CN102234407A - 阻燃型丙烯腈-苯乙烯-丁二烯树脂组合物及其制备方法 - Google Patents
阻燃型丙烯腈-苯乙烯-丁二烯树脂组合物及其制备方法 Download PDFInfo
- Publication number
- CN102234407A CN102234407A CN2011101170453A CN201110117045A CN102234407A CN 102234407 A CN102234407 A CN 102234407A CN 2011101170453 A CN2011101170453 A CN 2011101170453A CN 201110117045 A CN201110117045 A CN 201110117045A CN 102234407 A CN102234407 A CN 102234407A
- Authority
- CN
- China
- Prior art keywords
- styrene
- acrylonitrile
- parts
- resin composition
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 69
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title claims abstract description 62
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 239000011342 resin composition Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims description 8
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title abstract description 20
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 20
- 239000000314 lubricant Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000003365 glass fiber Substances 0.000 claims description 20
- 239000003112 inhibitor Substances 0.000 claims description 18
- 230000003647 oxidation Effects 0.000 claims description 18
- 238000007254 oxidation reaction Methods 0.000 claims description 18
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical group O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 16
- -1 tribromophenoxy Chemical group 0.000 claims description 16
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 12
- 238000005469 granulation Methods 0.000 claims description 10
- 230000003179 granulation Effects 0.000 claims description 10
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 10
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 claims description 8
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 8
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 8
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 8
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 6
- 230000000979 retarding effect Effects 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000007983 Tris buffer Substances 0.000 claims description 4
- 229940059574 pentaerithrityl Drugs 0.000 claims description 4
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 235000019260 propionic acid Nutrition 0.000 claims description 4
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 4
- DGZQEAKNZXNTNL-UHFFFAOYSA-N 1-bromo-4-butan-2-ylbenzene Chemical class CCC(C)C1=CC=C(Br)C=C1 DGZQEAKNZXNTNL-UHFFFAOYSA-N 0.000 claims description 3
- WSEFPKKOUNRCAJ-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;octadecanoic acid Chemical compound OCC(CO)(CO)CO.CCCCCCCCCCCCCCCCCC(O)=O WSEFPKKOUNRCAJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 3
- 229920001893 acrylonitrile styrene Polymers 0.000 claims 8
- 229920002857 polybutadiene Polymers 0.000 claims 8
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims 8
- 238000005452 bending Methods 0.000 abstract description 4
- 239000003963 antioxidant agent Substances 0.000 abstract 2
- 230000003078 antioxidant effect Effects 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 9
- 238000011056 performance test Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 230000035939 shock Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000003595 mist Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Abstract
Description
ABS 757(台湾奇美公司产品) | 100份 |
ABS 181(韩国锦湖石化公司产品) | 3份 |
氯化聚乙烯 | 5份 |
FR245 | 18份 |
三氧化二锑 | 5份 |
抗滴落剂PTFE微粉 | 0.2份 |
抗氧剂4,4’-硫代双(6-叔丁基-3-甲基苯酚) | 0.3份 |
润滑剂EBS | 0.2份 |
ABS 757 | 100份 |
ABS DP270(韩国LG化学公司产品) | 8份 |
氯化聚乙烯 | 3份 |
十溴二苯乙烷 | 15份 |
三氧化二锑 | 6份 |
抗滴落剂PTFE颗粒 | 0.2份 |
抗氧剂4,4’-硫代双(6-叔丁基-3-甲基苯酚) | 0.3份 |
润滑剂EBS | 0.2份 |
ABS 747 | 100份 |
ABS 181(韩国锦湖公司产品) | 10份 |
溴化聚苯乙烯 | 25份 |
三氧化二锑 | 5份 |
抗滴落剂PTFE微粉 | 0.5份 |
抗氧剂4,4’-硫代双(6-叔丁基-3-甲基苯酚) | 0.2份 |
润滑剂PETS | 0.8份 |
ABS 757 | 100份 |
FR245 | 18份 |
三氧化二锑 | 5份 |
抗滴落剂PTFE微粉 | 0.2份 |
抗氧剂4,4’-硫代双(6-叔丁基-3-甲基苯酚) | 0.3份 |
润滑剂EBS | 0.2份 |
ABS 757 | 100份 |
ABS 181 | 8份 |
氯化聚乙烯CPE | 3份 |
十溴二苯乙烷 | 15份 |
三氧化二锑 | 6份 |
抗滴落剂PTFE | 0.2份 |
润滑剂EBS | 0.2份 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011101170453A CN102234407B (zh) | 2011-05-06 | 2011-05-06 | 阻燃型丙烯腈-苯乙烯-丁二烯树脂组合物及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011101170453A CN102234407B (zh) | 2011-05-06 | 2011-05-06 | 阻燃型丙烯腈-苯乙烯-丁二烯树脂组合物及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102234407A true CN102234407A (zh) | 2011-11-09 |
CN102234407B CN102234407B (zh) | 2013-03-20 |
Family
ID=44885562
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2011101170453A Active CN102234407B (zh) | 2011-05-06 | 2011-05-06 | 阻燃型丙烯腈-苯乙烯-丁二烯树脂组合物及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN102234407B (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102675811A (zh) * | 2012-05-11 | 2012-09-19 | 江苏安格特科技发展有限公司 | 一种低烟阻燃abs合金材料 |
CN103304911A (zh) * | 2013-06-28 | 2013-09-18 | 青岛国恩科技股份有限公司 | 一种阻燃增强abs材料及其制备方法 |
CN103509312A (zh) * | 2013-09-11 | 2014-01-15 | 青岛颐世保塑料有限公司 | 阻燃abs材料 |
CN103804833A (zh) * | 2014-01-23 | 2014-05-21 | 金发科技股份有限公司 | 一种高流动、高韧性阻燃hips母粒及其制备方法 |
CN104987688A (zh) * | 2015-06-08 | 2015-10-21 | 金发科技股份有限公司 | 一种聚碳酸酯组合物及其制备方法 |
CN106380711A (zh) * | 2016-08-26 | 2017-02-08 | 青岛海尔新材料研发有限公司 | 一种玻纤增强阻燃聚苯乙烯树脂组合物及其制备方法 |
CN108623982A (zh) * | 2017-03-26 | 2018-10-09 | 合肥杰事杰新材料股份有限公司 | 一种高光泽阻燃智能坐便洁身器专用料及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1765985A (zh) * | 2005-11-18 | 2006-05-03 | 王崇高 | 一种阻燃abs生产配方及其制作方法 |
CN101130617A (zh) * | 2006-08-25 | 2008-02-27 | 佛山市顺德区汉达精密电子科技有限公司 | 一种abs复合材料 |
CN101845197A (zh) * | 2009-03-25 | 2010-09-29 | 上海锦湖日丽塑料有限公司 | 一种高性能无卤阻燃abs改性树脂及其制备方法 |
-
2011
- 2011-05-06 CN CN2011101170453A patent/CN102234407B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1765985A (zh) * | 2005-11-18 | 2006-05-03 | 王崇高 | 一种阻燃abs生产配方及其制作方法 |
CN101130617A (zh) * | 2006-08-25 | 2008-02-27 | 佛山市顺德区汉达精密电子科技有限公司 | 一种abs复合材料 |
CN101845197A (zh) * | 2009-03-25 | 2010-09-29 | 上海锦湖日丽塑料有限公司 | 一种高性能无卤阻燃abs改性树脂及其制备方法 |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102675811A (zh) * | 2012-05-11 | 2012-09-19 | 江苏安格特科技发展有限公司 | 一种低烟阻燃abs合金材料 |
CN103304911A (zh) * | 2013-06-28 | 2013-09-18 | 青岛国恩科技股份有限公司 | 一种阻燃增强abs材料及其制备方法 |
CN103509312A (zh) * | 2013-09-11 | 2014-01-15 | 青岛颐世保塑料有限公司 | 阻燃abs材料 |
CN103804833A (zh) * | 2014-01-23 | 2014-05-21 | 金发科技股份有限公司 | 一种高流动、高韧性阻燃hips母粒及其制备方法 |
CN103804833B (zh) * | 2014-01-23 | 2016-05-18 | 金发科技股份有限公司 | 一种高流动、高韧性阻燃hips母粒及其制备方法 |
CN104987688A (zh) * | 2015-06-08 | 2015-10-21 | 金发科技股份有限公司 | 一种聚碳酸酯组合物及其制备方法 |
CN104987688B (zh) * | 2015-06-08 | 2017-03-08 | 金发科技股份有限公司 | 一种聚碳酸酯组合物及其制备方法 |
CN106380711A (zh) * | 2016-08-26 | 2017-02-08 | 青岛海尔新材料研发有限公司 | 一种玻纤增强阻燃聚苯乙烯树脂组合物及其制备方法 |
CN106380711B (zh) * | 2016-08-26 | 2019-03-26 | 青岛海尔新材料研发有限公司 | 一种玻纤增强阻燃聚苯乙烯树脂组合物及其制备方法 |
CN108623982A (zh) * | 2017-03-26 | 2018-10-09 | 合肥杰事杰新材料股份有限公司 | 一种高光泽阻燃智能坐便洁身器专用料及其制备方法 |
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