KR101968514B1 - Functional triple staff with fever function - Google Patents

Functional triple staff with fever function Download PDF

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KR101968514B1
KR101968514B1 KR1020170040269A KR20170040269A KR101968514B1 KR 101968514 B1 KR101968514 B1 KR 101968514B1 KR 1020170040269 A KR1020170040269 A KR 1020170040269A KR 20170040269 A KR20170040269 A KR 20170040269A KR 101968514 B1 KR101968514 B1 KR 101968514B1
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weight
functional
yarn
filler
function
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KR20180110545A (en
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엄기영
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지유코리아 주식회사
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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00—Double or multi-ply fabrics not otherwise provided for
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    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
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  • Engineering & Computer Science (AREA)
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  • Chemical Or Physical Treatment Of Fibers (AREA)
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Abstract

본 발명은 발열기능을 갖는 기능성 삼중직원단에 관한 것으로, 보다 상세하게는 방한성을 높인 이불, 옷감 등으로 사용되는 삼중직원단에 발열기능을 강화하고, 찐득이 방지, 항균성 및 원적외선 방출 기능을 높여 효용성을 증대시키면서 특히, 덮거나 착용시 발열 기능 강화에 따른 혈류개선을 통해 건강증진에 기여할 수 있는 발열기능을 갖는 기능성 삼중직원단에 관한 것이다.More specifically, the present invention relates to a functional triplet crew having a heat-generating function, and more particularly, to a triplet crew which is used for quilts and cloths having enhanced heat resistance, enhances a heat generating function, enhances anti-aging, antimicrobial and far- And more particularly, to a functional triplet staff having a fever function capable of contributing to health improvement through improvement of blood flow due to enhancement of fever function during covering or wearing.

Description

발열기능을 갖는 기능성 삼중직원단{Functional triple staff with fever function}Functional triple staff with fever function with fever function

본 발명은 발열기능을 갖는 기능성 삼중직원단에 관한 것으로, 보다 상세하게는 방한성을 높인 이불, 옷감 등으로 사용되는 삼중직원단에 발열기능을 강화하고, 찐득이 방지, 항균성 및 원적외선 방출 기능을 높여 효용성을 증대시키면서 특히, 덮거나 착용시 발열 기능 강화에 따른 혈류개선을 통해 건강증진에 기여할 수 있는 발열기능을 갖는 기능성 삼중직원단에 관한 것이다.More specifically, the present invention relates to a functional triplet crew having a heat-generating function, and more particularly, to a triplet crew which is used for quilts and cloths having enhanced heat resistance, enhances a heat generating function, enhances anti-aging, antimicrobial and far- And more particularly, to a functional triplet staff having a fever function capable of contributing to health improvement through improvement of blood flow due to enhancement of fever function during covering or wearing.

생활수준이 향상되면서 기존의 의류 개념을 넘어서 인체를 더욱 편안하게 하고 쾌적하게 하면서 외관상 심미적기능을 갖는 기능성을 갖는 의류를 생산할 수 있는 원단의 출현이 기대되고 있으며, 섬유제조업체에서도 이와 같은 시장의 요구에 앞서 더 향상된 기능의 원사 및 원단을 출시하고 있다.As the level of living has improved, it has been expected that fabrics that can produce apparel having functionalities with aesthetic functions in appearance while making the human body more comfortable and comfortable beyond the conventional clothing concept are expected to appear. We are introducing more advanced yarns and fabrics.

최근에는 합성섬유의 고기능화는 천연섬유의 취약점을 보완하는 물성의 개선과 동시에 합성섬유의 장점을 극대화시키는 방향으로 전개가 되고 있다.In recent years, functionalization of synthetic fibers has been developed to maximize the advantages of synthetic fibers while improving physical properties that complement weakness of natural fibers.

그 대표적인 기능성 소재로는 속건, 제전, 자외선 차단 기능이 부여된 직물 및 이의 이차적 섬유제품 등이다.Representative functional materials include quick-drying, antistatic, ultraviolet-shielding fabrics and secondary textile products.

이와 같은 의류에 기능성을 부여하기 위한 기능성 섬유소재는 크게 흡수성을 높이거나 흡수속건 기능의 수분을 제어하는 섬유소재, 겨울용인 발열기능의 보온성 또는 여름용인 냉감성 등의 온도를 제어하는 섬유소재, 원적외선이나 음이온 등 몸에 이로운 에너지를 방사는 섬유소재, 질병의 치료나 완화 기능을 갖는 의류용 섬유소재 등 다양한 기능성 섬유소재가 현재 개발되고 출시되고 있다.The functional fiber material for imparting functionality to such a garment may be a fiber material that largely improves the absorbency or controls the moisture of the quick-drying absorbent function, a fiber material that controls the temperature such as the warmth of the winter heat function or the cold sensibility of the summer, A variety of functional fiber materials such as textile materials that emit energy beneficial to the body such as anion and anion, and textile materials that have the function of treating or alleviating diseases are currently being developed and released.

이러한 다양한 기능성 섬유소재 중 온도를 제어하는 섬유소재는 다양한 기능성물질의 개발로 이를 통한 섬유에 함유시키거나 원단에 프린팅하는 방법으로 많은 발전이 되어왔다.Among these various functional fiber materials, the temperature controlling fiber material has been developed as a method of developing various functional materials to be contained in fibers or printing on fabrics.

특히, 항균성을 부여하여 인체 유해성을 줄인 기술들도 개시되고 있으나, 이들 대부분은 단순히 섬유, 즉 원사에 항균제를 코팅하는 수준이기 때문에 세탁시 표백제나 세제류 등에 의해 벗겨지거나 혹은 용출되어 없어져 버리는 문제로 인해 항균효과를 지속시키기 어렵다는 한계를 가지고 있다.In particular, techniques for reducing the harmfulness of human body by imparting antimicrobial properties have been disclosed, but most of them are merely coated with fibers, that is, the yarn is coated with an antimicrobial agent, so that it is peeled off or leached out by bleaching agents or detergents It is difficult to maintain the antimicrobial effect.

또한, 겨울용인 발열기능의 보온성 원단은 3중직 방식을 구현하고 있으나, 단순히 섬유가 겹을 이루도록 3중 직조하는 방식이라 차열성을 높인 단순 보온성에 불과할 뿐 잠열에 따른 발열 보온 기능에 미치지 못하므로 혹한기, 외부 작업자들이 착용하거나 혹은 추운 곳에서 덮는 이불로 사용될 경우 방한에 따른 체온 유지 기능이 미비하다는 한계를 가지고 있다.In addition, although the heat-resistant fabric for winter function is implemented in a triple-stitched manner, it is merely a simple warmth which increases the heat resistance due to the method of triple weaving so that the fibers are folded, When used as an outdoor worker's bedding or in a cold-covered bedding, there is a limit to the ability to maintain body temperature due to cold weather.

대한민국 공개특허 제10-2001-0007755호(2001.02.05), '3중직 직물의 제직방법 및 3중직 직물'Korean Patent Laid-Open No. 10-2001-0007755 (Feb. 22, 2001), 'Method of Weaving Three-Dimensional Fabrics and Three- 대한민국 특허 등록번호 제10-0865713호(2008.10.22.), '3중직 파일원단 제조방법 및 그 3중직 파일원단'Korean Patent Registration No. 10-0865713 (Oct. 22, 2008), 'Method for manufacturing three-dimensional filament fabrics and its three- 대한민국 특허 등록번호 제10-1372929호(2014.03.05.), '축열기능과 이면소프트성이 우수한 3층 구조 보온성 원단'Korea Patent Registration No. 10-1372929 (Apr. 31, 2014), "Three-layer structure with excellent heat storage function and softness on the back" 대한민국 특허 등록번호 제10-1434842호(2014.08.21.), '전도성천연원사 및 이를 이용한 직물 발열체'Korean Patent Registration No. 10-1434842 (Aug. 21, 2014), "Conductive Natural Yarn and Fabric Heating Element Using the Same" 대한민국 특허 등록번호 제10-1689289호(2016.12.19), '발열 페이스트 조성물을 이용한 발열 코팅사 제조방법'Korean Patent Registration No. 10-1689289 (Dec. 19, 2016), a method of producing an exothermic coating yarn using an exothermic paste composition,

본 발명은 상술한 바와 같은 종래 기술상의 제반 문제점들을 감안하여 이를 해결하고자 창출된 것으로, 방한성을 높인 이불, 옷감 등으로 사용되는 삼중직원단에 발열기능을 강화하고, 찐득이 방지, 항균성 및 원적외선 방출 기능을 높여 효용성을 증대시키면서 특히, 덮거나 착용시 발열 기능 강화에 따른 혈류개선을 통해 건강증진에 기여할 수 있는 발열기능을 갖는 기능성 삼중직원단을 제공함에 그 주된 목적이 있다.The present invention has been made in view of the above-described problems in the prior art, and it is an object of the present invention to provide a threefold staff member, which is used for quilts and cloths having enhanced cold resistance, The main purpose of the present invention is to provide a functional triplet staff member having a fever function capable of contributing to health promotion by improving function and increasing utility, and particularly improving blood flow due to enhancement of fever function during covering or wearing.

본 발명은 상기한 목적을 달성하기 위한 수단으로, 표면사와 이면사 사이에 충전사가 배치되게 삼중 직조된 삼중직원단에 있어서; 상기 충전사는 충전사용 쉘과, 상기 충전사용 쉘에 충전되는 기능성 충전물로 이루어지되, 상기 충전사용 쉘은 폴리에스테르 수지로 이루어지고; 상기 기능성 충전물은 옥틸 메톡시 시너메이트(Octyl MethoxyCinnamate)액 15중량%, DBNPA(2,2-Dibromo-3-nitrilopropionamide) 5중량%, 1-2㎛의 입도를 갖는 원적외선 방출용 분쇄물 15중량%, 축열성을 갖는 잠열용액(Lantent Liquid) 20중량%, 페닐트리메톡시실란 5중량%, 시트로넬라(citronella) 오일 3중량%, 하이드록시프로필메틸셀룰로우즈 2중량% 및 나머지 폴리우레탄수지로 이루어진 것을 특징으로 하는 발열기능을 갖는 기능성 삼중직원단을 제공한다.In order to achieve the above-mentioned object, the present invention provides a triple-woven tri-folded sewing machine in which a filling yarn is disposed between a surface yarn and a back yarn, Wherein the filling yarn comprises a filling use shell and a functional filling to be filled in the filling use shell, wherein the filling use shell is made of a polyester resin; 15 wt% of Octyl Methoxy Cinnamate solution, 5 wt% of 2,2-Dibromo-3-nitrilopropionamide (DBNPA), 15 wt% of pulverized far infrared rays having a particle size of 1-2 mu m, 20% by weight of a latent heat liquid having a thermo-setting property, 5% by weight of phenyltrimethoxysilane, 3% by weight of citronella oil, 2% by weight of hydroxypropyl methylcellulose, The present invention provides a triple functioning functional unit having a heat generating function.

이때, 상기 원적외선 방출용 분쇄물은, 산화규소 20중량%, 붕산 10중량%, 초산 10중량%, 산화아연 20중량%, 바륨 10중량%, 산화코발트 10중량%, 지르코늄 10중량%, 산화티타늄 10중량%를 혼합교반한 후 1500℃에서 용융 냉각한 다음 1-2㎛의 입도로 분쇄한 것이고; 상기 축열성을 갖는 잠열용액은, 물 60중량%에 우레아(Urea) 34중량%를 녹이고, 여기에 육수화질산아연(Zn(NO3)2ㆍ6H2O) 2중량% 및 아세트산나트륨(CH3COONaㆍ3H2O) 4중량%를 투입하여 만든 것을 사용하는 것에도 그 특징이 있다.The pulverized material for far-infrared ray emission comprises 20 wt% of silicon oxide, 10 wt% of boric acid, 10 wt% of acetic acid, 20 wt% of zinc oxide, 10 wt% of barium, 10 wt% of cobalt oxide, 10% by weight were mixed and stirred, then melt-cooled at 1500 占 폚 and then ground to a particle size of 1-2 占 퐉; The latent heat solution having the thermostability was prepared by dissolving 34% by weight of urea in 60% by weight of water, adding 2% by weight of zinc sulfate (Zn (NO 3 ) 2 .6H 2 O) and sodium acetate 3 COONa and 3H 2 O) 4 to the use of that made by putting a weight percent are also characterized in that.

본 발명에 따르면, 방한성을 높인 이불, 옷감 등으로 사용되는 삼중직원단에 발열기능을 강화하고, 찐득이 방지, 항균성 및 원적외선 방출 기능을 높여 효용성을 증대시키면서 특히, 덮거나 착용시 발열 기능 강화에 따른 혈류개선을 통해 건강증진에 기여하는 효과를 얻을 수 있다.According to the present invention, it is possible to enhance the heat-generating function of a triple staff member used for quilts and cloths having enhanced cold resistance, enhance the utility by enhancing the anti-aging effect, anti- Thereby contributing to health promotion.

이하에서는, 본 발명에 따른 바람직한 실시예를 보다 상세하게 설명하기로 한다.Hereinafter, preferred embodiments according to the present invention will be described in detail.

본 발명 설명에 앞서, 이하의 특정한 구조 내지 기능적 설명들은 단지 본 발명의 개념에 따른 실시예를 설명하기 위한 목적으로 예시된 것으로, 본 발명의 개념에 따른 실시예들은 다양한 형태로 실시될 수 있으며, 본 명세서에 설명된 실시예들에 한정되는 것으로 해석되어서는 아니된다.Before describing the present invention, the following specific structural or functional descriptions are merely illustrative for the purpose of describing an embodiment according to the concept of the present invention, and embodiments according to the concept of the present invention may be embodied in various forms, And should not be construed as limited to the embodiments described herein.

또한, 본 발명의 개념에 따른 실시예는 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있으므로, 본 발명의 사상 및 기술 범위에 포함되는 모든 변경물, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다.In addition, it should be understood that the embodiments according to the concept of the present invention include various modifications, equivalents, and alternatives included in the spirit and technical scope of the present invention, .

먼저, 3중직 원단은 방한용으로 널리 사용되는 직물로서, 아주 일반적인 초기 개념은 세 겹의 직물을 서로 포갠 상태로 재봉하여 누빈 형태지만 이것은 방한성, 즉 보온성이 떨어지기 때문에 본 발명에서는 원사를 처음부터 3중으로 직조한 형태로서 봉제(누비)한 것이 아닌 직조한 구조의 3중직 원단이다.First, the triple-woven fabrics are widely used for cold weather. In a very general initial concept, the triple-layered fabrics are sewn together to form a quilted fabric, but since they have low heat resistance, It is a triple-woven fabric of a woven structure that is not sewn (quilted).

즉, 본 발명은 표면사, 이면사, 충전사로 나뉘어 이 3가지 원사가 직조되어 이루어진 3중직 원단으로서, 충전사는 표면사와 이면사 사이에 배치된다. 즉, 표면사와 이면사가 교차하는 부분에 상하로 엇갈리게 충전사가 배치된다.That is, the present invention is a three-ply fabric having a surface yarn, a backing yarn, and a filling yarn, wherein the three yarns are woven, and the filling yarn is disposed between the surface yarn and the back yarn. That is, the filling yarns are arranged in the upper and lower portions alternately at the portions where the surface yarns and the back yarns intersect.

이때, 상기 표면사와 이면사는 제품의 종류에 따라 다양한 원사가 선택 사용되는데, 이를 테면 폴리에스터사, 폴리에틸렌사 등 다양한 원사가 될 수 있다.At this time, the surface yarns and the back yarns may be selected from a variety of yarns depending on the type of product, such as polyester yarns and polyethylene yarns.

또한, 상기 충전사도 다양한 원사를 사용할 수 있지만, 본 발명에서는 발열기능(잠열기능), 진득이 방지기능, 항균기능, 원적외선 발산기능을 갖도록 충전사를 구성하는 원사 자체를 다음과 같이 배합하여 방사함으로써 충전사를 제조한다.In the present invention, the yarn itself constituting the filled yarn is blended and emulsified as follows so as to have a heat generating function (latent heat function), an anti-jamming function, an antibacterial function and a far-infrared ray diverging function To prepare a charged yarn.

즉, 본 발명에 따른 충전사는 충전사용 쉘과 상기 충전사용 쉘에 충전되는 기능성 충전물로 이루어진다.That is, the filler according to the present invention comprises a filler shell and a functional filler filled in the filler shell.

이러한 충전사는 이중다이스를 이용하여 기능성 충전물을 방출하면서 그 밖을 감싸도록 충전사용 쉘 소재를 방출하여 충전사용 쉘이 충전물을 감싸는 형태가 되도록 만들어진다.Such a filler yarn is made such that the filler shell surrounds the filler by releasing the filler shell material to surround the other while discharging the functional filler by using a double die.

이때, 상기 충전사용 쉘은 폴리에스테르 수지이고, 상기 기능성 충전물은 옥틸 메톡시 시너메이트(Octyl MethoxyCinnamate)액 15중량%, DBNPA(2,2-Dibromo-3-nitrilopropionamide) 5중량%, 1-2㎛의 입도를 갖는 원적외선 방출용 분쇄물 15중량%, 축열성을 갖는 잠열용액(Lantent Liquid) 20중량%, 페닐트리메톡시실란 5중량%, 시트로넬라(citronella) 오일 3중량%, 하이드록시프로필메틸셀룰로우즈 2중량% 및 나머지 폴리우레탄수지로 이루어진다.In this case, the filling-use shell is a polyester resin, and the functional packing is composed of 15% by weight of octyl methoxy cinnamate solution, 5% by weight of DBNPA (2,2-Dibromo-3-nitrilopropionamide) 15 wt% of a far infrared ray-emitting powder having a particle size of 20 wt%, a latent heat liquid having a heat-shrinking property (Lantent Liquid) 20 wt%, phenyltrimethoxysilane 5 wt%, citronella oil 3 wt% 2% by weight of methylcellulose and the rest of the polyurethane resin.

여기에서, 상기 폴리에스테르 수지는 에틸렌글리콜과 테레프탈산으로부터 생성되는 긴 사슬구조를 갖는 수지로서, 수분은 거의 흡수하지 않는 특성을 가지며, 내화학성이 뛰어난 수지로서 본 발명에서는 충전사의 충전사용 쉘을 구성하게 된다.Here, the polyester resin is a resin having a long chain structure formed from ethylene glycol and terephthalic acid, and has a property of hardly absorbing moisture, and is a resin excellent in chemical resistance. In the present invention, do.

그리고, 상기 옥틸 메톡시 시너메이트액은 시너메이트를 코코넛 오일에 녹인 액상의 자외선 흡수제로서 자외선을 흡수하여 열로 전환시킴으로써 발열기능을 강화시키기 위해 첨가된다.The octyl methoxycinnamate liquid is added as a liquid ultraviolet absorber in which cinnamate is dissolved in coconut oil so as to enhance heat-generating function by absorbing ultraviolet light and converting it into heat.

또한, 상기 DBNPA(2,2-Dibromo-3-nitrilopropionamide)는 액상 항균제로서 알카리 환경에서도 항균 특성이 우수한 물질로서, 특히 포도상구균, 대장균, 폐렴균 및 진드기와 곰팡이에 대한 항균특성이 매우 우수한 것으로 알려져 있다.The above-mentioned DBNPA (2,2-Dibromo-3-nitrilopropionamide) is a liquid antimicrobial agent having excellent antimicrobial properties even in an alkaline environment, and is known to have excellent antimicrobial properties especially against Staphylococcus, Escherichia coli, Pneumococcus and mites and fungi .

따라서, 본 발명에서는 액상 항균제가 바인더인 폴리우레탄 수지에 완전히 점착되어 충전사용 쉘을 통해 미세하게 오랜시간동안 서서히 방출됨으로써 원단의 수명이 다할 때 까지 항균특성을 유지할 수 있도록 구성된다. 이것은 후술하는 바와 같이, 충전사용 쉘에 충전된 기능성 충전물이 마이크로 크기의 물줄기를 통해 워터젯 가공된 표면의 미세한 바늘구멍에 의해 달성될 수 있다.Accordingly, in the present invention, the liquid antimicrobial agent is completely adhered to the polyurethane resin as the binder and slowly released for a long time through the packed shell, so that the antimicrobial properties can be maintained until the life of the fabric is completed. This can be accomplished by a fine needle hole in the surface of the water-jetted functional filler filled in the filler shell, as described below, through a micro-sized stream.

아울러, 상기 원적외선 방출용 분쇄물은 통상적으로 알려진 숯이나 토르말린, 제올라이트, 맥반석 등을 사용하지 않고 특별히 가공된 것으로서, 이것은 2500-3000nm 파장 대역의 파장을 진동시키도록 유도하여 이 파장대역에 반응하는 혈류의 순환을 촉진하기 위한 것이다. 또한, 이 분쇄물은 실험결과 악취를 분해 제거하는 특성도 있음이 확인되었다.The pulverized product for far-infrared ray emission is specially processed without using charcoal, tourmaline, zeolite, quartz stone or the like which is conventionally known. It is induced to vibrate the wavelength band of 2500-3000 nm, To promote the circulation of. In addition, it was confirmed that the crushed material had a characteristic of decomposing and removing odor as a result of the experiment.

이러한 원적외선 방출용 분쇄물은 산화규소 20중량%, 붕산 10중량%, 초산 10중량%, 산화아연 20중량%, 바륨 10중량%, 산화코발트 10중량%, 지르코늄 10중량%, 산화티타늄 10중량%를 혼합교반한 후 1500℃에서 용융 냉각한 다음 1-2㎛의 입도로 분쇄한 것이다.The pulverized product for far-infrared ray emission comprises 20 wt% of silicon oxide, 10 wt% of boric acid, 10 wt% of acetic acid, 20 wt% of zinc oxide, 10 wt% of barium, 10 wt% of cobalt oxide, 10 wt% of zirconium, Followed by melt-cooling at 1500 DEG C, followed by pulverization at a particle size of 1-2 mu m.

이들 성분들은 원적외선 방출 기능을 갖는 것들과, 방출되는 원적외선을 상기 파장대역으로 유지시키는 성분들이 상보기능하도록 구성된 것이다.These components are configured such that those having a far-infrared ray emitting function and those for keeping the far-infrared rays emitted in the wavelength band complement each other.

따라서, 이들의 효용성을 높이기 위해 본 발명에서는 이들 혼합물을 용융 냉각한 후 분쇄하여 초미분 상태로 투입하여 사용토록 한다.Therefore, in order to enhance their utility, the mixture is melt-cooled, pulverized and put into an ultra-fine powder state.

또한, 상기 잠열용액은 물 60중량%에 우레아(Urea) 34중량%를 녹이고, 여기에 육수화질산아연(Zn(NO3)2ㆍ6H2O) 2중량% 및 아세트산나트륨(CH3COONaㆍ3H2O) 4중량%를 투입하여 만든 것이다.The latent heat solution was prepared by dissolving 34 wt% of urea in 60 wt% of water and adding 2 wt% of zinc sulfate (Zn (NO 3 ) 2 .6H 2 O) and sodium acetate (CH 3 COONa 3H 2 O).

이때, 우레아는 상변화성물질로서 잠열 특성이 있고, 육수화질산아연과 아세트산나트륨은 공융점 형성에 따른 축열성 강화 기능이 있어 열보지성을 높이기 위해 본 발명에 의해 특정된 것이다.At this time, urea has a latent heat characteristic as a phase-transforming substance, and zinc and sodium acetate of the hydrographic quality are specified by the present invention in order to enhance the heat retention due to the function of strengthening the thermoregulation by the formation of the eutectic point.

아울러, 상기 페닐트리메톡시실란은 일종의 실란커플링제로서, 소수화 특성도 가져 내습성은 물론 발수성도 제공하며, 특히 본 발명의 기능성 충전물의 바인더로 첨가되는 폴리우레탄수지와, 상기 충전사용 쉘을 구성하는 폴리에스테르수지간의 접합특성을 강화시켜 일체화되게 작용하며, 내열성도 확보하기 위해 첨가된다.In addition, the phenyltrimethoxysilane is a kind of silane coupling agent, which has hydrophobicity and moisture resistance as well as water repellency. In particular, a polyurethane resin added as a binder of the functional filler of the present invention, Which is added to reinforce the bonding properties between the polyester resins and to ensure the heat resistance.

또한, 상기 시트로넬라(citronella) 오일은 방충성을 높이고, 점도 조절 및 배합성을 촉진하기 위해 첨가된다.In addition, the citronella oil is added to enhance the insect repellency and to promote viscosity control and embryogenesis.

뿐만 아니라, 상기 하이드록시프로필메틸셀룰로우즈는 상기 기능성 충전물의 신축변형성과 굴신성을 높이기 위해 첨가된다.In addition, the hydroxypropyl methylcellulose is added to enhance the elastic constancy and oyster of the functional filler.

마지막으로, 상기 폴리우레탄 수지는 앞서 설명하여듯이, 기능성 충전물들을 바인딩시켜 점결화되게 일체화시키기 위해 첨가된다.Finally, the polyurethane resin is added as described above to integrate the functional fillers by binding and dotting them.

이와 같은 구성을 갖는 충전사를 제조하는 방법은, 먼저 상술한 기능성 충전물을 조성하는 제1단계; 상기 제1단계 후 이중다이스를 통해 기능성 충전물과 충전사용 쉘을 구성하는 폴리에스테르 수지를 방출하면서 정해진 데이어를 갖는 충전사용 쉘 및 충전사용 쉘에 충전된 기능성 충전물 구조의 충전사를 만드는 제2단계; 그리고 제2단계 후 인출되는 충전사가 냉각되기 전에 마이크로 단위의 워터젯(Water Jet)에 통과시켜 충전사의 둘레에 미세한 바늘구성을 형성하는 제3단계; 제3단계 후 액상의 나노 티타늄옥사이드에 함침시켜 바늘구성에 나노 티타늄옥사이드가 쐐기상으로 박히도록 하는 제4단계;를 통해 이루어진다.A method for manufacturing a packed yarn having such a structure includes: a first step of first forming the functional filler described above; A second step of making a filling yarn of a functional filling structure filled in a filling use shell and a filling use shell having predetermined dies while discharging a polyester resin constituting the filling use shell through the double dies after the first step; ; And a third step of forming a fine needle structure around the filling yarn by passing the filling yarn after the second step through a water jet of a micro unit before the filling yarn is cooled down; And a fourth step of impregnating the liquid nano titanium oxide after the third step so that the nano titanium oxide is embedded in the wedge shape in the needle structure.

이렇게 제조하는 이유는 보통 티타늄옥사이드가 자외선을 분산 교란시켜 자외선이 피부에 닫지 못하도록 억제하는 용도로 화장품에 주로 첨가되지만, 본 발명에서는 용출량 조절특성 및 항균성 특성을 강화하기 위한 것으로 충전사의 바늘구멍에 쐐기상으로 박혀 있으면서 바늘구멍을 통한 내부 기능성 충전물이 단시간에 빠져나가지 못하고 미세하게 용출되도록 하여 기능성 충전물의 특성이 장기간 동안 발현되게 하면서 용출량 조절특성이 함께 표출되게 하기 위함이다.The reason for this is that titanium oxide is usually added to cosmetics in order to disperse ultraviolet rays to disturb the ultraviolet rays and to prevent ultraviolet rays from clogging the skin. In the present invention, in order to enhance the elution amount control property and antimicrobial property, So that the internal functional filler through the needle hole can not escape in a short time and can be eluted finely so that the characteristics of the functional filler can be exhibited for a long period of time while exhibiting the controllability of the elution amount.

이러한 방법으로 제조된 충전사를 이용하여 표면사와 이면사 사이에 배치된 삼중직원단을 직조하여 만들고, 이를 사용하게 되면 용출량 조절이 확보되고, 항균성이 강화되어 곰팡이, 진득이는 물론 포도상구균, 대장균, 폐렴균 등을 사멸할 수 있을 뿐만 아니라, 세탁시에도 기능성 충전물이 충전사용 쉘로 감싸져 있기 때문에 세제나 표백제로부터 영향을 받지 않아 기능 표출의 장수명화를 달성할 수 있다.By using the filling yarn manufactured by this method, the triple staff member disposed between the surface yarn and the back yarn is woven, and when it is used, the amount of elution can be controlled, and the antimicrobial property is strengthened so that staphylococcus, Pneumococci and the like can be killed. Also, since the functional filling material is wrapped in the filling use shell even when washing, it is not affected by the detergent or the bleaching agent, and the longevity of functional expression can be achieved.

뿐만 아니라, 원적외선 방출은 인체의 혈류 촉진에 따른 건강증진에 기여하며, 혹한기 방한 기능을 충실히 달성할 수 있게 된다.In addition, the far-infrared ray emission contributes to health promotion by promoting blood flow of the human body, and it is possible to faithfully achieve cold weathering function.

이에 더하여, 발수특성을 더욱 강화시키기 위해 상기 기능성 충전물에는 상기 폴리우레탄수지 100중량부를 기준으로 스쿠알렌을 5중량부 더 첨가할 수 있으며, 이와 동시에 오염물질에 대한 분산작용, 연화작용을 위해 이온결정 구조를 갖는 규산나트륨의 수화물인 오르토규산나트륨을 3중량부 더 첨가할 수 있고, 또한 열분해되는 것을 최대한 억제하고 쉽게 변질되지 않도록 하여 형상 유지성을 높이기 위해 리시놀레인산 바륨을 3중량부 더 첨가할 수 있다.In order to further enhance the water repellency, 5 weight parts of squalene may be added to the functional filler based on 100 weight parts of the polyurethane resin. At the same time, an ionic crystal structure 3 parts by weight of sodium orthosilicate which is a hydrate of sodium silicate can be further added. In addition, 3 parts by weight of barium ricinoleate may be further added in order to suppress the thermal decomposition to the maximum extent and to prevent deterioration easily, have.

이하, 실시예에 대하여 설명한다.Hereinafter, examples will be described.

[실시예 1][Example 1]

서너메이트를 코코넛 오일에 녹인 옥틸 메톡시 시너메이트(Octyl MethoxyCinnamate)액 15중량%; DBNPA(2,2-Dibromo-3-nitrilopropionamide) 5중량%; 산화규소 20중량%, 붕산 10중량%, 초산 10중량%, 산화아연 20중량%, 바륨 10중량%, 산화코발트 10중량%, 지르코늄 10중량%, 산화티타늄 10중량%를 혼합교반한 후 1500℃에서 용융 냉각한 다음 1-2㎛의 입도로 분쇄한 원적외선 방출용 분쇄물 15중량%; 물 60중량%에 우레아(Urea) 34중량%, 육수화질산아연(Zn(NO3)2ㆍ6H2O) 2중량% 및 아세트산나트륨(CH3COONaㆍ3H2O) 4중량%를 투입하여 만든 축열성을 갖는 잠열용액(Lantent Liquid) 20중량%; 페닐트리메톡시실란 5중량%; 시트로넬라(citronella) 오일 3중량%; 하이드록시프로필메틸셀룰로우즈 2중량% 및 나머지 폴리우레탄수지로 이루어진 기능성 충전물을 폴리에스테르 수지로 된 충전사용 쉘에 충전시켜 충전사를 만들고, 이 충전사를 폴리에스테르 수지로 된 이면사와 표면사 사이에 배치되게 3중 직조하여 제1시료인 삼중직원단을 만들었다.15% by weight of octyl methoxy cinnamate solution in which cermic acid was dissolved in coconut oil; 5% by weight of DBNPA (2,2-Dibromo-3-nitrilopropionamide); 10 weight% of boric acid, 10 weight% of acetic acid, 20 weight% of zinc oxide, 10 weight% of barium, 10 weight% of cobalt oxide, 10 weight% of zirconium and 10 weight% of titanium oxide were mixed and stirred, 15% by weight of a far infrared ray-emitting pulverized product having a particle size of 1-2 mu m after melt-cooling the product; 34% by weight of Urea, 2% by weight of Zn (NO 3 ) 2 .6H 2 O) and 4% by weight of sodium acetate (CH 3 COONa · 3H 2 O) were added to 60% 20% by weight of a latent heat solution (Lantent Liquid) having a thermostability; 5% by weight of phenyltrimethoxysilane; 3% by weight citronella oil; 2% by weight of hydroxypropyl methylcellulose and the remaining polyurethane resin was charged into a filled shell made of a polyester resin to prepare a filled yarn, and the filled yarn was wound around the back yarn made of polyester resin and the surface yarn So that a triple staff member, a first sample, was made.

[실시예 2][Example 2]

실시예 1과 동일하게 하되, 상기 기능성 충전물에 상기 폴리우레탄수지 100중량부를 기준으로 스쿠알렌 5중량부, 오르토규산나트륨 3중량부, 리시놀레인산 바륨 3중량부를 더 첨가하여 제2시료를 만들었다.5 parts by weight of squalene, 3 parts by weight of sodium orthosilicate, and 3 parts by weight of barium ricinoleate were added to the above-mentioned functional filler based on 100 parts by weight of the above polyurethane resin to prepare a second sample.

[실시예 3][Example 3]

실시예 1과 동일하게 하되, 충전사는 워터젯처리 후 액상의 나노 티타늄옥사이드에 함침시킨 것을 사용하여 제3시료를 만들었다.The same procedure as in Example 1 was carried out except that the packed yarn was subjected to water jet treatment and impregnated with liquid nano-titanium oxide to prepare a third sample.

본 발명에 따른 충전사의 특성중 항균성을 테스트하기 위해, 제1,2,3시료 표면에 표면에 진균(Gliocladium virens ATCC 9645), 포도상구균(Staphylococcus aureus) 및 진득이를 노출시킨 다음에 이에 대한 항균 활성을 시험하였다.To test the antimicrobial properties among the characteristics of the packed yarn according to the present invention, the surfaces of the first, second and third samples were exposed to fungi (Gliocladium virens ATCC 9645), Staphylococcus aureus, Activity was tested.

시험은 균에 노출시킨 후 24시간이 경과한 시점에서 KICM-FIR-1002법으로 측정하여 항균력을 테스트하였고, 시험결과 각 시료에서 99.21%, 99.45%, 99.62%의 항균효과가 확인되었다.The antimicrobial activity was tested by KICM-FIR-1002 at 24 hours after exposure to the bacteria, and 99.21%, 99.45% and 99.62% of antibacterial activity was confirmed in each sample.

그리고, 진득이는 모든 시료에서 모두 사멸되었다.And all the samples were killed.

또한, 원적외선 방출 기능을 확인하기 위해, FT-IR 스펙트로메터를 이용하여 KFIA-F1-1005에 의거 제1,2,3시료에 대한 원적외선 방사시험을 실시하였다.Further, in order to confirm the far-infrared ray emission function, far-infrared ray radiation tests were performed on the first, second and third samples according to KFIA-F1-1005 using an FT-IR spectrometer.

실시결과, 30℃에서 원적외선 방사율 각각 0.814, 0.821, 0.857로 확인되었고, 방사에너지(W/㎡)도 2.43×102, 2.49×102, 2.68×102으로 각각 나타나 원적외선 방출효과가 있는 것으로 확인되었다.As a result, far infrared ray emissivity at 30 ℃ was found to be 0.814, 0.821 and 0.857, respectively. Radiation energy (W / ㎡) was also found to be 2.43 × 10 2 , 2.49 × 10 2 and 2.68 × 10 2 , .

뿐만 아니라, 본 발명에 따른 충전사의 축열성을 평가하기 위해 제1,2,3시료를 10℃로 유지되는 항습실에 각각 투입한 상태에서 열풍을 가해 항습실 내부가 25℃로 10분간 유지되게 하였다.In addition, in order to evaluate the heat-shrinkability of the packed yarn according to the present invention, the first, second, and third samples were placed in a humidity chamber maintained at 10 ° C, respectively, and hot air was applied thereto to maintain the inside of the humidity chamber at 25 ° C for 10 minutes.

그런 다음, 적외선 온도계를 제1,2,3시료의 표면에 조사하여 열손실 여부를 확인하는 방식으로 진행하였으며, 시험결과 1시간 경과시 제1,2,3시료의 표면온도는 각각 22℃, 22.4℃, 22.8℃였고, 2시간 경과시에는 각각 18.2℃, 18.8℃, 19.1℃였으며, 3시간 경과시에는 각각 15.6℃, 15.9℃, 16.5℃였다.Then, the infrared thermometer was irradiated to the surfaces of the first, second and third samples to confirm whether the heat loss occurred. As a result of the test, the surface temperatures of the first, second and third samples were 22 ° C., 22.4 ° C and 22.8 ° C, respectively, and 18.2 ° C, 18.8 ° C and 19.1 ° C respectively for 2 hours and 15.6 ° C, 15.9 ° C and 16.5 ° C for 3 hours, respectively.

이를 통해, 상당한 시간이 경과하더라도 온도가 급격히 떨어짐이 방지됨을 확인할 수 있었고, 이를 통해 축열성이 있음을 확인하였다.As a result, it was confirmed that the temperature was prevented from dropping rapidly even after a considerable period of time.

Claims (2)

표면사와 이면사가 교차하는 부분에 상하로 엇갈리게 충전사가 배치되어 삼중 직조된 삼중직원단에 있어서;
상기 충전사는 충전사용 쉘과, 상기 충전사용 쉘에 충전되는 기능성 충전물로 이루어지되,
상기 충전사용 쉘은 폴리에스테르 수지로 이루어지고;
상기 기능성 충전물은 옥틸 메톡시 시너메이트(Octyl MethoxyCinnamate)액 15중량%, DBNPA(2,2-Dibromo-3-nitrilopropionamide) 5중량%, 1-2㎛의 입도를 갖는 원적외선 방출용 분쇄물 15중량%, 축열성을 갖는 잠열용액(Lantent Liquid) 20중량%, 페닐트리메톡시실란 5중량%, 시트로넬라(citronella) 오일 3중량%, 하이드록시프로필메틸셀룰로우즈 2중량% 및 나머지 폴리우레탄수지로 이루어진 것을 특징으로 하는 발열기능을 갖는 기능성 삼중직원단.
In a triple weave in which the filling yarns are arranged vertically and alternately at the intersection of the surface yarn and the back yarn,
Wherein the filler comprises a filler shell and a functional filler filled in the filler shell,
Wherein the filling-use shell is made of a polyester resin;
15 wt% of Octyl Methoxy Cinnamate solution, 5 wt% of 2,2-Dibromo-3-nitrilopropionamide (DBNPA), 15 wt% of pulverized far infrared rays having a particle size of 1-2 mu m, 20% by weight of a latent heat liquid having a thermo-setting property, 5% by weight of phenyltrimethoxysilane, 3% by weight of citronella oil, 2% by weight of hydroxypropyl methylcellulose, Wherein the functional triplet employee has a heat-generating function.
청구항 1에 있어서,
상기 원적외선 방출용 분쇄물은, 산화규소 20중량%, 붕산 10중량%, 초산 10중량%, 산화아연 20중량%, 바륨 10중량%, 산화코발트 10중량%, 지르코늄 10중량%, 산화티타늄 10중량%를 혼합교반한 후 1500℃에서 용융 냉각한 다음 1-2㎛의 입도로 분쇄한 것이고;
상기 축열성을 갖는 잠열용액은, 물 60중량%에 우레아(Urea) 34중량%를 녹이고, 여기에 육수화질산아연(Zn(NO3)2ㆍ6H2O) 2중량% 및 아세트산나트륨(CH3COONaㆍ3H2O) 4중량%를 투입하여 만든 것을 사용하는 것을 특징으로 하는 발열기능을 갖는 기능성 삼중직원단.The method according to claim 1,
The pulverized material for far-infrared ray emission is composed of 20 weight% of silicon oxide, 10 weight% of boric acid, 10 weight% of acetic acid, 20 weight% of zinc oxide, 10 weight% of barium, 10 weight% of cobalt oxide, 10 weight% of zirconium, % By weight, followed by melt-cooling at 1500 占 폚, followed by pulverization at a particle size of 1-2 占 퐉;
The latent heat solution having the thermostability was prepared by dissolving 34% by weight of urea in 60% by weight of water, adding 2% by weight of zinc sulfate (Zn (NO 3 ) 2 .6H 2 O) and sodium acetate 3 COONa and 3H 2 O) 4 having a functional exothermic function characterized by using the input made by the staff wt% triple-stage.
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