CN102282486B - 包含表面处理物的高折射率无机氧化物纳米粒子、可聚合树脂和制品 - Google Patents

包含表面处理物的高折射率无机氧化物纳米粒子、可聚合树脂和制品 Download PDF

Info

Publication number
CN102282486B
CN102282486B CN2009801548947A CN200980154894A CN102282486B CN 102282486 B CN102282486 B CN 102282486B CN 2009801548947 A CN2009801548947 A CN 2009801548947A CN 200980154894 A CN200980154894 A CN 200980154894A CN 102282486 B CN102282486 B CN 102282486B
Authority
CN
China
Prior art keywords
acrylate
film
inorganic nanoparticles
meth
microstructured film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2009801548947A
Other languages
English (en)
Chinese (zh)
Other versions
CN102282486A (zh
Inventor
克林顿·L·琼斯
布兰特·U·科尔布
特温·L·麦肯齐
戴维·B·奥尔森
内森·K·奈史密斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN102282486A publication Critical patent/CN102282486A/zh
Application granted granted Critical
Publication of CN102282486B publication Critical patent/CN102282486B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3676—Treatment with macro-molecular organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10—Treatment with macromolecular organic compounds
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/08—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of polarising materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C09K2323/03—Viewing layer characterised by chemical composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
    • C09K2323/051—Inorganic, e.g. glass or silicon oxide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
    • C09K2323/057—Ester polymer, e.g. polycarbonate, polyacrylate or polyester
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
    • C09K2323/059—Unsaturated aliphatic polymer, e.g. vinyl
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033—Means for improving the coupling-out of light from the light guide
    • G02B6/005—Means for improving the coupling-out of light from the light guide provided by one optical element, or plurality thereof, placed on the light output side of the light guide
    • G02B6/0053—Prismatic sheet or layer; Brightness enhancement element, sheet or layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y10T428/24405—Polymer or resin [e.g., natural or synthetic rubber, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y10T428/24413—Metal or metal compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Nanotechnology (AREA)
  • Optics & Photonics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Composite Materials (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
CN2009801548947A 2008-12-15 2009-11-20 包含表面处理物的高折射率无机氧化物纳米粒子、可聚合树脂和制品 Active CN102282486B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12270608P 2008-12-15 2008-12-15
US61/122,706 2008-12-15
PCT/US2009/065352 WO2010074862A1 (en) 2008-12-15 2009-11-20 High refractive index inorganic oxide nanoparticles comprising surface treatment, polymerizable resin, and articles

Publications (2)

Publication Number Publication Date
CN102282486A CN102282486A (zh) 2011-12-14
CN102282486B true CN102282486B (zh) 2013-10-09

Family

ID=41651134

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2009801548947A Active CN102282486B (zh) 2008-12-15 2009-11-20 包含表面处理物的高折射率无机氧化物纳米粒子、可聚合树脂和制品

Country Status (7)

Country Link
US (3) US8282863B2 (https=)
EP (1) EP2370841B1 (https=)
JP (1) JP5330539B2 (https=)
KR (1) KR101588073B1 (https=)
CN (1) CN102282486B (https=)
SG (1) SG171872A1 (https=)
WO (1) WO2010074862A1 (https=)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010074862A1 (en) * 2008-12-15 2010-07-01 3M Innovative Properties Company High refractive index inorganic oxide nanoparticles comprising surface treatment, polymerizable resin, and articles
CN102639650A (zh) 2009-12-03 2012-08-15 3M创新有限公司 通过添加疏水性纳米粒子抑制粉末吸水性的方法
EP2507336B1 (en) 2009-12-03 2017-08-09 3M Innovative Properties Company Method of electrostatic deposition of particles, abrasive grain and articles
FR2956672B1 (fr) * 2010-02-24 2013-04-12 Centre Nat Rech Scient Procede de preparation de biomateriaux hydrophobises, biomateriaux hydrophobises tels qu'obtenus et leurs utilisations
WO2011140018A1 (en) 2010-05-07 2011-11-10 3M Innovative Properties Company Antireflective films comprising microstructured surface
WO2011149631A2 (en) 2010-05-25 2011-12-01 3M Innovative Properties Company Method of surface treating inorganic oxide particles, hardenable dental compositions, surface treated particles, and surface treatment compounds
KR20130088037A (ko) * 2010-06-23 2013-08-07 니폰 가세이 가부시키가이샤 무기 유기 하이브리드 재료 및 그것을 사용한 광학 재료 그리고 무기 유기 복합재 조성물
US20130250614A1 (en) 2010-12-04 2013-09-26 3M Innovative Properties Company Illumination assembly and method of forming same
JP6073798B2 (ja) 2010-12-04 2017-02-01 スリーエム イノベイティブ プロパティズ カンパニー 照明アセンブリ及びその形成方法
EP2707424B1 (en) 2011-05-13 2020-10-28 3M Innovative Properties Company Benzyl (meth)acrylate monomers suitable for microstructured optical films
US9505700B2 (en) 2012-06-21 2016-11-29 Council Of Scientific & Industrial Research High refractive index (meth) acrylates
KR20150129057A (ko) 2012-09-20 2015-11-18 쓰리엠 이노베이티브 프로퍼티즈 컴파니 나노입자 및 알킬렌 옥사이드 반복 단위를 포함하는 단량체를 포함하는 미세구조화 필름
US20150353756A1 (en) * 2012-12-27 2015-12-10 3M Innovative Properties Company Coatings for indium-tin oxide layers
US20140242343A1 (en) 2013-02-27 2014-08-28 3M Innovative Properties Company Lamination transfer films for forming embedded nanostructures
US9513406B2 (en) 2013-07-17 2016-12-06 University Of Oregon Soluble functionalized nanoparticles for use in optical materials
BR112016006775A2 (pt) 2013-10-02 2017-08-01 3M Innovative Properties Co pilha de filmes ópticos e artigo
WO2015050862A1 (en) 2013-10-02 2015-04-09 3M Innovative Properties Company Article comprising polyacrylate pressure sensitive primer and adhesive comprising polyacrylate component
WO2015050750A1 (en) 2013-10-02 2015-04-09 3M Innovative Properties Company Microstuctured diffuser comprising first microstructured layer and coating, optical stacks, and method
JP6436315B2 (ja) * 2013-12-12 2018-12-12 ナガセケムテックス株式会社 複合樹脂組成物および該樹脂組成物の製造方法
US9046637B1 (en) 2014-02-25 2015-06-02 3M Innovative Properties Company Tubular lighting systems with inner and outer structured surfaces
US10161593B2 (en) 2014-02-25 2018-12-25 3M Innovative Properties Company Solid state lighting device with virtual filament(s)
ES2675283T3 (es) * 2014-02-28 2018-07-10 Rhodia Operations Proceso para la preparación de sílices precipitadas, sílices precipitadas y sus usos, en particular para el refuerzo de polímeros
TW201539736A (zh) 2014-03-19 2015-10-16 ３Ｍ新設資產公司 用於藉白光成色之 oled 裝置的奈米結構
US9586385B2 (en) 2014-08-27 2017-03-07 3M Innovative Properties Company Inorganic multilayer lamination transfer films
CN106660355B (zh) 2014-08-27 2019-10-11 3M创新有限公司 电多层层合转印膜
US20180244876A1 (en) * 2015-03-02 2018-08-30 The Trustees Of The University Of Pennsylvania A robust smart film: reversibly switching from high transparency to angle-independent structural color display
WO2016160252A1 (en) 2015-03-30 2016-10-06 3M Innovative Properties Company Microstructured optical film comprising low refractive index layer disposed on base film substrate
CN104926137A (zh) * 2015-07-01 2015-09-23 合肥鼎亮光学科技有限公司 一种pc反光膜用玻璃微珠及其制备方法
US11312100B2 (en) 2015-12-28 2022-04-26 3M Innovative Properties Company Article with microstructured layer
JP6960407B2 (ja) 2015-12-28 2021-11-05 スリーエム イノベイティブ プロパティズ カンパニー 微細構造化層を有する物品
KR102406867B1 (ko) 2016-06-16 2022-06-13 쓰리엠 이노베이티브 프로퍼티즈 컴파니 나노입자 충전된 배리어 접착제 조성물
WO2018122749A1 (en) * 2016-12-29 2018-07-05 3M Innovative Properties Company Flexible nanoparticle optical coating compositions
WO2018160866A1 (en) 2017-03-02 2018-09-07 3M Innovative Properties Company Dynamic reflected color film with low optical caliper sensitivity
KR20200103816A (ko) 2018-01-08 2020-09-02 쓰리엠 이노베이티브 프로퍼티즈 컴파니 광학 필름 조립체
WO2019180621A2 (en) 2018-03-22 2019-09-26 3M Innovative Properties Company Charge-modified particles and methods of making the same
US11492495B2 (en) 2018-03-22 2022-11-08 3M Innovative Properties Company Modified aluminum nitride particles and methods of making the same
JP2021533226A (ja) * 2018-07-30 2021-12-02 スリーエム イノベイティブ プロパティズ カンパニー 透明エラストマーナノ複合体ブレンド
KR102794145B1 (ko) * 2019-06-04 2025-04-11 주식회사 동진쎄미켐 광중합성 조성물 및 이를 이용한 경화막, 표시장치
WO2021064530A1 (en) 2019-09-30 2021-04-08 3M Innovative Properties Company Dicarboxylic acid compounds. inorganic particles treated with the dicarboxylic acid compounds, and compositions thereof
CN112143368B (zh) * 2020-09-22 2021-11-16 北京化工大学常州先进材料研究院 一种高折射率uv单体的制备方法及其在涂层上的应用
TW202233802A (zh) * 2021-02-17 2022-09-01 歆熾電氣技術股份有限公司 光轉換複合材料以及製造光轉換複合材料之方法
KR102816339B1 (ko) * 2022-05-07 2025-06-02 샨둥 시노세라 펑셔널 머티리얼 컴퍼니 리미티드 지르코니아 수지형 분산액, uv 경화 접착제 및 이의 제조방법과 응용
CN115201944A (zh) * 2022-07-07 2022-10-18 鲁隽韬 仿生变色材料、其制备工艺以及仿生变色体系

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1486344A (zh) * 2000-12-15 2004-03-31 Ucb 含反应性纳米粒子的粉末涂料组合物
CN1486351A (zh) * 2000-12-15 2004-03-31 Ucb 辐射固化油墨印刷和涂布技术中颜料和/或染料的表面官能化作用
CN1871531A (zh) * 2003-09-12 2006-11-29 3M创新有限公司 耐用光学元件
US20080221291A1 (en) * 2007-03-07 2008-09-11 3M Innovative Properties Company Microstructured optical films comprising biphenyl difunctional monomers
CN101305301A (zh) * 2005-11-15 2008-11-12 3M创新有限公司 增亮膜以及对无机纳米颗粒进行表面处理的方法

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4576850A (en) * 1978-07-20 1986-03-18 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
US5175030A (en) * 1989-02-10 1992-12-29 Minnesota Mining And Manufacturing Company Microstructure-bearing composite plastic articles and method of making
US5183597A (en) * 1989-02-10 1993-02-02 Minnesota Mining And Manufacturing Company Method of molding microstructure bearing composite plastic articles
US5424365A (en) * 1990-10-01 1995-06-13 Mcwhorter Technologies, Inc. Two package ambient temperature curing coating composition
US5882774A (en) * 1993-12-21 1999-03-16 Minnesota Mining And Manufacturing Company Optical film
US5828488A (en) * 1993-12-21 1998-10-27 Minnesota Mining And Manufacturing Co. Reflective polarizer display
US5825543A (en) * 1996-02-29 1998-10-20 Minnesota Mining And Manufacturing Company Diffusely reflecting polarizing element including a first birefringent phase and a second phase
US5783120A (en) * 1996-02-29 1998-07-21 Minnesota Mining And Manufacturing Company Method for making an optical film
US6376590B2 (en) * 1999-10-28 2002-04-23 3M Innovative Properties Company Zirconia sol, process of making and composite material
US20040063813A1 (en) * 2001-12-10 2004-04-01 Bin Wu Powder coating compositions containing reactive nanoparticles
US6844950B2 (en) * 2003-01-07 2005-01-18 General Electric Company Microstructure-bearing articles of high refractive index
US7169375B2 (en) * 2003-08-29 2007-01-30 General Electric Company Metal oxide nanoparticles, methods of making, and methods of use
JP2007505359A (ja) * 2003-09-12 2007-03-08 スリーエム イノベイティブ プロパティズ カンパニー 耐久性光学素子
US7282272B2 (en) * 2003-09-12 2007-10-16 3M Innovative Properties Company Polymerizable compositions comprising nanoparticles
US7264872B2 (en) * 2004-12-30 2007-09-04 3M Innovative Properties Company Durable high index nanocomposites for AR coatings
US7241437B2 (en) * 2004-12-30 2007-07-10 3M Innovative Properties Company Zirconia particles
KR20070103033A (ko) 2005-02-17 2007-10-22 쓰리엠 이노베이티브 프로퍼티즈 컴파니 낮은 유리 전이 온도를 가진 중합된 유기 상을 포함하는밝기 증진 필름
WO2006098899A2 (en) * 2005-03-11 2006-09-21 3M Innovative Properties Company Light management films with zirconia particles
US20060204745A1 (en) * 2005-03-14 2006-09-14 Jones Clint L Light management films with zirconia particles
US20060204676A1 (en) * 2005-03-11 2006-09-14 Jones Clinton L Polymerizable composition comprising low molecular weight organic component
US20070286994A1 (en) * 2006-06-13 2007-12-13 Walker Christopher B Durable antireflective film
US7615283B2 (en) * 2006-06-13 2009-11-10 3M Innovative Properties Company Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film
TW200900723A (en) 2007-02-27 2009-01-01 3M Innovative Properties Co Brightness enhancing film comprising nanocomposite structure having improved crack resistance
CN101945824B (zh) * 2007-12-28 2014-07-23 3M创新有限公司 制备含氧化锆的纳米粒子的方法
WO2010074862A1 (en) 2008-12-15 2010-07-01 3M Innovative Properties Company High refractive index inorganic oxide nanoparticles comprising surface treatment, polymerizable resin, and articles

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1486344A (zh) * 2000-12-15 2004-03-31 Ucb 含反应性纳米粒子的粉末涂料组合物
CN1486351A (zh) * 2000-12-15 2004-03-31 Ucb 辐射固化油墨印刷和涂布技术中颜料和/或染料的表面官能化作用
CN1871531A (zh) * 2003-09-12 2006-11-29 3M创新有限公司 耐用光学元件
CN101305301A (zh) * 2005-11-15 2008-11-12 3M创新有限公司 增亮膜以及对无机纳米颗粒进行表面处理的方法
US20080221291A1 (en) * 2007-03-07 2008-09-11 3M Innovative Properties Company Microstructured optical films comprising biphenyl difunctional monomers

Also Published As

Publication number Publication date
US20120329959A1 (en) 2012-12-27
EP2370841A1 (en) 2011-10-05
EP2370841B1 (en) 2012-12-26
US8535576B2 (en) 2013-09-17
WO2010074862A1 (en) 2010-07-01
JP5330539B2 (ja) 2013-10-30
KR101588073B1 (ko) 2016-01-22
US20110227008A1 (en) 2011-09-22
JP2012512273A (ja) 2012-05-31
CN102282486A (zh) 2011-12-14
US8821770B2 (en) 2014-09-02
KR20110110169A (ko) 2011-10-06
US20130323467A1 (en) 2013-12-05
US8282863B2 (en) 2012-10-09
SG171872A1 (en) 2011-07-28

Similar Documents

Publication Publication Date Title
CN102282486B (zh) 包含表面处理物的高折射率无机氧化物纳米粒子、可聚合树脂和制品
EP2118149B1 (en) Brightness enhancing film comprising nanocomposite structure having improved crack resistance
US12415878B2 (en) Benzyl (meth)acrylate monomers suitable for microstructured optical films
CN101305301B (zh) 增亮膜以及对无机纳米颗粒进行表面处理的方法
US9360591B2 (en) Microstructured film comprising nanoparticles and monomer comprising alkylene oxide repeat units
US7981986B2 (en) Optical films comprising fluorenol (meth)acrylate monomer
US20090275720A1 (en) Ortho-benzylphenol mono(meth)acrylate monomers suitable for microstructured optical films
US8080608B2 (en) Optical films comprising phenyl ethylene (meth)acrylate monomers

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant