CN102199883A - Mordant-free dyeing method of monascorubin on protein fibers - Google Patents
Mordant-free dyeing method of monascorubin on protein fibers Download PDFInfo
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- CN102199883A CN102199883A CN 201110085198 CN201110085198A CN102199883A CN 102199883 A CN102199883 A CN 102199883A CN 201110085198 CN201110085198 CN 201110085198 CN 201110085198 A CN201110085198 A CN 201110085198A CN 102199883 A CN102199883 A CN 102199883A
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- China
- Prior art keywords
- dyeing
- monascus
- rubin
- sodium alginate
- monascorubin
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- 239000000835 fiber Substances 0.000 title claims abstract description 43
- 238000004043 dyeing Methods 0.000 title claims abstract description 37
- 102000004169 proteins and genes Human genes 0.000 title claims abstract description 31
- 108090000623 proteins and genes Proteins 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 20
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 29
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 29
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 29
- 239000000661 sodium alginate Substances 0.000 claims abstract description 29
- 239000000975 dye Substances 0.000 claims abstract description 11
- 241000228347 Monascus <ascomycete fungus> Species 0.000 claims abstract 14
- 239000000344 soap Substances 0.000 claims description 3
- 239000001044 red dye Substances 0.000 claims 2
- 239000001054 red pigment Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 229930182559 Natural dye Natural products 0.000 abstract description 8
- 239000000978 natural dye Substances 0.000 abstract description 8
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 5
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 4
- 238000005411 Van der Waals force Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- -1 carboxylic acid ion Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 240000002853 Nelumbo nucifera Species 0.000 description 2
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 2
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- AEMOLEFTQBMNLQ-SYJWYVCOSA-N (2s,3s,4s,5s,6r)-3,4,5,6-tetrahydroxyoxane-2-carboxylic acid Chemical group O[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@@H]1O AEMOLEFTQBMNLQ-SYJWYVCOSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000031003 Monascus ruber Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000001093 anti-cancer Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000576 food coloring agent Substances 0.000 description 1
- 235000002864 food coloring agent Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
本发明公开了一种红曲红素在蛋白质纤维上的无媒染色方法，其特征在于：利用海藻酸钠替代传统的化学媒染剂，提高红曲红素在蛋白质纤维上的上染率、固色率和色牢度，实现红曲红素天然染料无媒染色。本发明将环境友好的海藻酸钠用于红曲红素天然染料染色，克服了传统化学媒染剂染色的重金属离子污染问题，提供了一种既符合环保要求、又有较高得色率和色牢度的蛋白质纤维红曲红素染色工艺。The invention discloses a mordant-free dyeing method of monascus rubin on protein fibers, which is characterized in that sodium alginate is used to replace traditional chemical mordants to improve the dyeing rate and fixation rate of monascus rubin on protein fibers. The color rate and color fastness are improved, and the natural dye of monascus rubin can be dyed without a mordant. The invention uses environmentally friendly sodium alginate for the dyeing of natural monascus rubin dyes, overcomes the heavy metal ion pollution problem of traditional chemical mordant dyeing, and provides a method that not only meets environmental protection requirements, but also has high color yield and color. Fastness of protein fiber monascus rubin dyeing process.
Description
Technical field:
The invention belongs to the light industry field, relate to the no mordant dyeing color method of a kind of monascorubin on protein fibre, specifically a kind of in the presence of sodium alginate, adopt monascorubin protein fibre not to be had the method for mordant dyeing look.
Background technology:
Monascorubin is a kind of natural colouring matter that utilizes the monascus ruber fermented and cultured to make, have abundant raw material, production process non-environmental-pollution, look valency height, good stability, safe, advantage such as tinctorial property is good, also have reducing blood lipid, anti-oxidant, suppress sudden change and effect such as anticancer, be widely used in food color.At present, red colouring agent for food, also used as a Chinese medicine manufacturing enterprise only limits to the exploitation of curable product and food coloring, because the variation of consumption structure, benefit is generally depressed.The present invention inquires into monascorubin is used for fabrics printing and dyeing processing, is intended to enlarge the monascorubin Application Areas, improves economic benefit of enterprises.
The natural dye exploitation is renewable because of its raw material, helps protecting national resource and ecological environment, is particularly suitable for developing the high added value ecological textile.Yet most of natural dye is poor to fiber affinity, need add mordant during dyeing.The mordant that natural dye dying is used is chemical reagent mostly, normally divalence or trivalent metal, and as sulfate, acetate or the oxide of aluminium, iron, copper, tin, chromium, these heavy metal ion major parts are harmful to human body and environment, are unfavorable for ecology and environmental protection.
Therefore, develop a kind of natural dye that does not need to add mordant protein fibre dyeed, be a kind of brand-new field and technology.
Summary of the invention:
The objective of the invention is to improve at the dyeing of traditional employing chemistry mordant, improve the no mordant dyeing color method of a kind of monascorubin on protein fibre, use this method and can improve dye-uptake, degree of fixation and the COLOR FASTNESS of monascorubin on protein fibre, realize the no mordant dyeing look of monascorubin on protein fibre.
The technical scheme that the present invention takes is as follows, and the no mordant dyeing color method of a kind of monascorubin on protein fibre is characterized in that: add sodium alginate in the monascorubin dye liquor, protein fibre is dyeed, the sodium alginate consumption is 1～4g/L.
Further, the present invention includes following steps:
1, dyeing: in the monascorubin dye liquor, add sodium alginate, protein fibre is dyeed, the monascorubin consumption is 1-5%o.w.f., the sodium alginate consumption is 1～4g/L; bath raio 1:20-1:40, dye bath pH=3-6, and 30 ℃ are dyed; 1-2 ℃/min is warming up to dyeing temperature 70-90 ℃, insulation 60min;
2, post processing: after dyeing is finished, with 0.5-2g/L standard soap flakes the protein fibre after dyeing is cleaned, bath raio is 1:30-1:50, adds protein fibre under the room temperature, is warming up to 60 ℃ of insulations and cleans 20min, cold wash then, oven dry.
Operation principle of the present invention and beneficial effect are as follows:
Operation principle: sodium alginate is a kind of hydrophily polysaccharide that proposes from the seaweed plant sea-tangle, and it has carboxyl, is the high polyuronide that the aldehyde radical of beta-D-mannuronic acid forms with glycosidic bond, and low-heat is nontoxic, and is easily expanded, suppleness is high.The present invention utilizes sodium alginate to have the carboxylic acid ion of cloudy lotus property, can have an effect to increase with the amino isopolarity group on the protein fibre on the one hand and dye seat, also can form hydrogen bond and Van der Waals force on the other hand with groups such as the hydroxyl of monascorubin, carbonyls, improve the affinity of fiber to monascorubin, pigment molecular and fiber molecule can be combined better, thereby improve Dry Sack rate and the COLOR FASTNESS of monascorubin on protein fibre.
Beneficial effect: the present invention is used for the monascorubin natural dye dying with eco-friendly sodium alginate, a kind of not only compliance with environmental protection requirements is provided, but also higher Dry Sack rate and COLOR FASTNESS, simple protein fibre monascorubin natural dye dying technology has been arranged, overcome the heavy-metal pollution problem of traditional chemical mordant dyeing, had very significant effect aspect the dyeing quality and the feature of environmental protection.
The invention will be further described below in conjunction with the specific embodiment.
The specific embodiment:
Embodiment 1: monascorubin was to the no mordant dyeing look of cocoon fiber under sodium alginate existed.
At monascorubin consumption 3%o.w.f., pH=4, bath raio is 1:30, the sodium alginate consumption is respectively 0,1, and 2,3, under the condition of 4g/L, cocoon fiber is dyeed, after dyeing is finished, with 0.5-2g/L standard soap flakes the protein fibre after dyeing is cleaned, bath raio is 1:30-1:50, add protein fibre under the room temperature, be warming up to 60 ℃ of insulations and clean 20min, cold wash then, oven dry.
Measure dye uptake and the K/S value of embodiment 1, statistics is as shown in table 1.
As can be seen from Table 1, can significantly improve dye uptake and K/S value after adding people's sodium alginate in the dye bath.Sodium alginate be carboxylic acid sodium salt (contain-COONa), can be water-soluble, and the carboxylic acid ion (COO-) with cloudy lotus property, can form hydrogen bond with monascorubin and fiber and Van der Waals force combines, improve the affinity of fiber to monascorubin, make between pigment molecular and the fiber molecule and can combine better, thus the dyeability of raising monascorubin.
。
Embodiment 2: monascorubin was to the no mordant dyeing look of wool fibre under sodium alginate existed.
Process is with embodiment 1, and difference is monascorubin consumption 3%o.w.f., pH=4; bath raio is 1:30, and the sodium alginate consumption is respectively 0,2, under the condition of 4g/L, according to process curve wool fibre is dyeed; measure dye uptake and K/S value, the result is as shown in table 2.
Table 2, sodium alginate consumption are to the influence of monascorubin dyeability on wool.
。
Embodiment 3: the dyefastness contrast.
Technical process is distinguished at sodium alginate consumption 4g/L with embodiment 1, monascorubin consumption 2%owf, and pH=4, bath raio is under the condition of 1:30, according to process curve cocoon fiber is dyeed, and measures soaping fastness and light fastness.
The foregoing description and the dyefastness that does not add the sodium alginate sample are compared, the results are shown in Table 3.
As can be seen from Table 3, add sodium alginate in the monascorubin dyeing course, the stained specimens soaping fastness can be improved about 1 grade, light fastness improves about 1.5 grades.Sodium alginate can form hydrogen bond with monascorubin, fiber molecule and Van der Waals force combines, thereby COLOR FASTNESS is improved.
。
In conjunction with the foregoing description as can be seen, adopt sodium alginate to substitute traditional chemical mordant, can effectively improve dye-uptake, degree of fixation and the COLOR FASTNESS of monascorubin on protein fibre, realize that the monascorubin natural dye does not have the mordant dyeing look.Overcome the heavy-metal pollution problem of traditional chemical mordant dyeing simultaneously, compliance with environmental protection requirements.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100851984A CN102199883B (en) | 2011-04-06 | 2011-04-06 | Mordant-free dyeing method of monascorubin on protein fibers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100851984A CN102199883B (en) | 2011-04-06 | 2011-04-06 | Mordant-free dyeing method of monascorubin on protein fibers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102199883A true CN102199883A (en) | 2011-09-28 |
| CN102199883B CN102199883B (en) | 2012-06-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011100851984A Expired - Fee Related CN102199883B (en) | 2011-04-06 | 2011-04-06 | Mordant-free dyeing method of monascorubin on protein fibers |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102199883B (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101368341A (en) * | 2008-09-28 | 2009-02-18 | 殷大卫 | Natural vegetable dye textile dyeing and printing technique |
-
2011
- 2011-04-06 CN CN2011100851984A patent/CN102199883B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101368341A (en) * | 2008-09-28 | 2009-02-18 | 殷大卫 | Natural vegetable dye textile dyeing and printing technique |
Non-Patent Citations (2)
| Title |
|---|
| 《印染助剂》 20001020 程万里 红曲米对真丝绸染色性能的研究 第17卷, 第05期 * |
| 《染整技术》 20010622 于伯龄等 10种天然染料染羊毛与丝绸的试验 第23卷, 第03期 * |
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| Publication number | Publication date |
|---|---|
| CN102199883B (en) | 2012-06-27 |
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