CN102199305A - 防静电性硬质涂层塑料薄膜的制造方法 - Google Patents
防静电性硬质涂层塑料薄膜的制造方法 Download PDFInfo
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- CN102199305A CN102199305A CN 201110068503 CN201110068503A CN102199305A CN 102199305 A CN102199305 A CN 102199305A CN 201110068503 CN201110068503 CN 201110068503 CN 201110068503 A CN201110068503 A CN 201110068503A CN 102199305 A CN102199305 A CN 102199305A
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- Prior art keywords
- hard coating
- antistatic
- acrylate
- antistatic hard
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000576 coating method Methods 0.000 title claims abstract description 24
- 239000011248 coating agent Substances 0.000 title claims abstract description 23
- 239000002985 plastic film Substances 0.000 title claims abstract description 15
- 229920006255 plastic film Polymers 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims abstract description 13
- 239000003999 initiator Substances 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 6
- -1 acrylic ester Chemical class 0.000 claims description 29
- 239000004033 plastic Substances 0.000 claims description 18
- 229920003023 plastic Polymers 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 230000003068 static effect Effects 0.000 claims description 16
- 230000005611 electricity Effects 0.000 claims description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 8
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 4
- 239000012965 benzophenone Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 4
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 4
- 244000028419 Styrax benzoin Species 0.000 claims description 3
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 3
- 235000008411 Sumatra benzointree Nutrition 0.000 claims description 3
- 230000009471 action Effects 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 229960002130 benzoin Drugs 0.000 claims description 3
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 3
- 235000019382 gum benzoic Nutrition 0.000 claims description 3
- 229920001427 mPEG Polymers 0.000 claims description 3
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 claims description 3
- 125000003944 tolyl group Chemical group 0.000 claims description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 2
- 229920006289 polycarbonate film Polymers 0.000 claims description 2
- 239000004973 liquid crystal related substance Substances 0.000 abstract description 2
- 230000001678 irradiating effect Effects 0.000 abstract 1
- 239000010408 film Substances 0.000 description 31
- 239000000463 material Substances 0.000 description 19
- 230000000694 effects Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 2
- KEYRRLATNFZVGW-UHFFFAOYSA-N ethyl(trihydroxy)silane Chemical compound CC[Si](O)(O)O KEYRRLATNFZVGW-UHFFFAOYSA-N 0.000 description 2
- IOANYFLVSWZRND-UHFFFAOYSA-N hydroxy(tripropyl)silane Chemical compound CCC[Si](O)(CCC)CCC IOANYFLVSWZRND-UHFFFAOYSA-N 0.000 description 2
- MQNNNLJCDJBERF-UHFFFAOYSA-N hydroxy-tri(propan-2-yl)silane Chemical compound CC(C)[Si](O)(C(C)C)C(C)C MQNNNLJCDJBERF-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 231100000241 scar Toxicity 0.000 description 2
- AAPLIUHOKVUFCC-UHFFFAOYSA-N trimethylsilanol Chemical compound C[Si](C)(C)O AAPLIUHOKVUFCC-UHFFFAOYSA-N 0.000 description 2
- PJAKWOZHTFWTNF-UHFFFAOYSA-N (2-nonylphenyl) prop-2-enoate Chemical compound CCCCCCCCCC1=CC=CC=C1OC(=O)C=C PJAKWOZHTFWTNF-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- XDFYLDYPTBNHRY-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)C(C(=O)OCCCCCCCCCCCCCCCCCC)=C.C(C=C)(=O)O Chemical compound C(CCCCCCCCCCCCCCCCC)C(C(=O)OCCCCCCCCCCCCCCCCCC)=C.C(C=C)(=O)O XDFYLDYPTBNHRY-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- XPJRQAIZZQMSCM-UHFFFAOYSA-N heptaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCO XPJRQAIZZQMSCM-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000004441 surface measurement Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- WVMSIBFANXCZKT-UHFFFAOYSA-N triethyl(hydroxy)silane Chemical compound CC[Si](O)(CC)CC WVMSIBFANXCZKT-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
Description
实施例一 | 普通PET膜 | |
全线透光率 | 91.0% | 89.6% |
雾度 | 0.4% | 0.6% |
铅笔硬度 | 3H | HB |
耐刮擦性 | O | X |
表面阻抗值 | 3.0E+09Ω/sq | >1012 |
有机硅 | 多官能丙烯酸酯单体 | 引发剂 | 溶剂 | |
实施例二 | 3% | 35% | 0.2% | 61.8% |
实施例三 | 5% | 30% | 0.5% | 64.5% |
实施例四 | 2% | 43% | 0.7% | 54.3% |
实施例五 | 2.5% | 45% | 1% | 51.5% |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110068503 CN102199305B (zh) | 2011-03-22 | 2011-03-22 | 防静电性硬质涂层塑料薄膜的制造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN 201110068503 CN102199305B (zh) | 2011-03-22 | 2011-03-22 | 防静电性硬质涂层塑料薄膜的制造方法 |
Publications (2)
Publication Number | Publication Date |
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CN102199305A true CN102199305A (zh) | 2011-09-28 |
CN102199305B CN102199305B (zh) | 2013-03-20 |
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CN 201110068503 Active CN102199305B (zh) | 2011-03-22 | 2011-03-22 | 防静电性硬质涂层塑料薄膜的制造方法 |
Country Status (1)
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CN (1) | CN102199305B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016148825A (ja) * | 2015-02-09 | 2016-08-18 | 大日本印刷株式会社 | 光学フィルム、これを備えた偏光板、液晶パネル、画像表示装置 |
CN112876987A (zh) * | 2021-01-19 | 2021-06-01 | 首都师范大学 | 一种室温固化有机硅透明硬质涂料及其制备方法 |
CN112876890A (zh) * | 2021-01-19 | 2021-06-01 | 首都师范大学 | 一种抗静电有机硅透明硬质涂层材料及其制备方法 |
CN116239924A (zh) * | 2022-11-10 | 2023-06-09 | 浙江巨化技术中心有限公司 | 一种电子级防护剂 |
CN110922897B (zh) * | 2019-11-18 | 2024-03-08 | 宁波日晟新材料有限公司 | 一种用于硅化合物的低雾值无损伤抛光液及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1422307A (zh) * | 2000-04-10 | 2003-06-04 | 积水化学工业株式会社 | 抗静电硬涂层用组合物、抗静电硬涂层、其制造方法及抗静电硬涂层层压体膜 |
CN101029937A (zh) * | 2006-03-02 | 2007-09-05 | 富士胶片株式会社 | 光学膜、防反射膜、偏振板和图像显示装置 |
-
2011
- 2011-03-22 CN CN 201110068503 patent/CN102199305B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1422307A (zh) * | 2000-04-10 | 2003-06-04 | 积水化学工业株式会社 | 抗静电硬涂层用组合物、抗静电硬涂层、其制造方法及抗静电硬涂层层压体膜 |
CN101029937A (zh) * | 2006-03-02 | 2007-09-05 | 富士胶片株式会社 | 光学膜、防反射膜、偏振板和图像显示装置 |
Non-Patent Citations (1)
Title |
---|
《塑料包装》 20070415 陈昌杰 功能性薄膜之一-抗静电薄膜 第16页 1-4 第17卷, 第2期 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016148825A (ja) * | 2015-02-09 | 2016-08-18 | 大日本印刷株式会社 | 光学フィルム、これを備えた偏光板、液晶パネル、画像表示装置 |
CN110922897B (zh) * | 2019-11-18 | 2024-03-08 | 宁波日晟新材料有限公司 | 一种用于硅化合物的低雾值无损伤抛光液及其制备方法 |
CN112876987A (zh) * | 2021-01-19 | 2021-06-01 | 首都师范大学 | 一种室温固化有机硅透明硬质涂料及其制备方法 |
CN112876890A (zh) * | 2021-01-19 | 2021-06-01 | 首都师范大学 | 一种抗静电有机硅透明硬质涂层材料及其制备方法 |
CN116239924A (zh) * | 2022-11-10 | 2023-06-09 | 浙江巨化技术中心有限公司 | 一种电子级防护剂 |
CN116239924B (zh) * | 2022-11-10 | 2023-12-01 | 浙江巨化技术中心有限公司 | 一种电子级防护剂 |
Also Published As
Publication number | Publication date |
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CN102199305B (zh) | 2013-03-20 |
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Address after: 215400 Taicang Economic Development Zone, Jiangsu, Qingdao West Road, No. 11, No. Applicant after: Suzhou Sidike New Material Science & Technology Co., Ltd. Address before: 215400 Luoyang, Jiangsu, Taicang Banqiao Town, East Road, No. 221, No. Applicant before: Suzhou Sidike Stickiness Electron Stuff Co., Ltd. |
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Application publication date: 20110928 Assignee: Sidike New Materials (Jiangsu) Co.,Ltd. Assignor: Suzhou Sidike New Material Science & Technology Co., Ltd. Contract record no.: 2015320010031 Denomination of invention: Manufacturing process for antistatic hard coating plastic film Granted publication date: 20130320 License type: Exclusive License Record date: 20150408 |
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Address after: 223900 Sihong Province Economic Development Zone, Suqian, West Ocean West Road, No. 6 Patentee after: Jiangsu Stick new materials Polytron Technologies Inc Address before: 215400 Taicang Economic Development Zone, Jiangsu, Qingdao West Road, No. 11, No. Patentee before: Suzhou Sidike New Material Science & Technology Co., Ltd. |