CN102264871B - 烃的联合加氢裂化和脱蜡 - Google Patents

烃的联合加氢裂化和脱蜡 Download PDF

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Publication number
CN102264871B
CN102264871B CN200980150071.7A CN200980150071A CN102264871B CN 102264871 B CN102264871 B CN 102264871B CN 200980150071 A CN200980150071 A CN 200980150071A CN 102264871 B CN102264871 B CN 102264871B
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Prior art keywords
dewaxing
zsm
hydrocracking
surface area
effluent
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Expired - Fee Related
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CN200980150071.7A
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English (en)
Chinese (zh)
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CN102264871A (zh
Inventor
G·P·施莱克尔
S·J·麦卡锡
W·F·莱
K·M·普伦蒂斯
M·达格
C·G·奥利韦里
T·F·戴格南
J·G·桑蒂斯特班
A·B·单德卡尔
W·J·诺瓦克
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ExxonMobil Technology and Engineering Co
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ExxonMobil Research and Engineering Co
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Priority claimed from PCT/US2009/006738 external-priority patent/WO2010077352A1/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/12Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/207Acid gases, e.g. H2S, COS, SO2, HCN
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02Gasoline
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04Diesel oil
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10Lubricating oil

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
CN200980150071.7A 2008-12-31 2009-12-30 烃的联合加氢裂化和脱蜡 Expired - Fee Related CN102264871B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US20405708P 2008-12-31 2008-12-31
US61/204,057 2008-12-31
US12/655,128 2009-12-23
US12/655,128 US8394255B2 (en) 2008-12-31 2009-12-23 Integrated hydrocracking and dewaxing of hydrocarbons
PCT/US2009/006738 WO2010077352A1 (en) 2008-12-16 2009-12-30 Integrated hydrocracking and dewaxing of hydrocarbons

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CN102264871A CN102264871A (zh) 2011-11-30
CN102264871B true CN102264871B (zh) 2014-04-16

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US (1) US8394255B2 (https=)
EP (1) EP2486108A4 (https=)
JP (1) JP5584699B2 (https=)
CN (1) CN102264871B (https=)
BR (1) BRPI0922275A2 (https=)
MY (1) MY152287A (https=)
RU (1) RU2011129062A (https=)
TW (1) TWI466995B (https=)

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US9200218B2 (en) * 2011-03-31 2015-12-01 Exxonmobil Research And Engineering Company Fuels hydrocracking with dewaxing of fuel products
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SG11201400160PA (en) * 2011-09-13 2014-05-29 Exxonmobil Res & Eng Co Process for the production of diesel fuel and lubricant base oil
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US20130165717A1 (en) * 2011-12-23 2013-06-27 Exxonmobil Research And Engineering Company Process for increased production of fcc gasoline
CN103773467B (zh) * 2012-10-24 2015-12-02 中国石油化工股份有限公司 一种加氢异构脱蜡生产润滑油基础油的方法
CN107723022B (zh) * 2013-03-14 2021-04-27 精炼技术解决方案有限责任公司 用于通过全液氢化处理和脱蜡改善中间馏分原料的冷流特性并增加其收率的方法
US9719034B2 (en) * 2013-12-23 2017-08-01 Exxonmobil Research And Engineering Company Co-production of lubricants and distillate fuels
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US10227536B2 (en) 2014-12-01 2019-03-12 Uop Llc Methods for alternating production of distillate fuels and lube basestocks from heavy hydrocarbon feed
CN106675643B (zh) * 2015-11-11 2018-03-16 中国石油化工股份有限公司 一种劣质柴油降凝改质方法
CN106675642B (zh) * 2015-11-11 2018-03-16 中国石油化工股份有限公司 一种低凝柴油的生产方法
CN106675641B (zh) * 2015-11-11 2018-03-16 中国石油化工股份有限公司 一种优质低凝柴油的生产方法
CN106675644B (zh) * 2015-11-11 2018-03-16 中国石油化工股份有限公司 一种低硫、低凝柴油的生产方法
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US10494579B2 (en) 2016-04-26 2019-12-03 Exxonmobil Research And Engineering Company Naphthene-containing distillate stream compositions and uses thereof
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US10472581B2 (en) 2016-06-30 2019-11-12 Uop Llc Process and apparatus for hydrocracking and hydroisomerizing a hydrocarbon stream
CN109563418B (zh) 2016-08-03 2022-03-18 埃克森美孚研究工程公司 用于生产高性能基础油料的萃余油加氢转化
US20180105761A1 (en) * 2016-10-14 2018-04-19 Exxonmobil Research And Engineering Company Lubricant basestock production with enhanced aromatic saturation
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TWI466995B (zh) 2015-01-01
JP5584699B2 (ja) 2014-09-03
US8394255B2 (en) 2013-03-12
MY152287A (en) 2014-09-15
EP2486108A4 (en) 2013-01-16
EP2486108A1 (en) 2012-08-15
RU2011129062A (ru) 2013-02-10
JP2012514052A (ja) 2012-06-21
BRPI0922275A2 (pt) 2019-09-24
CN102264871A (zh) 2011-11-30
US20100187155A1 (en) 2010-07-29
TW201035303A (en) 2010-10-01

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