CN102218970B - Enamel decorative board for art paintings and processing method thereof - Google Patents
Enamel decorative board for art paintings and processing method thereof Download PDFInfo
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- CN102218970B CN102218970B CN 201110091112 CN201110091112A CN102218970B CN 102218970 B CN102218970 B CN 102218970B CN 201110091112 CN201110091112 CN 201110091112 CN 201110091112 A CN201110091112 A CN 201110091112A CN 102218970 B CN102218970 B CN 102218970B
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- enamel
- pressed steel
- enamelled pressed
- decorative board
- adhesive sticker
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- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 57
- 238000010422 painting Methods 0.000 title claims abstract description 22
- 238000003672 processing method Methods 0.000 title claims abstract description 10
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 61
- 239000010959 steel Substances 0.000 claims abstract description 61
- 239000000463 material Substances 0.000 claims abstract description 20
- 239000000853 adhesive Substances 0.000 claims description 51
- 230000001070 adhesive effect Effects 0.000 claims description 51
- 239000004698 Polyethylene Substances 0.000 claims description 24
- -1 polyethylene Polymers 0.000 claims description 21
- 229920000573 polyethylene Polymers 0.000 claims description 21
- 239000013032 Hydrocarbon resin Substances 0.000 claims description 14
- 229920006270 hydrocarbon resin Polymers 0.000 claims description 14
- 239000007921 spray Substances 0.000 claims description 11
- 239000002313 adhesive film Substances 0.000 claims description 10
- 238000005507 spraying Methods 0.000 claims description 10
- 238000001354 calcination Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000009877 rendering Methods 0.000 claims description 5
- 230000000007 visual effect Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 description 12
- 238000002203 pretreatment Methods 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 230000006978 adaptation Effects 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 239000002585 base Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 206010027146 Melanoderma Diseases 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000005238 degreasing Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000840 Capped steel Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000009503 electrostatic coating Methods 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000013000 roll bending Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention relates to an enamel decorative material, in particular to an enamel decorative board which is widely applied to the ground, walls, ceilings and the like of bathrooms and a method for processing the enamel decorative board for art paintings. The invention provides the enamel decorative board for the art paintings and the improvement of the processing method thereof. The obtained decorative board is three-dimensional in appearance and intense in texture, has the embossed visual effect, and has the characteristics of high quality of products and low cost of the products. In the technical scheme, the enamel decorative board for the art paintings comprises an enamel steel plate, and is characterized in that a layer of colored enamel glaze slip is sprayed on the outer surface of the enamel steel plate uniformly by a template on which decorative patterns are hollowed.
Description
Technical field
The present invention relates to a kind of enamel decorative material, be specially a kind of bathroom floor that is widely used in, wall, the enamel decorative board for art paintings on the ground such as ceiling.
The invention still further relates to a kind of processing method of processing this enamel decorative board for art paintings.
Background technology
At present, the metope of building adopts glass plate or aluminum plate etc. to decorate mostly, the outer surface ubiquity of these materials easily scratches, the problem such as easy cleaning not, and exposing to the sun and rain easily makes the organic pigment generation chemical change in above-mentioned material and cause dim the fading in surface.Enamel decoration board has good wearability and corrosion resistance because of it, and outer surface is easy to clean, long service life and being widely used.
Enamel decoration board is to form at the matrix surface that is made of steel, cast iron, aluminium, copper material and stainless steel and other metal materials the product that glass quality enamel layer forms, that is: the metal-made matrix is configured as the regulation shape after, by impose glaze (frit) on its surface, then at high temperature burn till and make.The enamel decoration board surface is easily except degreasing, difficult generation defective, and heat resistance, acid resistance and alkaline resistance properties are good, thereby at the kitchen goods, has purposes widely in the interior and exterior finishes material of tableware, sanitary vessels and building etc.
Usually, carry out enamel and add man-hour on the steel plate that is shaped, generally carry out twice glazing, namely on the basis of pre-treatment (degreasing, pickling, plating Ni, Co etc.), form ground glaze layer in glazing after, then form cover coat.In recent years, due to the progress of steel plate, glazing technology, omit glazing technology of what is called of ground glaze layer also just practical.In pre-treatment, need the operating cost of cost of equipment, liquid, energy etc., and the equipment of liquid waste processing, disposal cost increases, there is the problem that is difficult to realize cost degradation.
Only carry out that pre-treatment is replaced in degreasing and with the technology of glaze electrostatic coating also just practical, but in order to ensure adaptation, only have to form and contain twice glazing that Ni, Co, Mo etc. have the ground glaze layer of the element that improves the adaptation effect and be practical.
As the technology of omitting pre-treatment, make like that oxide film thereon be formed on technology on steel plate just like Japanese Patent Publication 36-19385 communique, Japanese kokai publication sho 63-195284 communique.But the adaptation of steel plate and enamel layer is insufficient, can not satisfy gasproof bubble and blackspot, the quick-fried property of anti-squama.Therefore in addition, the enamel glazing when Japanese Patent Publication 36-19385 communique is applicable to there is no continuous casting is relatively easy to capped steel, in the situation that 100% be almost the steel of making by continuous casting at present, the enamel glazing is difficult, thereby can't be suitable for.After this, invented as Japanese kokai publication sho 63-293173 communique and flooded in Ni liquid after forming oxide film thereon on steel plate, and the improving technology that applies antirust oil as Japanese kokai publication hei 1-316470 communique, but can not satisfy sufficient adaptation, gasproof bubble and blackspot, the quick-fried property of anti-squama.In addition, as described in Japanese kokai publication sho 63-18086 communique, following technology is disclosed: given play to adjusting roughness take aim at decide effect in, by at coating antirust oil and the decomposition gas of the oil when glaze is burnt till make the glaze floating, thereby realize applying equably the effect of glaze.But, still be difficult to guarantee the stable adaptation identical with the situation of carrying out pre-treatment, gasproof bubble and blackspot, the quick-fried property of anti-squama.
And, disclose as Japanese kokai publication sho 53-108023 communique to omit pre-treatment as the technology of purpose, this pre-treatment refers to deoil by steel plate is removed in the lower heating of lower temperature (450 ℃-580 ℃), and the glaze agent that the oxide by manganese, molybdenum, cobalt, nickel etc. the is formed processing of adhering to.This technology in order to ensure adaptation to implement bead as prerequisite.But it is must have the technology of twice glazing of ground glaze layer as " the glaze agent that the oxide by manganese, molybdenum, cobalt, nickel etc. is formed is adhered to ", can't realize having omitted a glazing of pre-treatment.
Summary of the invention
Technical problem to be solved by this invention is the deficiency that overcomes the above-mentioned background technology, the improvement of a kind of enamel decorative board for art paintings and processing method thereof is provided, the decorative panel that obtains should have stereoscopic texture strong, have embossment visual effect, good product quality, characteristics that product cost is lower.
Technical scheme provided by the invention is: a kind of enamel decorative board for art paintings, comprise enamelled pressed steel, and it is characterized in that: the outer surface of described enamelled pressed steel evenly sprays the colored Enamel Slip of one deck by the dapple template of hollow out.
Described openworking template is the adhesive sticker that sticks on the enamelled pressed steel outer surface, and the thickness of described adhesive sticker is 0.3～0.5 millimeter, and on it, hollow out has decorative pattern.
Described adhesive sticker be the polyethylene film that positive and negative two faces scribble polyethylene hydrocarbon resin bonding material, the thickness of adhesive film is 0.15～0.30 millimeter, polyethylene hydrocarbon resin bonding material accounts for more than 60% of whole adhesive film thickness.
The processing method of described enamel decorative board for art paintings is carried out according to following steps.
1), dapple adhesive sticker is carved in preparation.
A, first make by computer graphics the pattern contour that needs spraying.
B, the pattern of rendering computer is printed on the adhesive sticker Sticky Note.
C, with the pattern part that needs on adhesive sticker to show, carve profile.
2), with dapple adhesive sticker at the above-mentioned quarter for preparing, entirely stick on enamelled pressed steel.
3), the pattern contour on adhesive sticker is plucked out after, spray equably the colored Enamel Slip of one deck at the outer surface of enamelled pressed steel.
4), with the above-mentioned enamelled pressed steel that is coated with colored Enamel Slip, be placed at 100～120 ℃ of temperature, dried 0.8～1 hour.
5), the oven dry after, tear all adhesive stickers of enamelled pressed steel outer surface off; And the assorted powdered frit of enamelled pressed steel outer surface remnants is cleaned out.
6), fire finished product: the enamelled pressed steel after clearing up is again put into calcining kiln, at 800～850 ℃ of temperature, fires 4～6min.
The colored Enamel Slip layer of the outer surface spraying of described enamelled pressed steel, thickness is 0.5～1mm.
Quarter in the present invention dapple adhesive sticker, polyethylene hydrocarbon resin bonding material on its adhesive surface can repeatedly melt and moulding, absorbing heat and melting when rising to certain temperature with aluminum deck and with the hot compound tense of PE (polyethylene) central layer, polyethylene hydrocarbon resin bonding material after thawing is coated in the aluminum deck surface equably, the gummed power that it is superpower and cohesive force make product compound firmly, have guaranteed the stable of product quality.Because composited aluminum and plastic decking bonding is that oxide-film by polar substances-aluminium and aluminum metal surface interacts, form ionic bond between metal surface and polymer interface; PE is bonding with apolar substance, contain the polyethylene of shuttle base stage group grafting and contain shuttle base ethylene copolymer, act on the metal surface, bonding by the chemical reaction generation of Suo Ji and metal surface, be proven the bonding combination property of this kind material and metal adhesive and PE better.Have higher temperature during this kind polyethylene hydrocarbon resin co-extrusion, guaranteed the requirement of compound tense high temperature; Coating is even when bonding, bonding strength is high and the characteristics of constant product quality thereby make.
Enamel decorative board for art paintings provided by the present invention, the decorative pattern of its panel surface are after plucking out by the pattern contour on adhesive sticker, spray equably the colored Enamel Slip of one deck at the outer surface of enamelled pressed steel and obtain.
Product provided by the invention has lightly, flatness is good, good product quality (good, shock-resistant, the surperficial anti-pollution burn into acid resistance of bending strength, alkali resistance, oil resistivity, solvent resistance, scrubbing property 〉=10000 time), panel surface have ridge design, stereoscopic texture is strong, have the embossment visual effect, product specification is high, product cost is also lower, and good processability, can can be processed into various special-shaped facades and geometry by modes such as cutting, fluting, roll bending, connections, be used widely on building and engineering at home.
The specific embodiment
Embodiment 1.
A kind of enamel decorative board for art paintings comprises enamelled pressed steel, and the outer surface of described enamelled pressed steel evenly sprays the colored Enamel Slip of one deck by the dapple template of hollow out.
Described openworking template is the adhesive sticker that sticks on the enamelled pressed steel outer surface, and the thickness of described adhesive sticker is 0.3 millimeter, and on it, hollow out has decorative pattern.
Described adhesive sticker be the polyethylene film that positive and negative two faces scribble polyethylene hydrocarbon resin bonding material, the thickness of adhesive film is 0.15 millimeter, polyethylene hydrocarbon resin bonding material accounts for 60% of whole adhesive film thickness.
The processing method of described enamel decorative board for art paintings is carried out according to following steps.
1), dapple adhesive sticker is carved in preparation.
A, first make by computer graphics the pattern contour that needs spraying.
B, the pattern of rendering computer is printed on the adhesive sticker Sticky Note.
C, with the pattern part that needs on adhesive sticker to show, carve profile.
2), with dapple adhesive sticker at the above-mentioned quarter for preparing, entirely stick on enamelled pressed steel.
3), the pattern contour on adhesive sticker is plucked out after, spray equably the colored Enamel Slip of one deck at the outer surface of enamelled pressed steel.
4), with the above-mentioned enamelled pressed steel that is coated with colored Enamel Slip, be placed at 100 ℃ of temperature, dried 0.8 hour.
5), the oven dry after, tear all adhesive stickers of enamelled pressed steel outer surface off; And the assorted powdered frit of enamelled pressed steel outer surface remnants is cleaned out.
6), fire finished product: the enamelled pressed steel after clearing up is again put into calcining kiln, at 800 ℃ of temperature, fires 6min.
The colored Enamel Slip layer of the outer surface spraying of described enamelled pressed steel, thickness is 0.5～1mm.
It is satisfactory for result that institute obtains product.
Embodiment 2.
A kind of enamel decorative board for art paintings comprises enamelled pressed steel, it is characterized in that: the outer surface of described enamelled pressed steel evenly sprays the colored Enamel Slip of one deck by the dapple template of hollow out.
Described openworking template is the adhesive sticker that sticks on the enamelled pressed steel outer surface, and the thickness of described adhesive sticker is 0.5 millimeter, and on it, hollow out has decorative pattern.
Described adhesive sticker be the polyethylene film that positive and negative two faces scribble polyethylene hydrocarbon resin bonding material, the thickness of adhesive film is 0.30 millimeter, polyethylene hydrocarbon resin bonding material accounts for 70% of whole adhesive film thickness.
The processing method of described enamel decorative board for art paintings is carried out according to following steps.
1), dapple adhesive sticker is carved in preparation.
A, first make by computer graphics the pattern contour that needs spraying.
B, the pattern of rendering computer is printed on the adhesive sticker Sticky Note.
C, with the pattern part that needs on adhesive sticker to show, carve profile.
2), with dapple adhesive sticker at the above-mentioned quarter for preparing, entirely stick on enamelled pressed steel.
3), the pattern contour on adhesive sticker is plucked out after, spray equably the colored Enamel Slip of one deck at the outer surface of enamelled pressed steel.
4), with the above-mentioned enamelled pressed steel that is coated with colored Enamel Slip, be placed at 120 ℃ of temperature, dried 1 hour.
5), the oven dry after, tear all adhesive stickers of enamelled pressed steel outer surface off; And the assorted powdered frit of enamelled pressed steel outer surface remnants is cleaned out.
6), fire finished product: the enamelled pressed steel after clearing up is again put into calcining kiln, at 850 ℃ of temperature, fires 4min.
The colored Enamel Slip layer of the outer surface spraying of described enamelled pressed steel, thickness is 0.5～1mm.
It is satisfactory for result that institute obtains product.
Embodiment 3.
A kind of enamel decorative board for art paintings comprises enamelled pressed steel, it is characterized in that: the outer surface of described enamelled pressed steel evenly sprays the colored Enamel Slip of one deck by the dapple template of hollow out.
Described openworking template is the adhesive sticker that sticks on the enamelled pressed steel outer surface, and the thickness of described adhesive sticker is 0.4 millimeter, and on it, hollow out has decorative pattern.
Described adhesive sticker be the polyethylene film that positive and negative two faces scribble polyethylene hydrocarbon resin bonding material, the thickness of adhesive film is 0.2 millimeter, polyethylene hydrocarbon resin bonding material accounts for 65% of whole adhesive film thickness.
The processing method of described enamel decorative board for art paintings is carried out according to following steps.
1), dapple adhesive sticker is carved in preparation.
A, first make by computer graphics the pattern contour that needs spraying.
B, the pattern of rendering computer is printed on the adhesive sticker Sticky Note.
C, with the pattern part that needs on adhesive sticker to show, carve profile.
2), with dapple adhesive sticker at the above-mentioned quarter for preparing, entirely stick on enamelled pressed steel.
3), the pattern contour on adhesive sticker is plucked out after, spray equably the colored Enamel Slip of one deck at the outer surface of enamelled pressed steel.
4), with the above-mentioned enamelled pressed steel that is coated with colored Enamel Slip, be placed at 110 ℃ of temperature, dried 0.9 hour.
5), the oven dry after, tear all adhesive stickers of enamelled pressed steel outer surface off; And the assorted powdered frit of enamelled pressed steel outer surface remnants is cleaned out.
6), fire finished product: the enamelled pressed steel after clearing up is again put into calcining kiln, at 830 ℃ of temperature, fires 5min.
The colored Enamel Slip layer of the outer surface spraying of described enamelled pressed steel, thickness is 0.5～1mm.
It is satisfactory for result that institute obtains product.
In the raw material of the polyethylene hydrocarbon resin bonding material of above each embodiment, the addition of curing agent (CT12), water base adhesive (BM3358), water base adhesive (BM3558) and hydroxyethylcellulose is the amount doesn't matter, also can only add a wherein part, even all do not add, depending on use habit and concrete condition.
Whole process equipments that the present invention adopts are all kinds of plant equipment of existing typing.All kinds of raw material (comprising industrial chemicals) that adopt all buyable obtain.
Claims (4)
1. enamel decorative board for art paintings, comprise enamelled pressed steel, it is characterized in that: the outer surface of described enamelled pressed steel evenly sprays the colored Enamel Slip of one deck by the dapple template of hollow out, the processing method of described enamel decorative board for art paintings, carry out according to following steps:
1) dapple adhesive sticker is carved in preparation;
A, first make by computer graphics the pattern contour that needs spraying;
B, the pattern of rendering computer is printed on the adhesive sticker Sticky Note;
C, with the pattern part that needs on adhesive sticker to show, carve profile;
2), with dapple adhesive sticker at the above-mentioned quarter for preparing, entirely stick on enamelled pressed steel;
3), the pattern contour on adhesive sticker is plucked out after, spray equably the colored Enamel Slip of one deck at the outer surface of enamelled pressed steel;
4), with the above-mentioned enamelled pressed steel that is coated with colored Enamel Slip, be placed at 100～120 ℃ of temperature, dried 0.8～1 hour;
5), the oven dry after, tear all adhesive stickers of enamelled pressed steel outer surface off; And the assorted powdered frit of enamelled pressed steel outer surface remnants is cleaned out;
6), fire finished product: the enamelled pressed steel after clearing up is again put into calcining kiln, at 800～850 ℃ of temperature, fires 4～6min.
2. enamel decorative board for art paintings according to claim 1, is characterized in that, described openworking template is the adhesive sticker that sticks on the enamelled pressed steel outer surface, and the thickness of described adhesive sticker is 0.3～0.5 millimeter, and on it, hollow out has decorative pattern.
3. enamel decorative board for art paintings according to claim 1 and 2, it is characterized in that: described adhesive sticker be the polyethylene film that positive and negative two faces scribble polyethylene hydrocarbon resin bonding material, the thickness of adhesive film is 0.15～0.30 millimeter, and polyethylene hydrocarbon resin bonding material accounts for more than 60% of whole adhesive film thickness.
4. enamel decorative board for art paintings according to claim 1 is characterized in that: the colored Enamel Slip layer of the outer surface spraying of described enamelled pressed steel, thickness is 0.5～1mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110091112 CN102218970B (en) | 2011-04-12 | 2011-04-12 | Enamel decorative board for art paintings and processing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110091112 CN102218970B (en) | 2011-04-12 | 2011-04-12 | Enamel decorative board for art paintings and processing method thereof |
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| Publication Number | Publication Date |
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| CN102218970A CN102218970A (en) | 2011-10-19 |
| CN102218970B true CN102218970B (en) | 2013-05-08 |
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| CN103407317B (en) * | 2013-07-26 | 2018-02-23 | 陈权胜 | Ceramic tile colored carving spray-drawing process and its product |
| CN112681652A (en) * | 2020-12-24 | 2021-04-20 | 宝丰大博瓷画文化创意有限公司 | Manufacturing method and application of eye-protecting ultrathin diamond-jade television background wall |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0660421B2 (en) * | 1987-02-10 | 1994-08-10 | 新日本製鐵株式会社 | Coated steel plate for enamel |
| CN2516364Y (en) * | 2001-12-14 | 2002-10-16 | 张艳玲 | Decorative board with enamal surface |
| CN1539656A (en) * | 2003-04-24 | 2004-10-27 | 商艳艳 | Rubbing material and rubbing method |
| CN1814460A (en) * | 2005-01-31 | 2006-08-09 | 张煌平 | Sand blast flower graving process and device |
| CN1799873B (en) * | 2006-01-10 | 2011-05-04 | 张维 | Process for preparing metallic enamel embossment |
| CN201084054Y (en) * | 2007-07-19 | 2008-07-09 | 和成欣业股份有限公司 | Notebook computer outer housing possessing porcelain enamel metallic structure |
| CN100540289C (en) * | 2007-08-15 | 2009-09-16 | 吕世敏 | Tubulose enamelled iron skill assembly and preparation method thereof |
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Denomination of invention: The invention relates to an enamel art painting decorative board and a processing method thereof Effective date of registration: 20220111 Granted publication date: 20130508 Pledgee: China Co. truction Bank Corp Jinhua branch Pledgor: ZHEJIANG KAIER NEW MATERIALS Co.,Ltd. Registration number: Y2022980000304 |
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