KR20180110544A - Functional triple staff with cold function - Google Patents

Functional triple staff with cold function Download PDF

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KR20180110544A
KR20180110544A KR1020170040268A KR20170040268A KR20180110544A KR 20180110544 A KR20180110544 A KR 20180110544A KR 1020170040268 A KR1020170040268 A KR 1020170040268A KR 20170040268 A KR20170040268 A KR 20170040268A KR 20180110544 A KR20180110544 A KR 20180110544A
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weight
yarn
functional
triple
cold
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KR1020170040268A
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KR101966945B1 (en
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엄기영
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지유코리아 주식회사
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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00—Double or multi-ply fabrics not otherwise provided for
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D03D15/247—Mineral
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D03D15/25—Metal
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/52—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads thermal insulating, e.g. heating or cooling
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
    • D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial
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    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
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    • D10B2501/00—Wearing apparel

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention relates to a functional triple-woven cloth having a cooling function. More particularly, the present invention relates to a functional triple-woven cloth having a cooling function which enhances the cooling function of the triple-woven cloth used as a blanket and cloth, increases utility by enhancing anti-tick, antimicrobial and far-infrared ray releasing functions, and prevents the rise of body temperature by strengthening of the cooling function when covered or worn to enhance the coolness, thereby increasing activity during hot summer.

Description

냉감기능을 갖는 기능성 삼중직원단{Functional triple staff with cold function}Functional triple staff with cold function.

본 발명은 냉감기능을 갖는 기능성 삼중직원단에 관한 것으로, 보다 상세하게는 이불, 옷감 등으로 사용되는 삼중직원단에 냉감기능을 강화하고, 진득이 방지, 항균성 및 원적외선 방출 기능을 높여 효용성을 증대시키면서 특히, 덮거나 착용시 냉감 기능 강화에 따른 체온상승을 막고 청량감을 강화시켜 더운 여름에도 활동성을 높일 수 있도록 개선된 냉감기능을 갖는 기능성 삼중직원단에 관한 것이다.More particularly, the present invention relates to a functional triplet crew having a cold function, and more particularly, to a triplet crew used for a quilt or a cloth, enhancing the cooling function, enhancing the utility by enhancing the anti-jamming, antimicrobial and far- And more particularly, to a functional triple staff member having an improved cold feeling function to prevent the rise in body temperature due to the strengthening of the cold feeling function during covering or wearing and to enhance the cooling sensation to enhance the activity in hot summer.

생활수준이 향상되면서 기존의 의류 개념을 넘어서 인체를 더욱 편안하게 하고 쾌적하게 하면서 외관상 심미적기능을 갖는 기능성을 갖는 의류를 생산할 수 있는 원단의 출현이 기대되고 있으며, 섬유제조업체에서도 이와 같은 시장의 요구에 앞서 더 향상된 기능의 원사 및 원단을 출시하고 있다.As the level of living has improved, it has been expected that fabrics that can produce apparel having functionalities with aesthetic functions in appearance while making the human body more comfortable and comfortable beyond the conventional clothing concept are expected to appear. We are introducing more advanced yarns and fabrics.

최근에는 합성섬유의 고기능화는 천연섬유의 취약점을 보완하는 물성의 개선과 동시에 합성섬유의 장점을 극대화시키는 방향으로 전개가 되고 있다.In recent years, functionalization of synthetic fibers has been developed to maximize the advantages of synthetic fibers while improving physical properties that complement weakness of natural fibers.

그 대표적인 기능성 소재로는 속건, 제전, 자외선 차단 기능이 부여된 직물 및 이의 이차적 섬유제품 등이다.Representative functional materials include quick-drying, antistatic, ultraviolet-shielding fabrics and secondary textile products.

이와 같은 의류에 기능성을 부여하기 위한 기능성 섬유소재는 크게 흡수성을 높이거나 흡수속건 기능의 수분을 제어하는 섬유소재, 겨울용인 발열기능의 보온성 또는 여름용인 냉감성 등의 온도를 제어하는 섬유소재, 원적외선이나 음이온 등 몸에 이로운 에너지를 방사는 섬유소재, 질병의 치료나 완화 기능을 갖는 의류용 섬유소재 등 다양한 기능성 섬유소재가 현재 개발되고 출시되고 있다.The functional fiber material for imparting functionality to such a garment may be a fiber material that largely improves the absorbency or controls the moisture of the quick-drying absorbent function, a fiber material that controls the temperature such as the warmth of the winter heat function or the cold sensibility of the summer, A variety of functional fiber materials such as textile materials that emit energy beneficial to the body such as anion and anion, and textile materials that have the function of treating or alleviating diseases are currently being developed and released.

이러한 다양한 기능성 섬유소재 중 온도를 제어하는 섬유소재는 다양한 기능성물질의 개발로 이를 통한 섬유에 함유시키거나 원단에 프린팅하는 방법으로 많은 발전이 되어왔다.Among these various functional fiber materials, the temperature controlling fiber material has been developed as a method of developing various functional materials to be contained in fibers or printing on fabrics.

특히, 항균성을 부여하여 인체 유해성을 줄인 기술들도 개시되고 있으나, 이들 대부분은 단순히 섬유, 즉 원사에 항균제를 코팅하는 수준이기 때문에 세탁시 표백제나 세제류 등에 의해 벗겨지거나 혹은 용출되어 없어져 버리는 문제로 인해 항균효과를 지속시키기 어렵다는 한계를 가지고 있다.In particular, techniques for reducing the harmfulness of human body by imparting antimicrobial properties have been disclosed, but most of them are merely coated with fibers, that is, the yarn is coated with an antimicrobial agent, so that it is peeled off or leached out by bleaching agents or detergents It is difficult to maintain the antimicrobial effect.

또한, 여름용인인 냉감기능을 갖는 원단을 3중직 방식으로 구현하고 있으나, 단순히 섬유가 겹을 이루도록 3중 직조하는 방식이라 차열성을 높인 단순 보온성에 불과할 뿐 냉감 기능을 구현되지 못하므로 혹서기, 외부 작업자들이 착용할 때 냉감에 따른 청량감이 없고, 이불로 사용될 경우에는 잠을 설치게 되는 한계가 있었다.In addition, although the fabric having a cold feeling function as a summer tolerance is implemented in a triple-stitched manner, since it is merely a simple warming function that enhances heat resistance due to a method of triple weaving so that the fibers are folded, There was no cooling sensation due to cold feeling when wearing them, and there was a limit in that sleeping was provided when used as a futon.

대한민국 공개특허 제10-2001-0007755호(2001.02.05), '3중직 직물의 제직방법 및 3중직 직물'Korean Patent Laid-Open No. 10-2001-0007755 (Feb. 22, 2001), 'Method of Weaving Three-Dimensional Fabrics and Three- 대한민국 특허 등록번호 제10-0865713호(2008.10.22.), '3중직 파일원단 제조방법 및 그 3중직 파일원단'Korean Patent Registration No. 10-0865713 (Oct. 22, 2008), 'Method for manufacturing three-dimensional filament fabrics and its three- 대한민국 특허 등록번호 제10-1608406호(2016.03.28.), '고수분 전이성을 갖는 냉감성 섬유시트'Korea Patent Registration No. 10-1608406 (Feb. 26, 201), "Cold Sensitive Fiber Sheet Having High Water Transition" 대한민국 특허 등록번호 제10-1339949호(2013.12.04.), '냉감조성물이 함유된 기능성 원단의 제조방법'Korean Patent Registration No. 10-1339949 (Apr. 20, 2013), 'Method for producing functional fabric containing cold-sensitive composition'

본 발명은 상술한 바와 같은 종래 기술상의 제반 문제점들을 감안하여 이를 해결하고자 창출된 것으로, 이불, 옷감 등으로 사용되는 삼중직원단에 냉감기능을 강화하고, 진득이 방지, 항균성 및 원적외선 방출 기능을 높여 효용성을 증대시키면서 특히, 덮거나 착용시 냉감 기능 강화에 따른 체온상승을 막고 청량감을 강화시켜 더운 여름에도 활동성을 높일 수 있도록 개선된 냉감기능을 갖는 기능성 삼중직원단을 제공함에 그 주된 목적이 있다.The present invention has been made in view of the above-mentioned problems in the prior art, and has been made to solve the above problems, and it is an object of the present invention to enhance the cold feeling function on the triple staff members used for futons, cloths, etc. and improve the anti- The main object of the present invention is to provide a functional triplet staff member having an improved cold feeling function so as to increase efficiency and increase the activity even in hot summer by preventing the rise of body temperature due to the strengthening of the cold feeling function during covering or wearing and enhancing the cooling sensation.

본 발명은 상기한 목적을 달성하기 위한 수단으로, 표면사와 이면사 사이에 충전사가 배치되게 삼중 직조된 삼중직원단에 있어서; 상기 충전사는 외피와, 상기 외피에 충전되는 기능성 충전물로 이루어지되, 상기 외피는 폴리에스테르 수지로 이루어지고; 상기 기능성 충전물은 자일리톨과 에리스리톨이 1:1의 중량비로 혼합된 제1혼합물 10중량%, 멘톨(Menthol)과 DL-Camphor(DL-캄파)가 1:1의 중량비로 혼합된 제2혼합물 5중량%, DBNPA(2,2-Dibromo-3-nitrilopropionamide) 5중량%, 1-2㎛의 입도를 갖는 원적외선 방출용 소결성 분쇄물 15중량%, 냉감성을 갖는 수용액 10중량%, 페닐트리메톡시실란 5중량%, 시트로넬라(citronella) 오일 3중량%, 하이드록시프로필메틸셀룰로우즈 2중량% 및 나머지 폴리우레탄수지로 이루어진 것을 특징으로 하는 냉감기능을 갖는 기능성 삼중직원단을 제공한다.In order to achieve the above-mentioned object, the present invention provides a triple-woven tri-folded sewing machine in which a filling yarn is disposed between a surface yarn and a back yarn, Wherein the filling yarn comprises a shell and a functional packing filled in the shell, the shell being made of a polyester resin; The functional packing consisted of 10 wt% of a first mixture of xylitol and erythritol in a weight ratio of 1: 1, 5 wt% of a second mixture of menthol and DL-Camphor (DL-Kamp) in a weight ratio of 1: 5% by weight of DBNPA (2,2-Dibromo-3-nitrilopropionamide), 15% by weight of a sinterable pulverized product for far-infrared ray emission having a particle size of 1-2 μm, 10% by weight of an aqueous solution having cold sensibility, 5% by weight of citronella oil, 3% by weight of citronella oil, 2% by weight of hydroxypropylmethylcellulose and the balance of polyurethane resin.

본 발명에 따르면, 이불, 옷감 등으로 사용되는 삼중직원단에 냉감기능을 강화하고, 진득이 방지, 항균성 및 원적외선 방출 기능을 높여 효용성을 증대시키면서 특히, 덮거나 착용시 냉감 기능 강화에 따른 체온상승을 막고 청량감을 강화시켜 더운 여름에도 활동성을 높일 수 있는 효과를 얻을 수 있다.According to the present invention, it is possible to enhance the cold feeling function of triple staff members used for quilts, cloths, etc., increase the efficiency by enhancing the anti-perspiration, antimicrobial and far infrared ray releasing functions, It is possible to obtain the effect of enhancing the cooling sensation and enhancing the activity in the hot summer.

이하에서는, 본 발명에 따른 바람직한 실시예를 보다 상세하게 설명하기로 한다.Hereinafter, preferred embodiments according to the present invention will be described in detail.

본 발명 설명에 앞서, 이하의 특정한 구조 내지 기능적 설명들은 단지 본 발명의 개념에 따른 실시예를 설명하기 위한 목적으로 예시된 것으로, 본 발명의 개념에 따른 실시예들은 다양한 형태로 실시될 수 있으며, 본 명세서에 설명된 실시예들에 한정되는 것으로 해석되어서는 아니된다.Before describing the present invention, the following specific structural or functional descriptions are merely illustrative for the purpose of describing an embodiment according to the concept of the present invention, and embodiments according to the concept of the present invention may be embodied in various forms, And should not be construed as limited to the embodiments described herein.

또한, 본 발명의 개념에 따른 실시예는 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있으므로, 본 발명의 사상 및 기술 범위에 포함되는 모든 변경물, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다.In addition, it should be understood that the embodiments according to the concept of the present invention include various modifications, equivalents, and alternatives included in the spirit and technical scope of the present invention, .

먼저, 3중직 원단은 주로 방한용으로 널리 사용되는 직물이지만, 최근에는 냉감성분을 포함시킴으로써 혹서기 냉감용으로도 많이 활용되고 있다.First, the triple-woven fabric is widely used as a winter fabric, but recently, it is widely used for cold feeling by including a cold component.

다만, 본 발명은 단순히 세 겹의 직물을 서로 포갠 상태로 재봉하여 누빈 형태가 아닌 원사를 처음부터 3중으로 직조한 형태의 3중직 원단에 효율적이면서 세탁 후에도 장기간 냉감기능을 구현할 수 있도록 한 것이다.However, the present invention can efficiently perform a long-time cold feeling function even after washing the triple-layered fabric in which the triple-layered fabrics are stitched together to form a triple-woven fabric in which the yarn is not triangularly woven from the beginning.

즉, 본 발명은 표면사, 이면사, 충전사로 나뉘어 이 3가지 원사가 직조되어 이루어진 3중직 원단으로서, 충전사는 표면사와 이면사 사이에 배치된다.That is, the present invention is a three-ply fabric having a surface yarn, a backing yarn, and a filling yarn, wherein the three yarns are woven, and the filling yarn is disposed between the surface yarn and the back yarn.

이때, 상기 표면사와 이면사는 제품의 종류에 따라 다양한 원사가 선택 사용되는데, 이를 테면 폴리에스터사, 폴리에틸렌사 등 다양한 원사가 될 수 있다.At this time, the surface yarns and the back yarns may be selected from a variety of yarns depending on the type of product, such as polyester yarns and polyethylene yarns.

또한, 상기 충전사도 다양한 원사를 사용할 수 있지만, 본 발명에서는 냉감기능, 진득이 방지기능, 항균기능, 원적외선 방출기능을 갖도록 충전사를 구성하는 원사 자체를 다음과 같이 배합하여 방사함으로써 충전사를 제조한다.In the present invention, the filament yarn constituting the filament yarn is mixed with the following yarn so as to have a cold function, an anti-fouling function, an antibacterial function, a far-infrared ray emitting function, do.

즉, 본 발명에 따른 충전사는 외피와 상기 외피에 충전되는 기능성 충전물로 이루어진다.That is, the filling yarn according to the present invention comprises a shell and a functional packing to be filled in the shell.

이러한 충전사는 이중다이스를 이용하여 기능성 충전물을 방출하면서 그 밖을 감싸도록 외피 소재를 방출하여 외피가 충전물을 감싸는 형태가 되도록 만들어진다.Such a filling yarn is made to have a form in which the covering material surrounds the filling material by discharging the functional filling material by using the double dice and releasing the covering material to cover the outside.

이때, 상기 외피는 폴리에스테르 수지이고, 상기 기능성 충전물은 자일리톨과 에리스리톨이 1:1의 중량비로 혼합된 제1혼합물 10중량%, 멘톨(Menthol)과 DL-Camphor(DL-캄파)가 1:1의 중량비로 혼합된 제2혼합물 5중량%, DBNPA(2,2-Dibromo-3-nitrilopropionamide) 5중량%, 1-2㎛의 입도를 갖는 원적외선 방출용 소결성 분쇄물 15중량%, 냉감성을 갖는 수용액 10중량%, 페닐트리메톡시실란 5중량%, 시트로넬라(citronella) 오일 3중량%, 하이드록시프로필메틸셀룰로우즈 2중량% 및 나머지 폴리우레탄수지로 이루어진다.10% by weight of the first mixture of xylitol and erythritol in a weight ratio of 1: 1, 1: 1 by weight of menthol and DL-Camphor (DL-camp) 5% by weight of a second mixture of DBNPA (2,2-Dibromo-3-nitrilopropionamide), 15% by weight of a sinterable pulverized product for far-infrared ray emission having a particle size of 1 to 2 m, 10% by weight of aqueous solution, 5% by weight of phenyltrimethoxysilane, 3% by weight of citronella oil, 2% by weight of hydroxypropyl methylcellulose and the rest of the polyurethane resin.

여기에서, 상기 폴리에스테르 수지는 에틸렌글리콜과 테레프탈산으로부터 생성되는 긴 사슬구조를 갖는 내화학성이 뛰어난 수지로서 본 발명에서는 충전사의 외피를 구성하게 된다.Here, the polyester resin is a resin having a long-chain structure produced from ethylene glycol and terephthalic acid and excellent in chemical resistance, and constitutes the outer shell of the filled yarn in the present invention.

그리고, 상기 자일리톨과 에리스리톨은 당알코올로 수분과 반응하여 흡열반응을 일으켜 주변의 열을 빼앗아 냉감성을 느끼게 하며, 또한 피부와 접촉시에는 강한 청량감(시원한 느낌)을 주므로 이러한 청량감 확보와 흡열에 따른 냉감성 확보를 위해 첨가된다.In addition, xylitol and erythritol react with moisture with sugar alcohol to cause an endothermic reaction, thereby depriving the surrounding heat of the sensation of coldness, and giving a strong cooling sensation (cool feeling) upon contact with the skin, It is added for securing cold sensibility.

아울러, 상기 멘톨(Menthol)과 DL-Camphor(DL-캄파)는 혈관을 확장시켜 시원한 느낌을 주는 청량감을 강화시킴으로써 냉감기능을 증대시키기 위해 첨가된다.In addition, the menthol and DL-camphor (DL-campa) are added to enhance cold sensation by enhancing a cooling sensation that expands blood vessels and gives a cool feeling.

또한, 상기 DBNPA(2,2-Dibromo-3-nitrilopropionamide)는 액상 항균제로서 알카리 환경에서도 항균 특성이 우수한 물질로서, 특히 포도상구균, 대장균, 폐렴균 및 진드기와 곰팡이에 대한 항균특성이 매우 우수한 것으로 알려져 있다.The above-mentioned DBNPA (2,2-Dibromo-3-nitrilopropionamide) is a liquid antimicrobial agent having excellent antimicrobial properties even in an alkaline environment, and is known to have excellent antimicrobial properties especially against Staphylococcus, Escherichia coli, Pneumococcus and mites and fungi .

따라서, 본 발명에서는 액상 항균제가 바인더인 폴리우레탄 수지에 완전히 점착되어 외피를 통해 미세하게 오랜시간동안 서서히 방출됨으로써 원단의 수명이 다할 때까지 항균특성을 유지할 수 있도록 구성된다. 이것은 후술하는 바와 같이, 외피에 충전된 기능성 충전물이 마이크로 크기의 물줄기를 통해 워터젯 가공된 표면의 미세한 바늘구멍에 의해 달성될 수 있다.Therefore, in the present invention, the liquid antimicrobial agent is completely adhered to the polyurethane resin as a binder and gradually released for a long time through the skin, thereby maintaining the antibacterial property until the life of the fabric is completed. This can be accomplished by fine needle holes in the surface of the water-jetted functional filler through a micro-sized stream, as described below.

아울러, 상기 원적외선 방출용 소결성 분쇄물은 통상적으로 알려진 숯이나 토르말린, 제올라이트, 맥반석 등을 사용하지 않고 특별히 가공된 것으로서, 이것은 2500-3000nm 파장 대역의 파장을 진동시키도록 유도하여 이 파장대역에 반응하는 혈류의 순환을 촉진하기 위한 것이다. 또한, 이 분쇄물은 실험결과 악취를 분해 제거하는 특성도 있음이 확인되었다.In addition, the sintered pulverized product for far-infrared ray emission is specially processed without using charcoal, tourmaline, zeolite, or quartz, which is known in the art. It induces a wavelength of 2500-3000 nm to vibrate and reacts to this wavelength band To promote circulation of blood flow. In addition, it was confirmed that the crushed material had a characteristic of decomposing and removing odor as a result of the experiment.

이러한 원적외선 방출용 소결성 분쇄물은 산화규소 20중량%, 붕산 10중량%, 초산 10중량%, 산화아연 20중량%, 바륨 10중량%, 산화코발트 10중량%, 지르코늄 10중량%, 산화티타늄 10중량%를 혼합교반한 후 1500℃에서 용융 소결한 다음 1-2㎛의 입도로 분쇄한 것이다.The sinterable pulverized product for far-infrared ray emission is composed of 20 weight% of silicon oxide, 10 weight% of boric acid, 10 weight% of acetic acid, 20 weight% of zinc oxide, 10 weight% of barium, 10 weight% of cobalt oxide, 10 weight% of zirconium, % Were mixed and stirred, and the mixture was melt-sintered at 1500 DEG C and then pulverized to a particle size of 1-2 mu m.

이들 성분들은 원적외선 방출 기능을 갖는 것들과, 방출되는 원적외선을 상기 파장대역으로 유지시키는 성분들이 상보기능하도록 구성된 것이다.These components are configured such that those having a far-infrared ray emitting function and those for keeping the far-infrared rays emitted in the wavelength band complement each other.

따라서, 이들의 효용성을 높이기 위해 본 발명에서는 이들 혼합물을 용융 소결한 후 분쇄하여 초미분 상태로 투입하여 사용토록 한다.Therefore, in order to enhance their utility, the mixture is sintered, pulverized and put into an ultra-fine powder state to be used in the present invention.

또한, 상기 냉감성을 갖는 수용액은 물 70중량%에 빙초산(Glacial Acetic Acide) 15중량%, 리튬브로마이드(LiBr) 15중량%를 녹인 것을 사용한다.The aqueous solution having a cold sensibility is prepared by dissolving 15% by weight of glacial acetic acid and 15% by weight of lithium bromide (LiBr) in 70% by weight of water.

이때, 빙초산은 어느점이 14.5℃ 이상으로서 상온에서도 어는 특성이 있어 냉감성을 강화시키며, 리튬브로마이드는 흡습성이 매우 커 주변의 수분을 끌어 당기면서 냉감성을 증대시키므로 첨가 사용된다.At this time, glacial acetic acid has a characteristic of freezing at 14.5 ° C or higher at room temperature and strengthens the cold sensibility. Lithium bromide is added because it is highly hygroscopic and attracts moisture from the surroundings and increases cold sensibility.

아울러, 상기 페닐트리메톡시실란은 일종의 실란커플링제로서, 소수화 특성도 가져 내습성은 물론 발수성도 제공하며, 특히 본 발명의 기능성 충전물의 바인더로 첨가되는 폴리우레탄수지와, 상기 외피를 구성하는 폴리에스테르수지간의 접합특성을 강화시켜 일체화되게 작용하며, 내열성도 확보하기 위해 첨가된다.In addition, the phenyltrimethoxysilane is a silane coupling agent having hydrophobicity and moisture resistance as well as water repellency. In particular, the phenyltrimethoxysilane is a polyurethane resin added as a binder of the functional filler of the present invention and a poly Ester resin is added to strengthen the bonding property between the ester resin and the ester resin, and to ensure heat resistance.

또한, 상기 시트로넬라(citronella) 오일은 방충성을 높이고, 점도 조절 및 배합성을 촉진하기 위해 첨가된다.In addition, the citronella oil is added to enhance the insect repellency and to promote viscosity control and embryogenesis.

뿐만 아니라, 상기 하이드록시프로필메틸셀룰로우즈는 상기 기능성 충전물의 신축변형성과 굴신성을 높이기 위해 첨가된다.In addition, the hydroxypropyl methylcellulose is added to enhance the elastic constancy and oyster of the functional filler.

마지막으로, 상기 폴리우레탄 수지는 앞서 설명하여듯이, 기능성 충전물들을 바인딩시켜 점결화되게 일체화시키기 위해 첨가된다.Finally, the polyurethane resin is added as described above to integrate the functional fillers by binding and dotting them.

이와 같은 구성을 갖는 충전사를 제조하는 방법은, 먼저 상술한 기능성 충전물을 조성하는 제1단계; 상기 제1단계 후 이중다이스를 통해 기능성 충전물과 외피를 구성하는 폴리에스테르 수지를 방출하면서 정해진 데이어를 갖는 외피 및 외피에 충전된 기능성 충전물 구조의 충전사를 만드는 제2단계; 그리고 제2단계 후 인출되는 충전사가 냉각되기 전에 마이크로 단위의 워터젯(Water Jet)에 통과시켜 충전사의 둘레에 미세한 바늘구성을 형성하는 제3단계; 제3단계 후 액상의 나노 티타늄옥사이드에 함침시켜 바늘구성에 나노 티타늄옥사이드가 쐐기상으로 박히도록 하는 제4단계;를 통해 이루어진다.A method for manufacturing a packed yarn having such a structure includes: a first step of first forming the functional filler described above; A second step of making a filling yarn of a functional filling structure filled in an outer shell and an outer shell having predetermined dies while discharging a functional resin and a polyester resin constituting the outer shell through the double dies after the first step; And a third step of forming a fine needle structure around the filling yarn by passing the filling yarn after the second step through a water jet of a micro unit before the filling yarn is cooled down; And a fourth step of impregnating the liquid nano titanium oxide after the third step so that the nano titanium oxide is embedded in the wedge shape in the needle structure.

이렇게 제조하는 이유는 보통 티타늄옥사이드가 자외선을 분산 교란시켜 자외선이 피부에 닫지 못하도록 억제하는 용도로 화장품에 주로 첨가되지만, 본 발명에서는 용출량 조절특성 및 항균성 특성을 강화하기 위한 것으로 충전사의 바늘구멍에 쐐기상으로 박혀 있으면서 바늘구멍을 통한 내부 기능성 충전물이 단시간에 빠져나가지 못하고 미세하게 용출되도록 하여 기능성 충전물의 특성이 장기간 동안 발현되게 하면서 용출량 조절특성이 함께 표출되게 하기 위함이다.The reason for this is that titanium oxide is usually added to cosmetics in order to disperse ultraviolet rays to disturb the ultraviolet rays and to prevent ultraviolet rays from clogging the skin. In the present invention, in order to enhance the elution rate control property and antibacterial property, So that the internal functional filler through the needle hole can not escape in a short time and can be eluted finely so that the characteristics of the functional filler can be exhibited for a long period of time while exhibiting the controllability of the elution amount.

이러한 방법으로 제조된 충전사를 이용하여 표면사와 이면사 사이에 배치된 삼중직원단을 직조하여 만들고, 이를 사용하게 되면 용출량 조절이 확보되고, 항균성이 강화되어 곰팡이, 진득이는 물론 포도상구균, 대장균, 폐렴균 등을 사멸할 수 있을 뿐만 아니라, 세탁시에도 기능성 충전물이 외피로 감싸져 있기 때문에 세제나 표백제로부터 영향을 받지 않아 기능 표출의 장수명화를 달성할 수 있다.By using the filling yarn manufactured by this method, the triple staff member disposed between the surface yarn and the back yarn is woven, and when it is used, the amount of elution can be controlled, and the antimicrobial property is strengthened so that staphylococcus, Pneumococci and the like can be killed, and since the functional packing is wrapped in the outer skin even during washing, the effect of the detergent or the bleaching agent is not affected and the longevity of the functional expression can be achieved.

뿐만 아니라, 원적외선 방출은 인체의 혈류 촉진에 따른 건강증진에 기여하며, 냉감 특성은 혹서기 인체 활동성을 높여 준다.In addition, the far-infrared radiation contributes to health promotion by promoting the blood flow of the human body, and the cold feeling characteristic enhances the human activity during the hot period.

이에 더하여, 오염물질에 대한 분산작용, 연화작용을 강화시키기 위해 상기 기능성 충전물에는 상기 폴리우레탄수지 100중량부를 기준으로 이온결정 구조를 갖는 규산나트륨의 수화물인 오르토규산나트륨을 3중량부 더 첨가할 수 있고, 또한 열분해되는 것을 최대한 억제하고 쉽게 변질되지 않도록 하여 형상 유지성을 높이기 위해 리시놀레인산 바륨을 3중량부 더 첨가할 수 있다.In addition, in order to enhance the dispersing action and softening action on the contaminant, 3 weight parts of sodium orthosilicate which is a hydrate of sodium silicate having an ionic crystal structure based on 100 weight parts of the polyurethane resin may be added to the functional filler 3 parts by weight of barium ricinoleate may be further added so as to suppress the pyrolysis to the greatest extent and to prevent deterioration easily and to improve the shape retentivity.

이하, 실시예에 대하여 설명한다.Hereinafter, examples will be described.

[실시예 1][Example 1]

자일리톨과 에리스리톨이 1:1의 중량비로 혼합된 제1혼합물 10중량%; 멘톨(Menthol)과 DL-Camphor(DL-캄파)가 1:1의 중량비로 혼합된 제2혼합물 5중량%; DBNPA(2,2-Dibromo-3-nitrilopropionamide) 5중량%; 산화규소 20중량%, 붕산 10중량%, 초산 10중량%, 산화아연 20중량%, 바륨 10중량%, 산화코발트 10중량%, 지르코늄 10중량%, 산화티타늄 10중량%를 혼합교반한 후 1500℃에서 용융 소결한 다음 1-2㎛의 입도로 분쇄한 원적외선 방출용 소결성 분쇄물 15중량%; 물 60중량%에 우레아(Urea) 34중량%, 육수화질산아연(Zn(NO3)2ㆍ6H2O) 2중량% 및 물 70중량%에 빙초산(Glacial Acetic Acide) 15중량%, 리튬브로마이드(LiBr) 15중량%를 녹인 냉감성을 갖는 수용액 20중량%; 페닐트리메톡시실란 5중량%; 시트로넬라(citronella) 오일 3중량%; 하이드록시프로필메틸셀룰로우즈 2중량% 및 나머지 폴리우레탄수지로 이루어진 기능성 충전물을 폴리에스테르 수지로 된 외피에 충전시켜 충전사를 만들고, 이 충전사를 폴리에스테르 수지로 된 이면사와 표면사 사이에 배치되게 3중 직조하여 제1시료인 삼중직원단을 만들었다.10% by weight of a first mixture of xylitol and erythritol in a weight ratio of 1: 1; 5 wt% of a second mixture of menthol (Menthol) and DL-Camphor (DL-Kamp) in a weight ratio of 1: 1; 5% by weight of DBNPA (2,2-Dibromo-3-nitrilopropionamide); 10 weight% of boric acid, 10 weight% of acetic acid, 20 weight% of zinc oxide, 10 weight% of barium, 10 weight% of cobalt oxide, 10 weight% of zirconium and 10 weight% of titanium oxide were mixed and stirred, 15 wt% of a sinterable pulverized product for far-infrared ray emission pulverized into particles having a particle size of 1-2 mu m after melt-sintering; A mixture of 34% by weight of Urea, 2% by weight of zinc (Zn (NO 3 ) 2 .6H 2 O) and 15% by weight of glacial acetic acid in 70% by weight of water, 20% by weight of an aqueous solution having a cold sensation characteristic in which 15% by weight of LiBr was dissolved; 5% by weight of phenyltrimethoxysilane; 3% by weight citronella oil; 2% by weight of hydroxypropyl methylcellulose and the remaining polyurethane resin was filled in a shell made of a polyester resin to prepare a filled yarn, and the filled yarn was placed between a back yarn made of a polyester resin and a surface yarn We made triple weave of the first sample.

[실시예 2][Example 2]

실시예 1과 동일하게 하되, 상기 기능성 충전물에 상기 폴리우레탄수지 100중량부를 기준으로 오르토규산나트륨 3중량부, 리시놀레인산 바륨 3중량부를 더 첨가하여 제2시료를 만들었다.3 parts by weight of sodium orthosilicate and 3 parts by weight of barium ricinoleate were added to the above-mentioned functional filler based on 100 parts by weight of the polyurethane resin to prepare a second sample.

[실시예 3][Example 3]

실시예 1과 동일하게 하되, 충전사는 워터젯처리 후 액상의 나노 티타늄옥사이드에 함침시킨 것을 사용하여 제3시료를 만들었다.The same procedure as in Example 1 was carried out except that the packed yarn was subjected to water jet treatment and impregnated with liquid nano-titanium oxide to prepare a third sample.

본 발명에 따른 충전사의 특성중 항균성을 테스트하기 위해, 제1,2,3시료 표면에 표면에 진균(Gliocladium virens ATCC 9645), 포도상구균(Staphylococcus aureus) 및 진득이를 노출시킨 다음에 이에 대한 항균 활성을 시험하였다.To test the antimicrobial properties among the characteristics of the packed yarn according to the present invention, the surfaces of the first, second and third samples were exposed to fungi (Gliocladium virens ATCC 9645), Staphylococcus aureus, Activity was tested.

시험은 균에 노출시킨 후 24시간이 경과한 시점에서 KICM-FIR-1002법으로 측정하여 항균력을 테스트하였고, 시험결과 각 시료에서 99.20%, 99.46%, 99.57%의 항균효과가 확인되었다.The test was conducted by KICM-FIR-1002 at 24 hours after exposure to the bacteria, and the antibacterial activity was tested. The antibacterial activity of each sample was 99.20%, 99.46%, and 99.57%.

그리고, 진득이는 모든 시료에서 모두 사멸되었다.And all the samples were killed.

또한, 원적외선 방출 기능을 확인하기 위해, FT-IR 스펙트로메터를 이용하여 KFIA-F1-1005에 의거 제1,2,3시료에 대한 원적외선 방사시험을 실시하였다.Further, in order to confirm the far-infrared ray emission function, far-infrared ray radiation tests were performed on the first, second and third samples according to KFIA-F1-1005 using an FT-IR spectrometer.

실시결과, 30℃에서 원적외선 방사율은 각각 0.813, 0.824, 0.859로 확인되었고, 방사에너지(W/㎡)도 2.43×102, 2.50×102, 2.69×102으로 각각 나타나 원적외선 방사효과가 있는 것으로 확인되었다.As a result, the far infrared ray emissivity at 30 ℃ was 0.813, 0.824 and 0.859, respectively, and the radiant energy (W / ㎡) was 2.43 × 10 2 , 2.50 × 10 2 and 2.69 × 10 2 , .

뿐만 아니라, 본 발명에 따른 충전사의 냉감성을 평가하기 위해 제1,2,3시료를 열풍에 의해 30℃로 유지되는 항습실에 각각 투입한 상태에서 열풍을 끄고 40분간 유지되게 하여 자연 냉각시켰다.In addition, in order to evaluate the cold sensibility of the filling yarn according to the present invention, the first, second, and third samples were put into a humidity chamber maintained at 30 캜 by hot air, respectively, and then kept hot for 40 minutes.

그런 다음, 적외선 온도계를 제1,2,3시료의 표면에 조사하여 냉감 여부를 확인하는 방식으로 진행하였으며, 시험결과 10분 경과시 제1,2,3시료의 표면온도는 각각 26.4℃, 25.7℃, 25.1℃였고, 20분 경과시에는 각각 24.1℃, 24.0℃, 23.4℃였으며, 30분 경과시에는 각각 22.3℃, 21.8℃, 20.9℃였다.Then, the infrared thermometer was irradiated to the surfaces of the first, second and third samples to check whether they were cold. As a result of the test, the surface temperatures of the first, second and third samples were 26.4 ° C and 25.7 ℃, and 25.1 ℃, respectively, and it was 24.1 ℃, 24.0 ℃ and 23.4 ℃ respectively for 20 minutes and 22.3 ℃, 21.8 ℃ and 20.9 ℃ respectively for 30 minutes.

이를 통해, 상당한 시간이 경과할수록 온도가 떨어지면서 냉감기능을 발현함을 확인할 수 있었다.As a result, it was confirmed that as the temperature was lowered over a considerable period of time, the cold feeling function appeared.

Claims (2)

표면사와 이면사 사이에 충전사가 배치되게 삼중 직조된 삼중직원단에 있어서;
상기 충전사는 외피와, 상기 외피에 충전되는 기능성 충전물로 이루어지되,
상기 외피는 폴리에스테르 수지로 이루어지고;
상기 기능성 충전물은 자일리톨과 에리스리톨이 1:1의 중량비로 혼합된 제1혼합물 10중량%, 멘톨(Menthol)과 DL-Camphor(DL-캄파)가 1:1의 중량비로 혼합된 제2혼합물 5중량%, DBNPA(2,2-Dibromo-3-nitrilopropionamide) 5중량%, 1-2㎛의 입도를 갖는 원적외선 방출용 소결성 분쇄물 15중량%, 냉감성을 갖는 수용액 10중량%, 페닐트리메톡시실란 5중량%, 시트로넬라(citronella) 오일 3중량%, 하이드록시프로필메틸셀룰로우즈 2중량% 및 나머지 폴리우레탄수지로 이루어진 것을 특징으로 하는 냉감기능을 갖는 기능성 삼중직원단.
In a triple-woven triplet so that a charged yarn is disposed between the surface yarn and the back yarn;
Wherein the filling yarn comprises a shell and a functional filler filled in the shell,
The shell is made of a polyester resin;
The functional packing consisted of 10 wt% of a first mixture of xylitol and erythritol in a weight ratio of 1: 1, 5 wt% of a second mixture of menthol and DL-Camphor (DL-Kamp) in a weight ratio of 1: 5% by weight of DBNPA (2,2-Dibromo-3-nitrilopropionamide), 15% by weight of a sinterable pulverized product for far-infrared ray emission having a particle size of 1-2 μm, 10% by weight of an aqueous solution having cold sensibility, 5% by weight of citronella oil, 3% by weight of citronella oil, 2% by weight of hydroxypropyl methylcellulose, and the rest of the polyurethane resin.
청구항 1에 있어서,
상기 원적외선 방출용 소결성 분쇄물은, 산화규소 20중량%, 붕산 10중량%, 초산 10중량%, 산화아연 20중량%, 바륨 10중량%, 산화코발트 10중량%, 지르코늄 10중량%, 산화티타늄 10중량%를 혼합교반한 후 1500℃에서 용융 소결한 다음 1-2㎛의 입도로 분쇄한 것이고;
상기 냉감성을 갖는 수용액은, 물 70중량%에 빙초산(Glacial Acetic Acide) 15중량%, 리튬브로마이드(LiBr) 15중량%를 녹인 것을 사용하는 것을 특징으로 하는 냉감기능을 갖는 기능성 삼중직원단.The method according to claim 1,
The sinterable pulverized product for far-infrared ray emission comprises 20 weight% of silicon oxide, 10 weight% of boric acid, 10 weight% of acetic acid, 20 weight% of zinc oxide, 10 weight% of barium, 10 weight% of cobalt oxide, 10 weight% of zirconium, % By weight, followed by melt-sintering at 1500 DEG C and then pulverizing to a particle size of 1-2 mu m;
Wherein the aqueous solution having a cold sensation is obtained by dissolving 15% by weight of glacial acetic acid and 15% by weight of lithium bromide (LiBr) in 70% by weight of water.
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KR101608406B1 (en) 2014-05-28 2016-04-04 벤텍스 주식회사 Refrigerant textile sheet having high moisture movement

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Publication number Priority date Publication date Assignee Title
KR102547844B1 (en) * 2022-12-28 2023-06-26 주식회사 유니온메디칼 Rack case for installation of high frequency generator of high frequency thermal cancer treatment device with cooling function

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