CN110028889A - A kind of environment-protection functional water paint on plastic material - Google Patents
A kind of environment-protection functional water paint on plastic material Download PDFInfo
- Publication number
- CN110028889A CN110028889A CN201910351233.9A CN201910351233A CN110028889A CN 110028889 A CN110028889 A CN 110028889A CN 201910351233 A CN201910351233 A CN 201910351233A CN 110028889 A CN110028889 A CN 110028889A
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- China
- Prior art keywords
- plastic material
- environment
- water paint
- functional water
- protection functional
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The environment-protection functional water paint that the present invention provides a kind of on plastic material, including 50~55% Hydroxylated acrylic resin dispersion liquid, 8~12% water, 0.1~0.3% levelling degasser, 2~4% wetting dispersing agent, 0.2~0.4% levelling agent, 0.05~0.2% surface active agent, 0.6~0.8% light stabilizer, 1.2~1.6% aqueous polyurethane paint curing catalysts, 1~1.4% water paint surface modifier, 0.1~0.3% cellulose thickener, 2.5~3% functional filler, 4~4.4% villus powder, 1.2~1.6% superfine talcum powder, the delustering agent of 11~13% iron oxide black 1.2~1.6%, 4~6% Borchers VP and 5~ 5.2% curing agent is prepared.The coating has fabulous adhesive force with metal to most plastics.Dry film comfortable feel, high resiliency, soft abrasion-resistant, scratch resistant have self-reparing capability, and against weather is good.It protects and covers with paint, lacquer, colour wash, etc. suitable for automobile interior exterior, the polymer composites such as mobile phone shell are more suitable for requiring the daily necessities top finishing of good hand touch.The VOC of whole process is zero, and low energy consumption, its main feature is that entire technical process green low-carbon, environmental protection and energy saving.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of aqueous painting of environment-protection functional on plastic material
Material.
Background technique
With the objective requirement of enhancing and the environmental protection of people's environmental consciousness, traditional solvent type coating is in coating process
In will cause the volatilizations of a large amount of organic solvents, not only will affect the performance of film, can also damage the health of operating personnel and cause
Environmental pollution.Traditional coating exists not in terms of curing rate, to the adhesive force, boiling resistance and wearability of metal surface etc.
Foot.
Summary of the invention
To solve the above problems, the environment-protection functional water paint that the present invention provides a kind of on plastic material, this
The coating of invention be it is a kind of use water as solvent, applied to the coating of surfaces of various materials, excellent performance to material rise
The defect for having arrived protecting effect, while having improved many material surfaces itself, plays aesthetic effect, and can provide for material
A variety of properties, to improve product competitiveness, specific implementation is as follows:
A kind of environment-protection functional water paint on plastic material, it is characterised in that: described to be used for plastic material
Environment-protection functional water paint include by weight percentage following components composition:
Further, the plastic material is one of poly- carbonic acid resin class plastics and poly terephthalic acid class plastics.
Further, the Hydroxylated acrylic resin dispersion liquid is 55% Hydroxylated acrylic resin dispersion liquid by mass fraction
It is formed with 40% Hydroxylated acrylic resin dispersion liquid, the 55% Hydroxylated acrylic resin dispersion liquid and 40% hydroxy acrylic acid tree
The mass ratio of rouge dispersion liquid is 1:0.7~0.75.
Further, the viscosity of the 40% Hydroxylated acrylic resin dispersion liquid be 15mPas, pH value 7.5, wherein
It is sodium salt, organic solvent content 0%, minimum film formation temperature≤0 DEG C with agent.
Further, the light stabilizer is the ethylene glycol butyraldehyde liquid that mass fraction is 75%.
Further, the mass fraction of the aqueous polyurethane paint curing catalysts is 10%.
Further, the curing agent is hydrophilic HDI polyisocyanates, the quality point of the hydrophilic HDI polyisocyanates
Number is 75%.
Further, the hydrophilic HDI polyisocyanates is solvent-free, wherein the mass fraction of free HDI≤
0.15% ,-NCO content is 17.4 ± 0.5%, and viscosity is 2800 ± 800mPas.
Beneficial effects of the present invention:
The present invention has most plastics with metal using the coating of Hydroxylated acrylic resin dispersion liquid preparation fabulous attached
Put forth effort.Villus powder is added in coating simultaneously and superfine talcum powder makes comfortable feel after coating dry film, high resiliency is soft resistance to
Mill, scratch resistant have self-reparing capability, and against weather is good.It protects and covers with paint, lacquer, colour wash, etc. suitable for automobile interior exterior, be more suitable for requiring the daily of good hand touch
Product top finishing.It in the VOC of the whole process of preparation is zero that the coating, which is water paint, and low energy consumption, its main feature is that entirely
Technical process green low-carbon, environmental protection and energy saving.
Specific embodiment
The present invention will be further described below with reference to implementing, but protection power of the invention is without being limited thereto:
Embodiment 1
A kind of environment-protection functional water paint on plastic material, it is characterised in that: described to be used for plastic material
Environment-protection functional water paint include by weight percentage following components composition:
According to above-mentioned formula, by 55% Hydroxylated acrylic resin dispersion liquid and 40% Hydroxylated acrylic resin homogeneous dispersion
It is dissolved in the water, then in 40 DEG C hereinafter, grinding villus powder and superfine talcum powder, then sequentially add levelling degasser, wetting
Dispersing agent, levelling agent, surface active agent, light stabilizer, aqueous polyurethane paint curing catalysts, water paint surface modifier, fiber
Plain thickener, functional filler, villus powder, superfine talcum powder, iron oxide black, delustering agent and Borchers VP are stirred evenly, most
Curing agent is added afterwards, the environment-protection functional water paint on plastic material is prepared.
Embodiment 2
A kind of environment-protection functional water paint on plastic material, it is characterised in that: described to be used for plastic material
Environment-protection functional water paint include by weight percentage following components composition:
According to above-mentioned formula, by 55% Hydroxylated acrylic resin dispersion liquid and 40% Hydroxylated acrylic resin homogeneous dispersion
It is dissolved in the water, then in 40 DEG C hereinafter, grinding villus powder and superfine talcum powder, then sequentially add levelling degasser, wetting
Dispersing agent, levelling agent, surface active agent, light stabilizer, aqueous polyurethane paint curing catalysts, water paint surface modifier, fiber
Plain thickener, functional filler, villus powder, superfine talcum powder, iron oxide black, delustering agent and Borchers VP are stirred evenly, most
Curing agent is added afterwards, the environment-protection functional water paint on plastic material is prepared.
Embodiment 3
A kind of environment-protection functional water paint on plastic material, it is characterised in that: described to be used for plastic material
Environment-protection functional water paint include by weight percentage following components composition:
According to above-mentioned formula, by 55% Hydroxylated acrylic resin dispersion liquid and 40% Hydroxylated acrylic resin homogeneous dispersion
It is dissolved in the water, then in 40 DEG C hereinafter, grinding villus powder and superfine talcum powder, then sequentially add levelling degasser, wetting
Dispersing agent, levelling agent, surface active agent, light stabilizer, aqueous polyurethane paint curing catalysts, water paint surface modifier, fiber
Plain thickener, functional filler, villus powder, superfine talcum powder, iron oxide black, delustering agent and Borchers VP are stirred evenly, most
Curing agent is added afterwards, the environment-protection functional water paint on plastic material is prepared.
The coating that Examples 1 to 3 is prepared is chosen, compressed air spraying is carried out, detects its performance ,-NCO of the coating
Mass ratio with-OH is 1.5:1, mass fraction of solids 45%, working life 30min, binder content 27.8%, pH
Value is 7~7.5, and pigments and fillers content is 20.9%.The coating has fabulous adhesive force with metal to most plastics.Dry film feel
Comfortably, high resiliency, soft abrasion-resistant, scratch resistant have self-reparing capability, and against weather is good.It protects and covers with paint, lacquer, colour wash, etc. suitable for automobile interior exterior, it is more suitable
In the daily necessities top finishing for requiring good hand touch.The VOC of whole process is zero, and low energy consumption, its main feature is that entire technique mistake
Journey green low-carbon, environmental protection and energy saving.
Claims (8)
1. a kind of environment-protection functional water paint on plastic material, it is characterised in that: described on plastic material
Environment-protection functional water paint includes following components composition by weight percentage:
2. a kind of environment-protection functional water paint on plastic material according to claim 1, it is characterised in that: institute
Stating plastic material is one of poly- carbonic acid resin class plastics and poly terephthalic acid class plastics.
3. a kind of environment-protection functional water paint on plastic material according to claim 1, it is characterised in that: institute
It is 55% Hydroxylated acrylic resin dispersion liquid and 40% hydroxy acrylic acid tree that Hydroxylated acrylic resin dispersion liquid, which is stated, by mass fraction
Rouge dispersion liquid forms, and the mass ratio of the 55% Hydroxylated acrylic resin dispersion liquid and 40% Hydroxylated acrylic resin dispersion liquid is
1:0.7~0.75.
4. a kind of environment-protection functional water paint on plastic material according to claims 1 and 2, feature exist
In: the viscosity of the 40% Hydroxylated acrylic resin dispersion liquid is 15mPas, and pH value 7.5, neutralizer is sodium salt, organic
Solvent content is 0%, minimum film formation temperature≤0 DEG C.
5. a kind of environment-protection functional water paint on plastic material according to claim 1, it is characterised in that: institute
Stating light stabilizer is the ethylene glycol butyraldehyde liquid that mass fraction is 75%.
6. a kind of environment-protection functional water paint on plastic material according to claim 1, it is characterised in that: institute
The mass fraction for stating aqueous polyurethane paint curing catalysts is 10%.
7. a kind of environment-protection functional water paint on plastic material according to claim 1, it is characterised in that: institute
Stating curing agent is hydrophilic HDI polyisocyanates, and the mass fraction of the hydrophilic HDI polyisocyanates is 75%.
8. existing according to claim 1 with a kind of environment-protection functional water paint on plastic material, feature described in 7
In: the hydrophilic HDI polyisocyanates is solvent-free, wherein mass fraction≤0.15% of free HDI ,-NCO content is 17.4
± 0.5%, viscosity is 2800 ± 800mPas.
Priority Applications (1)
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CN201910351233.9A CN110028889A (en) | 2019-04-28 | 2019-04-28 | A kind of environment-protection functional water paint on plastic material |
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CN201910351233.9A CN110028889A (en) | 2019-04-28 | 2019-04-28 | A kind of environment-protection functional water paint on plastic material |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111040544A (en) * | 2019-12-26 | 2020-04-21 | 南京华格电汽塑业有限公司 | Formula and preparation process of water-based paint for plastic parts |
CN111500174A (en) * | 2020-04-03 | 2020-08-07 | 长沙松润新材料有限公司 | Water-based matte coating for automotive interior and preparation method and application thereof |
CN112552809A (en) * | 2020-12-09 | 2021-03-26 | 惠州市百时达化工有限公司 | Water-based hand-feeling coating applied to automotive interior and preparation method thereof |
CN116694214A (en) * | 2023-06-26 | 2023-09-05 | 广东英凯建筑材料有限公司 | Slow-drying easy-to-knead velvet art paint and preparation method thereof |
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US3480577A (en) * | 1965-12-27 | 1969-11-25 | Shell Oil Co | Paint compositions comprising epoxy resin ester,pigment and glass fibers or polypropylene powder |
CN101240145A (en) * | 2008-03-13 | 2008-08-13 | 徐沛枫 | Single-component skin similar texture paint |
CN101245216A (en) * | 2007-02-16 | 2008-08-20 | 关西涂料株式会社 | Colored coating composition |
CN102504660A (en) * | 2011-11-15 | 2012-06-20 | 东莞劲胜精密组件股份有限公司 | Water-based finishing paint for plastics and preparation method and application thereof |
CN102876158A (en) * | 2011-07-11 | 2013-01-16 | 上海富臣化工有限公司 | Soft anti-stain elastic interior wall latex paint and preparation method thereof |
CN105385250A (en) * | 2015-11-24 | 2016-03-09 | 安徽省金盾涂料有限责任公司 | Aqueous composite coating for plastic |
CN109294421A (en) * | 2017-07-25 | 2019-02-01 | 河北晨阳工贸集团有限公司 | A kind of dedicated resistant feel sealing wax of vacuum cup and preparation method thereof |
-
2019
- 2019-04-28 CN CN201910351233.9A patent/CN110028889A/en active Pending
Patent Citations (7)
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US3480577A (en) * | 1965-12-27 | 1969-11-25 | Shell Oil Co | Paint compositions comprising epoxy resin ester,pigment and glass fibers or polypropylene powder |
CN101245216A (en) * | 2007-02-16 | 2008-08-20 | 关西涂料株式会社 | Colored coating composition |
CN101240145A (en) * | 2008-03-13 | 2008-08-13 | 徐沛枫 | Single-component skin similar texture paint |
CN102876158A (en) * | 2011-07-11 | 2013-01-16 | 上海富臣化工有限公司 | Soft anti-stain elastic interior wall latex paint and preparation method thereof |
CN102504660A (en) * | 2011-11-15 | 2012-06-20 | 东莞劲胜精密组件股份有限公司 | Water-based finishing paint for plastics and preparation method and application thereof |
CN105385250A (en) * | 2015-11-24 | 2016-03-09 | 安徽省金盾涂料有限责任公司 | Aqueous composite coating for plastic |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111040544A (en) * | 2019-12-26 | 2020-04-21 | 南京华格电汽塑业有限公司 | Formula and preparation process of water-based paint for plastic parts |
CN111500174A (en) * | 2020-04-03 | 2020-08-07 | 长沙松润新材料有限公司 | Water-based matte coating for automotive interior and preparation method and application thereof |
CN112552809A (en) * | 2020-12-09 | 2021-03-26 | 惠州市百时达化工有限公司 | Water-based hand-feeling coating applied to automotive interior and preparation method thereof |
CN116694214A (en) * | 2023-06-26 | 2023-09-05 | 广东英凯建筑材料有限公司 | Slow-drying easy-to-knead velvet art paint and preparation method thereof |
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Application publication date: 20190719 |
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