CN102250656A - Method for preparing micro-emulsified procetane - Google Patents
Method for preparing micro-emulsified procetane Download PDFInfo
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- CN102250656A CN102250656A CN2011101665511A CN201110166551A CN102250656A CN 102250656 A CN102250656 A CN 102250656A CN 2011101665511 A CN2011101665511 A CN 2011101665511A CN 201110166551 A CN201110166551 A CN 201110166551A CN 102250656 A CN102250656 A CN 102250656A
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- Prior art keywords
- emulsified
- procetane
- naphthenate
- micro
- alkylphenol polyoxyethylene
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- 238000000034 method Methods 0.000 title abstract description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 6
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims abstract description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005642 Oleic acid Substances 0.000 claims abstract description 5
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims abstract description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 5
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 12
- 239000006280 diesel fuel additive Substances 0.000 claims description 12
- 239000004530 micro-emulsion Substances 0.000 claims description 12
- -1 polyoxyethylene Polymers 0.000 claims description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 3
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229920001174 Diethylhydroxylamine Polymers 0.000 claims description 3
- IPBJULRPVLXWIF-UHFFFAOYSA-M [Na+].C(CCC(=O)OCCCCCCCC)(=O)OCCCCCCCC.I(=O)(=O)[O-] Chemical compound [Na+].C(CCC(=O)OCCCCCCCC)(=O)OCCCCCCCC.I(=O)(=O)[O-] IPBJULRPVLXWIF-UHFFFAOYSA-M 0.000 claims description 3
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229940120693 copper naphthenate Drugs 0.000 claims description 3
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 claims description 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 3
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 claims description 3
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 3
- OFUAIAKLWWIPTC-UHFFFAOYSA-L magnesium;naphthalene-2-carboxylate Chemical compound [Mg+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 OFUAIAKLWWIPTC-UHFFFAOYSA-L 0.000 claims description 3
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 239000002283 diesel fuel Substances 0.000 abstract description 26
- 239000007789 gas Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 2
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 2
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 abstract 1
- 230000003750 conditioning effect Effects 0.000 abstract 1
- 239000002737 fuel gas Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 235000011067 sorbitan monolaureate Nutrition 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 11
- 238000011161 development Methods 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 6
- 238000004945 emulsification Methods 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 238000004134 energy conservation Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 208000019901 Anxiety disease Diseases 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 230000003394 haemopoietic effect Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
- Colloid Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention provides a method for preparing a micro-emulsified procetane. The method comprises the following steps of: selecting the following components in percentage by weight: 60% of oleic acid, 10% of naphthenic acid, 6% of ethanolamine, 2% of triethanolamine, 7% of cyclohexylamine, 3% of n-butyl alcohol, 3% of isopropanol, 2% of Span-80, 0.5% of Span-20, 0.5% of polyethylene glycol, 2% of alkylphenol polyoxyethylene ether OP4, 0.5% of alkylphenol polyoxyethylene ether OP10 and 3.5% of conditioning agent; agitating the mixture at room temperature and normal pressure for 40-60 minutes to prepare the micro-emulsified procetane. By using the method provided by the invention, the physicochemical performance and use effects of the emulsified fuel gas are improved and energy is saved by more than 30%; the exhaust gas purification rate is more than 30-60%, the cost is reduced by more than 15-20% and the dynamic performance and the oil consumption of the micro-emulsified procetane have little difference from those of pure diesel oil.
Description
(1) technical field
The present invention relates to chemistry subject, is exactly a kind of preparation method of micro emulsion diesel fuel additive specifically.
(2) background technology
In energy dilemma and environmental pollution serious today, can source throttling, cleaning subtracts a dirty significant problem that has become whole world national governments.2009, domestic diesel oil consumption was 1.07 hundred million tons, and 2010, domestic diesel oil consumption reached 1.4 hundred million tons, the rapid rising of diesel oil consumption, and domestic diesel oil aggregate supply self hematopoietic deficiency, import diesel oil meets with the price differential between wholesale and retail of great number again.Recently, to occur diesel oil from south to north again and again in short supply in the whole nation, and many southern service stations do not have diesel oil to supply, and also putting on short allowance of oil arranged, and a car can only add the oil of 100 yuan or 200 yuan.Some car owners often will run a lot of service stations, the team of row's several hrs.Similarly " diesel oil famine " has not been to occur for the first time.The floating carbon, hydrocarbon polymer, carbon monoxide, oxynitride, oxysulfide, sulfide and the solia particle that not exclusively give off of diesel combustion become the primary pollution source in big or middle city in addition, has a strong impact on ecotope, human health and Economic development.Therefore, for energy-conservation and environmental protection, development diesel oil is newly filled a prescription, the development of new environmental protection diesel oil is imperative.Since the seventies in 20th century, global oil crisis and environmental stress have stimulated exploitation and the development of various countries to the clean fuel technology greatly.States such as U.S., Europe, day and Russia classify exploitation clean fuel technology as state key development research project in succession.China also makes a series of research and development planning in succession, and has obtained very big development.
Whole world energy shortage is a well known fact, and further aggravation, and this is the inevitable outcome that oil reserve gradually reduces.Because the world oil anxiety, the countries in the world scientist explores in research and seeks new forms of energy, as wind energy, sun power, biomass, Hydrogen Energy etc.The additivated method of diesel oil can be saved diesel oil 30% or more more, that is to say that 0.7 ton of diesel oil of actual usefulness has become 1 ton of emulsified fuel oil.This means that the whole world all uses diesel oil emulsification,, exploit 30% diesel oil resource less and just can satisfy present consumption that clearly, the use diesel oil emulsification means a great with the diesel consumption of saving 30%.At first, it can postpone the dry spells of China's oil resource greatly, secondly, because the diesel oil emulsification cost is lower, will bring certain profit to the producer, and great economic interests are arranged; The 3rd; Because the taxation environment-friendly energy-saving diesel fuel needs a large amount of diesel-dopes, will promote the development of fine chemistry industry.Because 80% to 90% tail gas of global urban waste gas from vehicular emission, urban air pollution has become the environmental problem that threatens human survival to press for solution, China is to atmosphere, especially the improvement of urban air pollution is attached great importance to, but Economic development brings the increase of motor vehicle, causes various Fuel Demand amounts also to increase considerably.It is reported, in the past, scientist is in order to improve the environmental protection quality of vapour, diesel oil, realize the target of fuel-economizing, once adopted multiple technology and the device that allows motor vehicle reduce discharge of poisonous waste amount and fuel-economizing in the tail gas, as " three-way catalytic apparatus ", the relevant expert thinks, though this device has reduced oxynitride, made more nitrous oxide, its Greenhouse effect are 300 times of carbonic acid gas.In addition, additive that various chemicals constitute and sanitising agent and oil liquefied gas, ethanol New-type fuel etc., for cutting down the consumption of energy, discharge of poisonous waste has played positive effect in the minimizing motor-vehicle tail-gas, but effect that these technology and measure are reached and ideal are administered the overall goal of atmospheric pollution, save energy and required also not by a long sight.
(3) summary of the invention
The object of the present invention is to provide a kind of preparation method of micro emulsion diesel fuel additive.
The object of the present invention is achieved like this: step is as follows:
Step 1: choose by weight percentage: 8%120# solvent oil, 8% pimelinketone, 7% ethyl acetate, 9% calcium sulphonate, 21% nitric acid isooctyl, 14% iodate dioctyl succinate sodium salt, 8% copper naphthenate, 7% manganese naphthenate, 7% barium naphthenate, 3.5% magnesium naphthenate, 7% methylethyl ketone peroxide, 0.35% hydrazine hydrate and 0.15% diethyl hydroxylamine, at normal temperatures and pressures, above-mentioned raw materials is sequentially added in the stirred pot, makes adjusting material through 100 minutes abundant stirrings;
Step 2: choose by weight percentage: oleic acid 60%, naphthenic acid 10%, thanomin 6%, trolamine 2%, hexahydroaniline 7%, propyl carbinol 3%, Virahol 3%, Span-80 2%, this dish-20 0.5%, polyoxyethylene glycol 0.5%, alkylphenol polyoxyethylene OP
42%, alkylphenol polyoxyethylene OP
100.5% and by the adjusting material 3.5% that step 1 makes, at normal temperatures and pressures, above-mentioned raw materials is sequentially added in the stirred pot, make brown yellow transparent liquid through 40-60 minute abundant stirring, be the micro emulsion diesel fuel additive.
The preparation method of a kind of micro emulsion diesel fuel additive of the present invention has following characteristics: the micro emulsion diesel fuel additive outward appearance of the present invention's preparation is as diesel oil, and is as clear as crystal, not muddy, do not have the sort of oyster white in the past fully, and the user is acceptant; The stability of guaranteeing the quality: consider market and application need that diesel oil is present, the quality guaranteed period never degenerates more than half a year, do not precipitate, profit does not separate, and can guarantee user's needs fully.The product mutual solubility: diesel oil emulsification has good mutual solubility, and this point is the most important factor that can oil in water emulsion be promoted on a large scale, otherwise promote impossible; Energy-conservation practicality: the micro emulsion diesel fuel additive of the present invention's preparation has improved the physicochemical property and the result of use of emulsified fuel oil greatly, energy-conservation more than 30%, more than the tail gas clean-up rate 30-60%, more than the cost decline 15-20%, dynamic performance and oil consumption and pure diesel oil do not have big-difference.General generalization: (1) equipment is simple, less investment, high efficiency, go up detective; (2) need not to transform engine, can mix use, and not limited by ratio, also can use separately with existing diesel oil; (3) simple, easy to operate, the abundant raw material of technology, cost is low, is easy to apply; (4) ignition characteristic good, easily start, non-oxidation, burn into thermo-efficiency height not; (5) yield faster results and bigger economic returns and call for smaller investment; (6) explosive power is strong, and horsepower does not subtract, and flue dust reduces, and machine is not had any infringement; (7) oil colours is constant, and artificial mechanism all can be operated; (8) have characteristics such as good security and stability.
(4) embodiment
Below the invention will be further described.
Embodiment 1: the preparation method of a kind of micro emulsion diesel fuel additive of the present invention, and step is as follows:
Step 1: choose by weight percentage: 8%120# solvent oil, 8% pimelinketone, 7% ethyl acetate, 9% calcium sulphonate, 21% nitric acid isooctyl, 14% iodate dioctyl succinate sodium salt, 8% copper naphthenate, 7% manganese naphthenate, 7% barium naphthenate, 3.5% magnesium naphthenate, 7% methylethyl ketone peroxide, 0.35% hydrazine hydrate and 0.15% diethyl hydroxylamine, at normal temperatures and pressures, above-mentioned raw materials is sequentially added in the stirred pot, makes adjusting material through 100 minutes abundant stirrings;
Step 2: choose by weight percentage: oleic acid 60%, naphthenic acid 10%, thanomin 6%, trolamine 2%, hexahydroaniline 7%, propyl carbinol 3%, Virahol 3%, Span-80 2%, this dish-200.5%, polyoxyethylene glycol 0.5%, alkylphenol polyoxyethylene OP
42%, alkylphenol polyoxyethylene OP
100.5% and by the adjusting material 3.5% that step 1 makes, at normal temperatures and pressures, above-mentioned raw materials is sequentially added in the stirred pot, make brown yellow transparent liquid through 40-60 minute abundant stirring, be the micro emulsion diesel fuel additive.
Embodiment 2: choose by weight percentage: oleic acid 68%, thanomin 6%, trolamine 2%, hexahydroaniline 8%, propyl carbinol 4%, Virahol 3%, Span-80 2%, this dish-20 0.5%, polyoxyethylene glycol 0.5%, alkylphenol polyoxyethylene OP
42%, alkylphenol polyoxyethylene OP
100.5%, adjusting material 3.5%, under the condition of normal temperature and pressure, above-mentioned raw materials is sequentially added in the stirred pot, makes brown xanchromatic transparent liquid through 40-60 minute abundant stirring, is the micro emulsion diesel fuel additive.
Embodiment 3: following is the examining report of diesel oil emulsification:
Heilongjiang Province's quality surveillance detects research institute
The?Academy?of?Quality?Supervision?and?Inspection?in?Heilongjiang?Province
Survey report
Test?Report
Claims (1)
1. the preparation method of a micro emulsion diesel fuel additive, it is characterized in that: step is as follows:
Step 1: choose by weight percentage: 8%120# solvent oil, 8% pimelinketone, 7% ethyl acetate, 9% calcium sulphonate, 21% nitric acid isooctyl, 14% iodate dioctyl succinate sodium salt, 8% copper naphthenate, 7% manganese naphthenate, 7% barium naphthenate, 3.5% magnesium naphthenate, 7% methylethyl ketone peroxide, 0.35% hydrazine hydrate and 0.15% diethyl hydroxylamine, at normal temperatures and pressures, above-mentioned raw materials is sequentially added in the stirred pot, makes adjusting material through 100 minutes abundant stirrings;
Step 2: choose by weight percentage: oleic acid 60%, naphthenic acid 10%, thanomin 6%, trolamine 2%, hexahydroaniline 7%, propyl carbinol 3%, Virahol 3%, Span-80 2%, this dish-20 0.5%, polyoxyethylene glycol 0.5%, alkylphenol polyoxyethylene OP
42%, alkylphenol polyoxyethylene OP
100.5%, the adjusting material 3.5% that is made by step 1 at normal temperatures and pressures, is sequentially added into above-mentioned raw materials in the stirred pot, makes brown yellow transparent liquid through 40-60 minute abundant stirring, is the micro emulsion diesel fuel additive.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643692A (en) * | 2012-05-08 | 2012-08-22 | 刘少君 | Concentrated emulsified diesel fuel and preparation method thereof |
| CN103013591A (en) * | 2012-12-28 | 2013-04-03 | 长安大学 | Microemulsified diesel and preparation method thereof |
| CN103045311A (en) * | 2013-01-18 | 2013-04-17 | 福建省新然环保能源有限公司 | Micro-emulsified diesel oil and preparation method thereof |
| CN103254952A (en) * | 2012-02-20 | 2013-08-21 | 闫冬良 | Preparation method of water-based micro-emulsion diesel oil |
| CN104845686A (en) * | 2015-03-28 | 2015-08-19 | 宁夏宝塔石化科技实业发展有限公司 | Formula of diesel oil micro-emulsified complexing agent and preparation method of emulsified diesel oil |
| CN105199789A (en) * | 2015-08-26 | 2015-12-30 | 福建省新然环保能源有限公司 | High-temperature-resisting superstrong dynamic water-repelling microemulsification diesel fuel main additive and preparation method thereof |
| CN105199790A (en) * | 2015-08-26 | 2015-12-30 | 福建省新然环保能源有限公司 | High-temperature-resisting superstrong dynamic water-repelling microemulsion diesel fuel auxiliary additive and preparation method thereof |
| CN105199791A (en) * | 2015-08-26 | 2015-12-30 | 福建省新然环保能源有限公司 | High-temperature-resisting superstrong dynamic water-repelling microemulsification diesel fuel composite additive and preparation method thereof |
| CN110317648A (en) * | 2019-08-21 | 2019-10-11 | 章敏 | A kind of peace and quiet synergist of diesel oil environmental protection and preparation method |
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|---|---|---|---|---|
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| CN103254952B (en) * | 2012-02-20 | 2015-08-19 | 闫冬良 | A kind of preparation of water base micro-emulsion diesel |
| CN103254952A (en) * | 2012-02-20 | 2013-08-21 | 闫冬良 | Preparation method of water-based micro-emulsion diesel oil |
| CN102643692B (en) * | 2012-05-08 | 2014-04-16 | 刘少君 | Concentrated emulsified diesel fuel and preparation method thereof |
| CN102643692A (en) * | 2012-05-08 | 2012-08-22 | 刘少君 | Concentrated emulsified diesel fuel and preparation method thereof |
| CN103013591B (en) * | 2012-12-28 | 2015-07-08 | 长安大学 | Microemulsified diesel and preparation method thereof |
| CN103013591A (en) * | 2012-12-28 | 2013-04-03 | 长安大学 | Microemulsified diesel and preparation method thereof |
| CN103045311B (en) * | 2013-01-18 | 2015-01-07 | 福建省新然环保能源有限公司 | Micro-emulsified diesel oil and preparation method thereof |
| CN103045311A (en) * | 2013-01-18 | 2013-04-17 | 福建省新然环保能源有限公司 | Micro-emulsified diesel oil and preparation method thereof |
| CN104845686A (en) * | 2015-03-28 | 2015-08-19 | 宁夏宝塔石化科技实业发展有限公司 | Formula of diesel oil micro-emulsified complexing agent and preparation method of emulsified diesel oil |
| CN104845686B (en) * | 2015-03-28 | 2017-01-18 | 宁夏宝塔石化科技实业发展有限公司 | Formula of diesel oil micro-emulsified complexing agent and preparation method of emulsified diesel oil |
| CN105199789A (en) * | 2015-08-26 | 2015-12-30 | 福建省新然环保能源有限公司 | High-temperature-resisting superstrong dynamic water-repelling microemulsification diesel fuel main additive and preparation method thereof |
| CN105199790A (en) * | 2015-08-26 | 2015-12-30 | 福建省新然环保能源有限公司 | High-temperature-resisting superstrong dynamic water-repelling microemulsion diesel fuel auxiliary additive and preparation method thereof |
| CN105199791A (en) * | 2015-08-26 | 2015-12-30 | 福建省新然环保能源有限公司 | High-temperature-resisting superstrong dynamic water-repelling microemulsification diesel fuel composite additive and preparation method thereof |
| CN110317648A (en) * | 2019-08-21 | 2019-10-11 | 章敏 | A kind of peace and quiet synergist of diesel oil environmental protection and preparation method |
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