CN102250511A - Pad printing ink for elastic paint surface decoration - Google Patents
Pad printing ink for elastic paint surface decoration Download PDFInfo
- Publication number
- CN102250511A CN102250511A CN2011100218008A CN201110021800A CN102250511A CN 102250511 A CN102250511 A CN 102250511A CN 2011100218008 A CN2011100218008 A CN 2011100218008A CN 201110021800 A CN201110021800 A CN 201110021800A CN 102250511 A CN102250511 A CN 102250511A
- Authority
- CN
- China
- Prior art keywords
- printing ink
- paint surface
- surface decoration
- pad
- transfer printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 39
- 238000005034 decoration Methods 0.000 title claims abstract description 31
- 238000007649 pad printing Methods 0.000 title abstract 5
- 239000002904 solvent Substances 0.000 claims abstract description 26
- 239000000049 pigment Substances 0.000 claims abstract description 16
- 229920001225 polyester resin Polymers 0.000 claims abstract description 15
- 239000004645 polyester resin Substances 0.000 claims abstract description 15
- 238000010023 transfer printing Methods 0.000 claims description 25
- 238000007639 printing Methods 0.000 claims description 16
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 14
- 239000013530 defoamer Substances 0.000 claims description 13
- 239000006185 dispersion Substances 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 150000002576 ketones Chemical class 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Polymers C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 230000007613 environmental effect Effects 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Polymers COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229920003225 polyurethane elastomer Polymers 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 238000013461 design Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000000007 visual effect Effects 0.000 abstract description 3
- 229920001971 elastomer Polymers 0.000 abstract description 2
- 238000012545 processing Methods 0.000 abstract description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 229920005749 polyurethane resin Polymers 0.000 abstract 1
- 238000007790 scraping Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WUNYIZFTHRAWOD-UHFFFAOYSA-N 6-butoxyhexan-1-ol Chemical compound CCCCOCCCCCCO WUNYIZFTHRAWOD-UHFFFAOYSA-N 0.000 description 1
- 235000007926 Craterellus fallax Nutrition 0.000 description 1
- 240000007175 Datura inoxia Species 0.000 description 1
- RMMPZDDLWLALLJ-UHFFFAOYSA-N Thermophillin Chemical compound COC1=CC(=O)C(OC)=CC1=O RMMPZDDLWLALLJ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 201000001371 inclusion conjunctivitis Diseases 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229910052705 radium Inorganic materials 0.000 description 1
- HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 1
- 206010044325 trachoma Diseases 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Abstract
The invention discloses pad printing ink for elastic paint surface decoration. The pad printing ink comprises: be weight, 20 to 40% of a polyurethane resin, 15 to 30% of a modified polyester resin, 20 to 35% of one or two solvents, 5 to 35% of pigment, 0.1 to 5% of a dispersant and 0.1 to 5% of a defoaming agent. The one or two solvents adopted in the invention do not contain polycyclic aromatic hydrocarbons (PAHS) thus are environmentally friendly. After being baked at a temperature of 80 DEG C for 30 to 60 minutes, the pad printing ink coated on a rubber paint product and the surface of elastic paint has the characteristics of excellent adhesiveness, scraping resistance, alcohol resistance, aging resistance and wear resistance. The pad printing ink simplifies a decoration processing technology for elastic paint surfaces, improves production efficiency, reduces an unqualified rate of products, and provides multiple choices for enriching decorative designs and visual effects of elastic paint surface materials.
Description
Technical field
The present invention relates to a kind of pad-transfer printing ink, but relate in particular to a kind of elastomeric paint surface decoration printing ink of bat printing.
Background technology
Be accompanied by the continuous pursuit of people to high-quality life, a large amount of handheld mobile devices adopt elastomeric paints, class skin lacquer etc. to have fine and smooth surfacing smooth, comfortable feel to be used for surface decoration on the market; And printing common ink sticking power fastness is poor on the material surface after this type of application, and after traditional method generally adopted the in-mould injection moulding, again at plastic external coating elastomeric paint, this just can't satisfy the various requirement of design rich color; Also have adopt application after, carry out technologies such as laser, radium carving, but inevitably bring as variable color, fade, problems such as the breakage of pattern corner, coating shedding.
Therefore, prior art awaits improving and development.
Summary of the invention
But the object of the present invention is to provide a kind of elastomeric paint surface decoration with pad-transfer printing ink, be intended to solve the deficiencies in the prior art.
In order to solve the problems of the technologies described above, technical scheme of the present invention is as follows:
But a kind of elastomeric paint surface decoration pad-transfer printing ink, by weight percentage, this printing ink is composed of the following components:
Urethane resin 20-40;
Modified polyester resin 15-30;
Solvent 20-35;
Pigment 5-35;
Dispersion agent 0.1-5;
Defoamer 0.1-5.
But described elastomeric paint surface decoration pad-transfer printing ink, wherein, by weight percentage, this printing ink is composed of the following components:
Urethane resin 35;
Modified polyester resin 24;
Solvent 20;
Pigment 18;
Dispersion agent 1.5;
Defoamer 1.5.
But described elastomeric paint surface decoration pad-transfer printing ink, wherein, described urethane resin is the solid thermoplastic urethane resin, and its solids content is more than or equal to 35%, and elongation is more than or equal to 500%; Described modified polyester resin is the polyurethane elastomer modified polyester resin, and its hydroxyl value is 50, admittedly contain greater than 99.5%, proportion is 1.26g/cm
3
But described elastomeric paint surface decoration pad-transfer printing ink, wherein, described defoamer is silicone based defoamer.
But described elastomeric paint surface decoration pad-transfer printing ink, wherein, described dispersion agent is the polyurethane-modified acrylic acid multipolymer.
But described elastomeric paint surface decoration pad-transfer printing ink, wherein, described solvent is one or both of ketones solvent or pure ether solvent.
But described elastomeric paint surface decoration pad-transfer printing ink, wherein, described pigment is inorganic or organic feature of environmental protection pigment, and is not halogen-containing.
But described elastomeric paint surface decoration pad-transfer printing ink, wherein, but described elastomeric paint surface decoration is 20000-30000CPS with the viscosity of pad-transfer printing ink under 20 ℃ of room temperatures.
Beneficial effect of the present invention: solvent used in the present invention is than environmental protection, and no PAHS behind 80 ℃ of baking 30-60min, has the sticking power, scratch resistance, ethanol-tolerant of excellence, characteristic such as ageing-resistant, wear-resistant on elastomeric paint surface and rubber paint goods; Simplified technology, improved production efficiency, reduced percent defective greatly in the processing of elastomeric paint surface decoration; Simultaneously, the decoration conceptual design of horn of plenty elastomeric paint surfacing and visual effect provide more various selection.
Description of drawings
But Fig. 1 is benzene inventive embodiments gained elastomeric paint surface decoration pad-transfer printing ink printing effect and physical and chemical index state table on material.
Embodiment
Below, preferred embodiment of the present invention is described in further detail.
But the invention provides a kind of elastomeric paint surface decoration pad-transfer printing ink, by weight percentage, this printing ink is composed of the following components:
Urethane resin 20-40;
Modified polyester resin 15-30;
Solvent 20-35;
Pigment 5-35;
Dispersion agent 0.1-5;
Defoamer 0.1-5.
But elastomeric paint surface decoration of the present invention pad-transfer printing ink, by weight percentage, this printing ink can be composed of the following components:
Urethane resin 35;
Modified polyester resin 24;
Solvent 20;
Pigment 18;
Dispersion agent 1.5;
Defoamer 1.5.
Specifically, described urethane resin is the solid thermoplastic urethane resin, and its solids content is more than or equal to 35%, and elongation is more than or equal to 500%; Described modified polyester resin is the polyurethane elastomer modified polyester resin, and its hydroxyl value is 50, admittedly contain greater than 99.5%, proportion is 1.26g/cm
3, the second-order transition temperature of filming is low, is in elastomeric state under the normal temperature.
Described defoamer is silicone based defoamer; Described dispersion agent is the polyurethane-modified acrylic acid multipolymer; Described solvent is one or more of ketones solvent, pure ether solvent; Described pigment is inorganic or organic feature of environmental protection pigment, and is not halogen-containing; Described solvent is one or more of ketones solvent or pure ether solvent, and ketones solvent can be isophorone, pimelinketone, methyl iso-butyl ketone (MIBK) etc., and pure ether solvent can be hexylene glycol butyl ether etc.
The effect of solvent is a dissolving resin, regulates ink viscosity; The effect of defoamer is elimination and is suppressed at the bubble that is produced in printing ink manufacturing and the use, prevents that disadvantages such as trachoma, pin hole from appearring in ink film; The effect of dispersion agent is to be used to help the dispersion of pigment in institute use system the inside, significantly shortens milling time, improves gloss and tinting strength, and improves the stability in storage of mill base greatly.
Printing ink of the present invention is under 20 ℃ of room temperatures, and its viscosity is 20000-30000CPS.Both can be used for silk-screen and also can be used for bat printing, and strong adhesion, paint film is flexible, and superior anti-ethanol, acidproof, alkaline-resisting, ageing resistance are arranged; Good wear resistance is arranged, and give soft texture and abundant visual effect.
Embodiment 1
Get 20 parts of ketones solvents (weight) under the normal temperature and pressure, 35 parts of urethane resins (weight), 24 parts of (weight) 600-1200r/min of modified polyester resin stirred 15-30 minute, after making its dissolving fully, add 1.5 parts of dispersion agents (weight), 18 parts of pigment (weight), crossing three-roller after stirring is ground to below the 10 ц m, add 1.5 parts of defoamers (weight) again, after dispersed with stirring is even, get product.
Embodiment 2
Get 15 parts of ketones solvents (weight) under the normal temperature and pressure, 30.5 parts of urethane resins (weight), 28.5 parts of (weight) 600-1200r/min of modified polyester resin stirred 15-30 minute, make its dissolving fully after, add 1.5 parts of dispersion agents (weight), 18 parts of pigment (weight), cross three-roller after stirring and be ground to below the 10 ц m, add 1.5 parts of defoamers (weight) again, 5 parts of pure ether solvents (weight), after dispersed with stirring is even, get product.
But on the elastomeric paint surface, when bat printing thickness was 10 ц m, printing ink printing effect and physical and chemical index state on material were seen shown in Figure 1 with pad-transfer printing ink for above embodiment gained elastomeric paint surface decoration.
Should be understood that, for those of ordinary skills, can be improved according to the above description or conversion, and all these improvement and conversion all should belong to the protection domain of claims of the present invention.
Claims (8)
1. but an elastomeric paint surface decoration is with pad-transfer printing ink, and by weight percentage, this printing ink is composed of the following components:
Urethane resin 20-40;
Modified polyester resin 15-30;
Solvent 20-35;
Pigment 5-35;
Dispersion agent 0.1-5;
Defoamer 0.1-5.
2. but elastomeric paint surface decoration according to claim 1 pad-transfer printing ink is characterized in that by weight percentage, this printing ink is composed of the following components:
Urethane resin 35;
Modified polyester resin 24;
Solvent 20;
Pigment 18;
Dispersion agent 1.5;
Defoamer 1.5.
3. but elastomeric paint surface decoration according to claim 1 and 2 is characterized in that with pad-transfer printing ink described urethane resin is the solid thermoplastic urethane resin, and its solids content is more than or equal to 35%, and elongation is more than or equal to 500%; Described modified polyester resin is the polyurethane elastomer modified polyester resin, and its hydroxyl value is 50, admittedly contain greater than 99.5%, proportion is 1.26g/cm
3
4. but elastomeric paint surface decoration according to claim 1 and 2 is characterized in that with pad-transfer printing ink described defoamer is silicone based defoamer.
5. but elastomeric paint surface decoration according to claim 1 and 2 is characterized in that with pad-transfer printing ink described dispersion agent is the polyurethane-modified acrylic acid multipolymer.
6. but elastomeric paint surface decoration according to claim 1 and 2 is characterized in that with pad-transfer printing ink described solvent is one or both of ketones solvent, pure ether solvent.
7. but elastomeric paint surface decoration according to claim 1 and 2 is characterized in that with pad-transfer printing ink described pigment is inorganic or organic feature of environmental protection pigment, and is not halogen-containing.
8. but elastomeric paint surface decoration according to claim 1 and 2 is characterized in that with pad-transfer printing ink, but described elastomeric paint surface decoration is 20000-30000CPS with the viscosity of pad-transfer printing ink under 20 ℃ of room temperatures.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110021800 CN102250511B (en) | 2011-01-19 | 2011-01-19 | Pad printing ink for elastic paint surface decoration |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110021800 CN102250511B (en) | 2011-01-19 | 2011-01-19 | Pad printing ink for elastic paint surface decoration |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102250511A true CN102250511A (en) | 2011-11-23 |
| CN102250511B CN102250511B (en) | 2013-10-02 |
Family
ID=44978092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110021800 Expired - Fee Related CN102250511B (en) | 2011-01-19 | 2011-01-19 | Pad printing ink for elastic paint surface decoration |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102250511B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103160198A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | Apple fragrant colorful super wear-resistant oily elastic paint |
| CN103232753A (en) * | 2013-04-25 | 2013-08-07 | 深圳市美丽华油墨涂料有限公司 | Transfer printing ink for elastic paint surface and preparation method thereof |
| CN103232752A (en) * | 2013-04-25 | 2013-08-07 | 深圳市美丽华油墨涂料有限公司 | Screen printing ink for UV (ultraviolet) paint surface and preparation method thereof |
| CN103254685A (en) * | 2013-04-25 | 2013-08-21 | 深圳市美丽华油墨涂料有限公司 | Ink for surface of finish paint and preparation method thereof |
| CN110204952A (en) * | 2019-05-31 | 2019-09-06 | 深圳市崯涛油墨科技有限公司 | Shock resistance screen printing ink and preparation method thereof for polycarbonate composite plate |
| CN111138904A (en) * | 2020-02-20 | 2020-05-12 | 深圳市崯涛油墨科技有限公司 | Composite board silk-screen printing ink with mirror-surface-protecting silver logo pattern and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004300393A (en) * | 2003-04-01 | 2004-10-28 | Seiko Epson Corp | Ink composition for inkjet-recording, and method for recording and recorded matter by using the same |
| JP2004315751A (en) * | 2003-04-18 | 2004-11-11 | Seiko Epson Corp | Ink composition and process for producing the same |
| CN1821328A (en) * | 2006-03-27 | 2006-08-23 | 佛山市万正涂料有限公司 | Polyurethane modified unsaturated polyester varnish |
-
2011
- 2011-01-19 CN CN 201110021800 patent/CN102250511B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004300393A (en) * | 2003-04-01 | 2004-10-28 | Seiko Epson Corp | Ink composition for inkjet-recording, and method for recording and recorded matter by using the same |
| JP2004315751A (en) * | 2003-04-18 | 2004-11-11 | Seiko Epson Corp | Ink composition and process for producing the same |
| CN1821328A (en) * | 2006-03-27 | 2006-08-23 | 佛山市万正涂料有限公司 | Polyurethane modified unsaturated polyester varnish |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103160198A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | Apple fragrant colorful super wear-resistant oily elastic paint |
| CN103160198B (en) * | 2011-12-13 | 2015-07-01 | 金甲化工企业(中山)有限公司 | Apple fragrant colorful super wear-resistant oily elastic paint |
| CN103232753A (en) * | 2013-04-25 | 2013-08-07 | 深圳市美丽华油墨涂料有限公司 | Transfer printing ink for elastic paint surface and preparation method thereof |
| CN103232752A (en) * | 2013-04-25 | 2013-08-07 | 深圳市美丽华油墨涂料有限公司 | Screen printing ink for UV (ultraviolet) paint surface and preparation method thereof |
| CN103254685A (en) * | 2013-04-25 | 2013-08-21 | 深圳市美丽华油墨涂料有限公司 | Ink for surface of finish paint and preparation method thereof |
| CN103232752B (en) * | 2013-04-25 | 2014-10-01 | 深圳市美丽华油墨涂料有限公司 | Screen printing ink for UV (ultraviolet) paint surface and preparation method thereof |
| CN103254685B (en) * | 2013-04-25 | 2015-06-17 | 深圳市美丽华油墨涂料有限公司 | Ink for surface of finish paint and preparation method thereof |
| CN110204952A (en) * | 2019-05-31 | 2019-09-06 | 深圳市崯涛油墨科技有限公司 | Shock resistance screen printing ink and preparation method thereof for polycarbonate composite plate |
| CN110204952B (en) * | 2019-05-31 | 2022-03-15 | 深圳市崯涛油墨科技有限公司 | Impact-resistant screen printing ink for polycarbonate composite board and preparation method thereof |
| CN111138904A (en) * | 2020-02-20 | 2020-05-12 | 深圳市崯涛油墨科技有限公司 | Composite board silk-screen printing ink with mirror-surface-protecting silver logo pattern and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102250511B (en) | 2013-10-02 |
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| C06 | Publication | ||
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| ASS | Succession or assignment of patent right |
Owner name: SHENZHEN MEILIHUA INK + COATING CO., LTD. Free format text: FORMER OWNER: YIKE INKS + PAINTS (SHENGZHEN) CO., LTD. Effective date: 20120330 |
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Effective date of registration: 20120330 Address after: 518103, Feng Tong Road 243, Fuyong Town, Shenzhen, Guangdong, Baoan District Applicant after: Shenzhen Meilihua Ink & Coating Co., Ltd. Address before: 518103 Guangdong city of Shenzhen province Baoan District Fuyong Whitehead industrial district Applicant before: Yike Inks & Paints (Shengzhen) Co., Ltd. |
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Address after: Shenzhen, Guangdong, Baoan District province Fuyong street, Feng Tong Avenue and Yonghe Road intersection Patentee after: Shenzhen beautiful Polytron Technologies Inc Address before: 518103, Feng Tong Road 243, Fuyong Town, Shenzhen, Guangdong, Baoan District Patentee before: Shenzhen Meilihua Ink & Coating Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131002 Termination date: 20190119 |