pipe;
Described liquid metals is gallium, gallium-base alloy, Na-K alloy or the Wood's metal that contains indium;
Described composition and the proportioning that contains the Wood's metal of indium is: bismuth 50wt%, plumbous 25wt%, tin 12.5wt%, cadmium 125wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010219755.2A CN102296405B (en) | 2010-06-28 | 2010-06-28 | Compound-type fabric containing liquid metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010219755.2A CN102296405B (en) | 2010-06-28 | 2010-06-28 | Compound-type fabric containing liquid metal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102296405A true CN102296405A (en) | 2011-12-28 |
| CN102296405B CN102296405B (en) | 2013-08-21 |
Family
ID=45357072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010219755.2A Active CN102296405B (en) | 2010-06-28 | 2010-06-28 | Compound-type fabric containing liquid metal |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102296405B (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102754961A (en) * | 2012-08-13 | 2012-10-31 | 中国人民解放军海军电磁兼容研究检测中心 | Electromagnetic shielding protective shoe cover |
| CN103331754A (en) * | 2013-06-26 | 2013-10-02 | 清华大学 | Metal phase-change based flexible mechanical joint device |
| CN103657748A (en) * | 2012-09-25 | 2014-03-26 | 中国科学院理化技术研究所 | Printing type paper microfluid chip and manufacture method thereof |
| CN106435826A (en) * | 2016-09-21 | 2017-02-22 | 东莞市联洲知识产权运营管理有限公司 | Liquid metal composite fibers based on bubble spinning technology and preparation method of liquid metal composite fibers |
| CN107557957A (en) * | 2017-09-14 | 2018-01-09 | 清华大学 | It is a kind of can be with the textile material of hard and soft switching |
| CN108301152A (en) * | 2018-02-08 | 2018-07-20 | 盐城工业职业技术学院 | The textile fabric processing technology of filling nano material in pipe |
| CN108951196A (en) * | 2018-07-20 | 2018-12-07 | 北京梦之墨科技有限公司 | A kind of loomage and preparation method thereof |
| CN109402818A (en) * | 2018-12-06 | 2019-03-01 | 清华大学 | A kind of conductive micron fibers and its preparation and application based on liquid metal |
| CN109453423A (en) * | 2018-11-20 | 2019-03-12 | 中国科学院理化技术研究所 | A kind of antimicrobial spray and its preparation method and application based on nano material |
| CN110042524A (en) * | 2019-05-09 | 2019-07-23 | 德州恒丰纺织有限公司 | A kind of anti pilling collagen scribbled |
| CN112188657A (en) * | 2020-09-23 | 2021-01-05 | 江西复萍科技有限公司 | Elastic heating cloth and preparation method thereof |
| CN114068056A (en) * | 2021-11-19 | 2022-02-18 | 郑州大学第三附属医院(河南省妇幼保健院) | Medical ionizing radiation protective clothing |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4390589A (en) * | 1982-02-26 | 1983-06-28 | Bell Telephone Laboratories, Incorporated | Metal coating of fibers |
| CN1262355A (en) * | 1999-01-27 | 2000-08-09 | 孙安国 | Multifunctional spinnable metallic fibres |
| CN2483969Y (en) * | 2001-05-30 | 2002-04-03 | 纪祖煌 | Nanometer-silver sterilizing shoe-pad |
| CN1710187A (en) * | 2005-07-04 | 2005-12-21 | 西安工程科技学院 | Nano composite metal coated fabric and its preparing process |
| CN1804203A (en) * | 2006-01-17 | 2006-07-19 | 浙江理工大学 | Method for in-situ generating ultrafine silver particles in textile |
| CN1944714A (en) * | 2005-10-05 | 2007-04-11 | 斯奈克玛 | Process for the metallic coating of fibres by liquid means |
| CN101302682A (en) * | 2008-07-03 | 2008-11-12 | 吉林邦安宝医用设备有限公司 | Production method and apparatus of antibiotic superfine fibre nonwoven cloth with nano-silver being embedded |
| CN101660125A (en) * | 2009-09-18 | 2010-03-03 | 邵楠 | Technology for plating nano-metal on fiber |
| CN102428202A (en) * | 2009-05-25 | 2012-04-25 | 斯奈克玛 | Method and device for the liquid metal coating of fibers made of a ceramic material |
-
2010
- 2010-06-28 CN CN201010219755.2A patent/CN102296405B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4390589A (en) * | 1982-02-26 | 1983-06-28 | Bell Telephone Laboratories, Incorporated | Metal coating of fibers |
| CN1262355A (en) * | 1999-01-27 | 2000-08-09 | 孙安国 | Multifunctional spinnable metallic fibres |
| CN2483969Y (en) * | 2001-05-30 | 2002-04-03 | 纪祖煌 | Nanometer-silver sterilizing shoe-pad |
| CN1710187A (en) * | 2005-07-04 | 2005-12-21 | 西安工程科技学院 | Nano composite metal coated fabric and its preparing process |
| CN1944714A (en) * | 2005-10-05 | 2007-04-11 | 斯奈克玛 | Process for the metallic coating of fibres by liquid means |
| CN1804203A (en) * | 2006-01-17 | 2006-07-19 | 浙江理工大学 | Method for in-situ generating ultrafine silver particles in textile |
| CN101302682A (en) * | 2008-07-03 | 2008-11-12 | 吉林邦安宝医用设备有限公司 | Production method and apparatus of antibiotic superfine fibre nonwoven cloth with nano-silver being embedded |
| CN102428202A (en) * | 2009-05-25 | 2012-04-25 | 斯奈克玛 | Method and device for the liquid metal coating of fibers made of a ceramic material |
| CN101660125A (en) * | 2009-09-18 | 2010-03-03 | 邵楠 | Technology for plating nano-metal on fiber |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102754961A (en) * | 2012-08-13 | 2012-10-31 | 中国人民解放军海军电磁兼容研究检测中心 | Electromagnetic shielding protective shoe cover |
| CN103657748A (en) * | 2012-09-25 | 2014-03-26 | 中国科学院理化技术研究所 | Printing type paper microfluid chip and manufacture method thereof |
| CN103657748B (en) * | 2012-09-25 | 2015-12-09 | 中国科学院理化技术研究所 | Printing-type papery micro-fluid chip and preparation method |
| CN103331754A (en) * | 2013-06-26 | 2013-10-02 | 清华大学 | Metal phase-change based flexible mechanical joint device |
| CN103331754B (en) * | 2013-06-26 | 2015-07-15 | 清华大学 | Metal phase-change based flexible mechanical joint device |
| CN106435826A (en) * | 2016-09-21 | 2017-02-22 | 东莞市联洲知识产权运营管理有限公司 | Liquid metal composite fibers based on bubble spinning technology and preparation method of liquid metal composite fibers |
| CN107557957A (en) * | 2017-09-14 | 2018-01-09 | 清华大学 | It is a kind of can be with the textile material of hard and soft switching |
| CN108301152B (en) * | 2018-02-08 | 2020-02-14 | 盐城工业职业技术学院 | Processing technology of textile fabric filled with nano material in tube |
| CN108301152A (en) * | 2018-02-08 | 2018-07-20 | 盐城工业职业技术学院 | The textile fabric processing technology of filling nano material in pipe |
| CN108951196A (en) * | 2018-07-20 | 2018-12-07 | 北京梦之墨科技有限公司 | A kind of loomage and preparation method thereof |
| CN109453423A (en) * | 2018-11-20 | 2019-03-12 | 中国科学院理化技术研究所 | A kind of antimicrobial spray and its preparation method and application based on nano material |
| CN109453423B (en) * | 2018-11-20 | 2021-06-25 | 中国科学院理化技术研究所 | Antibacterial spray based on nano material and preparation method and application thereof |
| CN109402818A (en) * | 2018-12-06 | 2019-03-01 | 清华大学 | A kind of conductive micron fibers and its preparation and application based on liquid metal |
| CN109402818B (en) * | 2018-12-06 | 2021-04-06 | 清华大学 | Conductive micron fiber based on liquid metal and preparation and application thereof |
| CN110042524A (en) * | 2019-05-09 | 2019-07-23 | 德州恒丰纺织有限公司 | A kind of anti pilling collagen scribbled |
| CN112188657A (en) * | 2020-09-23 | 2021-01-05 | 江西复萍科技有限公司 | Elastic heating cloth and preparation method thereof |
| CN114068056A (en) * | 2021-11-19 | 2022-02-18 | 郑州大学第三附属医院(河南省妇幼保健院) | Medical ionizing radiation protective clothing |
| CN114068056B (en) * | 2021-11-19 | 2023-06-02 | 郑州大学第三附属医院(河南省妇幼保健院) | Medical ionizing radiation protective clothing |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102296405B (en) | 2013-08-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102296405B (en) | Compound-type fabric containing liquid metal | |
| CN205474200U (en) | Multi -functional yarn of graphene fiber blending | |
| CN102161248A (en) | Deodorant warm-keeping fabric | |
| CN204281985U (en) | A kind of double-deck one-way wet-guide concave-convex fabric | |
| CN203174261U (en) | Knitting yarn with cool function and healthcare function | |
| TWM568270U (en) | The structure of the cool sensory sheath-core fibers and its composite yarn containing four components | |
| CN102210499A (en) | Insole | |
| CN202766732U (en) | Jade fiber fabric | |
| US20140109285A1 (en) | Performance Dress Shirt | |
| KR102106530B1 (en) | Two ply fabiric having thermal comfort of human body | |
| CN103911742A (en) | Constant-temperature cotton fabric, processing technique of constant-temperature cotton fabric and constant-temperature underwear | |
| CN103614796B (en) | A kind of production method of cool feeling cellular fibronectin | |
| Duru et al. | Innovation in the comfort of intimate apparel | |
| CN203128768U (en) | Mica ice-cold fiber terry fabric | |
| CN108796795A (en) | A kind of preparation process of winged woven fabric material and its application | |
| CN102370264A (en) | Sportswear | |
| KR20160109170A (en) | Antimicrobial Double Raschel Fabric | |
| CN204653795U (en) | A kind of health-care underclothes | |
| TW201912858A (en) | Multi-functional sheath-core fiber and manufacturing method of composite yarn thereof combine the yarn characteristics of cool feeling function such as sweat absorption, heat resistance, cool feeling, quick drying, gloss, and UV resistance | |
| CN204232340U (en) | A kind of cool-down garments | |
| KR20180110545A (en) | Functional triple staff with fever function | |
| CN102877190A (en) | Jade fiber fabric | |
| KR20180110544A (en) | Functional triple staff with cold function | |
| CN203137152U (en) | Antibacterial and deodorizing blended swimwear fabric | |
| Lin et al. | Evaluation of the function and manufacturing technique of bamboo charcoal complex yarns and knitted fabrics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20111228 Assignee: BEIJING DREAM INK TECHNOLOGIES Co.,Ltd. Assignor: TECHNICAL INSTITUTE OF PHYSICS AND CHEMISTRY OF THE CHINESE ACADEMY OF SCIENCES Contract record no.: 2016990000417 Denomination of invention: Compound-type fabric containing liquid metal Granted publication date: 20130821 License type: Exclusive License Record date: 20161008 |
|
| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240222 Address after: 100081 room 9009, 9 / F, 65 North Fourth Ring Road West, Haidian District, Beijing Patentee after: BEIJING DREAM INK TECHNOLOGIES Co.,Ltd. Country or region after: China Address before: 100190 No. 2, north of Haidian District, Beijing, Zhongguancun Patentee before: TECHNICAL INSTITUTE OF PHYSICS AND CHEMISTRY OF THE CHINESE ACADEMY OF SCIENCES Country or region before: China |
|
| TR01 | Transfer of patent right |