CN102272181A - 异氰酸酯三聚催化剂体系，前体制剂，使异氰酸酯三聚的方法，由其制备的硬质聚异氰脲酸酯/聚氨酯泡沫体，和制备这种泡沫体的方法 - Google Patents

异氰酸酯三聚催化剂体系，前体制剂，使异氰酸酯三聚的方法，由其制备的硬质聚异氰脲酸酯/聚氨酯泡沫体，和制备这种泡沫体的方法 Download PDF

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Publication number
CN102272181A
CN102272181A CN2009801539011A CN200980153901A CN102272181A CN 102272181 A CN102272181 A CN 102272181A CN 2009801539011 A CN2009801539011 A CN 2009801539011A CN 200980153901 A CN200980153901 A CN 200980153901A CN 102272181 A CN102272181 A CN 102272181A
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catalyst
trimerization
optionally
isocyanate
optional
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Chinese (zh)
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菲利普.阿西
纳森.维尔莫特
理查德.基顿
戴维.巴布
塞西尔.波耶
蒂莫西.莫利
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
    • C08G18/022—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only the polymeric products containing isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1858—Catalysts containing secondary or tertiary amines or salts thereof having carbon-to-nitrogen double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1875—Catalysts containing secondary or tertiary amines or salts thereof containing ammonium salts or mixtures of secondary of tertiary amines and acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
    • C08G18/2027—Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2045—Heterocyclic amines; Salts thereof containing condensed heterocyclic rings
    • C08G18/2063—Heterocyclic amines; Salts thereof containing condensed heterocyclic rings having two nitrogen atoms in the condensed ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
CN2009801539011A 2008-11-10 2009-11-09 异氰酸酯三聚催化剂体系，前体制剂，使异氰酸酯三聚的方法，由其制备的硬质聚异氰脲酸酯/聚氨酯泡沫体，和制备这种泡沫体的方法 Pending CN102272181A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11319608P 2008-11-10 2008-11-10
US61/113,196 2008-11-10
PCT/US2009/063733 WO2010054317A2 (en) 2008-11-10 2009-11-09 An isocyanate trimerisation catalyst system, a precursor formulation, a process for trimerising isocyanates, rigid polyisocyanurate/polyurethane foams made therefrom, and a process for making such foams

Publications (1)

Publication Number Publication Date
CN102272181A true CN102272181A (zh) 2011-12-07

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CN2009801539011A Pending CN102272181A (zh) 2008-11-10 2009-11-09 异氰酸酯三聚催化剂体系，前体制剂，使异氰酸酯三聚的方法，由其制备的硬质聚异氰脲酸酯/聚氨酯泡沫体，和制备这种泡沫体的方法

Country Status (6)

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US (1) US20110201709A1 (https=)
EP (1) EP2346919B1 (https=)
JP (1) JP2012508303A (https=)
CN (1) CN102272181A (https=)
ES (1) ES2436013T3 (https=)
WO (1) WO2010054317A2 (https=)

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CN107531875A (zh) * 2015-04-21 2018-01-02 科思创德国股份有限公司 用于生产具有功能化表面的聚异氰脲酸酯塑料的方法
CN107531874A (zh) * 2015-04-21 2018-01-02 科思创德国股份有限公司 聚异氰脲酸酯聚合物以及制备聚异氰脲酸酯聚合物的方法
CN109071764A (zh) * 2015-04-21 2018-12-21 科思创德国股份有限公司 疏水改性的聚异氰脲酸酯塑料及其制造方法
CN109923143A (zh) * 2016-11-14 2019-06-21 科思创德国股份有限公司 由前体制造物体的方法和可自由基交联的树脂在增材制造法中的用途
CN114072441A (zh) * 2019-07-11 2022-02-18 科思创知识产权两合公司 由脲二酮制备异氰脲酸酯的方法

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JP2012508302A (ja) * 2008-11-10 2012-04-05 ダウ グローバル テクノロジーズ エルエルシー イソシアネートの三量化触媒系、前駆体配合物、イソシアネートの三量化方法、それから作製された硬質ポリイソシアヌレート／ポリウレタン発泡体、および該発泡体の作製方法
US8709544B2 (en) * 2009-11-23 2014-04-29 Basf Se Catalysts for polyurethane coating compounds
CN102432813B (zh) * 2011-03-21 2014-04-30 江苏科泰绝热新材料有限公司 一种用离子液体催化制备pir材料的方法
WO2013024108A1 (de) * 2011-08-16 2013-02-21 Bayer Intellectual Property Gmbh Verfahren zur herstellung eines polyurethan-polyisocyanurat-hartschaums
EP2602023A1 (de) * 2011-12-07 2013-06-12 Basf Se Katalysatorkombination zur Herstellung von Polyurethanschaumstoffformkörpern
EP2797994A2 (en) 2011-12-30 2014-11-05 Dow Global Technologies LLC Foam composition with olefin block copolymer gel particles
CN104093759B (zh) * 2012-02-08 2016-09-21 科思创德国股份有限公司 聚氨酯-聚异氰脲酸酯-硬质泡沫材料的制备方法
CN105189595B (zh) 2013-03-28 2018-03-02 陶氏环球技术有限责任公司 用于制备氨基甲酸酯‑异氰脲酸酯的方法
AU2014318649B2 (en) 2013-09-13 2017-09-07 Dow Global Technologies Llc Thixotropic polyol compositions containing dispersed urethane-modified polyisocyanurates
US10017599B2 (en) 2013-09-13 2018-07-10 Dow Global Technologies Llc Polyisocyanate polyaddition polyol manufacturing process using stabilizers
RU2676285C1 (ru) * 2013-12-16 2018-12-27 Роквул Интернэшнл А/С Композиты на основе вспененного полиизоцианурата, их получение и применение
EP2924058B1 (en) 2014-03-28 2016-05-25 Huntsman International Llc Reinforced organic natural fiber composites
RU2707290C2 (ru) 2014-04-03 2019-11-26 Хантсмэн Интернэшнл Ллс Катализатор тримеризации изоцианата для изготовления полиизоцианурат-содержащих пеноматериалов
EP3286241B1 (en) * 2015-04-21 2020-04-15 Covestro Deutschland AG Process for producing polyisocyanurate plastics
US10597484B2 (en) * 2015-04-21 2020-03-24 Covestro Deutschland Ag Polyisocyanurate plastics having high thermal stability
CN107021920B (zh) * 2016-08-12 2019-07-23 万华化学集团股份有限公司 一种异氰酸酯聚合催化剂及其制备方法，及其用于制备聚异氰酸酯的方法
WO2019014582A1 (en) * 2017-07-13 2019-01-17 Dow Global Technologies Llc SILYLAMMONIUM SALTS AS LATENT POLYURETHANE CATALYSTS
CN117120500A (zh) 2021-04-14 2023-11-24 赢创运营有限公司 硬质聚氨酯或聚异氰脲酸酯泡沫的生产
EP4282892A1 (de) * 2022-05-25 2023-11-29 Evonik Operations GmbH Herstellung von polyurethanschaum unter verwendung von katalysatoren auf basis ionischer flüssigkeiten
WO2024038025A1 (de) * 2022-08-16 2024-02-22 Basf Se Neue polyurethan-schaumkatalysatoren mit verbesserter lagerstabilität
CN120424305A (zh) 2024-02-02 2025-08-05 赢创运营有限公司 聚氨酯或聚异氰脲酸酯泡沫的生产
CN120424304A (zh) 2024-02-02 2025-08-05 赢创运营有限公司 聚氨酯或聚异氰脲酸酯泡沫的生产

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CN107531875A (zh) * 2015-04-21 2018-01-02 科思创德国股份有限公司 用于生产具有功能化表面的聚异氰脲酸酯塑料的方法
CN107531874A (zh) * 2015-04-21 2018-01-02 科思创德国股份有限公司 聚异氰脲酸酯聚合物以及制备聚异氰脲酸酯聚合物的方法
CN109071764A (zh) * 2015-04-21 2018-12-21 科思创德国股份有限公司 疏水改性的聚异氰脲酸酯塑料及其制造方法
CN107531875B (zh) * 2015-04-21 2020-09-22 科思创德国股份有限公司 用于生产具有功能化表面的聚异氰脲酸酯塑料的方法
CN109923143A (zh) * 2016-11-14 2019-06-21 科思创德国股份有限公司 由前体制造物体的方法和可自由基交联的树脂在增材制造法中的用途
CN109923143B (zh) * 2016-11-14 2022-04-22 科思创德国股份有限公司 由前体制造物体的方法和可自由基交联的树脂在增材制造法中的用途
CN114072441A (zh) * 2019-07-11 2022-02-18 科思创知识产权两合公司 由脲二酮制备异氰脲酸酯的方法

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US20110201709A1 (en) 2011-08-18
ES2436013T3 (es) 2013-12-26
JP2012508303A (ja) 2012-04-05
WO2010054317A8 (en) 2010-07-01
WO2010054317A2 (en) 2010-05-14
EP2346919B1 (en) 2013-09-04
EP2346919A2 (en) 2011-07-27

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